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公开(公告)号：US07608666B2
公开(公告)日：2009-10-27
申请号：US10555208
申请日：2004-04-28
IPC分类号： C08L23/00
CPC分类号： C08L67/02 , C08L23/025 , C08L23/0815 , C08L67/03 , C08L81/04 , C08L101/06 , C08L2666/02
摘要： This invention is a polyester resin composition comprising 100 parts by weight of a resin composition consisting of 60 to 95 wt % of (a) a polyester resin and 5 to 40 wt % of (b) an olefin-based resin, and 0.5 to 30 parts by weight of (c) one or more resins selected from polyphenylene sulfide resins and liquid crystal resins, wherein said olefin-based resin (b) is composed of (b-1) a functional group-containing olefin copolymer having at least one kind of functional groups selected from carboxylic acid groups, carboxylic anhydride groups, carboxylic ester groups, metal carboxylate groups and epoxy groups and (b-2) an ethylene/α-olefin copolymer obtained by copolymerizing ethylene and an a-olefin with 3 to 20 carbon atoms; and the polyester resin (a) forms a continuous phase, while the olefin-based resin (b) is dispersed as particles with an average particle size of 0.01 to 2 μm in the composition. This invention provides a polyester resin composition having excellent flexibility and impact resistance in a low-temperature atmosphere, also having excellent flowability and chemicals resistance, and suitable for injection molding.
摘要翻译： 本发明是一种聚酯树脂组合物，其包含100重量份由60至95重量％的（a）聚酯树脂和5至40重量％的（b）烯烃类树脂组成的树脂组合物和0.5至30重量份 （c）选自聚苯硫醚树脂和液晶树脂中的一种或多种树脂，其中所述烯烃类树脂（b）由（b-1）含有至少一种的含官能团的烯烃共聚物组成 选自羧酸基团，羧酸酐基团，羧酸酯基团，金属羧酸酯基团和环氧基团的官能团和（b-2）通过使乙烯和α-烯烃与3-20碳共聚而获得的乙烯/α-烯烃共聚物 原子 并且聚酯树脂（a）形成连续相，而烯烃类树脂（b）在组合物中作为平均粒径为0.01〜2μm的颗粒分散。 本发明提供一种在低温气氛中具有优异的柔韧性和耐冲击性的聚酯树脂组合物，其流动性和耐化学性优异，适用于注射成型。
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公开(公告)号：US20060178481A1
公开(公告)日：2006-08-10
申请号：US10555208
申请日：2004-04-28
CPC分类号： C08L67/02 , C08L23/025 , C08L23/0815 , C08L67/03 , C08L81/04 , C08L101/06 , C08L2666/02
摘要： This invention is a polyester resin composition comprising 100 parts by weight of a resin composition consisting of 60 to 95 wt % of (a) a polyester resin and 5 to 40 wt % of (b) an olefin-based resin, and 0.5 to 30 parts by weight of (c) one or more resins selected from polyphenylene sulfide resins and liquid crystal resins, wherein said olefin-based resin (b) is composed of (b-1) a functional group-containing olefin copolymer having at least one kind of functional groups selected from carboxylic acid groups, carboxylic anhydride groups, carboxylic ester groups, metal carboxylate groups and epoxy groups and (b-2) an ethylene/a-olefin copolymer obtained by copolymerizing ethylene and an a-olefin with 3 to 20 carbon atoms; and the polyester resin (a) forms a continuous phase, while the olefin-based resin (b) is dispersed as particles with an average particle size of 0.01 to 2 μm in the composition. This invention provides a polyester resin composition having excellent flexibility and impact resistance in a low-temperature atmosphere, also having excellent flowability and chemicals resistance, and suitable for injection molding.
摘要翻译： 本发明是一种聚酯树脂组合物，其包含100重量份由60至95重量％的（a）聚酯树脂和5至40重量％的（b）烯烃类树脂组成的树脂组合物和0.5至30重量份 （c）选自聚苯硫醚树脂和液晶树脂中的一种或多种树脂，其中所述烯烃类树脂（b）由（b-1）含有至少一种的含官能团的烯烃共聚物组成 选自羧酸基团，羧酸酐基团，羧酸酯基团，金属羧酸酯基团和环氧基团的官能团和（b-2）通过使乙烯和α-烯烃与3-20碳共聚而获得的乙烯/α-烯烃共聚物 原子 并且聚酯树脂（a）形成连续相，而烯烃类树脂（b）在组合物中作为平均粒径为0.01〜2μm的颗粒分散。 本发明提供一种在低温气氛中具有优异的柔韧性和耐冲击性的聚酯树脂组合物，其流动性和耐化学性优异，适用于注射成型。
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3.发明授权Dendritic polymer, method for producing the same, and thermoplastic resin composition 有权树枝状聚合物，其制造方法和热塑性树脂组合物公开(公告)号：US08097685B2
公开(公告)日：2012-01-17
申请号：US12225811
申请日：2007-03-30
申请人： Koji Tachikawa , Makito Yokoe , Mitsushige Hamaguchi , Makiko Saito , Hideo Matsuoka , Toru Yamanaka
发明人： Koji Tachikawa , Makito Yokoe , Mitsushige Hamaguchi , Makiko Saito , Hideo Matsuoka , Toru Yamanaka
IPC分类号： C08G63/00
CPC分类号： C08G63/605 , C08G63/914 , C08G83/005 , C08L63/00 , C08L67/00 , C08L77/00 , C08L101/005 , C08L2205/02 , C08L2666/18 , C08L2666/02
摘要： The present invention is directed to a hyperbranched-polyester comprising at least one kind of a structural unit selected from an aromatic oxycarbonyl unit (P), aromatic and/or aliphatic dioxy units (Q), and an aromatic dicarboxy unit (R), and a trifunctional or higher polyfunctional organic residue (B), wherein the content of B is within a range from 7.5 to 50 mol % based on entire monomers constituting the hyperbranched-polyester. The present invention provides a hyperbranched-polyester which can remarkably improve thin-wall flowability, stiffness and gas barrier property by blending with a thermoplastic resin, and a thermoplastic resin composition blended with the same.
摘要翻译： 本发明涉及包含选自芳族氧羰基单元（P），芳族和/或脂族二氧单元（Q）和芳族二羧单元（R）中的至少一种结构单元的超支化聚酯，以及 三官能以上的多官能性有机残基（B），其中B的含量相对于构成超支化聚酯的全部单体为7.5〜50摩尔％。 本发明提供一种超支化聚酯，其可以通过与热塑性树脂共混和与其共混的热塑性树脂组合物显着提高薄壁流动性，刚度和阻气性。
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公开(公告)号：US06830792B1
公开(公告)日：2004-12-14
申请号：US10089842
申请日：2002-04-04
IPC分类号： B32B102
CPC分类号： B32B27/08 , B32B27/32 , B32B2307/7242 , B32B2307/7265 , B32B2323/04 , B32B2323/10 , B32B2355/02 , B32B2369/00 , B32B2377/00 , B32B2439/00 , B32B2439/70 , B32B2439/80 , B32B2597/00 , C08L23/02 , C08L81/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31917 , C08L81/00 , C08L2666/04
摘要： Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyolefin resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronic microscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyolefin resin (a) forms a disperse phase. The thermoplastic resin structure gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.
摘要翻译： 本发明提供一种由树脂组合物形成的热塑性树脂组合物，其基本上包含（a）5-80体积％的聚烯烃树脂和（b）20〜95体积％的聚苯硫醚树脂，其特征在于， 在通过电子显微镜观察的形态中，聚苯硫醚树脂（b）形成基质相（连续相），聚烯烃树脂（a）形成分散相。 热塑性树脂结构使塑料容器，管及其附着部件具有良好的阻隔性，强度，耐久性和可加工性。
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公开(公告)号：US06730378B2
公开(公告)日：2004-05-04
申请号：US10099387
申请日：2002-03-15
IPC分类号： B29D2200
CPC分类号： C08L23/06 , C08L23/02 , C08L51/06 , C08L67/00 , C08L77/00 , C08L101/00 , C08L2205/08 , Y10S525/933 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , C08L2666/20 , C08L2666/24 , C08L2666/06
摘要： In the resin-molded articles comprising polyolefin resins (a) and thermoplastic resins other than the polyolefin resins (b), when thickness is defined as one along a direction vertical to the surface of the article, as morphology observed under an electron microscope in the article, a portion where the polyolefin resin (a) forms a continuous phase (A), a portion where the resin other than the polyolefin resin (b) forms the continuous phase and the polyolefin resin (a) forms a discontinuous phase (B), and a portion where the polyolefin resin (a) forms the continuous phase (A) are successively observed in order from the surface toward the inside along the thickness direction, such molded articles having nature such as toughness and fabrication quality inherent to the polyolefin resins and improved appreciably in resistance to permeation of liquid chemicals and gases.
摘要翻译： 在包含聚烯烃树脂（a）和除了聚烯烃树脂（b）以外的热塑性树脂的树脂模制品中，当沿着垂直于制品表面的方向将厚度定义为一个时，作为在电子显微镜中观察到的形态 制品，其中聚烯烃树脂（a）形成连续相（A）的部分，除聚烯烃树脂（b）以外的树脂形成连续相的部分和聚烯烃树脂（a）形成不连续相（B） ，并且从表面朝向厚度方向的内侧依次观察聚烯烃类树脂（a）形成连续相（A）的部分，这样的成型品具有如聚烯烃树脂固有的韧性和制造质量等性质 并在液体化学品和气体的耐渗透性方面得到明显改善。
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6.发明申请Dendritic Polymer, Method for Producing the Same, and Thermoplastic Resin Composition 有权树枝状聚合物，其制造方法和热塑性树脂组合物公开(公告)号：US20090118417A1
公开(公告)日：2009-05-07
申请号：US12225811
申请日：2007-03-30
申请人： Koji Tachikawa , Makito Yokoe , Mitsushige Hamaguchi , Makiko Saito , Hideo Matsuoka , Toru Yamanaka
发明人： Koji Tachikawa , Makito Yokoe , Mitsushige Hamaguchi , Makiko Saito , Hideo Matsuoka , Toru Yamanaka
CPC分类号： C08G63/605 , C08G63/914 , C08G83/005 , C08L63/00 , C08L67/00 , C08L77/00 , C08L101/005 , C08L2205/02 , C08L2666/18 , C08L2666/02
摘要： The present invention is directed to a hyperbranched-polyester comprising at least one kind of a structural unit selected from an aromatic oxycarbonyl unit (P), aromatic and/or aliphatic dioxy units (Q), and an aromatic dicarboxy unit (R), and a trifunctional or higher polyfunctional organic residue (B), wherein the content of B is within a range from 7.5 to 50 mol % based on entire monomers constituting the hyperbranched-polyester. The present invention provides a hyperbranched-polyester which can remarkably improve thin-wall flowability, stiffness and gas barrier property by blending with a thermoplastic resin, and a thermoplastic resin composition blended with the same.
摘要翻译： 本发明涉及包含选自芳族氧羰基单元（P），芳族和/或脂族二氧单元（Q）和芳族二羧单元（R）中的至少一种结构单元的超支化聚酯，以及 三官能以上的多官能性有机残基（B），其中B的含量相对于构成超支化聚酯的全部单体为7.5〜50摩尔％。 本发明提供一种超支化聚酯，其可以通过与热塑性树脂共混和与其共混的热塑性树脂组合物显着提高薄壁流动性，刚度和阻气性。
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公开(公告)号：US07303822B1
公开(公告)日：2007-12-04
申请号：US10089948
申请日：2000-09-29
IPC分类号： B32B27/34
CPC分类号： B32B27/08 , B29C47/0019 , B29C47/0021 , B29C47/0023 , B29C47/043 , B29C47/065 , B29C47/067 , B29C47/56 , B29C49/0005 , B29C49/04 , B29C49/22 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2323/043 , C08L77/00 , C08L77/02 , C08L77/06 , C08L81/02 , C08L2201/14 , Y10T428/31533 , Y10T428/31725 , C08L81/00
摘要： Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyamide resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronic microscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyamide resin (a) forms a disperse phase. The gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.
摘要翻译： 提供一种由树脂组合物形成的热塑性树脂结构体，其基本上包含（a）5-80体积％的聚酰胺树脂和（b）20至95体积％的聚苯硫醚树脂，其特征在于 在通过电子显微镜观察的形态中，聚苯硫醚树脂（b）形成基质相（连续相），聚酰胺树脂（a）形成分散相。 给塑料容器，管及其附件具有良好的阻隔性，强度，耐久性和可加工性。
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公开(公告)号：US20050181158A1
公开(公告)日：2005-08-18
申请号：US11080757
申请日：2005-03-15
CPC分类号： B32B27/08 , B32B27/32 , B32B2307/7242 , B32B2307/7265 , B32B2323/04 , B32B2323/10 , B32B2355/02 , B32B2369/00 , B32B2377/00 , B32B2439/00 , B32B2439/70 , B32B2439/80 , B32B2597/00 , C08L23/02 , C08L81/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31917 , C08L81/00 , C08L2666/04
摘要： Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyolefin resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronicmicroscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyolefin resin (a) forms a disperse phase. The thermoplastic resin structure gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.
摘要翻译： 本发明提供一种由树脂组合物形成的热塑性树脂组合物，其基本上包含（a）5-80体积％的聚烯烃树脂和（b）20〜95体积％的聚苯硫醚树脂，其特征在于， 在通过电子显微镜观察的形态中，聚苯硫醚树脂（b）形成基质相（连续相），聚烯烃树脂（a）形成分散相。 热塑性树脂结构使塑料容器，管及其附着部件具有良好的阻隔性，强度，耐久性和可加工性。
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公开(公告)号：US07115312B2
公开(公告)日：2006-10-03
申请号：US11080757
申请日：2005-03-15
CPC分类号： B32B27/08 , B32B27/32 , B32B2307/7242 , B32B2307/7265 , B32B2323/04 , B32B2323/10 , B32B2355/02 , B32B2369/00 , B32B2377/00 , B32B2439/00 , B32B2439/70 , B32B2439/80 , B32B2597/00 , C08L23/02 , C08L81/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31917 , C08L81/00 , C08L2666/04
摘要： Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyolefin resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronicmicroscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyolefin resin (a) forms a disperse phase. The thermoplastic resin structure gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.
摘要翻译： 本发明提供一种由树脂组合物形成的热塑性树脂组合物，其基本上包含（a）5-80体积％的聚烯烃树脂和（b）20〜95体积％的聚苯硫醚树脂，其特征在于， 在通过电子显微镜观察的形态中，聚苯硫醚树脂（b）形成基质相（连续相），聚烯烃树脂（a）形成分散相。 热塑性树脂结构使塑料容器，管及其附着部件具有良好的阻隔性，强度，耐久性和可加工性。
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公开(公告)号：US06900272B2
公开(公告)日：2005-05-31
申请号：US10715286
申请日：2003-11-17
CPC分类号： B32B27/08 , B32B27/32 , B32B2307/7242 , B32B2307/7265 , B32B2323/04 , B32B2323/10 , B32B2355/02 , B32B2369/00 , B32B2377/00 , B32B2439/00 , B32B2439/70 , B32B2439/80 , B32B2597/00 , C08L23/02 , C08L81/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31917 , C08L81/00 , C08L2666/04
摘要： Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyolefin resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronicmicroscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyolefin resin (a) forms a disperse phase. The thermoplastic resin structure gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.
摘要翻译： 本发明提供一种由树脂组合物形成的热塑性树脂组合物，其基本上包含（a）5-80体积％的聚烯烃树脂和（b）20〜95体积％的聚苯硫醚树脂，其特征在于， 在通过电子显微镜观察的形态中，聚苯硫醚树脂（b）形成基质相（连续相），聚烯烃树脂（a）形成分散相。 热塑性树脂结构使塑料容器，管及其附着部件具有良好的阻隔性，强度，耐久性和可加工性。
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