公开(公告)号：US10072144B2

公开(公告)日：2018-09-11

申请号：US15117362

申请日：2015-02-09

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran

IPC: C08L25/06 ,  C08L25/14 ,  C08L51/04 ,  C08L67/04

Abstract: Polymer blends comprising (A) at least one polystyrene (co)polymer other than styrene methyl methacrylate copolymer (SMMA), (B) at least one poly(lactic acid) (PLA) and (C) at least one styrene methyl methacrylate copolymer (SMMA) have advantageous properties.

公开(公告)号：US09873784B2

公开(公告)日：2018-01-23

申请号：US15035859

申请日：2014-11-10

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran

IPC: C08L53/02 ,  C08L25/14 ,  B65D81/34

CPC classification number: C08L25/14 ,  B65D81/3461 ,  C08L53/02 ,  C08L2201/08 ,  C08L2203/12 ,  C08L2205/03 ,  C08L2205/035 ,  C08L71/12 ,  C08L25/06

Abstract: The invention is directed to polymer compositions comprising components (a), (b), (c) and (d): (a) 80 to 97% by weight of component (a) comprising a copolymer (a1) of styrene (a11) and methyl methacrylate (a12), wherein the amount present of (a11) is from 70 to 90% by weight and the amount present of (a12) is from 10 to 30% by weight, based in each case on (a1), (b) 3 to 20% by weight of polyphenylene ether as component (b); (c) 0 to 2% by weight of polystyrene as component (c); (d) 0 to 17%, in particular 0 to 15% by weight of conventional additives as component (d), having improved heat resistance, surface hardness, depth of color and gloss.

公开(公告)号：US11999686B2

公开(公告)日：2024-06-04

申请号：US17419063

申请日：2020-01-07

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert Niessner ,  Bianca Wilhelmus ,  Hannes Kerschbaumer ,  Michiel Verswyvel ,  Petra Inghelbrecht ,  Thomas W. Cochran ,  KyungHo Shon ,  Mohammed Abboud ,  Ricardo Cuetos ,  Hans-Dieter Schwaben ,  Jens Kathmann ,  Thad Urquhart ,  Timothy A. Brown ,  Tim Wong ,  Walter De Vet ,  Hans-Werner Schmidt ,  Andreas Schedl ,  Tristan Kolb

IPC: C07C4/22 ,  B01D3/14 ,  B01D3/42 ,  C07C7/04 ,  C08J11/12 ,  C10B53/07

CPC classification number: C07C4/22 ,  B01D3/143 ,  B01D3/4227 ,  C07C7/04 ,  C08J11/12 ,  C10B53/07 ,  C08J2325/06

Abstract: The invention relates to an improved process for providing purified styrenic monomers, such as styrene, from styrene-containing polymer waste. Styrene-containing waste is depolymerized in a suitable reactor, and the depolymerization products are condensed and separated in a three-step distillation process.

公开(公告)号：US11220598B2

公开(公告)日：2022-01-11

申请号：US16461974

申请日：2017-11-15

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran

IPC: C08L53/02 ,  C08F297/04 ,  C08G83/00 ,  C08L25/14

Abstract: Polymer composition comprising (a) 33 to 52 wt.-% star-shaped block copolymers (a) comprising terminal vinylaromatic polymer blocks S1 and S2, and random styrene/butadiene copolymer blocks (B/S); and (b) 48 to 67 wt.-% SMMA copolymers (b). Moldings and shaped articles produced thereof have a high clarity and toughness and can be used in the household, appliance and healthcare sector.

公开(公告)号：US10150830B2

公开(公告)日：2018-12-11

申请号：US15117364

申请日：2015-02-09

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran ,  Norbert Niessner

IPC: C08F220/14 ,  C08F212/08 ,  C08L25/06 ,  C08L33/12 ,  C09D125/14

Abstract: A copolymer comprising (A) 20-50% (w/w) of methyl methacrylate (MMA), (B) 40-80% (w/w) of one or more vinylaromatic(s) and, optionally, (C) 0-10% (w/w) of one or more aliphatic vinyl(s) can be used in a polymer composition for generating translucent final products.

公开(公告)号：US10550260B2

公开(公告)日：2020-02-04

申请号：US15558293

申请日：2016-03-17

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran ,  John A. Morris

IPC: C08L51/04 ,  F25D23/06

Abstract: Polymer blends comprising components A), B) and C): A) 80 to 96% by weight of an impact modified styrenic polymer A), B) 1 to 7% by weight of a polymer blend B) comprising B1) 25 to 75% by weight of polyisobutylene and B2) 25 to 75% by weight of a polyolefin, C) 3 to 13% by weight of an elastomeric block copolymer C) of structure (A-(B/A))n-A, where A is a vinylaromatic block, (B/A) is a random copolymer block of vinylaromatic monomer and diene, and n is 1 to 10, exhibit improved environmental stress crack resistance properties in presence of hydrofluoro olefins.

公开(公告)号：US09850377B2

公开(公告)日：2017-12-26

申请号：US15035692

申请日：2014-11-11

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran ,  Michael Hamilton

IPC: C08L67/00 ,  C08L67/04 ,  C08F297/04

CPC classification number: C08L67/04 ,  C08F297/046 ,  C08L53/02

Abstract: The present invention relates to a polymer blend comprising 75-99.5% (w/w) of at least one polylactic acid) (PLA) and 0.5-25% (w/w) of at least one styrene butadiene copolymer containing at least 50% (w/w) styrene. The present invention further relates to the use of such polymer blend for producing products and to the resulting products. Moreover, an object of the present invention is the use of a styrene butadiene block copolymer having a dendrimer structure comprising 50-85% (w/w) styrene as an additive of polymer blends comprising at least 50% (w/w) of PLA and a method of producing the polymer blend according to the invention.

公开(公告)号：US09845374B2

公开(公告)日：2017-12-19

申请号：US14903505

申请日：2014-07-07

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert Niessner ,  Christof Mehler ,  Konrad Knoll ,  Thomas W. Cochran

IPC: C08L53/00 ,  C08F293/00 ,  C08F297/04 ,  C08L25/14

CPC classification number: C08F293/005 ,  C08F297/04 ,  C08L25/14 ,  C08L2201/08 ,  C08L2205/06 ,  C08L53/02

Abstract: The present invention relates to novel block copolymers comprising at least one mono vinyl aromatic monomer (also referred to as mono vinylarene) and at least one conjugated diene monomer, in particular to styrene butadiene block copolymers (SBC), with a defined block structure. The invention further relates to polymer blends which comprise at least one block copolymer and at least one mono vinylarene acrylate copolymer, in particular a styrene-methyl methacrylate copolymer. Related methods for preparation and articles prepared from the polymer blends are also provided.

公开(公告)号：US11352488B2

公开(公告)日：2022-06-07

申请号：US17046437

申请日：2019-04-12

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert Niessner ,  Gisbert Michels ,  Thomas W. Cochran ,  Shridhar Madhav ,  Kirit Gevaria ,  Mukesh Modi

IPC: C08L25/12 ,  C08L53/02

Abstract: Thermoplastic molding composition comprising (A) 40 to 80 wt.-% SAN copolymer (S/AN-ratio 78:22 to 65:35, Mw 80,000 to 250,000 g/mol); (B) 20 to 60 wt.-% SBC block copolymer (monovinylarene 61 to 64 wt.-%) comprising conjugated diene/monovinylarene tapered polymer blocks; and (C) 0 to 5 wt.-% additives and/or processing aids (C); exhibiting ultra-high melt flow with good mechanical, thermal and optical properties, a process for its preparation and its use for the production of bulky and/or thin walled articles.

公开(公告)号：US11267962B2

公开(公告)日：2022-03-08

申请号：US16349433

申请日：2017-11-06

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Thomas W. Cochran

IPC: C08L25/06 ,  C08K5/098 ,  C08L9/06 ,  C08K5/09

Abstract: The invention is directed to a method for producing a thermoplastic molding composition comprising at least one styrene polymer and at least one lubricant, selected from fatty acids and fatty acids derivatives, wherein the method encompasses the preparation of a master batch polymer composition, comprising at least one styrene polymer having a melt flow rate (measured according to ASTMD1238, 200° C./5 kg) in the range of 2 to 10 g/10 min; and 10 to 40% by weight, based on the master batch polymer composition, of the lubricant. In particular the styrene polymer is selected from standard polystyrenes (general purpose polystyrene (GPPS)) and high impact polystyrenes(HIPS).