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5 条记录 (耗时 0.019 秒)

    Process for producing a synthesis gas from carbon dioxide
    3.
    发明授权
    Process for producing a synthesis gas from carbon dioxide 失效
    从二氧化碳生产合成气的方法

    公开(公告)号：US5855815A

    公开(公告)日：1999-01-05

    申请号：US601025

    申请日：1996-04-29

    申请人： Sang-Eon Park ,  Jong-San Chang ,  Kyu-Wan Lee

    发明人： Sang-Eon Park ,  Jong-San Chang ,  Kyu-Wan Lee

    IPC分类号： C10J1/00 ,  B01J23/78 ,  C01B3/40 ,  C07C1/02

    CPC分类号： B01J23/78 ,  C01B3/40 ,  C01B2203/1052 ,  Y02P20/52

    摘要： A process for producing a synthesis gas having carbon monoxide and hydrogen from the reduction of carbon dioxide with natural gas or lower hydrocarbons having methane as a main component and oxygen and steam over catalyst composed of nickel and, as promotors, alkali metal and alkaline earth metal component supported on silicon-containing support such as zeolite, silica, silicate and silica-alumina which are stable under reaction condition is disclosed. This process characterized in that the catalytic activity and performance property are improved by supporting alkali metal, alkaline earth metal and nickel oxide from metal salts having low melting point uniformly on silicon-containing support having high surface area by solid-state reaction. The amounts of adding alkali metal, alkaline earth metal and nickel are 0.01 to 10% by weight, 1 to 20% by weight and 1 to 20% by weight, respectively. The present invention is conducted in the temperature range from 600.degree. C. to 1000 .degree. C., and under a pressure of normal pressure to 20 atm, and gas hourly space velocity of 1,000 to 500,000/hour.

    摘要翻译： PCT No.PCT / KR94 / 00113 Sec。 371日期：1996年4月29日 102（e）日期1996年4月29日PCT 1994年8月23日PCT公布。 出版物WO95 / 06000 日期1995年3月2日由具有甲烷作为主要成分的天然气或低级烃的二氧化碳还原制备具有一氧化碳和氢气的合成气的方法，由镍构成的催化剂和作为促进剂的碱 公开了在反应条件下稳定的负载在含硅载体如沸石，二氧化硅，硅酸盐和二氧化硅 - 氧化铝上的金属和碱土金属组分。 该方法的特征在于，通过在具有高表面积的含硅载体上通过固相反应将碱金属，碱土金属和氧化镍从具有低熔点的金属盐均匀地支撑而提高了催化活性和性能。 添加碱金属，碱土金属和镍的量分别为0.01〜10重量％，1〜20重量％和1〜20重量％。 本发明在600〜1000℃的温度范围内，在常压至20大气压的压力下进行，气时空速为1000〜500,000 /小时。

    Catalyst and method for preparing mixture of cyclohexanol and cyclohexanone
    4.
    发明授权
    Catalyst and method for preparing mixture of cyclohexanol and cyclohexanone 失效
    用于制备环己醇和环己酮混合物的催化剂和方法

    公开(公告)号：US5208392A

    公开(公告)日：1993-05-04

    申请号：US874624

    申请日：1992-04-27

    申请人： Kyu-Wan Lee ,  Ki-Won Jun ,  Eun-Kyung Shim

    发明人： Kyu-Wan Lee ,  Ki-Won Jun ,  Eun-Kyung Shim

    IPC分类号： B01J23/89 ,  C07C29/50 ,  C07C45/33

    CPC分类号： C07C29/50 ,  B01J23/8906 ,  C07C45/33 ,  C07C2101/14

    摘要： The present invention provides a novel Fe-Pd catalyst prepared by impregnating, either together or respectively, an iron source compound and a palladium source compound onto a carrier selected from the group consisting of silica, alumina and silica-alumina, and drying and calcining said Fe-Pd impregnated carrier in a flow of air or H.sub.2 /N.sub.2 ; and a method for preparing a mixture of cyclohexanol and cyclohexanone by selectively oxidizing cyclohexane in a reaction medium provided with hydrogen and oxygen gases in the presence of said Fe-Pd catalyst.

    摘要翻译： 本发明提供一种通过将铁源化合物和钯源化合物一起或分别浸渍在选自二氧化硅，氧化铝和二氧化硅 - 氧化铝的载体上而制备的新型Fe-Pd催化剂，并干燥和煅烧所述 Fe-Pd浸渍载体在空气流中或H2 / N2; 以及通过在所述Fe-Pd催化剂存在下，在具有氢气和氧气的反应介质中选择性地氧化环己烷，制备环己醇和环己酮的混合物的方法。

    Process for preparing supported nickel catalyst for reforming hydrocarbons
    5.
    发明授权
    Process for preparing supported nickel catalyst for reforming hydrocarbons 失效
    制备用于重整碳氢化合物的负载型镍催化剂的方法

    公开(公告)号：US06242380B1

    公开(公告)日：2001-06-05

    申请号：US08978799

    申请日：1997-11-26

    申请人： Sang-Eon Park ,  Jong-San Chang ,  Kyu-Wan Lee

    发明人： Sang-Eon Park ,  Jong-San Chang ,  Kyu-Wan Lee

    IPC分类号： B01J2946

    CPC分类号： B01J37/0081 ,  B01J29/072 ,  B01J37/088 ,  C01B3/40 ,  C01B2203/1052 ,  Y02P20/52 ,  Y10S502/514

    摘要： A process for preparing supported nickel catalyst consisting of supporting nickel or metal salt of nickel, alkali metal, alkaline earth metal having low melting point on silicon and aluminum-containing support having high surface area such as zeolite, silica and alumina as an oxide by melting effectively nickel or metal salt of nickel, alkali metal and alkaline earth metal having low melting point is disclosed. This process is characterized in that the supported nickel catalyst prepared by the present invention can be used in reforming reaction of hydrocarbons by using carbon dioxide, steam and oxygen as an oxidant. Metal salts used in the preparation of supported nickel catalyst is generally nitrate, chloride, acetate and carbonate having low melting point of 500° C. or less. The contents of nickel, alkali metal and alkaline earth metal of the catalyst are 1 to 20% by weight, 10% by weight or less and 20% by weight or less, respectively. The calcination temperature of the catalyst is in a range of 300° C. to 1200° C.

    摘要翻译： 一种制备负载型镍催化剂的方法，该方法包括将镍或镍的金属盐，碱金属，在硅上具有低熔点的碱土金属和具有高表面积的含铝载体如沸石，二氧化硅和氧化铝作为氧化物，通过熔化 公开了具有低熔点的镍，碱金属和碱土金属的镍或金属盐。 该方法的特征在于，通过使用二氧化碳，蒸汽和氧气作为氧化剂，通过本发明制备的负载型镍催化剂可用于烃的重整反应。 用于制备负载型镍催化剂的金属盐通常是具有500℃或更低熔点的硝酸盐，氯化物，乙酸盐和碳酸盐。 催化剂的镍，碱金属和碱土金属的含量分别为1〜20重量％，10重量％以下且20重量％以下。 催化剂的煅烧温度在300℃〜1200℃的范围内。