公开(公告)号：US07297394B2

公开(公告)日：2007-11-20

申请号：US10087718

申请日：2002-03-01

申请人： Kishan Khemani ,  Harald Schmidt ,  Simon K. Hodson

发明人： Kishan Khemani ,  Harald Schmidt ,  Simon K. Hodson

IPC分类号： B32B27/00 ,  B32B33/00

CPC分类号： C08J5/18 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2403/02 ,  C08K5/0016 ,  C08L3/02 ,  C08L67/02 ,  C08L67/04 ,  C08L77/12 ,  Y10T428/231 ,  Y10T428/234 ,  Y10T428/24 ,  Y10T428/24058 ,  Y10T428/24124 ,  Y10T428/24273 ,  Y10T428/249953 ,  Y10T428/249955 ,  Y10T428/249978 ,  Y10T428/25 ,  Y10T428/254 ,  C08L2666/18 ,  C08L2666/02 ,  C08L2666/26 ,  C08L67/03 ,  C08L91/06

摘要： Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel. Wraps will typically be manufactured to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” form.

摘要翻译： 适用于层压涂层，包装和其他包装材料的生物可降解聚合物共混物由至少一种“硬”生物聚合物和至少一种“软”生物聚合物制成。 “硬”生物聚合物倾向于更脆和刚性，并且通常具有大于约10℃的玻璃化转变温度。“软”生物聚合物倾向于更柔软和柔韧，并且通常具有低于约0℃的玻璃化转变温度。 虽然硬和软聚合物各自具有某些固有的优点，但已经发现了硬和软聚合物的某些共混物，其本身具有优于硬聚合物或软聚合物的协同性质。 可生物降解的聚合物包括聚酯，聚酯酰胺，聚酯氨酯，热塑性淀粉和其他天然聚合物。 聚合物共混物可任选地包括无机填料。 由聚合物共混物制成的薄膜和薄片可以是纹理化的，以便增加手感。 通常将制造包装以具有良好的“折叠”性质，以便保持在包裹位置并且不弹回到“展开”形式。

公开(公告)号：US06573340B1

公开(公告)日：2003-06-03

申请号：US09648471

申请日：2000-08-23

申请人： Kishan Khemani ,  Per Just Andersen ,  Simon K. Hodson ,  Harald Schmidt

发明人： Kishan Khemani ,  Per Just Andersen ,  Simon K. Hodson ,  Harald Schmidt

IPC分类号： C08F2000

CPC分类号： C08L101/16 ,  B32B27/06 ,  C08J5/18 ,  C08J2300/16 ,  C08J2367/02 ,  C08K3/08 ,  C08L3/02 ,  C08L67/02 ,  C08L67/025 ,  C08L67/04 ,  C08L77/12 ,  Y10T428/31786 ,  C08L2666/02 ,  C08L67/00 ,  C08L2666/18 ,  C08L77/00 ,  C08L2666/14

摘要： Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials manufactured from at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides and thermoplastically processable starch. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel. Wraps will typically be manufactured so as to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” and planar form. Laminate films will typically have good water vapor barrier properties as measured by the their Water Vapor Permeability Coefficient (WVPC).

摘要翻译： 适用于由至少一种“硬”生物聚合物和至少一种“软”生物聚合物制造的层压涂料，包装和其它包装材料的可生物降解的聚合物共混物。 “硬”生物聚合物倾向于更脆和刚性，并且通常具有大于约10℃的玻璃化转变温度。“软”生物聚合物倾向于更柔软和柔韧，并且通常具有小于约0℃的玻璃化转变温度。 虽然硬和软聚合物各自具有某些固有的优点，但已经发现了硬和软聚合物的某些共混物，其本身具有优于硬聚合物或软聚合物的协同性质。 可生物降解的聚合物包括聚酯，聚酯酰胺和热塑性可加工淀粉。 聚合物共混物可任选地包括无机填料。 由聚合物共混物制成的薄膜和薄片可以是纹理化的，以便增加手感。 通常将制造包装以具有良好的“折叠”性质，以便保持在包裹位置，并且不弹回到“展开”和平面形式。 通过其水蒸汽渗透系数（WVPC）测量，层压膜通常具有良好的水蒸气阻隔性能。

公开(公告)号：US07241832B2

公开(公告)日：2007-07-10

申请号：US10087256

申请日：2002-03-01

申请人： Kishan Khemani ,  Harald Schmidt ,  Simon K. Hodson

发明人： Kishan Khemani ,  Harald Schmidt ,  Simon K. Hodson

IPC分类号： C08L99/00 ,  C08L5/00 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00

CPC分类号： C08L77/12 ,  C08L3/02 ,  C08L67/02 ,  C08L67/03 ,  C08L67/04 ,  Y10T428/1307 ,  Y10T428/1334 ,  Y10T428/1352 ,  C08L67/00 ,  C08L2666/02 ,  C08L91/06 ,  C08L2666/18

摘要： Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel. Wraps will typically be manufactured to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” form.

摘要翻译： 适用于层压涂层，包装和其他包装材料的生物可降解聚合物共混物由至少一种“硬”生物聚合物和至少一种“软”生物聚合物制成。 “硬”生物聚合物倾向于更脆和刚性，并且通常具有大于约10℃的玻璃化转变温度。“软”生物聚合物倾向于更柔软和柔韧，并且通常具有小于约0℃的玻璃化转变温度。 虽然硬和软聚合物各自具有某些固有的优点，但已经发现了硬和软聚合物的某些共混物，其本身具有优于硬聚合物或软聚合物的协同性质。 可生物降解的聚合物包括聚酯，聚酯酰胺，聚酯氨酯，热塑性淀粉和其他天然聚合物。 聚合物共混物可任选地包括无机填料。 由聚合物共混物制成的薄膜和薄片可以是纹理化的，以便增加手感。 通常将制造包装以具有良好的“折叠”性质，以便保持在包裹位置并且不弹回到“展开”形式。

公开(公告)号：US20050182196A1

公开(公告)日：2005-08-18

申请号：US11103999

申请日：2005-04-12

申请人： Kishan Khemani ,  Harald Schmidt ,  Simon Hodson

发明人： Kishan Khemani ,  Harald Schmidt ,  Simon Hodson

IPC分类号： C08L3/02 ,  C08L67/02 ,  C08L67/03 ,  C08L67/04 ,  C08L77/12 ,  C08F8/30

CPC分类号： C08L77/12 ,  C08L3/02 ,  C08L67/02 ,  C08L67/03 ,  C08L67/04 ,  Y10T428/1307 ,  Y10T428/1334 ,  Y10T428/1352 ,  C08L67/00 ,  C08L2666/02 ,  C08L91/06 ,  C08L2666/18

摘要： Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from a blend of suitable biodegradable polymers, such as at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel. Wraps will typically be manufactured to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” form.

摘要翻译： 适用于层压涂层，包装和其他包装材料的可生物降解聚合物共混物由合适的可生物降解的聚合物如至少一种“硬”生物聚合物和至少一种“软”生物聚合物的混合物制成。 “硬”生物聚合物倾向于更脆和刚性，并且通常具有大于约10℃的玻璃化转变温度。“软”生物聚合物倾向于更柔软和柔韧，并且通常具有小于约0℃的玻璃化转变温度。 虽然硬和软聚合物各自具有某些固有的优点，但已经发现了硬和软聚合物的某些共混物，其本身具有优于硬聚合物或软聚合物的协同性质。 可生物降解的聚合物包括聚酯，聚酯酰胺，聚酯氨酯，热塑性淀粉和其他天然聚合物。 聚合物共混物可任选地包括无机填料。 由聚合物共混物制成的薄膜和薄片可以是纹理化的，以便增加手感。 通常将制造包装以具有良好的“折叠”性质，以便保持在包裹位置并且不弹回到“展开”形式。

公开(公告)号：US07214414B2

公开(公告)日：2007-05-08

申请号：US11103999

申请日：2005-04-12

申请人： Kishan Khemani ,  Harald Schmidt ,  Simon Hodson

发明人： Kishan Khemani ,  Harald Schmidt ,  Simon Hodson

IPC分类号： C08B30/00 ,  C08L5/00 ,  C08L99/00

CPC分类号： C08L77/12 ,  C08L3/02 ,  C08L67/02 ,  C08L67/03 ,  C08L67/04 ,  Y10T428/1307 ,  Y10T428/1334 ,  Y10T428/1352 ,  C08L67/00 ,  C08L2666/02 ,  C08L91/06 ,  C08L2666/18

摘要： Biodegradable polymer blends suitable for laminate coatings, wraps and other packaging materials are manufactured from a blend of suitable biodegradable polymers, such as at least one “hard” biopolymer and at least one “soft” biopolymer. “Hard” biopolymers tend to be more brittle and rigid and typically have a glass transition temperature greater than about 10° C. “Soft” biopolymers tend to be more flexible and pliable and typically have a glass transition temperature less than about 0° C. While hard and soft polymers each possess certain intrinsic benefits, certain blends of hard and soft polymers have been discovered which possess synergistic properties superior to those of either hard or soft polymers by themselves. Biodegradable polymers include polyesters, polyesteramides, polyesterurethanes, thermoplastic starch, and other natural polymers. The polymer blends may optionally include an inorganic filler. Films and sheets made from the polymer blends may be textured so as to increase the bulk hand feel. Wraps will typically be manufactured to have good “dead-fold” properties so as to remain in a wrapped position and not spring back to an “unwrapped” form.

摘要翻译： 适用于层压涂层，包装和其他包装材料的可生物降解聚合物共混物由合适的可生物降解的聚合物如至少一种“硬”生物聚合物和至少一种“软”生物聚合物的混合物制成。 “硬”生物聚合物倾向于更脆和刚性，并且通常具有大于约10℃的玻璃化转变温度。“软”生物聚合物倾向于更柔软和柔韧，并且通常具有小于约0℃的玻璃化转变温度。 虽然硬和软聚合物各自具有某些固有的优点，但已经发现了硬和软聚合物的某些共混物，其本身具有优于硬聚合物或软聚合物的协同性质。 可生物降解的聚合物包括聚酯，聚酯酰胺，聚酯氨酯，热塑性淀粉和其他天然聚合物。 聚合物共混物可任选地包括无机填料。 由聚合物共混物制成的薄膜和薄片可以是纹理化的，以便增加手感。 通常将制造包装以具有良好的“折叠”性质，以便保持在包裹位置并且不弹回到“展开”形式。

公开(公告)号：US08658146B2

公开(公告)日：2014-02-25

申请号：US12679631

申请日：2008-09-24

申请人： Franck Furno ,  Laurent Wattebled ,  Anne Ix-Mund ,  Harald Schmidt ,  Markus Henn ,  Jorg Harren

发明人： Franck Furno ,  Laurent Wattebled ,  Anne Ix-Mund ,  Harald Schmidt ,  Markus Henn ,  Jorg Harren

IPC分类号： A61L101/34 ,  A61K31/78

CPC分类号： C08F220/06 ,  A61L15/46 ,  A61L15/60 ,  A61L2300/216 ,  A61L2300/30 ,  A61L2300/622 ,  C08F220/40 ,  C08J3/128 ,  C08J3/245 ,  C08J2300/14 ,  C08J2333/02

摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures, on the surface of which is at least one tannin fraction which has a number-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, which has a weight-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, or which is a hydrolysable gallotannin.The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, chemical products, such as, for example, hygiene articles, the use of a water-absorbing composition or of a composite and the use of a tannin fraction.

摘要翻译： 本发明涉及一种吸水组合物，其包含吸水聚合物结构，其表面至少是根据本文所述的测试方法确定的至少一种具有数均分子量的单宁部分，至少 1,000g / mol，其具有根据本文所述的测试方法测定的重均分子量为至少1,000g / mol，或其是可水解的鞣兰宁。 本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料，化学产品， 例如卫生制品，吸水组合物或复合材料的使用以及单宁部分的使用。

公开(公告)号：US20120277429A1

公开(公告)日：2012-11-01

申请号：US13511164

申请日：2010-11-17

申请人： René Dicke ,  Christoph Hahn ,  Martin Burger ,  Andreas Endesfelder ,  Katarina Rot ,  Clemens Schwarzinger ,  Klaus Bretterbauer ,  Heinrich Trischler ,  Harald Schmidt

发明人： René Dicke ,  Christoph Hahn ,  Martin Burger ,  Andreas Endesfelder ,  Katarina Rot ,  Clemens Schwarzinger ,  Klaus Bretterbauer ,  Heinrich Trischler ,  Harald Schmidt

IPC分类号： C07D251/70

CPC分类号： C07D251/64 ,  C07D251/70 ,  C08G12/32

摘要： The present invention relates to Melamine based Mannich compounds of the general formulae (1)-(12) and a process for synthesizing melamine based Mannich-products comprising the steps of a) reacting at least one substituted melamine with at least one aldehyde, in particular formaldehyde, under basic conditions to form at least one OH-containing compound, b) reacting the at least one OH-containing compound in the presence of a catalyst to form at least one mannich-base, c1) reacting the at least one mannich-base with at least one enol-forming carbonyl compound, or c2) reacting the at least one mannich-base with at least one aromatic compound, and d) working up the reaction mixture. The invention relates further to precondensates obtainable from these products.

摘要翻译： 本发明涉及通式（1） - （12）的三聚氰胺基曼尼希化合物和合成三聚氰胺的曼尼希产物的方法，包括以下步骤：a）使至少一种取代的三聚氰胺与至少一种醛反应，特别是 甲醛，在碱性条件下形成至少一种含OH化合物，b）在催化剂存在下使所述至少一种含OH化合物反应以形成至少一种甘露糖基，c1）使所述至少一种甘露醇 - 与至少一种烯醇形成羰基化合物反应，或c2）使至少一种甘露糖基与至少一种芳族化合物反应，和d）处理反应混合物。 本发明还涉及可从这些产品获得的预缩合物。

公开(公告)号：US08247499B2

公开(公告)日：2012-08-21

申请号：US11912219

申请日：2006-04-21

申请人： Mirko Walden ,  Franck Furno ,  Harald Schmidt

发明人： Mirko Walden ,  Franck Furno ,  Harald Schmidt

IPC分类号： C08F8/42 ,  C08J3/24

CPC分类号： C08F8/44 ,  A61L15/18 ,  A61L15/60 ,  B01J20/26 ,  B01J2220/68 ,  C08F220/06 ,  C08J3/24 ,  C08J7/12 ,  C08J2300/14 ,  C08L33/02 ,  C08F20/06

摘要： A water-absorbing polymer structure is disclosed, whose surface has been brought into contact with a combination of a metal salt and an oxide of a metal. The invention also relates to a process for treating the surface of water-absorbing polymer structures whereby the surface of water-absorbing polymer structures is brought into contact with a combination of a metal salt and an oxide of a metal at a temperature of from about 50 to about 300° C. The present invention further relates to the water-absorbing polymer structures obtainable by this process, a composite comprising a water-absorbing polymer structure and a substrate, chemical products such as foams and fibers comprising water-absorbing polymer structures or a composite, and the use of a combination of an oxide of a metal and of a metal salt for treatment of the surface of super-absorbing polymer structures.

摘要翻译： 公开了一种吸水聚合物结构，其表面已经与金属盐和金属的氧化物的组合接触。 本发明还涉及一种用于处理吸水聚合物结构表面的方法，其中吸水聚合物结构的表面与金属盐和金属氧化物的组合在约50℃的温度下接触 本发明还涉及通过该方法获得的吸水聚合物结构，包含吸水聚合物结构和基材的复合材料，诸如泡沫的化学产品和包含吸水聚合物结构的纤维 复合材料，以及使用金属和金属盐的氧化物的组合来处理超吸收聚合物结构的表面。

公开(公告)号：US08114953B2

公开(公告)日：2012-02-14

申请号：US12280246

申请日：2007-02-22

申请人： Helmut Puchinger ,  Andreas Endesfelder ,  Martin Burger ,  Clemens Schwarzinger ,  Manuela Leidl ,  Werner Huber ,  Harald Schmidt

发明人： Helmut Puchinger ,  Andreas Endesfelder ,  Martin Burger ,  Clemens Schwarzinger ,  Manuela Leidl ,  Werner Huber ,  Harald Schmidt

IPC分类号： C08G12/32 ,  C08G12/00

CPC分类号： C08G12/32

摘要： The invention relates to melamine-formaldehyde condensates with thermoplastic properties that can be produced from formaldehyde and melamine derivatives, wherein at least one of the melamine derivatives organic radicals R have been used to substitute at least four of the total of six hydrogen atoms of the three melamine amino groups, and wherein the organic radicals R are mutually identical or different. The invention also relates to a process for production of the melamine-formaldehyde condensates, use thereof, and an analytical method for determining the constitution of the melamine-formaldehyde condensates.

摘要翻译： 本发明涉及可由甲醛和三聚氰胺衍生物生产的具有热塑性质的三聚氰胺 - 甲醛缩合物，其中三聚氰胺衍生物有机基团R中的至少一个已被用于代替三个胺的总共六个氢原子中的至少四个 三聚氰胺氨基，其中有机基团R相互相同或不同。 本发明还涉及三聚氰胺 - 甲醛缩合物的生产方法及其用途，以及用于测定三聚氰胺 - 甲醛缩合物的组成的分析方法。

公开(公告)号：US20110251399A1

公开(公告)日：2011-10-13

申请号：US13140921

申请日：2010-01-25

申请人： Uwe Dingerdissen ,  Jan Pfeffer ,  Thomas Tacke ,  Thomas Haas ,  Harald Schmidt ,  Florian Klasovsky ,  Roger Sheldon ,  Michiel Janssen ,  Michael Volland ,  Michael Rimbach ,  Stefanie Rinker

发明人： Uwe Dingerdissen ,  Jan Pfeffer ,  Thomas Tacke ,  Thomas Haas ,  Harald Schmidt ,  Florian Klasovsky ,  Roger Sheldon ,  Michiel Janssen ,  Michael Volland ,  Michael Rimbach ,  Stefanie Rinker

IPC分类号： C07D401/04 ,  C07C45/78 ,  C07D307/68 ,  C07C45/82 ,  C07C45/38 ,  C07C45/61 ,  C07C45/81

CPC分类号： C07C45/38 ,  C07C45/39 ,  C07D213/48 ,  C07D307/48 ,  C07D493/04 ,  C07C47/02 ,  C07C49/433 ,  C07C49/403

摘要： The invention relates to a method for producing aldehydes and ketones from easily accessible primary and secondary alcohols by oxidation with atmospheric oxygen or pure oxygen using a catalyst system which consists of a derivative of a free nitroxyl radical.

摘要翻译： 本发明涉及一种通过使用由游离硝酰基的衍生物组成的催化剂体系，通过用大气氧或纯氧氧化从容易获得的伯醇和仲醇生产醛和酮的方法。