PRIMERLESS HARDCOAT COMPOSITION
    3.
    发明申请

    公开(公告)号:US20170369729A1

    公开(公告)日:2017-12-28

    申请号:US15532603

    申请日:2015-12-22

    Inventor: Wen P. Liao

    Abstract: A coating composition suitable for providing a hardcoat comprising a topcoat and an epoxy modified adhesion promoter. The epoxy modified adhesion promoter comprises, in one embodiment, a molecule with the formula (1): U-Q-R1—SiR2gR3(3-g)   (1) wherein Q is —CH2CH(OH)CH2—O— or —CH2CH(OH)CH2—NR4—; U is: —O—(C6HhR2(4-h)—CR5—C6HhR2(4-b)—O—H2CH(OH)CH2—O)i—C6HhR2(4-h)—CR5—C6HhR2(4-h)—O-J; where R2 is chosen from a C1-C10 alkyl or a substituted or unsubstituted phenyl group; R3 is chosen from an alkoxy, an acetoxy, or a ketoxime radical; R1 is a C1-C4 alkylene; g is 0-2; h is 0-4; R4 is hydrogen or —CH2CH(OH)CH2—U—; R5 is hydrogen or an alkyl; i is 0-100; and J is H, Q-R1SiR2hR3(3-h), or formula (2). The coating composition is suitable for application to a substrate without the use of a primer.

    ANTIFOULING SYSTEM COMPRISING SILICONE HYDROGEL
    5.
    发明申请
    ANTIFOULING SYSTEM COMPRISING SILICONE HYDROGEL 有权
    包含硅胶水泥的防爆系统

    公开(公告)号:US20150353741A1

    公开(公告)日:2015-12-10

    申请号:US14826731

    申请日:2015-08-14

    Inventor: Wen P. Liao

    Abstract: A multi-layer or single layer antifouling coating system. A multi-layer coating system comprises (a) a base coating for coating a substrate, and (b) an antifouling coating composition adapted to be disposed over the base coating, the antifouling coating composition comprising a hydroxyl terminated polydimethylsiloxane, a curable polyether-containing silane of the Formula (1): (R1O)a(R1)(3-a)Si—R2—(Si(R1)2O)p—Si(R1)2—R2—O—(CH2—CHR1—O)q—R1  (1) where a is 1-3; R1 is H or alkyl radical from C1-C10; R2 is alkylene from C2-C10; p is 1-100; and q is 1-50. The base coating composition can comprise an epoxy modified adhesion promoter. A single layer coating composition comprises a compound of Formula (4): (R1O)a(R1)3-a—Si-M-(Si(R1)2O)r—(Si(R1)(O1/2)(O))t—(Si(X)(O1/2)(O))v—Si(R1)2-M-Si(OR1)a(R1)3-a  (4) where R1 is H or an alkyl radical M is R2 or oxygen; r is 0-1000; t is 1 to 20; v is 0 to 20; X is —R2—(N(R1)1-b(Y)b—R2)c—N(R1)2-b(Y)b; b is 0-2; c is 0-5; Y is R1 or an organic radical with an epoxide at one terminal; and R2 is an alkylene from C2-C10, with the proviso that at least one Y is an organic radical with an epoxide at one terminal.The respective compositions are such that the antifouling coating composition sufficiently adheres to the base coating composition without the need for a tie coat layer.

    Abstract translation: 多层或单层防污涂层系统。 多层涂布系统包括(a)用于涂覆基材的基底涂层,和(b)适于设置在基底涂层上的防污涂料组合物,所述防污涂料组合物包含羟基封端的聚二甲基硅氧烷,可固化聚醚的 式(1)的硅烷:(R1O)a(R1)(3-a)Si-R2-(Si(R1)2O)p-Si(R1)2-R2-O-(CH2-CHR1-O) q-R1(1)其中a为1-3; R1是H或C1-C10的烷基; R2是C2-C10的亚烷基; p是1-100; q为1-50。 基础涂料组合物可以包含环氧改性的粘合促进剂。 单层涂料组合物包含式(4)化合物:(R1O)a(R1)3-a-Si-M-(Si(R1)2O)r-(Si(R1)(O1 / 2) )(t(Si)(X)(O1 / 2)(O))v-Si(R1)2-M-Si(OR1)a(R1)3-a(4)其中R1是H或烷基 M为R2或氧; r为0-1000; t为1〜20; v为0〜20; X是-R2-(N(R1)1-b(Y)b-R2)c-N(R1)2-b(Y)b; b为0-2; c为0-5; Y是R1或具有一个末端的环氧化物的有机基团; 并且R 2是来自C 2 -C 10的亚烷基,条件是至少一个Y是在一个末端具有环氧化物的有机基团。 相应的组合物使得防污涂料组合物充分粘附到基底涂料组合物上,而不需要粘结涂层。

    WATER SOLUBLE SILICONE MATERIAL
    6.
    发明申请
    WATER SOLUBLE SILICONE MATERIAL 审中-公开
    水溶性硅胶材料

    公开(公告)号:US20150368404A1

    公开(公告)日:2015-12-24

    申请号:US14765054

    申请日:2014-01-31

    Abstract: A water soluble silicone macromer comprising a siloxane backbone having grafted thereto a suitable number of hydrophilic groups to render the macromer water soluble, the macromer comprising a polymerizable functional group grafted to the siloxane backbone. In one aspect, the present invention provides a water soluble silicone macromer having a structure of Formula (1): where M is a hydrophilic group or segment; L is a hydrophilic or hydrophobic linkage; N is a hydrophilic or hydrophobic group or segment. Q is a polymerizable functional group; x is zero or an integer greater than zero; y is zero or an integer greater than zero; v is zero or an integer greater than zero; and z is greater than zero, with the proviso that both y and v are not zero.

    Abstract translation: 包含硅氧烷主链的水溶性硅氧烷大分子单体,其具有接枝到其上的合适数量的亲水基团以使大分子单体水溶性,大分子单体包含接枝到硅氧烷主链的可聚合官能团。 一方面,本发明提供具有式(1)结构的水溶性硅氧烷大分子单体:其中M是亲水基团或链段; L是亲水或疏水键; N是亲水或疏水基团或片段。 Q是可聚合官能团; x为零或大于零的整数; y为零或大于零的整数; v为零或大于零的整数; 并且z大于零,条件是y和v都不为零。

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