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公开(公告)号:US10118994B2
公开(公告)日:2018-11-06
申请号:US14765054
申请日:2014-01-31
Applicant: MOMENTIVE PERFORMANCE MATERIALS INC.
Inventor: Weihong Lang , Wen P. Liao , Susan Nye , Kenrick M. Lewis
IPC: G02B1/04 , C08G77/44 , C08G77/442 , C08G77/46 , A61F2/00 , C08F283/12 , C08F290/06 , A61L27/18 , A61L29/06 , C08L83/10 , A61F2/16 , A61B17/00
Abstract: A water soluble silicone macromer comprising a siloxane backbone having grafted thereto a suitable number of hydrophilic groups to render the macromer water soluble, the macromer comprising a polymerizable functional group grafted to the siloxane backbone. In one aspect, the present invention provides a water soluble silicone macromer having a structure of Formula (1): where M is a hydrophilic group or segment; L is a hydrophilic or hydrophobic linkage; N is a hydrophilic or hydrophobic group or segment. Q is a polymerizable functional group; x is zero or an integer greater than zero; y is zero or an integer greater than zero; v is zero or an integer greater than zero; and z is greater than zero, with the proviso that both y and v are not zero.
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公开(公告)号:US09988497B2
公开(公告)日:2018-06-05
申请号:US14826731
申请日:2015-08-14
Applicant: Momentive Performance Materials Inc.
Inventor: Wen P. Liao
IPC: C08G77/08 , C09D5/16 , C09D183/04 , C09D163/00 , C09D183/08 , C09D183/12 , C09D183/06 , C08G77/04 , C09J183/04 , C08G59/32 , C08G77/14 , C08G77/26 , C08G77/46 , C08K5/544
CPC classification number: C08G77/08 , C08G59/3281 , C08G77/04 , C08G77/14 , C08G77/26 , C08G77/46 , C08K5/544 , C09D5/1637 , C09D5/1693 , C09D163/00 , C09D183/04 , C09D183/06 , C09D183/08 , C09D183/12 , C09J183/04 , Y10T428/31511 , Y10T428/31663
Abstract: A multi-layer or single layer antifouling coating system. A multi-layer coating system comprises (a) a base coating for coating a substrate, and (b) an antifouling coating composition adapted to be disposed over the base coating, the antifouling coating composition comprising a hydroxyl terminated polydimethylsiloxane, a curable polyether-containing silane of the Formula (1): (R1O)a(R1)(3-a)Si—R2—(Si(R1)2O)p—Si(R1)2—R2—O—(CH2—CHR1—O)q—R1 (1) where a is 1-3; R1 is H or alkyl radical from C1-C10; R2 is alkylene from C2-C10; p is 1-100; and q is 1-50. The base coating composition can comprise an epoxy modified adhesion promoter. A single layer coating composition comprises a compound of Formula (4): (R1O)a(R1)3-a—Si-M-(Si(R1)2O)r—(Si(R1)(O1/2)(O))t—(Si(X)(O1/2)(O))v—Si(R1)2-M-Si(OR1)a(R1)3-a (4) where R1 is H or an alkyl radical M is R2 or oxygen; r is 0-1000; t is 1 to 20; v is 0 to 20; X is —R2—(N(R1)1-b(Y)b—R2)c—N(R1)2-b(Y)b; b is 0-2; c is 0-5; Y is R1 or an organic radical with an epoxide at one terminal; and R2 is an alkylene from C2-C10, with the proviso that at least one Y is an organic radical with an epoxide at one terminal. The respective compositions are such that the antifouling coating composition sufficiently adheres to the base coating composition without the need for a tie coat layer.
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公开(公告)号:US20170369729A1
公开(公告)日:2017-12-28
申请号:US15532603
申请日:2015-12-22
Applicant: Momentive Performance Materials Inc.
Inventor: Wen P. Liao
IPC: C09D133/08 , C09D5/00 , C09D7/12 , C08K5/5435
CPC classification number: C09G1/02 , B24B37/044 , C08K5/5435 , C08L63/00 , C09D5/00 , C09D7/63 , C09D7/65 , C09D133/08 , C09D183/04 , C09K3/1409 , H01L21/3212
Abstract: A coating composition suitable for providing a hardcoat comprising a topcoat and an epoxy modified adhesion promoter. The epoxy modified adhesion promoter comprises, in one embodiment, a molecule with the formula (1): U-Q-R1—SiR2gR3(3-g) (1) wherein Q is —CH2CH(OH)CH2—O— or —CH2CH(OH)CH2—NR4—; U is: —O—(C6HhR2(4-h)—CR5—C6HhR2(4-b)—O—H2CH(OH)CH2—O)i—C6HhR2(4-h)—CR5—C6HhR2(4-h)—O-J; where R2 is chosen from a C1-C10 alkyl or a substituted or unsubstituted phenyl group; R3 is chosen from an alkoxy, an acetoxy, or a ketoxime radical; R1 is a C1-C4 alkylene; g is 0-2; h is 0-4; R4 is hydrogen or —CH2CH(OH)CH2—U—; R5 is hydrogen or an alkyl; i is 0-100; and J is H, Q-R1SiR2hR3(3-h), or formula (2). The coating composition is suitable for application to a substrate without the use of a primer.
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公开(公告)号:US09822220B2
公开(公告)日:2017-11-21
申请号:US14768138
申请日:2013-12-13
Applicant: Momentive Performance Materials Inc.
Inventor: Wen P. Liao
IPC: C09D183/04 , C09D183/06 , C09D183/08 , C09D183/12 , C08G77/46 , C08G77/08 , C09D5/16 , C09D163/00 , C08G77/04 , C09J183/04 , C08G59/32 , C08G77/14 , C08G77/26 , C08K5/544
CPC classification number: C08G77/08 , C08G59/3281 , C08G77/04 , C08G77/14 , C08G77/26 , C08G77/46 , C08K5/544 , C09D5/1637 , C09D5/1693 , C09D163/00 , C09D183/04 , C09D183/06 , C09D183/08 , C09D183/12 , C09J183/04 , Y10T428/31511 , Y10T428/31663
Abstract: A multi-layer or single layer antifouling coating system. A multi-layer coating system comprises (a) a base coating for coating a substrate, and (b) an antifouling coating composition adapted to be disposed over the base coating, the antifouling coating composition comprising a functionalized polymer, and a curable polyether-containing silane of the Formula (1): (R1O)a(R1)(3-a)Si—R2—(Si(R1)2O)p—Si(R1)2—R2—O—(CH2—CHR1—O)q—R1 (1) where a is 1-3; R1 is H or alkyl radical from C1-C10; R2 is alkylene from C2-C10; p is 1-100; and q is 1-50. The base coating composition can comprise an epoxy modified adhesion promoter. Additionally, the anti-fouling coating composition can comprise an acetoxy, alkoxy, and/or ketoxime functional adhesion promoter.
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公开(公告)号:US20150353741A1
公开(公告)日:2015-12-10
申请号:US14826731
申请日:2015-08-14
Applicant: Momentive Performance Materials Inc.
Inventor: Wen P. Liao
IPC: C09D5/16 , C09D163/00 , C09D183/04
CPC classification number: C08G77/08 , C08G59/3281 , C08G77/04 , C08G77/14 , C08G77/26 , C08G77/46 , C08K5/544 , C09D5/1637 , C09D5/1693 , C09D163/00 , C09D183/04 , C09D183/06 , C09D183/08 , C09D183/12 , C09J183/04 , Y10T428/31511 , Y10T428/31663
Abstract: A multi-layer or single layer antifouling coating system. A multi-layer coating system comprises (a) a base coating for coating a substrate, and (b) an antifouling coating composition adapted to be disposed over the base coating, the antifouling coating composition comprising a hydroxyl terminated polydimethylsiloxane, a curable polyether-containing silane of the Formula (1): (R1O)a(R1)(3-a)Si—R2—(Si(R1)2O)p—Si(R1)2—R2—O—(CH2—CHR1—O)q—R1 (1) where a is 1-3; R1 is H or alkyl radical from C1-C10; R2 is alkylene from C2-C10; p is 1-100; and q is 1-50. The base coating composition can comprise an epoxy modified adhesion promoter. A single layer coating composition comprises a compound of Formula (4): (R1O)a(R1)3-a—Si-M-(Si(R1)2O)r—(Si(R1)(O1/2)(O))t—(Si(X)(O1/2)(O))v—Si(R1)2-M-Si(OR1)a(R1)3-a (4) where R1 is H or an alkyl radical M is R2 or oxygen; r is 0-1000; t is 1 to 20; v is 0 to 20; X is —R2—(N(R1)1-b(Y)b—R2)c—N(R1)2-b(Y)b; b is 0-2; c is 0-5; Y is R1 or an organic radical with an epoxide at one terminal; and R2 is an alkylene from C2-C10, with the proviso that at least one Y is an organic radical with an epoxide at one terminal.The respective compositions are such that the antifouling coating composition sufficiently adheres to the base coating composition without the need for a tie coat layer.
Abstract translation: 多层或单层防污涂层系统。 多层涂布系统包括(a)用于涂覆基材的基底涂层,和(b)适于设置在基底涂层上的防污涂料组合物,所述防污涂料组合物包含羟基封端的聚二甲基硅氧烷,可固化聚醚的 式(1)的硅烷:(R1O)a(R1)(3-a)Si-R2-(Si(R1)2O)p-Si(R1)2-R2-O-(CH2-CHR1-O) q-R1(1)其中a为1-3; R1是H或C1-C10的烷基; R2是C2-C10的亚烷基; p是1-100; q为1-50。 基础涂料组合物可以包含环氧改性的粘合促进剂。 单层涂料组合物包含式(4)化合物:(R1O)a(R1)3-a-Si-M-(Si(R1)2O)r-(Si(R1)(O1 / 2) )(t(Si)(X)(O1 / 2)(O))v-Si(R1)2-M-Si(OR1)a(R1)3-a(4)其中R1是H或烷基 M为R2或氧; r为0-1000; t为1〜20; v为0〜20; X是-R2-(N(R1)1-b(Y)b-R2)c-N(R1)2-b(Y)b; b为0-2; c为0-5; Y是R1或具有一个末端的环氧化物的有机基团; 并且R 2是来自C 2 -C 10的亚烷基,条件是至少一个Y是在一个末端具有环氧化物的有机基团。 相应的组合物使得防污涂料组合物充分粘附到基底涂料组合物上,而不需要粘结涂层。
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公开(公告)号:US20150368404A1
公开(公告)日:2015-12-24
申请号:US14765054
申请日:2014-01-31
Applicant: MOMENTIVE PERFORMANCE MATERIALS INC.
Inventor: Weihong Lang , Wen P. Liao , Susan Nye , Kenrick M. Lewis
CPC classification number: C08G77/44 , A61B2017/00942 , A61F2/14 , A61F2/16 , A61L27/18 , A61L29/06 , C08F283/12 , C08F290/068 , C08G77/46 , C08L83/10 , G02B1/043 , C08F230/08 , C08F220/54 , C08F226/10 , C08F220/20 , C08F220/56
Abstract: A water soluble silicone macromer comprising a siloxane backbone having grafted thereto a suitable number of hydrophilic groups to render the macromer water soluble, the macromer comprising a polymerizable functional group grafted to the siloxane backbone. In one aspect, the present invention provides a water soluble silicone macromer having a structure of Formula (1): where M is a hydrophilic group or segment; L is a hydrophilic or hydrophobic linkage; N is a hydrophilic or hydrophobic group or segment. Q is a polymerizable functional group; x is zero or an integer greater than zero; y is zero or an integer greater than zero; v is zero or an integer greater than zero; and z is greater than zero, with the proviso that both y and v are not zero.
Abstract translation: 包含硅氧烷主链的水溶性硅氧烷大分子单体,其具有接枝到其上的合适数量的亲水基团以使大分子单体水溶性,大分子单体包含接枝到硅氧烷主链的可聚合官能团。 一方面,本发明提供具有式(1)结构的水溶性硅氧烷大分子单体:其中M是亲水基团或链段; L是亲水或疏水键; N是亲水或疏水基团或片段。 Q是可聚合官能团; x为零或大于零的整数; y为零或大于零的整数; v为零或大于零的整数; 并且z大于零,条件是y和v都不为零。
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