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公开(公告)号：US07638670B2
公开(公告)日：2009-12-29
申请号：US12188587
申请日：2008-08-08
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
CPC分类号： C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基胺或杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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公开(公告)号：US07399874B2
公开(公告)日：2008-07-15
申请号：US11221990
申请日：2005-09-08
CPC分类号： C07F7/00 , C07F7/28 , C08F4/619 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/16 , C08F4/64148 , C08F210/14 , C08F2500/03 , C08F4/659
摘要： This invention relates to a catalyst compound represented by the formula: wherein: M is a Group 3 to 12 transition metal; each Ra is, independently, a hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group or halogen; each of R1, R2, R3, R4, R5, R7, R8, R9, R10, and R11 is, independently a hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group or halogen; R6 is hydrogen, a hydrocarbyl group, or a substituted hydrocarbyl group; x is 0, 1, 2, 3 or 4; and each Z is, independently, a group 15 atom. This invention also relates to catalyst systems comprising the above catalyst compound and a activator and the use of such catalyst systems to polymerize monomers, including olefin monomers.
摘要翻译： 本发明涉及由下式表示的催化剂化合物：其中：M为第3至12族过渡金属; 每个R a a独立地是氢，烃基，取代的烃基或卤素; R 1，R 2，R 3，R 4，R 5，R 5，...中的每一个 R 7，R 8，R 9，R 10和R 11， SUP>独立地是氢，烃基，取代的烃基或卤素; R 6是氢，烃基或取代的烃基; x为0,1,2,3或4; 并且每个Z独立地是基团15原子。 本发明还涉及包含上述催化剂化合物和活化剂的催化剂体系，以及这种催化剂体系用于聚合单体（包括烯烃单体）的用途。
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公开(公告)号：US07638671B2
公开(公告)日：2009-12-29
申请号：US12215626
申请日：2008-06-27
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
CPC分类号： C07C2/32 , B01J31/1815 , B01J31/2208 , B01J2231/20 , B01J2531/62 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/69146 , C08F4/69275 , C08F4/69103 , C08F4/69172
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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公开(公告)号：US07425661B2
公开(公告)日：2008-09-16
申请号：US11371983
申请日：2006-03-09
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
CPC分类号： C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基胺或杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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公开(公告)号：US07414006B2
公开(公告)日：2008-08-19
申请号：US11371614
申请日：2006-03-09
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, Jr. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
CPC分类号： C07C2/32 , B01J31/1815 , B01J31/2208 , B01J2231/20 , B01J2531/62 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/69146 , C08F4/69275 , C08F4/69103 , C08F4/69172
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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公开(公告)号：US20080293899A1
公开(公告)日：2008-11-27
申请号：US12188587
申请日：2008-08-08
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiahong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, JR. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiahong Bei , Matthew C. Kuchta , Tom Boussie , John F. Walzer, JR. , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
IPC分类号： C08F2/00
CPC分类号： C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和吡啶基胺或杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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公开(公告)号：US07217676B2
公开(公告)日：2007-05-15
申请号：US10758726
申请日：2004-01-16
申请人： George Rodriguez , Anthony N. Speca , Matthew C. Kuchta , David H. McConville , Terry J. Burkhardt
发明人： George Rodriguez , Anthony N. Speca , Matthew C. Kuchta , David H. McConville , Terry J. Burkhardt
CPC分类号： C08F110/06 , C08F4/65927 , Y10T428/31678 , C08F4/65908 , C08F4/65916 , C08F2500/18 , C08F2500/12
摘要： This invention relates to a catalyst support comprising the result of the combination of: (a) a support comprising hydroxyl groups; (b) a capping agent comprising a boron containing Lewis acid; and (c) an ionic activator, wherein at least some of the capping agent does not form a support bound activator.
摘要翻译： 本发明涉及一种催化剂载体，其包含以下组合的结果：（a）包含羟基的载体; （b）包含含硼的路易斯酸的封端剂; 和（c）离子活化剂，其中至少一些封端剂不形成支持结合的活化剂。
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公开(公告)号：US06894128B2
公开(公告)日：2005-05-17
申请号：US10634474
申请日：2003-08-05
申请人： Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
发明人： Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
IPC分类号： C08F4/02 , C08F4/06 , C08F4/44 , C08F4/642 , C08F4/645 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F4/69 , C08F10/00 , C08F10/02 , C08F210/16 , C08L23/08 , C08L23/16 , C08F4/72 , C08F4/80
CPC分类号： C08F10/02 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2420/04 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F2/00 , C08F4/025 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/02 , C08F2500/01 , C08F2500/26 , C08F2500/05 , C08F4/64148 , C08F4/65904 , C08F4/64158 , C08F4/64144 , C08F4/64151
摘要： Catalyst compositions and methods useful in polymerization processes utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe. The Group 15 containing metal compound is represented in one embodiment by the formulae: wherein M is a Group 4, 5, or 6 metal; each X is independently a leaving group; y is 0 or 1; n is the oxidation state of M; m is the formal change of the ligand comprising the YZL or YZL′ groups; L is a Group 15 or 16 element; L′ is a Group 15 or 16 element or Group 14 containing group; Y is a Group 15 element; Z is a Group 15 element; and the other groups are as defined herein.
摘要翻译： 公开了在使用至少两种金属化合物的聚合方法中有用的催化剂组合物和方法。 至少一种金属化合物是含有第15族金属化合物，另一种金属化合物优选为大体积配体金属茂型催化剂。 本发明还公开了一种新的聚烯烃，一般为聚乙烯，特别是多峰聚合物，更具体地说是双峰聚合物，以及其在各种最终用途应用如薄膜，模塑和管材中的应用。 含有金属化合物的第15族在一个实施方案中由下式表示：其中M是第4,5或6族金属; 每个X独立地为离去基团; y为0或1; n是M的氧化态; m是包含YZL或YZL'基团的配体的正式变化; L是15或16组元素; L'是15或16族元素或含14族的基团; Y是第15组元素; Z是15组元素; 并且其它基团如本文所定义。
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公开(公告)号：US06841631B2
公开(公告)日：2005-01-11
申请号：US10632295
申请日：2003-08-01
申请人： Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
发明人： Donald R. Loveday , David H. McConville , John F. Szul , Kersten Anne Erickson , Simon Mawson , Tae Hoon Kwack , Frederick J. Karol , David James Schreck
IPC分类号： C08F4/02 , C08F4/06 , C08F4/44 , C08F4/642 , C08F4/645 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F4/69 , C08F10/00 , C08F10/02 , C08F210/16 , C08L23/08 , C08L23/16
CPC分类号： C08F10/02 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2420/04 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F2/00 , C08F4/025 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/02 , C08F2500/01 , C08F2500/26 , C08F2500/05 , C08F4/64148 , C08F4/65904 , C08F4/64158 , C08F4/64144 , C08F4/64151
摘要： Catalyst compositions and methods, useful in polymerization processes, utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe.
摘要翻译： 公开了使用至少两种金属化合物的聚合方法中的催化剂组合物和方法。 至少一种金属化合物是含有第15族金属化合物，另一种金属化合物优选为大体积配体金属茂型催化剂。 本发明还公开了一种新的聚烯烃，一般为聚乙烯，特别是多峰聚合物，更具体地说是双峰聚合物，以及其在各种最终用途应用如薄膜，模塑和管材中的应用。
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公开(公告)号：US06696537B2
公开(公告)日：2004-02-24
申请号：US10147216
申请日：2002-05-16
IPC分类号： C08F1002
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2410/03 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2314/06 , Y10S526/901 , C08F4/659 , C08F4/65904 , C08F4/64148 , C08F4/025 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/02 , C08F2500/01 , C08F2500/26 , C08F4/64141 , C08F4/7019
摘要： A polymer produced by a polymerization process, in the gas or slurry phase, with a liquid carrier comprising an activator and a metal catalyst compound comprising a group 3 to 14 metal atom bound to at least one anionic leaving group and also bound to at least two group 15 atoms, at least one of which is also bound to a group 15 or 16 atom through another group which may be a C1 to C20 hydrocarbon group, a heteroatom containing group, silicon, germanium, tin, lead, phosphorus, or a halogen, wherein the group 15 or 16 atom may also be bound to nothing or a hydrogen, a group 14 atom containing group, a halogen, or a heteroatom containing group, and wherein each of the two group 15 atoms are also bound to a cyclic group and may optionally be bound to hydrogen, a halogen, a heteroatom or a hydrocarbyl group, or a heteroatom containing group.
摘要翻译： 通过在气体或浆料相中的聚合方法制备的聚合物与包含活化剂的液体载体和包含与至少一个阴离子离去基团结合的第3至14个金属原子的金属催化剂化合物，并且还结合至少两个 15个原子，其中至少一个还通过可以是C1至C20烃基，含杂原子的基团，硅，锗，锡，铅，磷或卤素的另一基团与基团15或16原子结合。 ，其中第15或16族原子也可以不结合任何氢或氢，含14个原子的基团，卤素或含杂原子的基团，并且其中两个基团15原子中的每一个也与环状基团结合 并且可以任选地与氢，卤素，杂原子或烃基或含杂原子的基团结合。
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