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    Oxyfunctionalization of polyolefins
    1.
    发明授权
    Oxyfunctionalization of polyolefins 有权
    聚烯烃的氧官能化

    公开(公告)号：US06953868B2

    公开(公告)日：2005-10-11

    申请号：US10831869

    申请日：2004-04-26

    申请人： Nicole K. Boaen ,  Marc A. Hillmyer ,  Stephen F. Hahn

    发明人： Nicole K. Boaen ,  Marc A. Hillmyer ,  Stephen F. Hahn

    IPC分类号： C08F8/06 ,  C07C31/18 ,  C08F138/00

    CPC分类号： C08C19/02 ,  C08F8/06 ,  C08F210/16

    摘要： The present invention is a method for oxyfunctionalizing, that is, introducing oxygen functionality to, a polyolefin such as polypropylene and poly(ethylene-alt-propylene). The polyolefin is contacted with an oxygen source such as a persulfate and catalytic amounts of a metal porphyrin complex under mild conditions to yield an oxyfunctionalized polymer that has a polydispersity that is very similar to that of the starting polymer.

    摘要翻译： 本发明是一种氧化官能化方法，即将聚氧乙烯（聚丙烯）和聚（亚乙基 - 高级 - 丙烯）等聚烯烃引入氧官能度。 聚烯烃在温和条件下与氧源如过硫酸盐和催化量的金属卟啉络合物接触，得到具有与起始聚合物非常相似的多分散性的氧化官能化聚合物。

    ISOSORBIDE-BASED POLYMETHACRYLATES
    3.
    发明申请
    ISOSORBIDE-BASED POLYMETHACRYLATES 有权
    异构体基聚异丁烯酸酯

    公开(公告)号：US20160229863A1

    公开(公告)日：2016-08-11

    申请号：US15019777

    申请日：2016-02-09

    申请人： Marc A. Hillmyer ,  Theresa Reineke ,  James Gallagher

    发明人： Marc A. Hillmyer ,  Theresa Reineke ,  James Gallagher

    IPC分类号： C07D493/04 ,  C08F122/10

    CPC分类号： C07D493/04 ,  C08F120/28 ,  C08F220/28 ,  C08F293/00 ,  C08F2438/03 ,  C08F2220/283 ,  C08F2220/1825

    摘要： A monomer comprises the structure wherein R1 comprises H or a substituted hydrocarbyl or unsubstituted hydrocarbyl, and wherein R2 comprises H, a halide, or a substituted or unsubstituted (C1-C4) hydrocarbyl. A method comprises (a) reacting a dianhydrohexitol precursor having the structure with an acyl-group containing compound having the structure wherein R1 comprises H or a substituted hydrocarbyl or unsubstituted hydrocarbyl, and X comprises a halide, a hydroxyl group, or an acyl group to form an acylated dianhydrohexitol ester intermediate having the structure and (b) reacting the acylated dianhydrohexitol ester intermediate with an acrylic-based compound having the structure wherein R2 comprises H, a halide, or a substituted or unsubstituted (C1-C4) hydrocarbyl, and Y comprises a halide, a hydroxyl group, or an acyl group, to form a dianhydrohexitol-based monomer having the structure

    摘要翻译： 单体包括其中R 1包含H或取代的烃基或未取代烃基的结构，并且其中R 2包含H，卤化物或取代或未取代的（C 1 -C 4）烃基。 一种方法包括（a）使具有结构的二脱水己糖醇前体与含酰基的化合物反应，其中R 1包含H或取代的烃基或未取代烃基，X包括卤化物，羟基或酰基， 形成具有以下结构的酰化二氢己糖醇中间体和（b）使酰化的二氢己糖醇中间体与具有以下结构的丙烯酸类化合物反应：其中R2包含H，卤化物或取代或未取代的（C1-C4）烃基，Y 包括卤化物，羟基或酰基，以形成具有该结构的二脱水己糖醇单体

    CHEWING GUMS AND GUM BASES COMPRISING MULTI-BLOCK COPOLYMERS
    5.
    发明申请
    CHEWING GUMS AND GUM BASES COMPRISING MULTI-BLOCK COPOLYMERS 有权
    包括多嵌段共聚物的CHEWING GUMS和GUM BASES

    公开(公告)号：US20140161931A1

    公开(公告)日：2014-06-12

    申请号：US14003998

    申请日：2012-03-09

    申请人： Leslie D. Morget ,  Michael S. Haas ,  Marc A. Hillmyer ,  Wilhelm Risse ,  Frank S. Bates ,  Mark T Martello ,  Sangwoo Lee

    发明人： Leslie D. Morget ,  Michael S. Haas ,  Marc A. Hillmyer ,  Wilhelm Risse ,  Frank S. Bates ,  Mark T Martello ,  Sangwoo Lee

    IPC分类号： A23G4/08

    CPC分类号： A23G4/08 ,  A23G4/123 ,  C08G63/66 ,  C08G81/00 ,  C12C12/00

    摘要： Chewing gums and chewing gum bases which are cud-forming and chewable at mouth temperature contains a multi-block copolymer having at least two repeating sequences of at least two different polymeric blocks having at least three monomer units each. The multi-block copolymer optionally includes linking units and may be formulated to have non-covalent crosslinking between the copolymer chains. The multi-block copolymer is optionally plasticized with a compatible di-block copolymer to function as an elastomer system in the gum base. Characteristics of the multi-block copolymers can be selected to produce gum bases and chewing gums having desired properties. In some cases, chewed cuds formed from the gum bases may exhibit improved removability from environmental surfaces to which they may become undesirably attached.

    摘要翻译： 咀嚼口香糖和口香糖咀嚼口香糖基质含有多嵌段共聚物，其具有至少两个具有至少三个单体单元的至少两个不同聚合物嵌段的重复序列。 多嵌段共聚物任选地包括连接单元，并且可以配制成在共聚物链之间具有非共价交联。 多嵌段共聚物任选地用相容的二嵌段共聚物增塑，用作胶基中的弹性体体系。 可以选择多嵌段共聚物的特性来生产具有所需性质的胶基和口香糖。 在一些情况下，由胶基形成的咀嚼嚼可以表现出从它们可能变得不期望地附着的环境表面的改进的可除去性。

    Romp of functionalized cyclic olefins using ruthenium and osmium carbene complexes
    6.
    发明授权
    Romp of functionalized cyclic olefins using ruthenium and osmium carbene complexes 失效
    使用钌和咔咔啉络合物对官能化环烯烃进行反应

    公开(公告)号：US5849851A

    公开(公告)日：1998-12-15

    申请号：US969969

    申请日：1997-11-13

    申请人： Robert H. Grubbs ,  Sonbinh T. Nguyen ,  Marc A. Hillmyer

    发明人： Robert H. Grubbs ,  Sonbinh T. Nguyen ,  Marc A. Hillmyer

    IPC分类号： B01J23/46 ,  B01J31/22 ,  C07C51/353 ,  C07C67/475 ,  C07F15/00 ,  C08F4/80 ,  C08F8/50 ,  C08F10/00 ,  C08F32/00 ,  C08F210/02 ,  C08G61/08 ,  C08G61/12

    CPC分类号： B01J31/2265 ,  B01J31/24 ,  B01J31/2404 ,  C07C51/353 ,  C07C67/333 ,  C07C67/475 ,  C07F15/002 ,  C07F15/0046 ,  C08C19/08 ,  C08F10/00 ,  C08F32/00 ,  C08F8/50 ,  C08G61/08 ,  C08G61/128 ,  B01J2231/14 ,  B01J2231/543 ,  B01J23/462 ,  B01J23/466 ,  B01J2531/821 ,  B01J2531/825 ,  C07C2101/10 ,  C08C2019/09 ,  C08F210/02 ,  Y10S525/938

    摘要： Disclosed are ruthenium and osmium carbene compounds which are stable in the presence of a variety of functional groups and which can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins. Specifically, the present invention relates to carbene compounds of the formula ##STR1## wherein: M is Os or Ru; R and R.sup.1 are independently selected from hydrogen and functional groups C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.2 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl or C.sub.1 -C.sub.20 alkylsulfinyl; each optionally substituted with C.sub.1 -C.sub.5 alkyl, a halogen, C.sub.1 -C.sub.5 alkoxy or with a phenyl group optionally substituted with a halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are each trialkyl phosphine ligands where at least one of the alkyl groups on the phosphine is a secondary alkyl or a cycloalkyl. A broad array of metathesis reactions are enabled including ring-opening metathesis polymerization of cyclic olefins, ring closing metathesis of acyclic dienes, cross metathesis involving at least one acyclic or unstrained cyclic olefin, and depolymerization of unsaturated polymers.

    摘要翻译： 公开了在各种官能团存在下稳定的钌和咔咔啉化合物，其可用于在未应变的环状和无环烯烃上催化烯烃复分解反应。 具体地说，本发明涉及下式的卡宾化合物：其中：M是Os或Ru; R和R 1独立地选自氢和官能团C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷基，芳基，C 1 -C 20羧酸酯，C 2 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基， C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基或C 1 -C 20烷基亚磺酰基; 每个任选被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基或任选被卤素，C 1 -C 5烷基或C 1 -C 5烷氧基取代的苯基取代; X和X 1独立地选自任何阴离子配体; L和L1各自为三烷基膦配体，其中膦上的至少一个烷基是仲烷基或环烷基。 复分解反应的范围广泛，包括环烯烃的开环易位聚合，无环二烯的闭环复分解，涉及至少一个无环或非应变的环烯烃的交叉复分解，以及不饱和聚合物的解聚。

    POLYLACTIDE COPOLYMERS
    8.
    发明申请
    POLYLACTIDE COPOLYMERS 审中-公开
    聚酰胺共聚物

    公开(公告)号：US20110294960A1

    公开(公告)日：2011-12-01

    申请号：US13115796

    申请日：2011-05-25

    申请人： Marc A. Hillmyer ,  Grayce C. Theryo ,  Louis M. Pitet ,  Feng Jing

    发明人： Marc A. Hillmyer ,  Grayce C. Theryo ,  Louis M. Pitet ,  Feng Jing

    IPC分类号： C08F279/00

    CPC分类号： C08G61/08 ,  C08G63/08 ,  C08G2261/3323 ,  C08G2261/3324 ,  C08G2261/74

    摘要： A polylactide copolymer comprises a graft copolymer of a hydrophobic backbone polymer having a plurality of pendant hydroxyl groups and lactide. In one example, a polylactide includes a graft copolymer of a poly(1,5-cyclooctadiene-co5-norbornene-2-methanol) copolymer and lactide. A method of preparing a toughened polylactide comprises forming a hydrophobic backbone copolymer having a plurality of pendant hydroxyl groups and forming a polylactide graft copolymer by reacting the hydrophobic backbone copolymer having a plurality of pendant hydroxyl groups with lactide, wherein polymerized lactide stems from at least one of the plurality of pendant hydroxyl groups. In one example, a method comprises forming poly(1,5-cyclooctadiene-co-5-norbornene-2-menthanol) by reacting 1,5-cyclooctadiene and 5-norbornene-2-methanol in the presence of a 2nd generation Grubbs' catalyst and cis-1,4-diacetoxy-2-butene as a chain transfer agent and forming poly(1,5-cyclooctadiene-co-5-norbornene-2-methanol-graft-lactide) by reacting the poly(1,5-cyclooctadiene-co-5-norbornene-2-menthanol) as a macroinitiator with lactide in the presence of tin 2-ethylhexanoate and toluene or in the presence of 1,5,7-triazabicyclo[4.4.0]dec-5-ene and dichloromethane.

    摘要翻译： 聚丙交酯共聚物包含具有多个侧基羟基的疏水骨架聚合物和丙交酯的接枝共聚物。 在一个实例中，聚交酯包括聚（1,5-环辛二烯-co5-降冰片烯-2-甲醇）共聚物和丙交酯的接枝共聚物。 制备增韧的聚丙交酯的方法包括通过使具有多个侧基羟基的疏水性主链共聚物与丙交酯反应形成具有多个侧羟基的疏水骨架共聚物并形成聚交酯接枝共聚物，其中聚合的丙交酯源自至少一个 的多个侧基羟基。 在一个实例中，一种方法包括在第二代格鲁布斯（Grubbs）的存在下，使1,5-环辛二烯和5-降冰片烯-2-甲醇反应形成聚（1,5-环辛二烯 - 共-5-降冰片烯-2-甲醇） 催化剂和顺式-1,4-二乙酰氧基-2-丁烯作为链转移剂，并通过使聚（1,5-环辛二烯 - 共-5-降冰片烯-2-甲醇 - 接枝丙交酯） - 环辛二烯 - 共-5-降冰片烯-2-薄荷醇）作为大分子引发剂，在2-乙基己酸锡和甲苯存在下，或在1,5,7-三氮杂双环[4.4.0]癸-5-烯 和二氯甲烷。

    Fluorinated polymers and methods for their preparation
    9.
    发明授权
    Fluorinated polymers and methods for their preparation 有权
    氟化聚合物及其制备方法

    公开(公告)号：US06433101B1

    公开(公告)日：2002-08-13

    申请号：US09453020

    申请日：1999-12-02

    申请人： Charles S. Woodson ,  Marc A. Hillmyer ,  Robert H. Grubbs ,  Timothy P. Lodge ,  Yu Ren

    发明人： Charles S. Woodson ,  Marc A. Hillmyer ,  Robert H. Grubbs ,  Timothy P. Lodge ,  Yu Ren

    IPC分类号： C08F818

    CPC分类号： C08F8/20 ,  C08F8/18

    摘要： The present invention relates to the post-polymerization fluorination methods of polymers produced via ring-opening metathesis polymerization. Unlike prior art methods that result in low product yields and generally involve chemically aggressive reagents, the inventive methods produce fluorinated polymers in quantitative yields and under mild conditions. In preferred embodiments, a source of difluorocarbene is reacted with the desired polydiene to form a fluorinated polymer product. In preferred embodiments, the source of difluorocarbene is hexafluoropropylene oxide and the polydiene is poly-dicyclopentadiene (“poly-DCPD”). Fluorination and the concomitant removal of unsaturated bonds result in polymers having improved physical properties such as improved strength characteristics, enhanced oxidative and chemical stability, and low surface energies.

    摘要翻译： 本发明涉及通过开环易位聚合制备的聚合物的后聚合氟化方法。 不同于导致低产物产率并且通常涉及化学腐蚀性试剂的现有技术方法，本发明方法以定量产率和温和条件下产生氟化聚合物。 在优选的实施方案中，将二氟卡宾源与所需的聚二烯反应以形成氟化聚合物产物。 在优选的实施方案中，二氟卡宾的来源是六氟环氧丙烷，聚二烯是聚二环戊二烯（“poly-DCPD”）。 氟化和伴随去除不饱和键导致具有改进的物理性质的聚合物，例如改进的强度特性，增强的氧化和化学稳定性和低表面能。