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38 条记录 (耗时 0.022 秒)

    Process for preparing bispicolyamine
    2.
    发明授权
    Process for preparing bispicolyamine 失效
    二聚多胺的制备方法

    公开(公告)号：US4080338A

    公开(公告)日：1978-03-21

    申请号：US782658

    申请日：1977-03-30

    申请人： Philip E. Garrou ,  George E. Hartwell

    发明人： Philip E. Garrou ,  George E. Hartwell

    IPC分类号： C07D213/38

    CPC分类号： C07D213/38

    摘要： Bispicolylamines are prepared by reacting (a) cyanopyridine with (b) hydrogen in the presence of a catalytic amount of (c) a palladium or carbon catalyst which has been preconditioned by contact with a reacting mixture of (a) and (b) for a time sufficient to cause said catalyst to preferentially produce bispicolylamine. The reaction is normally conducted under autogenous or superatmospheric pressure at a temperature of from about 20.degree. to about 75.degree. C in a lower alkanol (e.g., methanol) as the reaction medium.

    摘要翻译： 二氰基胺通过（a）氰基吡啶与（b）氢在催化量的（c）钯或碳催化剂存在下反应来制备，该催化剂已经通过与（a）和（b）的反应混合物接触来预处理 所述时间足以使所述催化剂优先产生双嘧啶胺。 反应通常在作为反应介质的低级链烷醇（例如甲醇）中，在约20℃至约75℃的自生或超大气压下进行。

    Hydroformylation of dicyclopentadiene to its dimethanolic derivatives
    3.
    发明授权
    Hydroformylation of dicyclopentadiene to its dimethanolic derivatives 失效
    二环戊二烯加氢甲酰化为其二甲醇衍生物

    公开(公告)号：US4262147A

    公开(公告)日：1981-04-14

    申请号：US21145

    申请日：1979-03-16

    申请人： Philip E. Garrou ,  George E. Hartwell

    发明人： Philip E. Garrou ,  George E. Hartwell

    IPC分类号： C07C29/16

    CPC分类号： C07C29/16 ,  C07C2103/68

    摘要： Dicyclopentadiene is selectively and substantially hydroformylated to its dimethanolic derivatives by a process comprising contacting dicyclopentadiene with a gaseous mixture of carbon monoxide and hydrogen at a temperature of at least about 100.degree. C. and a pressure of at least about 1,000 psig in the presence of a catalytic amount of a catalyst consisting essentially of a rhodium-cobalt bimetallic cluster, such as Rh.sub.2 Co.sub.2 CO.sub.12, supported on an amine resin, such as DOWEX.RTM. MWA-1.

    摘要翻译： 二环戊二烯通过包括使二环戊二烯与一氧化碳和氢气的气体混合物在至少约100℃的温度和至少约1,000psig的压力下在存在下接触的方法选择性且基本上加氢甲酰化为其二甲醇衍生物 催化量的催化剂基本上由负载在胺树脂上的铑 - 钴双金属簇如Rh 2 Co 2 CO 12组成，例如DOWEX TM MWA-1。

    Process of preparing mixtures of polyalkylenepolyamines and alkanolpolyamines
    7.
    发明授权
    Process of preparing mixtures of polyalkylenepolyamines and alkanolpolyamines 失效
    制备聚亚烷基多胺和链烷醇多胺的混合物的方法

    公开(公告)号：US5118851A

    公开(公告)日：1992-06-02

    申请号：US622444

    申请日：1990-12-05

    申请人： Robert G. Bowman ,  David C. Molzahn ,  George E. Hartwell

    发明人： Robert G. Bowman ,  David C. Molzahn ,  George E. Hartwell

    IPC分类号： C07C209/16 ,  C07C213/02

    CPC分类号： C07C209/16 ,  C07C213/02

    摘要： A process of preparing a mixture of polyalkylenepolyamines and alkanolpolyamines comprising contacting a difunctional aliphatic alcohol with a primary or secondary aliphatic amine in the presence of a metal silicate catalyst wherein the metal is selected from the group consisting of Groups IIA, IIIB, and the lanthanide and actinide metals. For example, monoethanolamine reacts with diethylenetriamine in the presence of magnesium silicate to yield a mixture of higher molecular weight linear and branched polyethylenepolyamines and their corresponding alkanolpolyamines. These product mixtures are useful in the formation of specialty polyurethanes.

    摘要翻译： 制备聚亚烷基多胺和链烷醇多胺的混合物的方法，包括在金属硅酸盐催化剂存在下使二官能脂族醇与伯或仲脂族胺接触，其中金属选自组IIA，IIIB和镧系元素，和 锕系金属。 例如，单乙醇胺在硅酸镁存在下与二亚乙基三胺反应，得到较高分子量的直链和支链聚亚乙基多胺及其相应的链烷醇多胺的混合物。 这些产品混合物可用于形成特种聚氨酯。

    Amination process employing group vib metal catalysts
    9.
    发明授权
    Amination process employing group vib metal catalysts 失效
    使用组合金属催化剂的胺化方法

    公开(公告)号：US4922024A

    公开(公告)日：1990-05-01

    申请号：US181622

    申请日：1988-04-14

    申请人： Robert G. Bowman ,  Marvin H. Tegen ,  George E. Hartwell

    发明人： Robert G. Bowman ,  Marvin H. Tegen ,  George E. Hartwell

    IPC分类号： C07C209/16

    CPC分类号： C07C209/16

    摘要： A process for preparing amines comprising contacting an alcohol with a reactant amine in the presence of hydrogen and a catalyst comprising at least one compound containing an element of Group VIB and at least one non-metallic element of Groups IIIA, IVA, and VA of the Periodic Table, the contacting occurring under conditions such that the hydroxyl moiety of the alcohol is replaced by the reactant amine to form an amine product.

    摘要翻译： 一种制备胺的方法，包括在氢气和催化剂存在下使醇与反应物胺接触，催化剂包含至少一种含有VIB族元素的化合物和至少一种IIIA，IVA和VA族的非金属元素 周期表中，在使得醇的羟基部分被反应物胺代替以形成胺产物的条件下发生接触。