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公开(公告)号：US06524991B2
公开(公告)日：2003-02-25
申请号：US09966535
申请日：2001-09-26
IPC分类号： B01J2106
CPC分类号： B01J23/50 , B01J23/52 , B01J23/66 , B01J29/89 , C07D301/04 , C07D301/10 , Y02P20/52 , Y02P20/584 , Y02P20/588
摘要： A process and catalyst for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to the corresponding olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen under reaction conditions in the presence of hydrogen and in the presence of a catalyst. The catalyst comprises gold on a titanosilicate, preferably a microporous or mesoporous titanosilicate, such as, TS-1, TS-2, Ti-beta, Ti-ZSM-48, or Ti-MCM-41. Selectivity to the olefin oxide is high at good conversions of the olefin. The catalyst is readily regenerated, and the time between catalyst regenerations is long.
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2.发明授权Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers 失效将多环芳族化合物烷基化成富含对位取代异构体的烷基化物
公开(公告)号：US4891448A
公开(公告)日：1990-01-02
申请号：US123741
申请日：1987-11-23
申请人： Juan Garces , Joseph J. Maj , G. John Lee , Stephen C. Rocke
发明人： Juan Garces , Joseph J. Maj , G. John Lee , Stephen C. Rocke
IPC分类号： C07C39/17 , B01J29/18 , C07B31/00 , C07B37/02 , C07B37/04 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/86 , C07C15/00 , C07C17/00 , C07C17/26 , C07C17/266 , C07C25/02 , C07C25/13 , C07C25/18 , C07C27/00 , C07C37/14 , C07C41/00 , C07C41/30 , C07C43/205 , C07C43/263 , C07C67/00 , C07C313/00 , C07C319/12 , C07C319/20 , C07C321/24 , C07C321/28 , C07C323/20 , C07C323/65
CPC分类号： C07C41/30 , B01J29/18 , C07C2/66 , C07C2/864 , C07C37/14 , C07C2101/14 , C07C2529/18
摘要： Polycyclic aromatic compounds, such as biphenyl, are alkylated with an alkylating agent, such as propylene, in the presence of an acidic mordenite zeolite catalyst under conditions sufficient to produce a mixture of substituted polycyclic aromatic compounds enriched in the para alkylated isomers, such as p,p'-di(isopropyl)biphenyl. The novel acidic mordenite catalyst is characterized by its silica/alumina molar ratio, its porosity, and a Symmetry Index. The p,p'-disubstituted isomers of polycyclic aromatic compounds are useful as monomers in the preparation of thermotropic, liquid crystal polymers.
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3.发明授权Alkylation of aromatic compounds to alkylates enriched in the linear substituted isomers 失效将芳族化合物烷基化成富含线性取代异构体的烷基化物
公开(公告)号：US5175135A
公开(公告)日：1992-12-29
申请号：US689411
申请日：1991-04-22
CPC分类号： C07C209/68 , B01J29/18 , C07C2/66 , C07C2/864 , C07C37/14 , C07C41/30 , C07C6/126 , C07C2101/14 , C07C2521/08 , C07C2529/18
摘要： Aromatic compounds, such as benzene or biphenyl, are alkylated with an alkylating agent having from one to eight carbons atoms, such as propylene, in the presence of an acidic mordenite zeolite catalyst under conditions sufficient to produce a mixture of substituted aromatic compounds enriched in the linear alkylated isomers, such as p-diisopropylbenzene or p,p'-di(isopropyl)biphenyl, respectively. The novel acidic mordenite catalyst is characterized by its silica/alumina molar ratio, its porosity, and a Symmetry Index. The p,p'-disubstituted isomers of aromatic compounds are useful as monomers in the preparation of thermotropic, liquid crystal polymers.
摘要翻译： 在酸性丝光沸石催化剂存在下，芳族化合物如苯或联苯在具有1至8个碳原子的烷基化剂如丙烯的条件下进行烷基化，所述条件足以产生富集的芳族化合物的混合物 线性烷基化异构体，如对二异丙苯或对，对 - 二（异丙基）联苯。 新型酸性丝光沸石催化剂的特征在于其二氧化硅/氧化铝摩尔比，孔隙率和对称指数。 芳族化合物的p，p'-二取代异构体可用作制备热致液晶聚合物的单体。
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公开(公告)号：US5965754A
公开(公告)日：1999-10-12
申请号：US209699
申请日：1998-12-11
IPC分类号： B01J23/66 , B01J23/50 , B01J23/52 , B01J23/96 , B01J29/89 , C07D301/04 , C07D301/06 , C07D301/10 , C07D303/04 , B01J21/08
CPC分类号： B01J23/50 , B01J23/52 , B01J23/66 , B01J29/89 , C07D301/04 , C07D301/10 , Y02P20/52 , Y02P20/584 , Y02P20/588
摘要： A process and catalyst for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen under reaction conditions in the presence of hydrogen and a catalyst. The catalyst comprises gold on a support of titanium dispersed on silica. The titanium phase is disorganized and substantially free of crystalline titanium dioxide, as determined by analytical methods, such as, high resolution transmission electron microscopy and Raman spectroscopy. Selectivity to olefin oxide is high at good conversions of the olefin. The time between catalyst regenerations is long, and the catalyst is readily regenerated.
摘要翻译： 用于将具有三个或更多个碳原子的烯烃（例如丙烯）通过氧气直接氧化成烯烃氧化物如环氧丙烷的方法和催化剂。 该方法包括在氢气和催化剂存在下，在反应条件下使烯烃与氧接触。 该催化剂包含分散在二氧化硅上的钛的载体上的金。 通过分析方法如高分辨率透射电子显微镜和拉曼光谱测定，钛相是无组织的并且基本上不含结晶二氧化钛。 烯烃氧化物的选择性高，烯烃转化率高。 催化剂再生之间的时间长，催化剂容易再生。
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5.发明授权Alkylation of polycyclic aromatic compounds to alkylates enriched in the linear- and near linear-substituted isomers 失效将多环芳族化合物烷基化成富含线性和近似直链取代的异构体的烷基化物
公开(公告)号：US5015797A
公开(公告)日：1991-05-14
申请号：US458036
申请日：1989-12-28
申请人： Guo-shuh J. Lee , Juan M. Garces , Joseph J. Maj
发明人： Guo-shuh J. Lee , Juan M. Garces , Joseph J. Maj
CPC分类号： C07C41/30 , B01J29/18 , C07C2/66 , C07C2/864 , C07C37/14 , C07C39/17 , C07C2101/14 , C07C2529/18
摘要： Polycyclic aromatic compounds, such as biphenyl, are alkylated with an alkylating agent, such as propylene, in the presence of an acidic mordenite zeolite catalyst under conditions sufficient to produce a mixture of substituted polycyclic aromatic compounds enriched in the linear- and near linear-alkylated isomers, such as p,p'- and p,m'-di(isopropyl)biphenyl. The novel acidic mordenite catalyst is characterized by its silica/alumina molar ratio, its porosity, and a Symmetry Index. Mixtures of the p,p'- and p,m'-disubstituted isomers of polycyclic aromatic compounds are useful as monomers in the preparation of improved thermotropic, liquid crystal polymers.
摘要翻译： 在酸性丝光沸石催化剂存在下，在足以产生富含线性和近似直链烷基化的取代多环芳香族化合物的混合物的条件下，将多环芳族化合物如联苯在烷基化剂如丙烯中烷基化 异构体，如p，p'-和p，m'-二（异丙基）联苯。 新型酸性丝光沸石催化剂的特征在于其二氧化硅/氧化铝摩尔比，孔隙率和对称指数。 多环芳族化合物的p，p'-和p，m'-二取代异构体的混合物可用作制备改进的热致液晶聚合物的单体。
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6.发明授权Alkylation of aromatic compounds to alkylates enriched in the linear-substituted isomers 失效将芳族化合物烷基化成富含直链取代的异构体的烷基化物
公开(公告)号：US5004841A
公开(公告)日：1991-04-02
申请号：US323530
申请日：1989-03-14
CPC分类号： C07C41/30 , B01J29/18 , C07C2/66 , C07C2/864 , C07C37/14 , C07C2101/14 , C07C2529/18
摘要： Aromatic compounds, such as benzene or biphenyl, are alkylated with an alkylating agent having from one to eight carbons atoms, such as propylene, in the presence of an acidic mordenite zeolite catalyst under conditions sufficient to produce a mixture of substituted aromatic compounds enriched in the linear alkylated isomers, such as p-diisopropylbenzene or p,p'-di(isopropyl)biphenyl, respectively. The novel acidic mordenite catalyst is characterized by its silica/alumina molar ratio, its porosity, and a Symmetry Index. The p,p'-disubstituted isomers of aromatic compounds are useful as monomers in the preparation of thermotropic, liquid crystal polymers.
摘要翻译： 在酸性丝光沸石催化剂存在下，芳族化合物如苯或联苯在具有1至8个碳原子的烷基化剂如丙烯的条件下进行烷基化，所述条件足以产生富集的芳族化合物的混合物 线性烷基化异构体，如对二异丙苯或对，对 - 二（异丙基）联苯。 新型酸性丝光沸石催化剂的特征在于其二氧化硅/氧化铝摩尔比，孔隙率和对称指数。 芳族化合物的p，p'-二取代异构体可用作制备热致液晶聚合物的单体。
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公开(公告)号：US4996353A
公开(公告)日：1991-02-26
申请号：US352575
申请日：1989-05-16
IPC分类号： C07C51/265
CPC分类号： C07C51/265
摘要： A process for the preparation of polyphenyl dicarboxylic acids is disclosed. The process comprises contacting para,para'-diisoalkyl or dialkyl-polyphenyl or an oxidation intermediate thereof with oxygen under reaction conditions sufficient to form para,para'-polyphenyldicarboxylic acid. The process is optionally carried out in the presence of cobalt, manganese, and bromine compounds.
摘要翻译： 公开了一种制备聚苯二羧酸的方法。 该方法包括在足以形成对位，对聚 - 多苯基二羧酸的反应条件下，使对位，对 - 二异烷基或二烷基 - 聚苯基或其氧化中间体与氧接触。 该方法任选在钴，锰和溴化合物的存在下进行。
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公开(公告)号：US6031116A
公开(公告)日：2000-02-29
申请号：US209700
申请日：1998-12-11
IPC分类号： B01J23/66 , B01J23/50 , B01J23/52 , B01J23/96 , B01J29/89 , C07D301/04 , C07D301/06 , C07D301/10 , C07D303/04
CPC分类号： B01J23/50 , B01J23/52 , B01J23/66 , B01J29/89 , C07D301/04 , C07D301/10 , Y02P20/52 , Y02P20/584 , Y02P20/588
摘要： A process and catalyst for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to the corresponding olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen under reaction conditions in the presence of hydrogen and in the presence of a catalyst. The catalyst comprises gold on a titanosilicate, preferably a microporous or mesoporous titanosilicate, such as, TS-1, TS-2, Ti-beta, Ti-ZSM-48, or Ti-MCM-41. Selectivity to the olefin oxide is high at good conversions of the olefin. The catalyst is readily regenerated, and the time between catalyst regenerations is long.
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9.发明授权On-line synthesis and regeneration of a catalyst used in autothermal oxidation 有权用于自热氧化的催化剂的在线合成和再生公开(公告)号：US06624116B1
公开(公告)日：2003-09-23
申请号：US09706464
申请日：2000-11-03
IPC分类号： B01J2396
CPC分类号： C07C5/48 , B01J21/04 , B01J21/10 , B01J23/40 , B01J23/54 , B01J23/56 , B01J23/626 , B01J23/6445 , B01J23/70 , B01J23/76 , B01J23/8926 , B01J23/8966 , B01J23/96 , B01J35/04 , B01J35/06 , B01J37/0201 , B01J37/0207 , B01J37/0238 , B01J37/18 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/14 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C07C2523/72 , C07C2527/224 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y10S502/514 , C07C11/04 , C07C11/02
摘要： An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.
摘要翻译： 合成或再生用于自热氧化方法的催化剂的在线方法，具体地，将链烷烃如乙烷，丙烷和石脑油氧化成烯烃，例如乙烯和丙烯。 催化剂在载体上，优选整料载体上包含8B族金属，例如铂族金属和任选的助催化剂，例如锡，锑或铜。 在线合成或再生包括在点燃或自热条件下将挥发性第8B族金属化合物和/或挥发性促进剂化合物与链烷烃和氧共同进料到氧化反应器中。
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公开(公告)号：US06566573B1
公开(公告)日：2003-05-20
申请号：US09388219
申请日：1999-09-01
申请人： Sameer S. Bharadwaj , Joseph J. Maj , Jonathan H. Siddall , Mark D. Bearden , Craig B. Murchison , Gerald E. Lazaruk
发明人： Sameer S. Bharadwaj , Joseph J. Maj , Jonathan H. Siddall , Mark D. Bearden , Craig B. Murchison , Gerald E. Lazaruk
IPC分类号： C07C5333
CPC分类号： C07C5/48 , B01J21/04 , B01J21/10 , B01J23/40 , B01J23/54 , B01J23/56 , B01J23/626 , B01J23/6445 , B01J23/70 , B01J23/76 , B01J23/8926 , B01J23/8966 , B01J23/96 , B01J35/04 , B01J35/06 , B01J37/0201 , B01J37/0207 , B01J37/0238 , B01J37/18 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/14 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C07C2523/72 , C07C2527/224 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y10S502/514 , C07C11/04 , C07C11/02
摘要： A process and catalyst for the partial oxidation of paraffinic hydrocarbons, such as ethane, propane, naphtha, and natural gas condensates, to olefins, such as ethylene and propylene. The process involves contacting a paraffinic hydrocarbon with oxygen in the presence of hydrogen and a catalyst under autothermal process conditions. Preheating the feed decreases oxygen consumption and increases the net hydrogen balance. The catalyst comprises a Group 8B metal, preferably, a platinum group metal, and at least one promoter selected from Groups 1B, 6B, 3A, 4A, and 5A, optionally supported on a catalytic support, such as magnesia or alumina. In preferred embodiments, the support is pretreated with a support modifier selected from Groups 1A, 2A, 3B, 4B, 5B, 6B, 1B, 3A, 4A, 5A, the rare earth lanthanides, and the actinides. A modified fluidized bed reactor is disclosed for the process.
摘要翻译： 用于将链烷烃（例如乙烷，丙烷，石脑油和天然气）部分氧化的方法和催化剂冷凝成烯烃，例如乙烯和丙烯。 该方法包括在自热过程条件下在氢气和催化剂存在下使链烷烃与氧接触。 饲料预热会减少氧气消耗，并增加净氢平衡。 该催化剂包含8B族金属，优选铂族金属和至少一种选自1B，6B，3A，4A和5A族的助催化剂，任选负载在催化载体如氧化镁或氧化铝上。 在优选的实施方案中，载体用选自组1A，2A，3B，4B，5B，6B，1B，3A，4A，5A，稀土镧系元素和锕系元素的载体改性剂预处理。 公开了改进的流化床反应器。
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