METHOD FOR CONVERTING UO3 OR U3O8 INTO HYDRATED UO4
    4.
    发明申请
    METHOD FOR CONVERTING UO3 OR U3O8 INTO HYDRATED UO4 有权
    将UO3或U3O8转化为水合UO4的方法

    公开(公告)号:US20130280157A1

    公开(公告)日:2013-10-24

    申请号:US13995277

    申请日:2011-12-16

    IPC分类号: C01G43/01

    摘要: A method for converting UO3 and/or U3O8 into hydrated UO4 of formula UO4.nH2O wherein n is 2 or 4, comprising the following successive steps: a) preparing an aqueous suspension of a UO3 powder and/or a U3O8 powder; b) adding hydrogen peroxide H2O2 to the aqueous suspension of a UO3 and/or U3O8 powder, converting the UO3 and/or U3O8 into hydrated UO4 and precipitating, crystallizing the hydrated UO4 in the suspension; g) recovering the precipitate, crystals of UO4 hydrate; h) optionally, washing the recovered UO4 hydrate precipitate, crystal(s); i) optionally, repeating step d); j) optionally, drying the precipitate, the crystals; wherein the addition of H2O2 to the aqueous suspension is carried out so that the suspension contains a stoichiometric excess of H2O2 relatively to the stoichiometry of the reaction from UO3: UO3+nH2O+H2O2→UO4.nH2O+H2O  (1) or of the reaction from U3O8 UO2.67+1.33H2O2+nH2O→UO4.nH2O+H2O  (2) and the pH of the suspension is maintained in steps a) and b) at a value comprised between 2 and 3.

    摘要翻译: 将UO 3和/或U 3 O 8转化为式UO·4H 2 O的水合UO 4的方法,其中n为2或4,包括以下连续步骤:a)制备UO 3粉末和/或U 3 O 8粉末的水性悬浮液; b)向UO 3和/或U 3 O 8粉末的水性悬浮液中加入过氧化氢H 2 O 2,将UO 3和/或U 3 O 8转化为水合UO 4并沉淀,使悬浮液中的水合UO4结晶; g)回收沉淀物,UO4水合物晶体; h)任选地,洗涤回收的UO4水合物沉淀物,晶体; i)任选地,重复步骤d); j)任选地,干燥沉淀物,晶体; 其中向含水悬浮液中加入H 2 O 2使得悬浮液相对于来自UO 3 :OO 3 + n H 2 O + H 2 O 2→UO 4·n H 2 O + H 2 O(1)的反应的化学计量比,含有化学计量过量的H 2 O 2 来自U3O8 UO2.67 + 1.33H2O2 + nH2O-> UO4·nH2O + H2O(2)的反应,并且悬浮液的pH在步骤a)和b)中保持在2和3之间的值。

    NON-DESTRUCTIVE METHOD FOR TESTING THE SEAL OF AN ELECTROLYTE OF AN ELECTROCHEMICAL CELL
    5.
    发明申请
    NON-DESTRUCTIVE METHOD FOR TESTING THE SEAL OF AN ELECTROLYTE OF AN ELECTROCHEMICAL CELL 有权
    用于测试电化学电解质密封剂的非破坏性方法

    公开(公告)号:US20130061661A1

    公开(公告)日:2013-03-14

    申请号:US13641998

    申请日:2011-04-28

    IPC分类号: G01M3/20

    摘要: A method for testing a seal of a part that includes an electrolyte of an electrochemical cell, the method including: forming a closed cavity delimited by a first outer surface of the part including the electrolyte to be tested; contacting a second outer surface of the part, opposite the first surface, with a first fluid; circulating a second fluid, separate from the first fluid, through the closed cavity between an inlet and an outlet of this cavity; and analyzing the fluid extracted via the outlet of the cavity, to detect possible presence of the first fluid.

    摘要翻译: 一种用于测试包括电化学电池的电解质的部件的密封件的方法,所述方法包括:形成由包括待测电解质的部件的第一外表面界定的封闭空腔; 使与所述第一表面相对的所述部分的第二外表面与第一流体接触; 使与所述第一流体分离的第二流体循环通过所述空腔的入口和出口之间的所述封闭空腔; 并且分析经由腔的出口提取的流体,以检测第一流体的可能存在。

    Method for converting UO3 or U3O8 into hydrated UO4
    6.
    发明授权
    Method for converting UO3 or U3O8 into hydrated UO4 有权
    将UO3或U3O8转化为水合UO4的方法

    公开(公告)号:US09045350B2

    公开(公告)日:2015-06-02

    申请号:US13995277

    申请日:2011-12-16

    摘要: A method for converting UO3 and/or U3O8 into hydrated UO4 of formula UO4.nH2O wherein n is 2 or 4, comprising the following successive steps: a) preparing an aqueous suspension of a UO3 powder and/or a U3O8 powder; b) adding hydrogen peroxide H2O2 to the aqueous suspension of a UO3 and/or U3O8 powder, converting the UO3 and/or U3O8 into hydrated UO4 and precipitating, crystallizing the hydrated UO4 in the suspension; c) recovering the precipitate, crystals of UO4 hydrate; d) optionally, washing the recovered UO4 hydrate precipitate, crystal(s); e) optionally, repeating step d); f) optionally, drying the precipitate, the crystals; wherein the addition of H2O2 to the aqueous suspension is carried out so that the suspension contains a stoichiometric excess of H2O2 relatively to the stoichiometry of the reaction from UO3: UO3+nH2O+H2O2→UO4.nH2O+H2O  (1) or of the reaction from U3O8 UO2.67+1.33H2O2+nH2O→UO4.nH2O+1.33H2O  (2), and the pH of the suspension is maintained in steps a) and b) at a value comprised between 2 and 3.

    摘要翻译: 将UO 3和/或U 3 O 8转化为式UO·4H 2 O的水合UO 4的方法,其中n为2或4,包括以下连续步骤:a)制备UO 3粉末和/或U 3 O 8粉末的水性悬浮液; b)向UO 3和/或U 3 O 8粉末的水性悬浮液中加入过氧化氢H 2 O 2,将UO 3和/或U 3 O 8转化为水合UO 4并沉淀,使悬浮液中的水合UO4结晶; c)回收沉淀物,UO4水合物晶体; d)任选地,洗涤回收的UO4水合物沉淀物,晶体; e)任选地,重复步骤d); f)任选地,干燥沉淀物,晶体; 其中向含水悬浮液中加入H 2 O 2使得悬浮液相对于来自UO 3 :OO 3 + nH 2 O + H 2 O 2→UO 4·n H 2 O + H 2 O(1)或反应的反应的化学计量比含有化学计量过量的H 2 O 2 从U3O8 UO2.67 + 1.33H2O2 + nH2O→UO4·nH2O + 1.33H2O(2),并且悬浮液的pH在步骤a)和b)中保持在2和3之间的值。

    Electrochromic element, materials for use in such element, processes for
making such element and such materials and use of such element in an
electrochromic glass device
    7.
    发明授权
    Electrochromic element, materials for use in such element, processes for making such element and such materials and use of such element in an electrochromic glass device 失效
    电致变色元件,用于这种元件的材料,制造这种元件和这种材料的方法以及这种元件在电致变色玻璃器件中的应用

    公开(公告)号:US5274493A

    公开(公告)日:1993-12-28

    申请号:US809497

    申请日:1992-03-12

    IPC分类号: G02F1/15 G02F1/01 G02B5/23

    CPC分类号: G02F1/1525 G02F1/1523

    摘要: An electrochromic element useful in an electrochromic glass or mirror device and a process for making such element. The element is a five-layered structure including an electrolyte ion conducting layer interposed between first and second inorganic electrochromic layers which are interposed between a pair of conductive electrodes. The second inorganic electrochromic layer is amorphous. The first and second inorganic electrochromic layers are different and are capable of exhibiting color-forming properties complementary to one another upon the incorporation of at least one H, Li, Na, K, Ag, Cu or Tl ion. The electrolyte ion conducting layer may be a copolymer of ethylene oxide, butylene oxide or methyl glycidyl ether, and optionally a small amount of allyl glycidyl ether, along with an ionizable salt, or may be a polyurethane gel formed by reacting the copolymer with triisocyanate, along with an ionizable salt. The second inorganic electrochromic layer comprises a transition element chalconide or halide which exhibits a color change when shifting between the +2 and +3 valence states or between the +3 and +4 valence states. The second inorganic electrochromic layer may be produced by an electrochemical process, a chemical process, a physical process or by a solid state process. The electrochromic element may also comprise a plurality of five-layer structures in tandem, each pair separated by a substrate. The electrochromic element of the invention is also useful as a supercapacitor.

    摘要翻译: PCT No.PCT / US90 / 03873 Sec。 371日期:1992年3月12日 102(e)1992年3月12日PCT PCT 1990年7月13日PCT公布。 出版物WO91 / 01510 日期1991年2月7日。用于电致变色玻璃或反射镜装置的电致变色元件和制造这种元件的方法。 该元件是包括插入在一对导电电极之间的介于第一和第二无机电致变色层之间的电解质离子传导层的五层结构。 第二无机电致变色层是无定形的。 第一和第二无机电致变色层是不同的,并且能够在引入至少一种H,Li,Na,K,Ag,Cu或Tl离子时表现出彼此互补的成色性质。 电解质离子传导层可以是环氧乙烷,环氧丁烷或甲基缩水甘油醚和任选的少量烯丙基缩水甘油醚与可电离盐的共聚物,或者可以是通过使共聚物与三异氰酸酯反应形成的聚氨酯凝胶, 以及可电离的盐。 第二无机电致变色层包括在+2和+3价态之间或在+3和+4价态之间变化时显示出颜色变化的过渡元素查洛酮或卤化物。 第二无机电致变色层可以通过电化学过程,化学过程,物理过程或固态过程来制备。 电致变色元件还可以包括串联的多个五层结构,每对由衬底隔开。 本发明的电致变色元件也可用作超级电容器。