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公开(公告)号：US20190153324A1
公开(公告)日：2019-05-23
申请号：US16301825
申请日：2017-05-23
Applicant: SHELL OIL COMPANY
Inventor： Vikrant Nanasaheb URADE , Laxmi Narasimhan CHILKOOR SOUNDARARAJAN , Madhusudhan Rao PANCHAGNULA , Alan Anthony DEL PAGGIO
IPC: C10G1/00 , C10G1/06 , C10G3/00 , B01J27/19 , B01J31/02 , B01J31/34 , B01J37/02 , B01J37/20 , B01J37/08 , C01B3/48
Abstract: A process for producing liquid hydrocarbon products from a biomass feedstock is provided. The process comprises:contacting the feedstock with one or more hydropyrolysis catalyst compositions and molecular hydrogen to produce a product stream comprising hydropyrolysis product that is at least partially deoxygenated;hydroconverting said hydropyrolysis product in the presence of one or more hydroconversion catalyst compositions to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product,wherein one or both of the hydropyrolysis catalyst composition and the hydroconversion catalyst composition is produced in a process comprising incorporating one or more metals selected from those of groups 6, 9, and 10 of the periodic table, into a shaped support; and incorporating one or more coordinating organic compounds into said shaped support, thus forming a catalyst precursor; and then either (i) treating the catalyst precursor in the presence of hydrogen and sulfiding it or (ii) calcining the catalyst precursor.
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公开(公告)号：US20170198222A1
公开(公告)日：2017-07-13
申请号：US15452912
申请日：2017-03-08
Applicant: SHELL OIL COMPANY
Inventor： Alan Anthony DEL PAGGIO , Michael John ROBERTS , Terry Louise MARKER , Larry Gordon FELIX , Martin Brendan LINCK
CPC classification number: C10B57/06 , B01D45/12 , B01J23/755 , B01J23/882 , B01J23/883 , B01J35/0026 , B01J35/026 , B01J37/0201 , B01J37/20 , C10B47/00 , C10B49/10 , C10B53/02 , C10B57/12 , C10G1/002 , C10G1/008 , C10G1/02 , C10G1/06 , C10G1/08 , C10G3/50 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10K1/024 , C10L1/023 , C10L1/026 , C10L2200/0469 , C10L2270/023 , C10L2270/026 , C10L2270/04 , C10L2290/02 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: A process for converting biomass to products is described. Biomasss is contacted with hydrogen in the presence of a fluidized bed of hydropyrolysis catalyst in a reactor vessel under hydropyrolysis conditions; and products and char are removed from the reactor vessel. The products leave the fluidized bed at an exit bed velocity, the char has a settling velocity that is less than the exit bed velocity and hydropyrolysis catalyst has a settling velocity that is greater than the exit bed velocity.
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公开(公告)号：US20170121609A1
公开(公告)日：2017-05-04
申请号：US15319058
申请日：2015-06-29
Applicant: SHELL OIL COMPANY
Inventor： Vikrant Nanasaheb URADE , Laxmi Narasimhan CHILKOOR SOUNDARARAJAN , Madhusudhan RAO PANCHAGNULA , Alan Anthony DEL PAGGIO
CPC classification number: C10G1/002 , C10G1/02 , C10G1/06 , C10G1/086 , C10G1/10 , C10G3/42 , C10G3/45 , C10G3/47 , C10G3/48 , C10G3/50 , C10G3/52 , C10G2300/1003 , C10G2300/1014 , C10G2300/202 , C10K1/004 , C10K3/04 , Y02P30/20
Abstract: The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of:a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1-C3 gases.
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公开(公告)号：US20180346823A1
公开(公告)日：2018-12-06
申请号：US15777867
申请日：2016-11-22
Applicant: SHELL OIL COMPANY
Inventor： Vikrant Nanasaheb URADE , Dhairya Dilip MEHTA , Laxmi Narasimhan CHILKOOR SOUNDARARAJAN , Alan Anthony DEL PAGGIO
Abstract: A process for producing liquid hydrocarbon products from a biomass-containing feedstock and/or a biomass-derived feedstock is provided. The process comprises: a) contacting the feedstock with a hydropyrolysis catalyst composition and molecular hydrogen in a hydropyrolysis reactor vessel to produce a product stream comprising a partially deoxygenated hydrocarbon product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; b) removing char and catalyst fines from said product stream; c) cooling the remaining product stream to a temperature in the range of from 150 to 400° C.; and d) hydroconverting said partially deoxygenated hydrocarbon product in a hydroconversion reactor in the presence of one or more catalyst compositions suitable for hydrodeoxygenation and aromatic saturation of the partially deoxygenated hydrocarbon product in the presence of H2O, CO2, CO, H2, and C1-C3 gas generated in step a), to produce a vapour phase product comprising a C4+ hydrocarbon product.
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公开(公告)号：US20180346820A1
公开(公告)日：2018-12-06
申请号：US15777856
申请日：2016-11-21
Applicant: SHELL OIL COMPANY
Inventor： Laxmi Narasimhan CHILKOOR SOUNDARARAJAN , Alan Anthony DEL PAGGIO , Dhairya Dilip MEHTA , Vikrant Nanasaheb URADE
Abstract: A process for producing liquid hydrocarbon products from a biomass-containing feedstock and/or a biomass-derived feedstock is provided. The process comprises:a) contacting the feedstock with a hydropyrolysis catalyst composition and molecular hydrogen in a hydropyrolysis reactor vessel to produce a product stream comprising a deoxygenated hydrocarbon product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines;b) removing char and catalyst fines from said product stream;c) cooling the remaining product stream to a temperature of no more than 300° C.; andd) hydroconverting all or a portion of said deoxygenated hydrocarbon product in a hydroconversion reactor in the presence of one or more catalyst compositions suitable for the aromatic saturation of the deoxygenated hydrocarbon product and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), to produce a product comprising C4+ hydrocarbon product, H2O, CO, CO2, and C1-C3 gases.
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Patent Agency Ranking
公开(公告)号：US20180298288A1
公开(公告)日：2018-10-18
申请号：US15569432
申请日：2016-04-25
Applicant: SHELL OIL COMPANY
Inventor： Vikrant Nanasaheb URADE , Alan Anthony DEL PAGGIO , Laxmi Narasimhan CHILKOOR SOUNDARARAJAN
Abstract: The present invention provides a process for producing liquid hydrocarbon products from solid biomass and/or residual waste feedstocks, said process comprising the steps of: a) a first stage of hydropyrolysing the solid feedstock in a hydropyrolysis reactor vessel in the presence of molecular hydrogen and one or more deoxygenation catalysts, producing a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; b) removing said char and catalyst fines from said product stream; c) a second stage of hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalysts and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), producing a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1-C3 gases; d) condensing the vapour phase product of step d) to 20 provide a liquid phase product comprising substantially fully deoxygenated C4+ hydrocarbon liquid and aqueous material and separating said liquid phase product from a gas phase product comprising H2, CO, CO2, and C1-C3 gases; e) removing the aqueous material from the substantially fully deoxygenated C4+ hydrocarbon liquid; and f) a third stage comprising combining an aliphatic hydrocarbon precursor or an aromatic hydrocarbon precursor with at least a portion of the substantially fully deoxygenated C4+ hydrocarbon liquid and co-processing the resultant liquid in a hydroprocessing reactor vessel in the presence of hydrogen and one or more hydroprocessing catalysts.
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公开(公告)号：US20180193823A1
公开(公告)日：2018-07-12
申请号：US15913458
申请日：2018-03-06
Applicant: SHELL OIL COMPANY
Inventor： Larry Gordon FELIX , Lawrence Stephen KRAUS , Martin Brendan LINCK , Terry Louise MARKER , Celeste Jean MCLEOD , Alan Anthony DEL PAGGIO , Michael John ROBERTS
IPC: B01J23/883 , C10G1/10 , B01J23/94 , B01J35/00 , C10G1/08 , C10G1/00 , B01J38/72 , B01J37/02 , B01J35/08 , B01J35/02
CPC classification number: B01J23/883 , B01J23/94 , B01J35/0026 , B01J35/0073 , B01J35/008 , B01J35/023 , B01J35/08 , B01J37/0201 , B01J37/0205 , B01J37/0213 , B01J38/72 , C10G1/002 , C10G1/086 , C10G1/10 , C10G2300/1011 , Y02P30/20
Abstract: A hydropyrolysis catalyst and a process using that catalyst are described. The catalyst comprises a support and an active metal component wherein the catalyst is an eggshell type catalyst having the active metal component located in the outer portion of the support.
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公开(公告)号：US20190169508A1
公开(公告)日：2019-06-06
申请号：US16322301
申请日：2017-08-02
Applicant: SHELL OIL COMPANY
Inventor： Vikrant Nanasaheb URADE , Laxmi Narasimhan CHILKOOR SOUNDARARAJAN , Alan Anthony DEL PAGGIO , Srikant GOPAL , Prakhar ARORA
Abstract: The present invention provides a process for producing liquid hydrocarbon products from a feedstock comprising at least one of a solid biomass-containing feedstock and a solid biomass-derived feedstock and in the range of from 50 to 15000 ppmw of chlorides, said process comprising the steps of: a) incorporating a chloride trap material into said feedstock to provide a combined feedstock/chloride trap material; b) densifying the combined feedstock/chloride trap material to form densified feed in the form of pellets or briquettes; c) contacting said densified feed with a hydropyrolysis catalyst composition and molecular hydrogen in a hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600° C. and a pressure in the range of from 0.50 to 7.50 MPa to produce a product stream comprising a deoxygenated hydrocarbon product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; and d) removing all or a portion of said char and catalyst fines from said product stream.
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公开(公告)号：US20170114283A1
公开(公告)日：2017-04-27
申请号：US15319040
申请日：2015-06-29
Applicant: SHELL OIL COMPANY
Inventor： Vikrant Nanasaheb URADE , Laxmi Narasimhan CHILKOOR SOUNDARARAJAN , Srikant GOPAL , Madhusudhan Rao PANCHAGNULA , Alan Anthony DEL PAGGIO
CPC classification number: C10G1/002 , C10G1/06 , C10G1/086 , C10G1/10 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/48 , C10G3/50 , C10G3/52 , C10G2300/1003 , C10G2300/1011 , C10G2300/1014 , C10K1/002 , C10K1/004 , C10K3/04 , Y02P30/20
Abstract: The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1-C3 gases.
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公开(公告)号：US20150337216A1
公开(公告)日：2015-11-26
申请号：US14758638
申请日：2013-12-19
Applicant: SHELL OIL COMPANY
Inventor： Vikrant Nanasaheb URADE , Alan Anthony DEL PAGGIO , Laxmi Narasimhan CHILKOOR SOUNDARARAJAN , Madhusudhan Rao PANCHAGNULA
CPC classification number: C10G3/47 , C10G3/48 , C10G3/49 , C10G3/50 , C10G3/52 , C10G29/205 , C10G29/22 , C10G49/08 , C10G65/02 , C10G2300/1011 , C10L1/04 , C10L2200/0469 , Y02P30/20
Abstract: A process for converting one or more C3-C12 oxygenates comprising:1) contacting a feed comprising C3-C12 oxygenates with hydrogen in the presence of a sulphided hydrogenation catalyst to produce a partially hydrogenated effluent; 2) contacting the partially hydrogenated effluent with hydrogen at a hydrogen partial pressure of at least 0.1 MegaPascal in the presence of a sulphided carbon-carbon coupling catalyst to produce a conversion product; 3) optionally contacting at least part of the conversion product with hydrogen in the presence of a sulphided hydrotreating catalyst and/or a sulphided hydroisomerization catalyst to produce a conversion product; and 4) optionally purifying the conversion product, optionally hydrotreated and/or hydroisomerized, conversion product to obtain a final product, wherein the carbon-carbon coupling catalyst comprises at least 60 wt % of a zeolite and in the range from 0.1 wt % to 10 wt % of a hydrogenation metal, based on the total weight of the carbon-carbon coupling catalyst.
Abstract translation: 一种用于转化一种或多种C 3 -C 12含氧化合物的方法，包括：1）在硫化氢化催化剂存在下使包含C 3 -C 12含氧化合物的进料与氢接触以产生部分氢化的流出物; 2）在硫化碳 - 碳偶联催化剂存在下，使部分氢化的流出物与氢气分压至少为0.1兆帕，使其产生转化产物; 3）任选地在硫化加氢处理催化剂和/或硫化加氢异构化催化剂存在下将至少部分转化产物与氢气接触以产生转化产物; 和4）任选地纯化转化产物，任选地加氢处理和/或加氢异构化的转化产物以获得最终产物，其中碳 - 碳偶联催化剂包含至少60重量％的沸石，并且在0.1重量％至10重量％的范围内 重量％的氢化金属，基于碳 - 碳偶联催化剂的总重量。
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