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公开(公告)号：US20170306249A1
公开(公告)日：2017-10-26
申请号：US15495082
申请日：2017-04-24
Applicant: SHELL OIL COMPANY
Inventor： Josiane Marie-Rose GINESTRA
IPC: C10G65/00 , B01J35/02 , B01J23/883 , B01J27/19
Abstract: An improved method of operating a conventional ebullated bed process for the hydroconversion of heavy hydrocarbon feedstocks so as to provide for low or reduced sediment content in the conversion product without the loss of hydrodesulfurization function.
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2.发明申请HIGH SURFACE AREA COMPOSITION FOR USE IN THE CATALYTIC HYDROCONVERSION OF A HEAVY HYDROCARBON FEEDSTOCK, A METHOD MAKING SUCH COMPOSITION AND ITS USE 有权高表面积组合物用于重油加氢催化剂的催化降解，制备这种组合物的方法及其用途公开(公告)号：US20140183099A1
公开(公告)日：2014-07-03
申请号：US14197292
申请日：2014-03-05
Applicant: SHELL OIL COMPANY
Inventor： Josiane Marie-Rose GINESTRA , John George KESTER , David Andrew KOMAR , David Edward SHERWOOD, JR.
IPC: B01J23/883 , C10G47/04
CPC classification number: B01J23/883 , B01J27/19 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108 , B01J37/0009 , B01J37/08 , C10G45/60 , C10G47/04 , C10G47/12 , C10G2300/70
Abstract: A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment.
Abstract translation: 一种催化剂组合物，其特别可用于重烃原料的沥青，微碳残余物和硫含量的加氢转化，而不会过度沉积。 催化剂组合物是含有氧化铝和低钼含量的相当高的表面积组成，具有高的镍 - 钼比例。 催化剂组合物还具有独特的孔分布，其结合特殊金属负载提供沥青和微碳残余物的良好转化而不产生过多的沉淀物。
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公开(公告)号：US20250135439A1
公开(公告)日：2025-05-01
申请号：US18835647
申请日：2022-02-18
Applicant: SHELL OIL COMPANY
Inventor： Josiane Marie-Rose GINESTRA , Ke-Wei HUANG , David Anthony Grisafe , Sarah SCHIMMING , Cornelius Mark BOLINGER
Abstract: Prior to reaction in an isomerization unit, the feed may be purified by contact with a composition comprising an alumina based catalyst including Group I or Group II cations or combinations thereof in a range from about 0 wt % to about 20 wt % Group I or Group II cations. In some embodiments, the alumina based catalyst has one or more of the following properties; pore volume in pores of less than 70 Å pore diameter of less than about 15% of Total Pore Volume: a pore volume in pores of greater than 350 Å pore diameter of less than 10% of Total Pore Volume; a median pore diameter by volume of less than 120 Å; a water pore volume of less than 1.10 cc/g;: and a surface area of greater than 160 m2/g.
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公开(公告)号：US20200055033A1
公开(公告)日：2020-02-20
申请号：US16663744
申请日：2019-10-25
Applicant: SHELL OIL COMPANY
Abstract: An improved process for the hydroconversion of micro carbon residue content of heavy hydrocarbon feedstocks by the use of a catalyst composition that is especially useful in the conversion of micro carbon residue of such feedstocks. The catalyst composition is a low surface area composition that further has a specifically define pore structure the combination of which provides for its enhance micro carbon residue conversion property.
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公开(公告)号：US20140330057A1
公开(公告)日：2014-11-06
申请号：US14265411
申请日：2014-04-30
Applicant: SHELL OIL COMPANY
Inventor： Ivo Johannes DIJS , Arjen NIEUWHOF , Johannes Pieter HAAN , Josiane Marie-Rose GINESTRA , Jozef Jacobus Titus SMITS , Colin John SCHAVERIEN , Leticia ESPINOSA ALONSO , Wouter SPIERING
IPC: C10G1/04
CPC classification number: C10G1/045 , C10B53/02 , C10G33/00 , C10G47/00 , C10G47/24 , C10G47/26 , C10G47/28 , C10L1/02 , Y02E50/14
Abstract: A process for converting a biomass material comprising a) pyrolyzing a biomass material to produce a biomass-derived pyrolysis product; b) mixing at least part of the biomass-derived pyrolysis product and a petroleum-derived hydrocarbon composition, which petroleum derived hydrocarbon composition has a C7-asphaltenes content of equal to or more than 0.2 wt %, based on the total weight of the petroleum-derived hydrocarbon composition, to produce a hydrocarbon-containing mixture; c) dewatering the hydrocarbon-containing mixture to produce a dewatered hydrocarbon-containing mixture; d) contacting the dewatered hydrocarbon-containing mixture with hydrogen in one or more ebullating bed reactors comprising a catalyst at a temperature in the range from 350 to 500° C. to produce a reaction product.
Abstract translation: 一种用于转化生物质材料的方法，包括a）热解生物质材料以产生生物质衍生的热解产物; b）将至少部分生物质衍生的热解产物和石油衍生的烃组合物混合，所述石油衍生的烃组合物具有基于石油的总重量等于或大于0.2重量％的C7-沥青质含量 得到的含烃混合物; c）使含烃混合物脱水以产生脱水的含烃混合物; d）使脱水的含烃混合物与氢在一个或多个沸腾床反应器中接触，所述反应床包含催化剂，温度为350-500℃，以产生反应产物。
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Patent Agency Ranking
6.发明申请公开(公告)号：US20170306250A1
公开(公告)日：2017-10-26
申请号：US15495129
申请日：2017-04-24
Applicant: SHELL OIL COMPANY
Inventor： Josiane Marie-Rose GINESTRA
Abstract: An ebullated bed process for the hydroconversion of heavy hydrocarbon feedstocks that provides for high conversion of the heavy hydrocarbon with a low sediment yield. The process uses for its catalyst bed an impregnated shaped ebullated bed catalyst having a low macroporosity and a geometry such that its characteristic cross section perimeter-to-cross sectional area is within a specifically defined range.
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7.发明申请公开(公告)号：US20170306248A1
公开(公告)日：2017-10-26
申请号：US15494964
申请日：2017-04-24
Applicant: SHELL OIL COMPANY
Inventor： Josiane Marie-Rose GINESTRA
Abstract: An ebullated bed process for the hydroconversion of heavy hydrocarbon feedstocks that provides for high conversion of the heavy hydrocarbon with a low sediment yield. The process uses for its catalyst bed small particles of a specifically defined shaped hydroprocessing catalyst which is contacted with the heavy hydrocarbon feedstock under hydroconversion conditions and yields a hydrocarbon conversion having a relatively low sediment content.
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8.发明申请HYDROPROCESSING CATALYST FOR TREATING A HYDROCARBON FEED HAVING AN ARSENIC CONCENTRATION AND A METHOD OF MAKING AND USING SUCH CATALYST 审中-公开用于处理具有浓度浓度的油料进料的氢化催化剂和制备和使用这种催化剂的方法公开(公告)号：US20160008795A1
公开(公告)日：2016-01-14
申请号：US14797447
申请日：2015-07-13
Applicant: SHELL OIL COMPANY
Inventor： Josiane Marie-Rose GINESTRA
CPC classification number: B01J27/19 , B01J21/04 , B01J35/0006 , B01J35/002 , B01J35/0073 , B01J35/026 , B01J37/0072 , B01J37/024 , B01J37/0242 , B01J37/088 , C10G45/08 , C10G65/04
Abstract: A catalyst that is useful for the removal of arsenic from hydrocarbon feedstocks. The catalyst comprises an alumina support, underbedded molybdenum and phosphorus components, and an overlayer of a nickel component. The catalyst further has the unique property of having a surface nickel-to-molybdenum atomic ratio of greater than 1.8 with a bulk nickel-to-molybdenum atomic ratio of less than 2.2. The nickel accessibility factor of the catalyst is greater than 1.2. The catalyst is prepared by the application of two metals impregnation steps with associated calcination steps that in combination provide for the underbedded metals and overlayer of nickel.
Abstract translation: 可用于从烃原料中除去砷的催化剂。 催化剂包括氧化铝载体，嵌入的钼和磷组分以及镍组分的覆层。 催化剂还具有独特的性能，其具有大于1.8的表面镍 - 钼原子比，体积镍 - 钼原子比小于2.2。 催化剂的镍可利用因子大于1.2。 通过应用两个金属浸渍步骤制备催化剂，所述浸渍步骤具有相关的煅烧步骤，其组合提供了嵌入的金属和镍的覆盖层。
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公开(公告)号：US20140343333A1
公开(公告)日：2014-11-20
申请号：US14277834
申请日：2014-05-15
Applicant: Shell Oil Company
IPC: C10G1/00
CPC classification number: C10G1/002 , C10G1/065 , C10G1/083 , C10G3/42 , C10G3/50 , C10G3/55 , C10G65/12 , C10G2300/1011 , C10G2300/1014 , C10G2300/1096 , C10G2300/206 , C10G2400/04 , C10G2400/06 , C10L1/023 , C10L1/026 , Y02P30/20
Abstract: A process for converting a solid biomass material comprising: a) providing a solid biomass material; b) contacting a feed comprising the solid biomass material and a petroleum-derived hydrocarbon composition, which petroleum derived hydrocarbon composition has a C7-asphaltenes content of equal to or more than 1.0 wt %, based on the total weight of the petroleum-derived hydrocarbon composition, co-currently with a source of hydrogen in one or more ebullating bed reactors comprising a catalyst at a temperature in the range from 350° C. to 500° C. to produce a reaction product.
Abstract translation: 一种用于转化固体生物质材料的方法，包括：a）提供固体生物质材料; b）将包含固体生物质材料的原料和石油衍生的烃组合物接触，所述石油衍生的烃组合物具有等于或大于1.0重量％的C7-沥青质含量，基于石油衍生的烃的总重量 组合物，在一个或多个沸腾床反应器中共同存在氢气源，其包含在350℃至500℃的温度范围内的催化剂以产生反应产物。
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10.发明申请HIGH SURFACE AREA COMPOSITION FOR USE IN THE CATALYTIC HYDROCONVERSION OF A HEAVY HYDROCARBON FEEDSTOCK, A METHOD MAKING SUCH COMPOSITION AND ITS USE 有权高表面积组合物用于重油加氢催化剂的催化降解，制备这种组合物的方法及其用途公开(公告)号：US20130126393A1
公开(公告)日：2013-05-23
申请号：US13718679
申请日：2012-12-18
Applicant: SHELL OIL COMPANY
Inventor： Josiane Marie-Rose GINESTRA , John George KESTER , David Andrew KOMAR , David Edward SHERWOOD, Jr.
IPC: B01J23/883 , C10G47/04
CPC classification number: B01J23/883 , B01J27/19 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108 , B01J37/0009 , B01J37/08 , C10G45/60 , C10G47/04 , C10G47/12 , C10G2300/70
Abstract: A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment.
Abstract translation: 一种催化剂组合物，其特别可用于重烃原料的沥青，微碳残余物和硫含量的加氢转化，而不会过度沉积。 催化剂组合物是含有氧化铝和低钼含量的相当高的表面积组成，具有高的镍 - 钼比例。 催化剂组合物还具有独特的孔分布，其结合特殊金属负载提供沥青和微碳残余物的良好转化而不产生过多的沉淀物。
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