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1.发明授权Selenium-containing hydroprocessing catalyst, its use, and method of preparation 有权含硒加氢催化剂，其用途和制备方法公开(公告)号：US09227179B2
公开(公告)日：2016-01-05
申请号：US13849829
申请日：2013-03-25
Applicant: SHELL OIL COMPANY
Inventor： Karl Marvin Krueger , Puneet Gupta
IPC: B01J27/057 , B01J27/19 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/188 , B01J37/02 , C10G45/08 , B01J27/02
CPC classification number: B01J27/0573 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/188 , B01J27/19 , B01J37/0201 , B01J37/0207 , C10G45/08
Abstract: A hydroprocessing catalyst composition that comprises a support material and a selenium component and which support material further includes at least one hydrogenation metal component. The hydroprocessing catalyst is prepared by incorporating a selenium component into a support particle and, after calcination thereof, incorporating at least one hydrogenation metal component into the selenium-containing support. The metal-incorporated, selenium-containing support is calcined to provide the hydroprocessing catalyst composition.
Abstract translation: 一种加氢处理催化剂组合物，其包括载体材料和硒组分，并且所述载体材料还包含至少一种氢化金属组分。 加氢处理催化剂通过将硒组分掺入载体颗粒中并在其煅烧之后将至少一种氢化金属组分并入含硒载体中来制备。 将含金属的含硒载体煅烧以提供加氢处理催化剂组合物。
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公开(公告)号：US11517891B2
公开(公告)日：2022-12-06
申请号：US17071731
申请日：2020-10-15
Applicant: SHELL OIL COMPANY
Inventor： Alexei Grigorievich Gabrielov , Karl Marvin Krueger
Abstract: A highly active hydroprocessing catalyst that comprises an inorganic oxide support particle having been impregnated with a metals-impregnation solution comprising a complexing agent and a hydrogenation metal that is further incorporated with an organic additive blend.
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公开(公告)号：US09724677B2
公开(公告)日：2017-08-08
申请号：US14944297
申请日：2015-11-18
Applicant: SHELL OIL COMPANY
Inventor： Karl Marvin Krueger , Puneet Gupta
IPC: B01J27/02 , B01J27/057 , B01J27/19 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/188 , B01J37/02 , C10G45/08
CPC classification number: B01J27/0573 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/188 , B01J27/19 , B01J37/0201 , B01J37/0207 , C10G45/08
Abstract: A hydroprocessing catalyst composition that comprises a support material and a selenium component and which support material further includes at least one hydrogenation metal component. The hydroprocessing catalyst is prepared by incorporating a selenium component into a support particle and, after calcination thereof, incorporating at least one hydrogenation metal component into the selenium-containing support. The metal-incorporated, selenium-containing support is calcined to provide the hydroprocessing catalyst composition.
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公开(公告)号：US11673124B2
公开(公告)日：2023-06-13
申请号：US16736917
申请日：2020-01-08
Applicant: SHELL OIL COMPANY
Inventor： Karl Marvin Krueger , Fernando Gabriel Maldonado
CPC classification number: B01J23/882 , B01D53/8603 , B01J35/108 , B01J35/109 , B01J35/1061 , B01J35/1066 , B01J35/1071 , B01J35/1076 , B01J37/0009 , B01J37/04 , B01J37/08 , B01D2255/2092 , B01D2255/20746 , B01D2255/20769 , B01D2255/92
Abstract: Disclosed is a composition useful in the hydrolysis of sulfur compounds that are contained in a gas stream. The composition comprises a calcined co-mulled mixture of psuedoboehmite, a cobalt compound, and a molybdenum compound such that the composition comprises gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt. The composition is made by forming into an agglomerate a co-mulled mixture pseudoboehmite, a cobalt component, and a molybdenum component followed by drying and calcining the agglomerate to provide a catalyst composition comprising gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt.
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Patent Agency Ranking
公开(公告)号：US11534747B2
公开(公告)日：2022-12-27
申请号：US17071769
申请日：2020-10-15
Applicant: SHELL OIL COMPANY
Inventor： Alexei Grigorievich Gabrielov , Karl Marvin Krueger
IPC: B01J37/02 , B01J21/04 , B01J23/75 , B01J23/755 , C10G45/08
Abstract: A highly active hydroprocessing catalyst that comprises a doped support having been impregnated with a metal-impregnation solution, comprising a complexing agent and a hydrogenation metal, and filled with an organic additive blend. The catalyst is made by providing a doped support particle followed by impregnating the doped support particle with a metal impregnation solution that contains both a hydrogenation metal component and a complexing agent component to provide a metal-impregnated doped support particle. The metal-impregnated doped support particle is dried, but not calcined, and impregnated with an organic additive blend component.
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6.发明授权Low-pressure process utilizing a stacked-bed system of specific catalysts for the hydrotreating of a gas oil feedstock 有权使用特定催化剂的层压床系统进行瓦斯油原料的加氢处理的低压方法公开(公告)号：US09404053B2
公开(公告)日：2016-08-02
申请号：US14248420
申请日：2014-04-09
Applicant: SHELL OIL COMPANY
Inventor： Lawrence Stephen Kraus , John Anthony Smegal , Karl Marvin Krueger
Abstract: A low-pressure process for hydrodenitrogenation and hydrodesulfurization of a gas oil feedstock. The process uses a multi-bed, stacked-bed reactor system. The first and third beds of the multi-bed, stacked-bed reactor system include catalysts that comprise cobalt and molybdenum supported on alumina. The middle, second bed, includes a catalyst comprising nickel and molybdenum supported on alumina that preferably includes an additive. The stacked bed arrangement with the use of the specific catalysts provides for the low-pressure operation and significantly improved HDN and HDS activity with relatively insignificant differences in hydrogen consumption.
Abstract translation: 用于瓦斯油原料加氢脱氮和加氢脱硫的低压方法。 该方法使用多床，堆叠床反应器系统。 多床堆叠床反应器系统的第一和第三床包括负载在氧化铝上的包含钴和钼的催化剂。 中间和第二床包括负载在氧化铝上的包含镍和钼的催化剂，其优选包括添加剂。 使用特定催化剂的堆叠床布置提供了低压操作并且显着改善了HDN和HDS活性，而氢消耗具有相当小的差异。
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公开(公告)号：US11819829B2
公开(公告)日：2023-11-21
申请号：US17378039
申请日：2021-07-16
Applicant: SHELL OIL COMPANY
Inventor： Karl Marvin Krueger
IPC: B01J23/882 , B01D53/86 , B01J6/00 , B01J37/02 , B01J37/08
CPC classification number: B01J23/882 , B01D53/8606 , B01D53/8609 , B01J6/001 , B01J37/0201 , B01J37/0215 , B01J37/08
Abstract: Presented is a catalyst composition having exceptional properties for converting sulfur, sulfur compounds, and carbon monoxide contained in gas streams by catalyzed hydrolysis, hydrogenation and water-gas shift reactions. The catalyst comprises underbedded molybdenum and cobalt with an overlayer of molybdenum and cobalt. These metals are present in the catalyst within certain concentration ranges and relative weight ratios. The underbedded metals are present in the catalyst within a specified range relative to the overlayer and total metals. The underbedded metals are formed by co-mulling an inorganic oxide with the catalytically active metals of molybdenum and cobalt. The co-mulled mixture is calcined and then impregnated with overlaid molybdenum and cobalt.
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公开(公告)号：US10562014B2
公开(公告)日：2020-02-18
申请号：US15464499
申请日：2017-03-21
Applicant: SHELL OIL COMPANY
Inventor： Karl Marvin Krueger , Fernando Gabriel Maldonado
Abstract: Disclosed is a composition useful in the hydrolysis of sulfur compounds that are contained in a gas stream. The composition comprises a calcined co-mulled mixture of psuedoboehmite, a cobalt compound, and a molybdenum compound such that the composition comprises gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt. The composition is made by forming into an agglomerate a co-mulled mixture pseudoboehmite, a cobalt component, and a molybdenum component followed by drying and calcining the agglomerate to provide a catalyst composition comprising gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt.
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9.发明授权公开(公告)号：US09546327B2
公开(公告)日：2017-01-17
申请号：US14248391
申请日：2014-04-09
Applicant: SHELL OIL COMPANY
Inventor： Lawrence Stephen Kraus , John Anthony Smegal , Karl Marvin Krueger
IPC: C10G45/08
CPC classification number: C10G45/08 , C10G2300/202 , C10G2300/301
Abstract: A process and catalyst that provides for the upgrading of a high endpoint gas oil feedstock that contains significant concentrations of organic sulfur compound and organic nitrogen compounds. Included among the sulfur compounds are the dimethyl-dibenzothiophenes and derivative thereof. The catalyst of the process is an additive impregnated composition or a derivative thereof that further comprises cobalt and molybdenum. The process provides for the upgrading the high endpoint gas oil feedstock by significantly reducing the difficult to remove thiophene and nitrogen compounds and the process does this with a significantly reduced hydrogen consumption relative to processes using comparative catalysts.
Abstract translation: 提供含有显着浓度的有机硫化合物和有机氮化合物的高终点瓦斯油原料升级的方法和催化剂。 硫化合物中包括二甲基 - 二苯并噻吩及其衍生物。 该方法的催化剂是进一步包含钴和钼的添加剂浸渍组合物或其衍生物。 该方法提供了通过显着减少难以除去噻吩和氮化合物来升级高端点瓦斯油原料，并且该方法相对于使用比较催化剂的方法显着降低了氢消耗。
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