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103 条记录 (耗时 0.063 秒)

    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS
    7.
    发明申请
    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS 失效
    从分散式异构体中分离出未结合的烃类的方法

    公开(公告)号：US20100197990A1

    公开(公告)日：2010-08-05

    申请号：US12668436

    申请日：2008-06-30

    申请人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    发明人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    IPC分类号： C07C7/12

    CPC分类号： C07C7/12 ,  B01J20/22 ,  B01J20/226 ,  B01J2220/56 ,  C07C7/135 ,  C10G25/003 ,  C07C9/00

    摘要： The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of—contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    摘要翻译： 本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法，其包括使流体混合物与 吸附剂，其包含多孔金属有机骨架材料，该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物，以获得非支化烃被吸附，其中至少一种至少二齿有机化合物是单环， 衍生自选自吡咯，α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统，并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基： 的卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，Ophenyl和OCi-6-alk 其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH， 苯基和OC 1-6烷基。 本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。

    PROCESS FOR PREPARING POROUS METAL ORGANIC FRAMEWORKS
    8.
    发明申请
    PROCESS FOR PREPARING POROUS METAL ORGANIC FRAMEWORKS 有权
    制备多孔金属有机框架的方法

    公开(公告)号：US20090171107A1

    公开(公告)日：2009-07-02

    申请号：US12300902

    申请日：2007-05-11

    申请人： Hermann Pütter ,  Markus Schubert ,  Ingo Richter ,  Ulrich Müller ,  Natalia Trukhan

    发明人： Hermann Pütter ,  Markus Schubert ,  Ingo Richter ,  Ulrich Müller ,  Natalia Trukhan

    IPC分类号： C07F1/08

    CPC分类号： C25B3/12

    摘要： The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

    摘要翻译： 本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种金属离子配位的至少两种有机化合物，其包括以下步骤：（a）至少一个阳极的氧化，所述至少一个阳极包含对应于至少一种金属 在至少一种第一有机化合物存在下的反应介质中，所述第一有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳已经被选自N，O 和S形成包含所述至少一种金属离子和所述第一有机化合物的反应中间体; 和（b）将反应中间体在规定温度下与至少一种与至少一种金属离子配位的第二有机化合物反应，第二有机化合物衍生自二羧酸，三羧酸或四羧酸。