公开(公告)号：US07214742B2

公开(公告)日：2007-05-08

申请号：US10497297

申请日：2002-11-21

申请人： Thomas Bolle ,  Andreas Valet ,  David George Leppard ,  Stephen Mark Andrews ,  Ramanathan Ravichandran ,  Markus Grob ,  Dirk Simon

发明人： Thomas Bolle ,  Andreas Valet ,  David George Leppard ,  Stephen Mark Andrews ,  Ramanathan Ravichandran ,  Markus Grob ,  Dirk Simon

IPC分类号： C08K5/3492 ,  C07D251/24

CPC分类号： C08F8/30 ,  C07D251/24 ,  C08F291/00 ,  C08K5/3492 ,  C08F222/1006

摘要： Compounds of the general formula I′ in which R1 is H, C1–C12alkyl; C5–C12cycloalkyl; C2–C18alkyl which is interrupted by one or more O; SR4; OR5; or is a group of formula II or III R2, R21 and R3 independently of one another, are H or —Y—T as defined in claim 1, where T is a reactive group selected from OH, acryl- and methacryloxy and arylcarbonate groups, and further symbols are as defined in claim 1, are effective as crosslinking agents for polymeric networks, especially as in flexographic printing plates, coatings, and plastic containers or films. Further provided is a method of protecting the content of a clear or lightly colored plastic container or film against the deleterious effects of ultraviolet radiation, which method comprises permanently and covalently bonding one or more UV absorbing moieties of a durable s-triazine UV absorber via condensation to a suitable polymer component.

摘要翻译： 其中R 1是H，C 1 -C 12烷基的通式I'的化合物; C 5 -C 12环烷基; 被一个或多个O中断的C 2 -C 18烷基; SR 4; 或5

公开(公告)号：US20050075465A1

公开(公告)日：2005-04-07

申请号：US10497297

申请日：2002-11-21

申请人： Thomas Bolle ,  Andreas Valet ,  David Leppard ,  Stephen Andrews ,  Ramanathan Ravichandran ,  Markus Grob ,  Dirk Simon

发明人： Thomas Bolle ,  Andreas Valet ,  David Leppard ,  Stephen Andrews ,  Ramanathan Ravichandran ,  Markus Grob ,  Dirk Simon

IPC分类号： C07D251/24 ,  C08F8/30 ,  C08F291/00 ,  C08K5/3492 ,  C08L101/00 ,  C07D201/00 ,  C08F20/00 ,  C09K3/00

CPC分类号： C08F8/30 ,  C07D251/24 ,  C08F291/00 ,  C08K5/3492 ,  C08F222/1006

摘要： Compounds of the general formula I′ in which R1 is H, C1-C12alkyl; C5-C12cycloalkyl; C2-C18alkyl which is interrupted by one or more O; SR4; OR5; or is a group of formula II or III R2, R21 and R3 independently of one another, are H or —Y-T as defined in claim 1, where T is a reactive group selected from OH, acryl- and methacryloxy and arylcarbonate groups, and further symbols are as defined in claim 1, are effective as crosslinking agents for polymeric networks, especially as in flexographic printing plates, coatings, and plastic containers or films. Further provided is a method of protecting the content of a clear or lightly colored plastic container or film against the deleterious effects of ultraviolet radiation, which method comprises permanently and covalently bonding one or more UV absorbing moieties of a durable s-triazine UV absorber via condensation to a suitable polymer component.

摘要翻译： 通式I'的化合物，其中R 1是H，C 1 -C 12烷基; C5-C12环烷基; 被一个或多个O中断的C 2 -C 18烷基; SR4; OR5; 或者是式II或III中的R 2，R 21和R 3彼此独立的基团是如权利要求1所定义的H或-YT，其中T是选自OH，丙烯酰基和甲基丙烯酰氧基和芳基碳酸酯基的反应性基团， 符号如权利要求1中所定义，可用作聚合物网络的交联剂，特别是在柔性版印刷版，涂料和塑料容器或薄膜中。 进一步提供了一种保护透明或浅色塑料容器或薄膜的含量以抵抗紫外线辐射的有害影响的方法，该方法包括通过冷凝物永久地和共价键合耐久的三嗪UV吸收剂的一个或多个UV吸收部分 到合适的聚合物组分。

公开(公告)号：US20050171253A1

公开(公告)日：2005-08-04

申请号：US10504278

申请日：2003-02-11

申请人： Stephen Andrews ,  Joseph Suhadolnik ,  Mervin Wood ,  Ramanathan Ravichandran ,  Dirk Simon

发明人： Stephen Andrews ,  Joseph Suhadolnik ,  Mervin Wood ,  Ramanathan Ravichandran ,  Dirk Simon

IPC分类号： B65D1/00 ,  B32B27/00 ,  B32B27/18 ,  B65D81/30 ,  C07D251/24 ,  C08F8/30 ,  C08G85/00 ,  C08J3/22 ,  C08K5/34 ,  C08K5/3492

CPC分类号： C08F8/30 ,  C07D251/24 ,  C08K5/3475 ,  C08K5/3492

摘要： The contents of clear or lightly colored plastic containers or films are protected from ultraviolet radiation by the incorporation of certain UV absorbers of the class of reactable, durable hydroxyphenylbenzotriazoles in the container or film. The hydroxyphenylbenzotriazoles are reacted into the containers or films via condensation reaction and are thereby covalently bonded therein. Contents to be protected include foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like.

摘要翻译： 透明或浅色的塑料容器或薄膜的内容物通过将一类可反应的，耐久的羟基苯基苯并三唑的某些UV吸收剂掺入容器或膜中而免受紫外线照射。 羟苯基苯并三唑通过缩合反应反应成容器或膜，由此共价结合。 要保护的内容包括食品，饮料，药品，化妆品，个人护理产品，洗发剂等。

公开(公告)号：US07514526B2

公开(公告)日：2009-04-07

申请号：US11348664

申请日：2006-02-07

申请人： Dirk Simon ,  Dario Lazzari ,  Stephen Mark Andrews ,  Heinz Herbst

发明人： Dirk Simon ,  Dario Lazzari ,  Stephen Mark Andrews ,  Heinz Herbst

IPC分类号： C08G63/02 ,  C08G63/16 ,  C08G63/18 ,  C08G63/44 ,  C08G63/68 ,  C08G69/00 ,  C08G18/42 ,  C08G18/48

CPC分类号： C08K5/0008 ,  C08G63/20 ,  C08L67/02 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L33/00

摘要： The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide, an anionic acrylic polymer or a cationic acrylamide copolymer; or (e) a hydroxylamine and/or a nitrone. Such polyesters, for example PET, when extrusion compounded exhibit a lower residual acetaldehyde content than does PET alone when similarly treated. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, pharmaceuticals, beverages and most especially water.

摘要翻译： 本发明公开了一种制备稳定的聚酯的方法，所述聚酯的生成量低，其包括在酯化过程中使一种或多种二酸与一种或多种二醇反应，和/或一种或多种二酯与一种或多种二醇 在有效量的选自以下的稳定剂的酯交换过程中：（a）多元醇，例如聚（乙烯 - 共 - 乙烯醇），聚（苯乙烯 - 共 - 烯丙醇）， 麦芽糖醇，异麦芽酮糖醇，山梨糖醇，木糖醇，蔗糖，粘酸二丁酯，粘酸二（苯基-1-乙基）酯，季戊四醇或二季戊四醇; （b）式II化合物，其为例如二异辛基次膦酸; （c）空间位阻胺，例如Tinuvin 123或Tinuvin 622; （d）聚丙烯酰胺，阴离子丙烯酸类聚合物或阳离子丙烯酰胺共聚物; 或（e）羟胺和/或硝酮。 当类似处理时，当挤出复合时，这种聚酯，例如PET显示出比单独的PET更低的残留乙醛含量。 本发明涉及用于制造瓶子或容器的任何聚酯，其又用于储存消费材料，特别是食品，药物，饮料，特别是水。

公开(公告)号：US07205379B2

公开(公告)日：2007-04-17

申请号：US10472789

申请日：2002-03-19

申请人： Dirk Simon ,  Dari Lazzari ,  Stephen Mark Andrews ,  Heinz Herbst

发明人： Dirk Simon ,  Dari Lazzari ,  Stephen Mark Andrews ,  Heinz Herbst

IPC分类号： C08G63/16 ,  C08G66/00 ,  C08G66/68 ,  C08G79/02 ,  B29D22/00 ,  B29D23/00 ,  B32B1/00 ,  B32B27/00

CPC分类号： C08K5/0008 ,  C08G63/20 ,  C08L67/02 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L33/00

摘要： The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II, which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide or a cationic acrylamide copolymer; or (e) a hydroxyamine and/or a nitrone. Such polyesters, for example PET, when extrusion compounded exhibit a lower residual acetaldehyde content than does PET alone when similarly treated. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, pharmaceuticals, beverages and most especially water

摘要翻译： 本发明公开了一种制备稳定的聚酯的方法，所述聚酯的生成量低，其包括在酯化过程中使一种或多种二酸与一种或多种二醇反应，和/或一种或多种二酯与一种或多种二醇 在有效量的选自以下的稳定剂的酯交换过程中：（a）多元醇，例如聚（乙烯 - 共 - 乙烯醇），聚（苯乙烯 - 共 - 烯丙醇）， 麦芽糖醇，异麦芽酮糖醇，山梨糖醇，木糖醇，蔗糖，粘酸二丁酯，粘酸二（苯基-1-乙基）酯，季戊四醇或二季戊四醇; （b）式II化合物，其为例如二异辛基次膦酸; （c）空间位阻胺，例如Tinuvin 123或Tinuvin 622; （d）聚丙烯酰胺或阳离子丙烯酰胺共聚物; 或（e）羟胺和/或硝酮。 当类似处理时，当挤出复合时，这种聚酯，例如PET显示出比单独的PET更低的残留乙醛含量。 本发明涉及用于制造瓶或容器的任何聚酯，其又用于储存消费材料，特别是食品，药品，饮料，特别是水

公开(公告)号：US07820865B2

公开(公告)日：2010-10-26

申请号：US12084335

申请日：2006-10-30

申请人： Katharina Fritzsche ,  Walter Fischer ,  Johannes Benkhoff ,  Karin Powell ,  Dirk Simon

发明人： Katharina Fritzsche ,  Walter Fischer ,  Johannes Benkhoff ,  Karin Powell ,  Dirk Simon

IPC分类号： C07C49/00 ,  A61K8/18 ,  A61Q5/02

CPC分类号： C07C49/84 ,  C07C49/825 ,  C07C49/83 ,  C07D209/48 ,  C07D249/20 ,  C08K5/134

摘要： The instant invention relates to new photolatent compounds of the formula I wherein R1 and R2 are each independently of the other C1-C10alkyl or C3-C8cycloalkyl, R3 is hydrogen or C1-C4alkyl, and wherein the photochemically cleaved group R4OH is selected from the group consisting of fragrances, UV absorbers, anti-microbials, anti-fogging agents and clarifiers; with the proviso that, when R1 and R2 are tert-butyl and R3 is hydrogen, R4 is not methyl or phenyl.

摘要翻译： 本发明涉及新的式I化合物，其中R 1和R 2各自独立地为C 1 -C 10烷基或C 3 -C 8环烷基，R 3为氢或C 1 -C 4烷基，并且其中光化学裂解基团R 4 OH选自 由香料，紫外线吸收剂，抗微生物剂，防雾剂和澄清剂组成; 条件是当R 1和R 2是叔丁基且R 3是氢时，R 4不是甲基或苯基。

公开(公告)号：US20060141187A1

公开(公告)日：2006-06-29

申请号：US11326552

申请日：2006-01-05

申请人： Paul Odorisio ,  Stephen Andrews ,  Dario Lazzari ,  Dirk Simon ,  Roswell King ,  Melissa Stamp ,  Roger Reinicker ,  Michael Tinkl ,  Natacha Berthelon ,  Daniel Muller ,  Urs Hirt

发明人： Paul Odorisio ,  Stephen Andrews ,  Dario Lazzari ,  Dirk Simon ,  Roswell King ,  Melissa Stamp ,  Roger Reinicker ,  Michael Tinkl ,  Natacha Berthelon ,  Daniel Muller ,  Urs Hirt

IPC分类号： B32B27/08 ,  B32B27/36

CPC分类号： C08K5/32 ,  C08K5/053 ,  C08K5/17 ,  C08K5/34 ,  C08L23/0861 ,  C08L29/04 ,  C08L33/26 ,  C08L67/02 ,  C08L77/00 ,  C08L101/06 ,  Y10T428/1352 ,  Y10T428/1359 ,  Y10T428/1383 ,  Y10T428/1393 ,  Y10T428/1397 ,  Y10T428/31786 ,  C08L2666/04

摘要： A mixture of a polyester, such as poly(ethylene terephthalate) PET, or a polyamide, and a suitable stabilizer selected from the group consisting of hydroxylamine stabilizers, substituted hydroxylamine stabilizers, nitrone stabilizers and amine oxide stabilizers, when extrusion compounded exhibits a lower residual acetaldehyde content than does polyester or polyamide alone when similarly treated. The invention pertains to any polyester or polyamide used in the manufacture of molded articles, fibers or films, for instance bottles or containers which are used to store consumer materials, for example food, beverages and water.

公开(公告)号：US07022344B1

公开(公告)日：2006-04-04

申请号：US09268719

申请日：1999-03-17

申请人： Stephan Kothrade ,  Gunther Berndl ,  Dirk Simon ,  Axel Sanner

发明人： Stephan Kothrade ,  Gunther Berndl ,  Dirk Simon ,  Axel Sanner

IPC分类号： A61K9/10 ,  A61K47/32

CPC分类号： C08F279/02 ,  A61K9/2027 ,  A61K9/2031 ,  A61K9/2095 ,  C08L51/04 ,  C08F212/08

摘要： A process for producing solid dosage forms by mixing at least one polymer binder, at least one active ingredient and, where appropriate, conventional additives to form a plastic mixture, and shaping, wherein a physiologically tolerated, water-swellable graft copolymer or a mixture of graft copolymers is employed as polymeric binder.

摘要翻译： 通过将至少一种聚合物粘合剂，至少一种活性成分和适当的情况下混合常规添加剂以形成塑料混合物和成型来制备固体剂型的方法，其中将生理上耐受的水溶胀性接枝共聚物或 接枝共聚物用作聚合物粘合剂。

公开(公告)号：US20050176859A1

公开(公告)日：2005-08-11

申请号：US10491598

申请日：2002-10-01

申请人： Michael Tinkl ,  Stephen Andrews ,  Jan Voldrich ,  Melissa Stamp ,  Roger Reinicker ,  Paul Odorisio ,  Walter Fischer ,  Daniel Muller ,  Natacha Berthelon ,  Dirk Simon ,  Klaus Stoll

发明人： Michael Tinkl ,  Stephen Andrews ,  Jan Voldrich ,  Melissa Stamp ,  Roger Reinicker ,  Paul Odorisio ,  Walter Fischer ,  Daniel Muller ,  Natacha Berthelon ,  Dirk Simon ,  Klaus Stoll

IPC分类号： C08G63/78 ,  C08K5/053 ,  C08K5/13 ,  C08K5/15 ,  C08K5/16 ,  C08L29/02 ,  C08L33/24 ,  C08L67/02 ,  C08L77/00

CPC分类号： C08K5/13 ,  C08K5/16 ,  C08L29/02 ,  C08L33/24 ,  C08L67/02 ,  C08L77/00 ,  C08L2666/02

摘要： A mixture of a polyester or a polyamide, such as poly(ethylene terephthalate) PET, and a suitable stabilizer selected from the group consisting of certain Mannich base compounds, when extrusion compounded exhibits a lower residual acetaldehyde content than does PET or polyamide alone when similarly treated. The invention pertains to any polyester or polyamide used in the manufacture of molded articles, fibers, or films, for instance bottles or containers which are used to store consumer materials, for example food, beverages and water.

摘要翻译： 当聚丙烯或聚酰胺如聚（对苯二甲酸乙二醇酯）PET和选自某些曼尼希碱基化合物的合适的稳定剂的混合物在挤出混合时显示比单独的PET或聚酰胺更低的残留乙醛含量 治疗。 本发明涉及用于制造模塑制品，纤维或薄膜的任何聚酯或聚酰胺，例如用于储存消费材料（例如食品，饮料和水）的瓶子或容器。

公开(公告)号：US20050129757A1

公开(公告)日：2005-06-16

申请号：US11039695

申请日：2005-01-21

申请人： Stephan Kothrade ,  Gunther Berndl ,  Dirk Simon ,  Axel Sanner

发明人： Stephan Kothrade ,  Gunther Berndl ,  Dirk Simon ,  Axel Sanner

IPC分类号： A61K9/20 ,  A61K9/22 ,  A61K47/32 ,  A61K47/34 ,  C08F279/02 ,  C08L51/04 ,  A61K9/14

CPC分类号： C08F279/02 ,  A61K9/2027 ,  A61K9/2031 ,  A61K9/2095 ,  C08L51/04 ,  C08F212/08

摘要： A process for producing solid dosage forms by mixing at least one polymer binder, at least one active ingredient and, where appropriate, conventional additives to form a plastic mixture, and shaping, wherein a physiologically tolerated, water-swellable graft copolymer or a mixture of graft copolymers is employed as polymeric binder.

摘要翻译： 通过将至少一种聚合物粘合剂，至少一种活性成分和适当的情况下混合常规添加剂以形成塑料混合物和成型来制备固体剂型的方法，其中将生理上耐受的水溶胀性接枝共聚物或 接枝共聚物用作聚合物粘合剂。