摘要:
An air purification system that comprises a substrate, and at least one layer of photocatalysts. The at least one layer of photocatalysts further comprise a plurality of metal clusters.
摘要:
An air purification system that comprises a substrate, and at least one layer of photocatalysts. The at least one layer of photocatalysts further comprise a plurality of metal clusters.
摘要:
Deactivation resistant photocatalysts can be formulated by coating one or more photocatalyst crystals onto a suitable substrate. The photocatalyst crystals are doped with a dopant M. The dopant could be used to repel the silicon-based compound or be used to attract the silicon-based compound. In one embodiment, the dopant can uniformly be distributed in the photocatalyst crystals. In another embodiment, the dopant can be introduced only to photocatalyst crystals between about 0.1 to about 2 nanomenters below the surface of the structure. In another embodiment, the doped photocatalyst crystals can be interdispersed with non-doped photocatalyst crystals.
摘要:
Deactivation resistant photocatalysts can be formulated by coating one or more photocatalyst crystals onto a suitable substrate. The photocatalyst crystals are doped with a dopant M. The dopant can be used to repel the silicon-based compound or be used to attract the silicon-based compound. The dopant can uniformly be distributed in the photocatalyst crystals. The dopant can be introduced only to photocatalyst crystals between about 0.1 to about 2 nanometers below the surface of the structure. The doped photocatalyst crystals can be interdispersed with non-doped photocatalyst crystals.
摘要:
A durable Pd-based alloy is used for a H2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes “X”, where “X” comprises at least one metal from group “M” that is BCC and acts to stabilize the β BCC phase for stability during operating temperatures. The metal from group “M” is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. “X” may further comprise at least one metal from a group “N” that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group “N” is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd—Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of “X” in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.
摘要:
A homogeneous ceria-based mixed-metal oxide, useful as a catalyst support, a co-catalyst and/or a getter has a relatively large surface area per weight, typically exceeding 150 m2/g, a structure of nanocrystallites having diameters of less than 4 nm, and including pores larger than the nanocrystallites and having diameters in the range of 4 to about 9 nm. The ratio of pore volumes, VP, to skeletal structure volumes, VS, is typically less than about 2.5, and the surface area per unit volume of the oxide material is greater than 320 m2/cm3, for low internal mass transfer resistance and large effective surface area for reaction activity. The mixed metal oxide is ceria-based, includes Zr and or Hf, and is made by a novel co-precipitation process. A highly dispersed catalyst metal, typically a noble metal such as Pt, may be loaded on to the mixed metal oxide support from a catalyst metal-containing solution following a selected acid surface treatment of the oxide support. Appropriate ratioing of the Ce and other metal constituents of the oxide support contribute to it retaining in a cubic phase and enhancing catalytic performance. Rhenium is preferably further loaded on to the mixed-metal oxide support and passivated, to increase the activity of the catalyst. The metal-loaded mixed-metal oxide catalyst is applied particularly in water gas shift reactions as associated with fuel processing systems, as for fuel cells.
摘要:
A homogeneous ceria-based mixed-metal oxide, useful as a catalyst support, a co-catalyst and/or a getter has a relatively large surface area per weight, typically exceeding 150 m2/g, a structure of nanocrystallites having diameters of less than 4 nm, and including pores larger than the nanocrystallites and having diameters in the range of 4 to about 9 nm. The ratio of pore volumes, VP, to skeletal structure volumes, VS, is typically less than about 2.5, and the surface area per unit volume of the oxide material is greater than 320 m2/cm3, for low internal mass transfer resistance and large effective surface area for reaction activity. The mixed metal oxide is ceria-based, includes Zr and or Hf, and is made by a novel co-precipitation process. A highly dispersed catalyst metal, typically a noble metal such as Pt, may be loaded on to the mixed metal oxide support from a catalyst metal-containing solution following a selected acid surface treatment of the oxide support. Appropriate ratioing of the Ce and other metal constituents of the oxide support contribute to it retaining in a cubic phase and enhancing catalytic performance. Rhenium is preferably further loaded on to the mixed-metal oxide support and passivated, to increase the activity of the catalyst. The metal-loaded mixed-metal oxide catalyst is applied particularly in water gas shift reactions as associated with fuel processing systems, as for fuel cells.
摘要翻译:可用作催化剂载体,助催化剂和/或吸气剂的均匀的二氧化铈基混合金属氧化物具有相对较大的每重量的表面积,通常超过150m 2 / g, 具有直径小于4nm的纳米晶体的结构,并且包括大于纳米微晶并且直径在4至约9nm范围内的孔。 孔体积V V P与骨架结构体积V S S的比例通常小于约2.5,并且氧化物材料的每单位体积的表面积为 大于320m 2 / cm 3,因为低的内部传质阻力和反应活性的大的有效表面积。 复合金属氧化物是二氧化铈基,包括Zr和Hf,并且通过新的共沉淀法制备。 通过选择的氧化物载体的酸表面处理,可以将高度分散的催化剂金属(通常为贵金属如Pt)负载到来自含催化剂金属的溶液的混合金属氧化物载体上。 Ce和其他金属成分对氧化物载体的适当比例有助于其保持立方相并提高催化性能。 优选将铼进一步负载在混合金属氧化物载体上并钝化,以提高催化剂的活性。 负载金属的混合金属氧化物催化剂特别适用于燃料处理系统与燃料电池相关的水煤气变换反应。
摘要:
An aluminum alloy article is cleaned to remove oxides and organic matter from a coatable surface, coated with a composition comprising an organic resin and a fluorine compound, and then heated to an elevated temperature to decompose the organic resin and at least a portion of the fluorine compound. After heating the coated surface is left with a protective oxyfluoride film that prevents blistering and hydrogen pickup and promotes hydrogen degassing from the article.
摘要:
A cermet inert anode having a reduced level of contaminating surface metal is disclosed. Methods for preparing cermet inert anodes and methods for treating cermet inert anodes are also disclosed. The methods generally use an oxidizing agent to convert metals on the surface of the anode to inert oxides and/or to otherwise remove the metal contaminants. The inert anodes of the present invention may be used in electrolytic reduction cells for the production of commercial purity aluminum, as well as other metals.
摘要:
A method of controlling bulk absorption of atomic hydrogen and facilitating degassing of hydrogen from aluminum alloy workpieces during heat treatments in furnaces with ambient and/or moisture-laden atmospheres by exposing the surface of the workpieces to a low molecular weight solution or dispersion of an alkyl phosphonic acid, an olefinic phosphonic acid or an aryl phosphonic acid before subjecting the workpieces to heat treatments. The workpieces exposed to the phosphonic acid solution or dispersion are subjected to heat treatment in furnaces having ambient or moisture-laden atmospheres. The solution or dispersion involves chemical species that are deposited onto the aluminum surface from the phosphonic acid solution or dispersion which substantially decrease the amount of atomic hydrogen entering the bulk of the workpieces from their surfaces during heat treatment and, in addition, facilitate removal of atomic and molecular hydrogen from the bulk of the workpieces during heat treatment.