Polymerizable compositions with acylgermanium compounds
    93.
    发明申请
    Polymerizable compositions with acylgermanium compounds 有权
    具有酰基锗化合物的可聚合组合物

    公开(公告)号:US20080277814A1

    公开(公告)日:2008-11-13

    申请号:US11902865

    申请日:2007-09-26

    CPC classification number: C08F2/50 A61K6/083 C08F4/72 Y10S522/908 C08L33/00

    Abstract: Composition with at least one polymerizable binder and at least one polymerization initiator, which contains at least one acylgermanium compound according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r−, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; wherein in each case two of the radicals R0, R1, R2 or R3 can be connected to each other accompanied by the formulation of a 5 to 8 member ring; and the use of acylegermanium compounds of Formula (I), for example, as initiator for radical polymerization.

    Abstract translation: 含有至少一种可聚合粘合剂和至少一种聚合引发剂的组合物,其含有至少一种根据通式(I)的酰基锗化合物,其中R 0是取代或未取代的C 1 -18-烷基或酰基; R 1和R 2均为H,酰基或具有R 3给出的含义之一; R 3是支链或直链C 1-18 - 烷基,其可以是未取代的或被-O - , - NH-,-NR- ,-S-或被其它基团中断,三甲基甲硅烷基,卤代(CH 3)2 Si- [OSi(CH 3)3) (CH 3)3 Si- [OSi(CH 3)3) -COOH,-COO-R 10,-CO-NR, - , - SO 2 - , - 11- 12,-CO-乙烯基,-CO-苯基,苯基-C 1-4 - 烷基,苯基,萘基或联苯基,C

    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides
    94.
    发明申请
    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides 有权
    基于可自由基聚合的N,O-官能化丙烯酸羟基酰胺的材料

    公开(公告)号:US20080234405A1

    公开(公告)日:2008-09-25

    申请号:US11898338

    申请日:2007-09-11

    CPC classification number: A61K6/0023 A61K6/0017 A61K6/083 C08L33/26 C08L33/14

    Abstract: A material contains at least a polymerizable N,O-functionalized acrylic acid hydroxyamide of the Formula (I) in which A is an n+m-valent linear or branched aliphatic C1 to C50 radical, in which the carbon chain can be interrupted by O, S, —CO—O—, CO—NH, O—CO—NH or NH—CO—NH, an n+m-valent aromatic C6 to C18 radical or an n+m-valent cycloaliphatic or heterocyclic C3 to C18 radical, wherein the radicals can carry one or more substituents, Y is not present, or is O, S, an ester, amide or urethane group, R1 is hydrogen, an aliphatic C1 to C20 alkyl or C3 to C8 cycloalkyl radical which can carry one or more substituents, R2 is H or a C1 to C10 alkyl radical, R3 is not present or is a C1 to C16 alkylene radical which can be interrupted by O, HG is not present, is —COOH, —P═O(OH)2; —P═O(OH)(OR4); —O—P═O(OH)2, —SO2OH or —O—P═O(OH)(OR4), R4 is a C1 to C15 alkyl radical, phenyl or benzyl radical and n is a number from 1 to 5 and m a number from 0 to 3.

    Abstract translation: 材料至少含有式(I)的可聚合的N,O-官能化丙烯酸羟基酰胺,其中A是n + m价的直链或支链脂肪族C 1至C 50 其中碳链可被O,S,-CO-O-,CO-NH,O-CO-NH或NH-CO-NH中断,n + m价芳族C < C 6至C 18或C 14环烷基或杂环C 3〜C 18 - 基团,其中 基团可以携带一个或多个取代基,Y不存在,或者是O,S,酯,酰胺或氨基甲酸酯基,R 1是氢,脂族C 1 C 20 -C 20烷基或C 3至C 8环烷基,其可以携带一个或多个取代基R 2 O / 是H或C 1至C 10烷基,R 3不存在或者是C 1〜 可以被O,HG中断的C 16 -C 16亚烷基,不存在,是-COOH,-PO(OH)2。 -P-O(OH)(OR 4); -OPO(OH)2,-SO 2 OH或-OPO(OH)(OR 4),R 4, SUP>是C 15 -C 15烷基,苯基或苄基,n是1至5的数和0至3的数。

    Polymerizable bicyclic cyclopropane derivatives and their use for the preparation of dental materials
    96.
    发明授权
    Polymerizable bicyclic cyclopropane derivatives and their use for the preparation of dental materials 有权
    可聚合双环环丙烷衍生物及其在牙科材料制备中的应用

    公开(公告)号:US07365222B2

    公开(公告)日:2008-04-29

    申请号:US10658993

    申请日:2003-09-10

    Abstract: Bicyclic cyclopropane derivatives of the general Formula (I) in which n+m is 0 to 8; r is 1 to 4; R1 is absent or is a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 arylene or C7-C20 alkylenearylene radical; R2 is for r=1 a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 aryl or a C7-C20 alkylaryl radical; is for r>1 an r-times substituted aliphatic C1 to C20 radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, an aromatic C6-C14 radical or aliphatic-aromatic C7-C20 radical; X is absent or is —CO—O—, —CO—NH— or —O—CO—NH—, and Y is CH2, O or S which is suitable in particular for the preparation of dental materials.

    Abstract translation: 通式(I)的双环环丙​​烷衍生物,其中n + m为0至8; r为1〜4; R 1不存在或可以被O或S中断的C 1 -C 20亚烷基,脂环族C 1 -C 20烷基, 4个C 12-12基团,双环C 4 -C 12 - 基团,C 6 - -C 14亚芳基或C 7 -C 20亚烷基亚芳基; R 2是针对r = 1,可以被O或S中断的C 1 -C 20 - 烷基,脂环族C 4个C 12 - 基团,双环C 4 -C 12 - 基团,C 6 -C 14芳基或C 7 -C 20烷基芳基; 是r> 1,可以被O或S中断的r-次取代的脂族C 1至C 20 - 基团,脂环族C 4 -C 12 -C 12的基团,芳族C 6 -C 14基团或脂族 - 芳族C 7 -C 20个基团; X不存在或是-CO-O-,-CO-NH-或-O-CO-NH-,Y是CH 2,O或S,其特别适用于制备 牙科材料。

    Polymerizable cyclopropyl acrylates

    公开(公告)号:US20060178469A1

    公开(公告)日:2006-08-10

    申请号:US11200488

    申请日:2005-08-09

    Abstract: Cyclopropyl acrylate of general formula (1), constitutional and stereoisomers thereof and their mixtures in which A is selected from: Y for A=A1 is absent, CH2 or 0, and for A=A2=CH2 or 0; n for Y is absent=0, 1, 2 or 3, and for Y=CH2 or 0=1; m for Y is absent=0, 1, 2 or 3, and for Y=CH2 or 0=1; r=1, 2, 3 or 4; R1=H, a C1 to C10 alkyl, C6 to C12 aryl, C1 to C10 arylalkyl or bicyclic C5-C12 radical or —R10—X—; R2=an aliphatic C1-C20 hydrocarbon radical, substituted r times by the expression in brackets, which can be interrupted by O or S, cycloaliphatic C4-C12 radical, bicyclic C5-C12 radical, a C6-C14 aryl or C7-C20 alkylaryl radical; R3=—CO—OR9, —CO—R9, —S(O)R9, SO2R9, —SO2(OR9), —PO(OR9)2, —CN, —H, —R9; R4=—CO—OR9, —CO—R9, —S(O)R9, —SO2R9, —SO2(OR9), —PO(OR9)2, —CN or —R11—R10—X—; R5-R8=independently of one another H, —CO—OR9, —CO—NHR9, —CO—NR92, —CO—R9, —CN, a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C5-C12 radical, a C6-C14 aryl, C7-C20 alkylaryl radical, or at least two of the radicals form together with the carbon atoms to which they are bonded a 5- to 8-membered ring system; R9=a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C5-C12 radical, a C6-C14 aryl or C7-C20 alkylaryl radical; R10=is absent or a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic or bicyclic C5-C12 radical, a C6-C14 arylene or C7-C20 alkylenearylene radical; R11=—COO—, —CO—, —SO—, —SO2—, —SO2(O—), —PO(OR9)(O—); X=is absent, —O—CO—, —CO—O—, —NH—CO—, —CO—NH—, —NH—CO—O— or —O—CO—NH—, wherein X has the meaning “is absent” if R10 is absent, wherein the radicals R2 and R5-9 can be substituted or unsubstituted, either R4=—R11—R10—X— or R1=—R10—X— and the expression in brackets is bonded to R2 via X and wherein several radicals of one type can be identical or different.

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