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    Polymerizable cyclopropyl acrylates
    1.
    发明申请
    Polymerizable cyclopropyl acrylates 有权

    公开(公告)号：US20060178469A1

    公开(公告)日：2006-08-10

    申请号：US11200488

    申请日：2005-08-09

    申请人： Norbert Moszner ,  Frank Zeuner ,  Urs-Karl Fischer ,  Volker Rheinberger ,  Armin de Meijere ,  Viktor Bahutski

    发明人： Norbert Moszner ,  Frank Zeuner ,  Urs-Karl Fischer ,  Volker Rheinberger ,  Armin de Meijere ,  Viktor Bahutski

    IPC分类号： C08L31/00 ,  C07C69/74

    CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C07C69/753 ,  C07C69/757 ,  C07C2602/18 ,  C07C2603/66 ,  C08L33/00

    摘要： Cyclopropyl acrylate of general formula (1), constitutional and stereoisomers thereof and their mixtures in which A is selected from: Y for A=A1 is absent, CH2 or 0, and for A=A2=CH2 or 0; n for Y is absent=0, 1, 2 or 3, and for Y=CH2 or 0=1; m for Y is absent=0, 1, 2 or 3, and for Y=CH2 or 0=1; r=1, 2, 3 or 4; R1=H, a C1 to C10 alkyl, C6 to C12 aryl, C1 to C10 arylalkyl or bicyclic C5-C12 radical or —R10—X—; R2=an aliphatic C1-C20 hydrocarbon radical, substituted r times by the expression in brackets, which can be interrupted by O or S, cycloaliphatic C4-C12 radical, bicyclic C5-C12 radical, a C6-C14 aryl or C7-C20 alkylaryl radical; R3=—CO—OR9, —CO—R9, —S(O)R9, SO2R9, —SO2(OR9), —PO(OR9)2, —CN, —H, —R9; R4=—CO—OR9, —CO—R9, —S(O)R9, —SO2R9, —SO2(OR9), —PO(OR9)2, —CN or —R11—R10—X—; R5-R8=independently of one another H, —CO—OR9, —CO—NHR9, —CO—NR92, —CO—R9, —CN, a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C5-C12 radical, a C6-C14 aryl, C7-C20 alkylaryl radical, or at least two of the radicals form together with the carbon atoms to which they are bonded a 5- to 8-membered ring system; R9=a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C5-C12 radical, a C6-C14 aryl or C7-C20 alkylaryl radical; R10=is absent or a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic or bicyclic C5-C12 radical, a C6-C14 arylene or C7-C20 alkylenearylene radical; R11=—COO—, —CO—, —SO—, —SO2—, —SO2(O—), —PO(OR9)(O—); X=is absent, —O—CO—, —CO—O—, —NH—CO—, —CO—NH—, —NH—CO—O— or —O—CO—NH—, wherein X has the meaning “is absent” if R10 is absent, wherein the radicals R2 and R5-9 can be substituted or unsubstituted, either R4=—R11—R10—X— or R1=—R10—X— and the expression in brackets is bonded to R2 via X and wherein several radicals of one type can be identical or different.

    Dental materials based on ring-opening polymerizable acid monomers
    2.
    发明申请
    Dental materials based on ring-opening polymerizable acid monomers 审中-公开
    基于开环聚合酸单体的牙科材料

    公开(公告)号：US20070287792A1

    公开(公告)日：2007-12-13

    申请号：US11585280

    申请日：2006-10-24

    申请人： Norbert Moszner ,  Jorg Angermann ,  Frank Zeuner ,  Armin de Mejere ,  Urs Karl Fischer ,  Volker Rheinberger

    发明人： Norbert Moszner ,  Jorg Angermann ,  Frank Zeuner ,  Armin de Mejere ,  Urs Karl Fischer ,  Volker Rheinberger

    IPC分类号： C08L31/00

    CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  C08L33/00

    摘要： Dental material which contains at least one radically polymerizable monomer according to the general formula (I): in which PG is a cyclic, ring-opening polymerizable group; X1 is absent, O, S, is an ester, amide or urethane group; X2 is absent with, O, S, is an ester, amide or urethane group; Y is absent, O, S, is an ester, amide or urethane group; R is an organic radical with a valency of (n+m), with 1 to 35 carbon atoms and 0 to 8 heteroatoms, the H atoms of which can be wholly or partially substituted by F atoms; R1 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; R2 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; n is 1, 2, 3, 4, 5 or 6; m is 1, 2 or 3; HG is —P═O(OH)2; —P═O(OH)(OR14); —O—P═O(OH)2, —O—P═O(OH)(OR15) or —SO2OH, wherein R14 is a C1-C15 alkyl radical, phenyl or benzyl radical; and R15 is a C1-C15 alkyl radical, phenyl or benzyl radical.

    摘要翻译： 含有至少一种根据通式（I）的可自由基聚合的单体的牙科材料：其中PG是环状可开环聚合基团; X 1不存在，O，S是酯，酰胺或氨基甲酸酯基; O，S不是酯，酰胺或氨基甲酸酯基; Y不存在，O，S是酯，酰胺或氨基甲酸酯基; R为化合价为（n + m），有1至35个碳原子和0至8个杂原子的有机基团，其H原子可以被F原子全部或部分取代; R 1不存在或可被O原子间断的C 1 -C 16亚烷基; R 2不存在或可被O原子间隔的C 1 -C 16亚烷基; n为1,2,3,4,5或6; m为1,2或3; HG是-P-O（OH）2; -P-O（OH）（OR 14）; -OPO（OH）2，-OPO（OH）（OR 15）或-SO 2 OH，其中R 14， CH 2是C 1 -C 15烷基，苯基或苄基; R 15是C 1 -C 15烷基，苯基或苄基。

    Dental materials based on dimer acid derivatives with ring opening polymerizable groups
    4.
    发明授权
    Dental materials based on dimer acid derivatives with ring opening polymerizable groups 有权
    基于具有开环聚合基团的二聚酸衍生物的牙科材料

    公开(公告)号：US08921450B2

    公开(公告)日：2014-12-30

    申请号：US13175988

    申请日：2011-07-05

    申请人： Norbert Moszner ,  Jörg Angermann ,  Urs Karl Fischer ,  Volker Rheinberger

    发明人： Norbert Moszner ,  Jörg Angermann ,  Urs Karl Fischer ,  Volker Rheinberger

    IPC分类号： A61K6/08 ,  A61K6/083 ,  C07D339/00 ,  A61K6/00

    CPC分类号： C07D339/00 ,  A61K6/0023 ,  A61K6/083 ,  C08L33/08 ,  C08L33/10 ,  C08L65/00

    摘要： The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.

    摘要翻译： 本发明涉及式（I）的自由基聚合性单体，其中W1和W2各自独立地表示H或X-R-Y-PG，其中W1和W2中的至少一个表示X-R-Y-PG，X 在每种情况下都独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，Y在每种情况下独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，R各自独立地缺失或表示 可以被一个或多个O原子中断的C1-C16亚烷基，其中只有当X和/或Y同时缺失时，R只能缺失，并且每种情况下PG都独立地表示环状的开环聚合基团， a，b，c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物，以及它们作为牙科材料和用于制备牙科材料的用途 ，特别是composi 水泥，粘合剂或涂料。

    (Meth) acrylate-substituted iminooxidiazine dione derivatives
    5.
    发明授权
    (Meth) acrylate-substituted iminooxidiazine dione derivatives 有权
    （甲基）丙烯酸酯取代的亚氨氧亚氨基二酮衍生物

    公开(公告)号：US07078446B2

    公开(公告)日：2006-07-18

    申请号：US10361961

    申请日：2003-02-10

    申请人： Norbert Moszner ,  Thomas Völkel ,  Urs Karl Fischer ,  Volker Rheinberger

    发明人： Norbert Moszner ,  Thomas Völkel ,  Urs Karl Fischer ,  Volker Rheinberger

    IPC分类号： A61K6/083 ,  A61C5/00 ,  C08G18/04

    CPC分类号： A61K6/083 ,  A61K6/0023 ,  C07D273/04 ,  C08L33/00

    摘要： The invention relates to iminooxadiazine dione derivatives with the formula (I) in which X, Y and Z represent a (meth)acrylic acid radical of the formula (II) in which R1 is hydrogen, an aliphatic hydrocarbon radical with 1 to 14 carbon atoms, which can be interrupted by oxygen atoms, or an aromatic hydrocarbon radical with to 16 carbon atoms; R2 is hydrogen, an aliphatic hydrocarbon radical with 1 to 5 carbon atoms or an aromatic hydrocarbon radical with 6 carbon atoms, n is 1 or 2; where the (meth)acrylic acid radical of formula (II) is bound to the radical of formula (I) by R1 or R2 and the binding point remaining at R2 or R1 is saturated by hydrogen and X, Y and Z can be the same or different; the individual radicals R being able to be the same or different and selected from alicyclic or aromatic hydrocarbon radicals with 5 to 10 or aliphatic hydrocarbon radicals with 1 to 10 carbon atoms.

    摘要翻译： 本发明涉及式（I）的亚氨基恶二嗪二酮衍生物，其中X，Y和Z表示式（II）的（甲基）丙烯酸基，其中R 1是氢，脂族 可以被氧原子中断的具有1至14个碳原子的烃基或具有16个碳原子的芳族烃基; R 2是氢，具有1至5个碳原子的脂族烃基或具有6个碳原子的芳族烃基，n是1或2; 其中式（II）的（甲基）丙烯酸基团通过R 1或R 2 2与式（I）的基团结合，并且R H 2和R 1可以被氢饱和，X，Y和Z可以相同或不同; 各个基团R能够相同或不同，并且选自具有5-10个碳原子的脂族或芳族烃基或具有1-10个碳原子的脂族烃基。

    Vinylcyclopropane-(meth)acrylates and their use
    7.
    发明授权
    Vinylcyclopropane-(meth)acrylates and their use 有权
    乙烯基环丙烷 - （甲基）丙烯酸酯及其用途

    公开(公告)号：US6136887A

    公开(公告)日：2000-10-24

    申请号：US266509

    申请日：1999-03-11

    申请人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Voelkel ,  Urs Karl Fischer

    发明人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Voelkel ,  Urs Karl Fischer

    IPC分类号： A61K6/00 ,  A61K6/083 ,  C07C69/743 ,  C08F22/10

    CPC分类号： A61K6/0023 ,  A61K6/083 ,  C07C69/743 ,  C08F22/105

    摘要： The invention relates to vinylcyclopropane derivatives according to the formula ##STR1## in which A is --[--Y--CO--C(.dbd.CH.sub.2)R.sup.4 ].sub.m or --C(.dbd.CH.sub.2)CO--O--C.sub.1-4 -alkyl, U and X, independently of each other, stand for CO, COO or CONH; Y and Z stand for O or NH or are absent, but Y and Z cannot be absent at the same time; n, m stand for a whole number from 0 to 4, but n and m are not 0 at the same time; R.sup.1 is H, CH.sub.3 or Cl; R.sup.2, R.sup.3 stand for H, a C.sub.1 - to C.sub.10 -alkyl or alkylene radical, which can be interrupted by O, S or NH, for a C.sub.6 - to C.sub.14 -aryl or arylene, C.sub.7 - to C.sub.14 -alkylaryl or alkylarylene or a C.sub.5 - to C.sub.8 -cycloalkyl or cycloalkylene radical; and R.sup.4 is H or a C.sub.1 - to C.sub.10 -alkyl radical, and to processes for their production. The compounds are suitable in particular for the production of adhesives, cements, composites and mouldings.

    摘要翻译： 本发明涉及下式的乙烯基环丙烷衍生物，其中A为 - [ - Y-CO-C（= CH2）R4] m或-C（= CH2）CO-O-C1-4烷基，U和X， 独立于代表CO，COO或CONH; Y和Z代表O或NH或不存在，但Y和Z不能同时不存在; n，m表示从0到4的整数，但n和m不同时为0; R1是H，CH3或Cl; R2，R3代表H，C 1至C 10 - 烷基或亚烷基，其可被O，S或NH中断，用于C 6至C 14 - 芳基或亚芳基，C 7至C 14 - 烷基芳基或烷基亚芳基或 C5至C8-环烷基或环亚烷基; 并且R4是H或C1-至C10-烷基，并且用于其制备。 该化合物特别适用于粘合剂，水泥，复合材料和模制品的生产。

    Urethane di(meth)acrylate derivatives of 1,3-bis(1-isocyanato-1-methylethyl)benzene
    8.
    发明授权
    Urethane di(meth)acrylate derivatives of 1,3-bis(1-isocyanato-1-methylethyl)benzene 有权
    苯乙烯的聚氨酯二（甲基）丙烯酸酯衍生物，1,3-双（1-异氰酸基-1-甲基乙基）苯

    公开(公告)号：US06653375B2

    公开(公告)日：2003-11-25

    申请号：US09236787

    申请日：1999-01-25

    申请人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Völkel ,  Urs Karl Fischer

    发明人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Völkel ,  Urs Karl Fischer

    IPC分类号： A61K6083

    CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/09 ,  C07C271/20 ,  C08L75/16

    摘要： The invention relates to urethane di(meth)acrylate derivatives of 1-3-bis(1-isocyanato-1-methylethyl)benzene according to Formula (I) in which R is hydrogen or a straight-chained C1-C8 alkyl radical; X and Y independently of each other stand for R1 being a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; R2 hydrogen, a C1- to C5-alkyl or a substituted or unsubstituted C6- to C12-aryl radical; R3 hydrogen or a methyl radical; R4 a C1- to C8-alkylene radical which can be broken by oxygen atoms, or a phenylene radical; R5 hydrogen or a methyl radical; R6 a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; Z being —CO— or a chemical bond and W standing for oxygen, sulphur or NR7, R7 being hydrogen or a straight-chained C1- to C6-alkyl radical. The substances are suitable in particular for the production of dental materials.

    摘要翻译： 本发明涉及式（I）的1,3-双（1-异氰酸基-1-甲基乙基）苯的氨基甲酸酯二（甲基）丙烯酸酯衍生物，其中R为氢或直链C1-C8烷基; X和Y彼此独立地代表R 1是取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; R 2为氢，C 1至C 5 - 烷基或取代或未取代的C 6至C 12 - 芳基; R 3氢或甲基; R 4可以被氧原子断裂的C1-至C8-亚烷基或亚苯基; R 5氢或甲基; R 6取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; Z是-CO-或化学键，W代表氧，硫或NR 7，R 7是氢或直链C 1至C 6烷基。 这些物质特别适用于生产牙科材料。