摘要:
A process is described for preparing adiponitrile and methylglutaronitrile, characterized by the following process steps: (a) reacting a reactant stream comprising pentenenitriles with hydrogen cyanide in the presence of at least one catalyst and of at least one promoter to obtain a reaction stream which comprises pentenenitriles, the at least one catalyst, catalyst degradation products, the at least one promoter, adiponitrile and methylglutaronitrile, (b) distilling the reaction stream to obtain a stream 3 which is depleted in pentenenitriles and comprises the at least one catalyst, catalyst degradation products, the at least one promoter, adiponitrile and methylglutaronitrile as the bottom product and a stream 4 enriched in pentenenitriles as the top product, (c) extracting the stream 3 using an extractant present in stream 5 to obtain a stream 6 enriched with extractant as the top product which comprises the catalyst, and a stream 7 depleted in extractant as the bottom product which comprises catalyst degradation products, the at least one promoter, pentenenitriles, adiponitrile and methylglutaronitrile, (d) distilling the stream 6 to obtain a stream 8 comprising the catalyst as the bottom product and a stream 9 comprising the extractant as the top product, (e) distilling the stream 7 to obtain a stream 10 as the bottom product which comprises catalyst degradation products, the at least one promoter, pentenenitriles, adiponitrile and methylglutaronitrile, and a stream 11 comprising the extractant as the top product, (f) distilling the stream 10 to obtain a stream 12 as the bottom product which comprises catalyst degradation products, the at least one promoter, adiponitrile and methylglutaronitrile, and a stream 13 comprising pentenenitriles as the top product, (g) distilling the stream 12 to obtain a stream 14 as the bottom product which comprises catalyst degradation products and the at least one promoter, and a stream 15 as the top product which comprises adiponitrile and methylglutaronitrile, (h) distilling the stream 15 to obtain a stream 16 comprising adiponitrile as the bottoms and a stream 17 comprising methylglutaronitrile as the top product.
摘要:
A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound. The method comprises a) removing the complex compound from mixture (I) to give a mixture (II), b) adding water to mixture (II) and placing mixture (II) under pressure and temperature conditions to provide a phase (III) and a phase (IV), c) adding a liquid diluent (V) which c1) does not form an azeotrope with water and whose boiling point under certain pressure conditions is higher than that of water, or c2) forms an azeotrope or heteroazeotrope with water under certain pressure conditions, to phase (III), d) subjecting the mixture of phase (III) and liquid diluent (V) to distillation under the pressure conditions mentioned in step c1) or c2), and e) subjecting mixture (VII) to hydrocyanation of an olefinically unsaturated compound to give the nitrile.
摘要:
The present invention pertains to radiation sources that mimic radiation environment(s) encountered by packaged semiconductor devices. The sources are suitable for use in test systems operative to test for soft error and/or failure rates in devices sensitive to such radiation. The radiation is highly active to exacerbate soft error rates and thereby accelerate testing and reduce test times. The sources are also relatively uniformly distributed within a medium to simulate the direction(s) and energy spectra of radiation that would actually be encountered by semiconductor devices in device operation.
摘要:
A master tool for a reception station on a press for shaping sheets of paper or cardboard, comprising a moving slide and a number of bars (1) adapted to form a grid for non-stop reception of blanks and a bottom separating tool comprising two boards (4, 5) adjustable on two transverse beams (9, 10) of the moving slide, the beams having top edges having the same profile, the profile of the top edge comprising a number of serrated recesses in shape matching the cross-section of the bars (1), the serrated recesses being adjusted to correspond to the transverse positions of the openings in the bottom blank-separating tool.
摘要:
The invention relates to a nickel-base superalloy for producing single-crystal components. The alloy according to the invention is characterized by the following chemical composition (details in % by weight): 7-13 Cr, 4-10 Co, 0.5-2 Mo, 2-8 W, 4-6 Ta, 3-6 Al, 1-4 Ti, 0.1-6 Ru, 0.01-0.5 Hf, 0.001-0.15 Si, 0-700 ppm C, 0-300 ppm B, remainder Ni and production-related impurities.
摘要:
A liquid desiccant dehumidifier includes a liquid desiccant absorber arranged to receive concentrated liquid desiccant and absorb moisture contained in ambient air passed through the absorber thereby diluting the liquid desiccant. A first heat exchanger is operative to heat dilute liquid desiccant received from the desiccant absorber prior to passage to a boiler that evaporates moisture from the diluted liquid desiccant to create steam and reconstitute the desiccant into a concentrated liquid desiccant. Dilute liquid desiccant from the first heat exchanger first passes to a condenser that receives steam from the boiler and sensibly heats the dilute liquid desiccant to a higher second temperature without direct exposure to steam or air. A second heat exchanger communicates with the condenser, the boiler and the first heat exchanger and is operative to further heat diluted liquid desiccant received from the condenser to a higher third temperature prior to entry into the boiler by recovering waste heat from the boiler. A pump draws concentrated liquid desiccant from the boiler through the heat exchangers and passes it to the absorber.
摘要:
In a method of brazing directionally solidified or monocrystalline components, the brazing deposit and the directionally solidified or monocrystalline component are moved through a heated zone. In this zone, the temperature applied by a heating system is greater than the liquidus temperature of the brazing alloy and less than the local incipient melting temperature of the component. A thermal gradient is applied between the component and the brazing deposit.
摘要:
The invention relates to a cementitious composition that can effectively reduce the adsorption of water, which comprises a) at least one polymer that is the polymerization product of one or more ethylenically unsaturated monomers, in the form of their polymer dispersions and water-redispersible polymer powders; and b) at least one alkyl and/or alkenyl substituted dicarboxylic acids or anhydrides.
摘要:
A process for coproducing di- and/or polyisocyanates and glycols, comprising process stages A, B, C and E for preparing glycols and process stages A, C, D, E, F and G for preparing di- and/or polyisocyanates,which comprises accomplishing the material coupling via the separation of the reaction mixture obtained in process stage A into process stages B and C, by in process stage A, reacting an aqueous alkylene oxide with carbon dioxide to give a reaction mixture comprising alkylene carbonate, hydrolyzing a portion of the alkylene carbonate-comprising reaction mixture obtained in process stage A to glycol in process stage B, dewatering the remaining alkylene carbonate-comprising stream of the reaction mixture from process stage A in process stage C, in process stage D, synthesizing amine by hydrogenating an aromatic nitro compound or a nitrile, in process stage E, transesterifying the dewatered alkylene carbonate-comprising mixture from process stage C with a monohydroxy alcohol to give the corresponding dialkyl carbonate, obtaining glycol as a coproduct, in process stage F, reacting the dialkyl carbonate-comprising reaction mixture obtained in process stage E with the amine obtained in process stage D to a mixture comprising the corresponding mono-, di- and/or polycarbamate, which in process stage G is cleaved to obtain the corresponding di- and/or polyisocyanate.
摘要:
A process is disclosed for separating the output from the reaction of EDDN or EDMN with hydrogen in the presence of THF, a catalyst, TETA or DETA, water, and optionally organic compounds having higher and lower boiling points than TETA or DETA. Hydrogen is removed, and the output is supplied to a distillation column DK1 in which an azeotrope, optionally comprising organic compounds with a boiling point lower than TETA or DETA, is removed from the top. A product comprising TETA or DETA is removed from the bottom and passed into a distillation column DK2, removing THF. A stream comprising TETA or DETA passes from the bottom of DK2. The DK1 azeotrope is condensed. Phase separation is induced by the addition of an organic solvent essentially immiscible with water, and the mixture is separated. The organic phase is recycled into DK1 and the water phase is discharged.