Method for producing dinitriles
    91.
    发明申请

    公开(公告)号:US20070155978A1

    公开(公告)日:2007-07-05

    申请号:US10586500

    申请日:2005-01-27

    IPC分类号: C07C253/10

    CPC分类号: C07C253/10 C07C255/04

    摘要: A process is described for preparing adiponitrile and methylglutaronitrile, characterized by the following process steps: (a) reacting a reactant stream comprising pentenenitriles with hydrogen cyanide in the presence of at least one catalyst and of at least one promoter to obtain a reaction stream which comprises pentenenitriles, the at least one catalyst, catalyst degradation products, the at least one promoter, adiponitrile and methylglutaronitrile, (b) distilling the reaction stream to obtain a stream 3 which is depleted in pentenenitriles and comprises the at least one catalyst, catalyst degradation products, the at least one promoter, adiponitrile and methylglutaronitrile as the bottom product and a stream 4 enriched in pentenenitriles as the top product, (c) extracting the stream 3 using an extractant present in stream 5 to obtain a stream 6 enriched with extractant as the top product which comprises the catalyst, and a stream 7 depleted in extractant as the bottom product which comprises catalyst degradation products, the at least one promoter, pentenenitriles, adiponitrile and methylglutaronitrile, (d) distilling the stream 6 to obtain a stream 8 comprising the catalyst as the bottom product and a stream 9 comprising the extractant as the top product, (e) distilling the stream 7 to obtain a stream 10 as the bottom product which comprises catalyst degradation products, the at least one promoter, pentenenitriles, adiponitrile and methylglutaronitrile, and a stream 11 comprising the extractant as the top product, (f) distilling the stream 10 to obtain a stream 12 as the bottom product which comprises catalyst degradation products, the at least one promoter, adiponitrile and methylglutaronitrile, and a stream 13 comprising pentenenitriles as the top product, (g) distilling the stream 12 to obtain a stream 14 as the bottom product which comprises catalyst degradation products and the at least one promoter, and a stream 15 as the top product which comprises adiponitrile and methylglutaronitrile, (h) distilling the stream 15 to obtain a stream 16 comprising adiponitrile as the bottoms and a stream 17 comprising methylglutaronitrile as the top product.

    Method for the recycling of a Lewis acid
    92.
    发明授权
    Method for the recycling of a Lewis acid 失效
    路易斯酸回收方法

    公开(公告)号:US07084294B2

    公开(公告)日:2006-08-01

    申请号:US10520007

    申请日:2003-07-04

    IPC分类号: C07C253/10

    摘要: A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound. The method comprises a) removing the complex compound from mixture (I) to give a mixture (II), b) adding water to mixture (II) and placing mixture (II) under pressure and temperature conditions to provide a phase (III) and a phase (IV), c) adding a liquid diluent (V) which c1) does not form an azeotrope with water and whose boiling point under certain pressure conditions is higher than that of water, or c2) forms an azeotrope or heteroazeotrope with water under certain pressure conditions,  to phase (III), d) subjecting the mixture of phase (III) and liquid diluent (V) to distillation under the pressure conditions mentioned in step c1) or c2), and e) subjecting mixture (VII) to hydrocyanation of an olefinically unsaturated compound to give the nitrile.

    摘要翻译: 从在不饱和化合物的氢氰化中获得的反应混合物(I)中回收路易斯酸的方法,该反应混合物在一定压力和温度条件下,在与 催化剂体系包含路易斯酸和络合物。 该方法包括:a)从混合物(I)中除去配合物,得到混合物(II),b)在混合物(II)中加入水并将混合物(II)置于压力和温度条件下以提供相(III)和 相(Ⅳ),c)加入一种不与水形成共沸物的液体稀释剂(Ⅴ),其某些压力条件下的沸点高于水,或c2)与水形成共沸混合物 (III),d)在步骤c1)或c2)所述的压力条件下使相(III)和液体稀释剂(V)的混合物进行蒸馏,和e)使混合物(VII) 对烯属不饱和化合物进行氢化,得到腈。

    Reception station on a shaping press and a set of tools for a said station
    94.
    发明授权
    Reception station on a shaping press and a set of tools for a said station 失效
    一台成型机上的接收台和一个所述车站的一套工具

    公开(公告)号:US06752586B2

    公开(公告)日:2004-06-22

    申请号:US09853438

    申请日:2001-05-10

    IPC分类号: B65H3132

    摘要: A master tool for a reception station on a press for shaping sheets of paper or cardboard, comprising a moving slide and a number of bars (1) adapted to form a grid for non-stop reception of blanks and a bottom separating tool comprising two boards (4, 5) adjustable on two transverse beams (9, 10) of the moving slide, the beams having top edges having the same profile, the profile of the top edge comprising a number of serrated recesses in shape matching the cross-section of the bars (1), the serrated recesses being adjusted to correspond to the transverse positions of the openings in the bottom blank-separating tool.

    摘要翻译: 一种用于成型纸张或纸板的印刷机上的接收台的主工具,包括移动滑块和适于形成用于不间断接收坯料的格栅的多个条(1)和包括两个板的底部分离工具 (4,5)可在移动滑动件的两个横梁(9,10)上调节,所述梁具有相同轮廓的顶部边缘,所述顶部边缘的轮廓包括多个锯齿形凹槽,其形状与 杆(1),锯齿形凹槽被调节以对应于底部分离工具中的开口的横向位置。

    Nickel-base superalloy
    95.
    发明授权
    Nickel-base superalloy 有权
    镍基超级合金

    公开(公告)号:US06706241B1

    公开(公告)日:2004-03-16

    申请号:US10291392

    申请日:2002-11-12

    IPC分类号: C22C1905

    CPC分类号: C22C19/057 C22C19/056

    摘要: The invention relates to a nickel-base superalloy for producing single-crystal components. The alloy according to the invention is characterized by the following chemical composition (details in % by weight): 7-13 Cr, 4-10 Co, 0.5-2 Mo, 2-8 W, 4-6 Ta, 3-6 Al, 1-4 Ti, 0.1-6 Ru, 0.01-0.5 Hf, 0.001-0.15 Si, 0-700 ppm C, 0-300 ppm B, remainder Ni and production-related impurities.

    摘要翻译: 本发明涉及一种用于生产单晶组分的镍基超合金。 根据本发明的合金的特征在于以下化学组成(细节重量%):7-13 Cr,4-10 Co,0.5-2 Mo,2-8 W,4-6 Ta,3-6 Al ,1-4Ti,0.1-6 Ru,0.01-0.5 Hf,0.001-0.15 Si,0-700 ppm C,0-300 ppm B,余量为Ni和与生产有关的杂质。

    Method of brazing directionally solidified or monocrystalline components
    97.
    发明授权
    Method of brazing directionally solidified or monocrystalline components 失效
    钎焊定向凝固或单晶组分的方法

    公开(公告)号:US6050477A

    公开(公告)日:2000-04-18

    申请号:US50901

    申请日:1998-03-31

    CPC分类号: B23K1/002

    摘要: In a method of brazing directionally solidified or monocrystalline components, the brazing deposit and the directionally solidified or monocrystalline component are moved through a heated zone. In this zone, the temperature applied by a heating system is greater than the liquidus temperature of the brazing alloy and less than the local incipient melting temperature of the component. A thermal gradient is applied between the component and the brazing deposit.

    摘要翻译: 在定向凝固或单晶组分钎焊的方法中,钎焊沉积物和定向凝固或单晶组分移动通过加热区。 在该区域中,由加热系统施加的温度大于钎焊合金的液相线温度,并且小于部件的局部初始熔化温度。 在组件和钎焊沉积物之间施加热梯度。

    Hydrophobic cementitious composition
    98.
    发明授权
    Hydrophobic cementitious composition 有权
    疏水性水泥组合物

    公开(公告)号:US09206082B2

    公开(公告)日:2015-12-08

    申请号:US13531782

    申请日:2012-06-25

    申请人: Robert Baumann

    发明人: Robert Baumann

    摘要: The invention relates to a cementitious composition that can effectively reduce the adsorption of water, which comprises a) at least one polymer that is the polymerization product of one or more ethylenically unsaturated monomers, in the form of their polymer dispersions and water-redispersible polymer powders; and b) at least one alkyl and/or alkenyl substituted dicarboxylic acids or anhydrides.

    摘要翻译: 本发明涉及一种可有效降低水分吸收的水泥质组合物,其包括:a)至少一种作为其一种或多种烯属不饱和单体的聚合产物的聚合物,其聚合物分散体和水可再分散聚合物粉末形式 ; 和b)至少一种烷基和/或烯基取代的二羧酸或酸酐。

    Process for coproducing di- and/or polyisocyanates and glycols
    99.
    发明授权
    Process for coproducing di- and/or polyisocyanates and glycols 有权
    共聚产生二 - 和/或多异氰酸酯和二醇的方法

    公开(公告)号:US09000213B2

    公开(公告)日:2015-04-07

    申请号:US13502763

    申请日:2010-10-27

    摘要: A process for coproducing di- and/or polyisocyanates and glycols, comprising process stages A, B, C and E for preparing glycols and process stages A, C, D, E, F and G for preparing di- and/or polyisocyanates,which comprises accomplishing the material coupling via the separation of the reaction mixture obtained in process stage A into process stages B and C, by in process stage A, reacting an aqueous alkylene oxide with carbon dioxide to give a reaction mixture comprising alkylene carbonate, hydrolyzing a portion of the alkylene carbonate-comprising reaction mixture obtained in process stage A to glycol in process stage B, dewatering the remaining alkylene carbonate-comprising stream of the reaction mixture from process stage A in process stage C, in process stage D, synthesizing amine by hydrogenating an aromatic nitro compound or a nitrile, in process stage E, transesterifying the dewatered alkylene carbonate-comprising mixture from process stage C with a monohydroxy alcohol to give the corresponding dialkyl carbonate, obtaining glycol as a coproduct, in process stage F, reacting the dialkyl carbonate-comprising reaction mixture obtained in process stage E with the amine obtained in process stage D to a mixture comprising the corresponding mono-, di- and/or polycarbamate, which in process stage G is cleaved to obtain the corresponding di- and/or polyisocyanate.

    摘要翻译: 用于共混生产二 - 和/或多异氰酸酯和二醇的方法,包括制备二元醇和工艺阶段A,C,D,E,F和G的制备二 - 和/或多异氰酸酯的工艺阶段A,B,C和E, 包括通过在工艺阶段A中将经处理阶段A获得的反应混合物分离成工艺阶段B和C来实现材料偶联,使环氧烷水溶液与二氧化碳反应,得到包含碳酸亚烷基酯的反应混合物,水解部分 在工艺阶段B中获得的含碳酸亚烷基酯的反应混合物在工艺阶段B中与二醇的混合物,在工艺阶段D中将来自反应混合物的剩余的含有碳酸亚烃的物流从工艺阶段C脱水,通过氢化合成胺 芳香族硝基化合物或腈,在工艺阶段E中,将来自工艺阶段C的脱水的含碳酸亚烷基酯混合物与单羟基醇酯交换,得到 相应的碳酸二烷基酯,在工艺阶段F中获得二醇作为副产物,将在工艺阶段E中获得的含碳酸二烷基酯的反应混合物与在工艺阶段D中获得的胺反应到包含相应的单 - ,二 - 和/ 或聚氨酯,其在工艺阶段G被切割以获得相应的二 - 和/或多异氰酸酯。