摘要:
A process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in a reactor which is manufactured from a steel with specific elemental composition on its side in contact with the reaction gas, and also partial oxidations of the dehydrogenated hydrocarbon and the reactor itself.
摘要:
In a process for heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid, the starting reaction gas mixture is oxidized over a fixed catalyst bed 1 which consists of at least two fixed catalyst bed zones and is accommodated in two successive temperature zones A, B, and the transition from temperature zone A to temperature zone B does not coincide with a transition from one fixed catalyst bed zone to another fixed catalyst bed zone.
摘要:
A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of propene to acrolein, in which the temperature of the fixed catalyst bed is increased over the time and the gas phase partial oxidation is interrupted at least once per calendar year and the gas mixture G consisting of molecular oxygen, inert gas and optionally steam is conducted through the fixed catalyst bed at a temperature of the fixed catalyst bed of from 250 to 550° C.
摘要:
A process for preparing an organic target compound by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound with molecular oxygen in two oxidation reactor lines operated in parallel and removal of the target compound from the mixture of the product gas streams in a workup line, wherein the catalyst charge of one of the oxidation lines comprises a portion of catalyst over which the heterogeneously catalyzed gas phase partial oxidation has already been carried out for longer than over the portions of catalyst of the catalyst charge of the other oxidation reactor line.
摘要:
A multimetal oxide material contains the elements Mo, V and Te and/or Sb and at least one of the elements Nb, Ti, W, Ta and Ce and promoters and has a specific X-ray diffraction pattern. Moreover, such a multimetal oxide material is used as a catalyst for heterogeneously catalyzed gas-phase partial oxidations of hydrocarbons.
摘要:
A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of propene to acrolein, in which the temperature of the fixed catalyst bed is increased over the time and the gas phase partial oxidation is interrupted at least once per calendar year and the gas mixture G consisting of molecular oxygen, inert gas and optionally steam is conducted through the fixed catalyst bed at a temperature of the fixed catalyst bed of from 250 to 550° C.
摘要:
A process for preparing (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound over a fresh fixed catalyst bed, in which the process is started up at a reduced hourly space velocity of charging gas mixture on the fixed catalyst bed.