公开(公告)号：US5399649A

公开(公告)日：1995-03-21

申请号：US232938

申请日：1994-04-25

申请人： Tadashi Okawa

发明人： Tadashi Okawa

IPC分类号： C08G77/06 ,  C08G77/08 ,  C08G77/16

CPC分类号： C08G77/06 ,  C08G77/08 ,  C08G77/16

摘要： A method for the high-purity synthesis of a diorganopolysiloxane having a functional group at only one molecular chain terminal, that is characterized by the preliminary silylation with a silylating agent of the silanol group-containing impurity present in the cyclic trisiloxane, and that is characterized by preliminarily converting the silanol group-containing impurity in the cyclic trisiloxane into a lithiated material by lithiation with an organolithium compound and then silylating this lithiated material using a silylating agent that contains silicon-bonded halogen.

摘要翻译： 一种仅在一个分子链末端具有官能团的二有机聚硅氧烷的高纯度合成方法，其特征在于用环状三硅氧烷中存在的含硅烷醇基的杂质的甲硅烷基化剂进行甲硅烷基化，其特征在于 通过用有机锂化合物锂化，将环状三硅氧烷中的含硅烷醇基的杂质预先转化为锂化物质，然后使用含硅键合的卤素的甲硅烷基化剂使该锂化物质甲硅烷基化。

公开(公告)号：US5238967A

公开(公告)日：1993-08-24

申请号：US7436

申请日：1993-01-22

申请人： Tadashi Okawa ,  Manabu Suto

发明人： Tadashi Okawa ,  Manabu Suto

IPC分类号： C08J9/02 ,  C08L83/04 ,  C08L83/05 ,  C08L83/06

CPC分类号： C08J9/02 ,  C08L83/04 ,  C08G77/12 ,  C08G77/16 ,  C08G77/70 ,  C08J2383/04

摘要： The presence in curable, foamable organosiloxane compositions of an organosiloxane containing at least one diphenylsiloxane unit, a triorganosiloxane unit and a silanol group imparts a high expansion ratio, an excellent moldability, and an excellent storage stability, and that is not subject to post-cure whitening.

公开(公告)号：US5041591A

公开(公告)日：1991-08-20

申请号：US567888

申请日：1990-08-15

申请人： Tadashi Okawa

发明人： Tadashi Okawa

IPC分类号： C08G77/48 ,  C08G77/50

CPC分类号： C08G77/50 ,  C08G77/485

摘要： The present invention provides an organohydrogenpolysiloxane which does not have an average chemical structure as encountered with organopolysiloxanes prepared by equilibration polymerization reactions, but rather which has a clear, defined chemical structure in which the position and number of silicon-bonded hydrogen groups is clearly defined. The organopolysiloxane has a branched structure in the vicinity of one terminal of the molecular chain and has the silicon-bonded hydrogen group at each of the resulting derivative terminals. The organopolysiloxanes can be addition-reacted with, for example, organic compounds having various functional groups to give organopolysiloxane having two organofunctional groups clustered at one terminal.

公开(公告)号：US4808933A

公开(公告)日：1989-02-28

申请号：US13545

申请日：1987-02-11

申请人： Sumio Kobayashi ,  Mutsuo Tokashiki ,  Hiroyuki Tomita ,  Tadashi Okawa ,  Hiroshi Sugai

发明人： Sumio Kobayashi ,  Mutsuo Tokashiki ,  Hiroyuki Tomita ,  Tadashi Okawa ,  Hiroshi Sugai

IPC分类号： G01P3/42 ,  G01P3/46 ,  G01P3/44 ,  G01P3/56

CPC分类号： G01P3/46

摘要： A signal whose frequency is proportional to a rotational speed of a rotor and whose rising and falling angles near points crossing zero becomes larger with the rotational speed of the rotor is used to produce a first signal of amplitude corresponding to the rising and falling angles and a second signal of amplitude corresponding to the frequency, a difference between the first and second signals is evaluated, and the first or second signals are corrected with the difference.

摘要翻译： 使用频率与转子的转速成比例的信号，并且其转角零点附近的上升和下降角随着转子的旋转速度变大而产生对应于上升和下降角的幅度的第一信号，以及 第二信号与频率相对应，第一和第二信号之间的差被评估，并且第一或第二信号用差值进行校正。

公开(公告)号：US09486652B2

公开(公告)日：2016-11-08

申请号：US12670410

申请日：2008-07-24

申请人： Hidefumi Araki ,  Kei Watanabe ,  Yasunari Nakama ,  Teruhiko Hineno ,  Tomohiro Ilmura ,  Tadashi Okawa

发明人： Hidefumi Araki ,  Kei Watanabe ,  Yasunari Nakama ,  Teruhiko Hineno ,  Tomohiro Ilmura ,  Tadashi Okawa

IPC分类号： A61K8/89 ,  A61Q19/00 ,  A61K8/04 ,  A61K8/34 ,  A61K8/891 ,  C08K5/05 ,  A61K8/58 ,  C08G77/04 ,  C08G77/14 ,  A61Q1/10 ,  A61Q1/02 ,  A61Q17/04 ,  C08G77/12

CPC分类号： A61Q19/007 ,  A61K8/042 ,  A61K8/34 ,  A61K8/585 ,  A61K8/891 ,  A61K2800/544 ,  A61Q1/02 ,  A61Q1/10 ,  A61Q17/04 ,  C08G77/045 ,  C08G77/12 ,  C08G77/14 ,  C08K5/05 ,  C08L83/06

摘要： The present invention provides a gel composition having improved texture in use. A gel composition consisting of an organosiloxane derivative represented by the following formula (1) or (3), a monohydric aliphatic alcohol having 10 to 30 carbon atoms, and water.

公开(公告)号：US08686174B2

公开(公告)日：2014-04-01

申请号：US13140560

申请日：2009-12-21

申请人： Tadashi Okawa

发明人： Tadashi Okawa

IPC分类号： C07F7/18

CPC分类号： C08G77/46 ,  A61K8/894 ,  A61Q19/00

摘要： The present invention provides a novel modified-polysiloxane, method for producing the same, and a cosmetic containing the same. The aforementioned modified-polysiloxane exhibits a reduced viscosity and superior operationability as compared with conventional polyoxyalkylene-modified polysiloxanes and polyglycerol-modified polysiloxanes. In addition, since the modified-polysiloxane is hardly oxidized in air, hardly produce allergenic compounds such as formates, and aldehydes such as formaldehyde, during storage over time, an increased environmental compatibility can be exhibited. In addition, the modified-polysiloxane of the present invention exhibits a reduced hydrolysis property and is stable. In the modified-polysiloxane of the present invention, the terminal hydroxyl groups of a polyglycerol-modified polysiloxane are partially blocked with hydrocarbon groups.

摘要翻译： 本发明提供了一种新的改性聚硅氧烷，其制备方法和含有该改性聚硅氧烷的化妆品。 与以往的聚氧化烯改性聚硅氧烷和聚甘油改性聚硅氧烷相比，上述改性聚硅氧烷显示出比较好的粘度和优异的操作性。 此外，由于改性聚硅氧烷在空气中几乎不被氧化，因此在储存期间几乎不会产生过敏化合物如甲酸盐和醛类等甲醛，因此可以显示出增加的环境相容性。 此外，本发明的改性聚硅氧烷显示出降低的水解性能并且是稳定的。 在本发明的改性聚硅氧烷中，聚甘油改性聚硅氧烷的末端羟基被烃基部分封端。

公开(公告)号：US08513174B2

公开(公告)日：2013-08-20

申请号：US12866286

申请日：2009-01-30

申请人： Hidefumi Araki ,  Tomohiko Kimura ,  Yasunari Nakama ,  Kei Watanabe ,  Tadashi Okawa ,  Tomohiro Iimura

发明人： Hidefumi Araki ,  Tomohiko Kimura ,  Yasunari Nakama ,  Kei Watanabe ,  Tadashi Okawa ,  Tomohiro Iimura

IPC分类号： C11D1/02 ,  C11D3/16 ,  C11D3/37

CPC分类号： A61K8/89 ,  A61K8/361 ,  A61K8/466 ,  A61K8/585 ,  A61Q1/14 ,  A61Q5/02 ,  C11D1/06 ,  C11D1/28 ,  C11D3/162 ,  C11D3/373 ,  C11D9/225 ,  C11D9/36

摘要： The present invention provides a cleanser which is excellent in both of the foaming property and the cleansing capability. The cleanser comprises an organosiloxane derivative salt represented by the following formula (1) or (3) and one or more anionic surfactants selected from a group consisting of carboxylate salt with an alkyl group having 10 to 20 carbon atoms, sulfate salt with an alkyl group having 10 to 20 carbon atoms, sulfonate salt with an alkyl group having 10 to 20 carbon atoms, and phosphate salt with an alkyl group having 10 to 20 carbon atoms.

摘要翻译： 本发明提供一种发泡性和清洁性都优异的清洁剂。 洗涤剂包含由下式（1）或（3）表示的有机硅氧烷衍生物盐和一种或多种选自羧酸盐与碳原子数为10〜20的烷基的阴离子表面活性剂，硫酸盐与烷基 具有10至20个碳原子的烷基，具有10至20个碳原子的烷基的磺酸盐和具有10至20个碳原子的烷基的磷酸盐。

公开(公告)号：US07989581B2

公开(公告)日：2011-08-02

申请号：US12301600

申请日：2007-05-17

申请人： Tadashi Okawa

发明人： Tadashi Okawa

IPC分类号： C08G65/28 ,  C08L71/08

CPC分类号： C07C43/178 ,  C08G65/22 ,  C08G65/2609 ,  C08G65/2648

摘要： Polyether represented by R(—O—Xn—Zm—Y)p {R is a monovalent hydrocarbyl group that contains no more than 20 carbon atoms and that may contain an aliphatically unsaturated bond or is a group comprising the preceding group having an ether linkage therein; n is 1 to 200; m is 0 to 200; 0

摘要翻译： 由R（-O-Xn-Zm-Y）表示的聚醚p {R是含有不超过20个碳原子并且可以含有脂族不饱和键的一价烃基，或者是包含前述具有醚键的基团 其中 n为1〜200; m为0〜200; 0

公开(公告)号：US20110135585A1

公开(公告)日：2011-06-09

申请号：US13057177

申请日：2009-07-31

申请人： Tomoko Ikeda ,  Shuji Nishihama ,  Tomo Osawa ,  Yasunari Nakama ,  Tomohiro Iimura ,  Tadashi Okawa

发明人： Tomoko Ikeda ,  Shuji Nishihama ,  Tomo Osawa ,  Yasunari Nakama ,  Tomohiro Iimura ,  Tadashi Okawa

IPC分类号： A61K8/92 ,  A61K47/44 ,  A61Q1/10 ,  A61Q1/02

CPC分类号： B01F17/0071 ,  A61K8/06 ,  A61K8/064 ,  A61K8/40 ,  A61K8/442 ,  A61K8/466 ,  A61K8/585 ,  A61K8/891 ,  A61Q1/02 ,  A61Q1/10 ,  A61Q19/00

摘要： A stable emulsion cosmetic having an excellent texture in use, and in particular, a solid emulsion cosmetic which is stable in a system containing a large amount of water is provided. The complex consists of an organosiloxane derivative represented by the following formula (1) or (2) and an amphoteric surfactant and/or semipolar surfactant.

摘要翻译： 提供了具有优异使用质地的稳定的乳液化妆品，特别是在含有大量水的体系中稳定的固体乳液化妆品。 复合物由下式（1）或（2）表示的有机硅氧烷衍生物和两性表面活性剂和/或半极性表面活性剂组成。

公开(公告)号：US20100310496A1

公开(公告)日：2010-12-09

申请号：US12810259

申请日：2008-12-25

申请人： Tomohiro Iimura ,  Shinya Oguri ,  Masaru Ozaki ,  Tadashi Okawa ,  Bethany Johnson ,  Anne-Marie Vincent ,  Giada Tonet

发明人： Tomohiro Iimura ,  Shinya Oguri ,  Masaru Ozaki ,  Tadashi Okawa ,  Bethany Johnson ,  Anne-Marie Vincent ,  Giada Tonet

IPC分类号： A61K31/765 ,  A61Q19/10 ,  A61Q5/02 ,  C08G77/38

CPC分类号： C08G77/388 ,  A61K8/898 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/00 ,  A61Q19/10 ,  C08G77/14

摘要： The present invention relates to an amino acid-modified organopolysiloxane emulsion obtainable by reacting (a) a carboxy-unprotected amino acid, and (b) organopolysiloxane having an epoxy group in the molecule in an aqueous medium in the presence of a surfactant, is incorporated in a cosmetic product. The present invention also relates to the simple and highly efficient production of emulsions of amino acid-modified polysiloxane, as well as the use of the emulsions as beautifying components.

摘要翻译： 本发明涉及通过在（a）羧基未保护的氨基酸和（b）分子中在表面活性剂存在下在水性介质中具有环氧基的有机聚硅氧烷反应而获得的氨基酸改性的有机聚硅氧烷乳液， 在化妆品中。 本发明还涉及氨基酸改性聚硅氧烷的乳液的简单且高效的生产，以及使用乳液作为美容成分。