WATERBASED FORMALDEHYDE FREE ADHESIVES
    92.
    发明申请
    WATERBASED FORMALDEHYDE FREE ADHESIVES 审中-公开
    含水甲醛免费粘合剂

    公开(公告)号:US20110200830A1

    公开(公告)日:2011-08-18

    申请号:US13054071

    申请日:2009-07-14

    摘要: There is described a formaldehyde-free laminating adhesive, optionally the with less than 3% by weight of co-solvent(s), the adhesive comprising: (I) a polyurethane that comprises from 30% to 65% by weight of hard segments, the polyurethane being obtained and/or obtainable from a first polyurethane dispersion (PUD) comprising the reaction product of (A) an organic isocyanate and (B) at least one chain extender reacting in a respective stoichiometric ratio (NCO to NCO reactive group) from 1:1 to 1:2.5 and; optionally the NCO reactive group(s) of the chain extender comprises one or more hydrazinyl-like group(s) (denoting isocyanate reactive groups selected from the group comprising, preferably consisting of: —NRNR2 (hydrazinyl groups); —CONRNR2 (hydrazidyl groups), —NRCONRNR2 (semicarbazidyl groups); and —ONR2 (oxyamine groups), where each R is independently selected from H or C1-10hydrocarbo); and (II) optionally a second polymer obtained and/or obtainable from a polymer precursor comprising at least one unsaturated moiety, preferably an ethylenically unsaturated group, and where optionally the second polymer may be iminated; with the provisos that: (α) when the first polyurethane does not comprise hydrazinyl-like group(s) then the second polymer is iminated; and (β) when the second polymer is un-iminated or is absent then the first polyurethane comprises hydrazinyl-like group(s). These adhesives may be used to adhere surface veneers to wood and/or to laminate the layers within plywood.

    摘要翻译: 描述了不含甲醛的层合粘合剂,任选地具有小于3重量%的助溶剂,粘合剂包含:(I)包含30重量%至65重量%硬链段的聚氨酯, 所述聚氨酯由包含(A)有机异氰酸酯和(B)至少一种以相应的化学计量比(NCO至NCO反应性基团)反应的至少一种扩链剂的反应产物的第一聚氨酯分散体(PUD)获得和/或获得, 1:1至1:2.5和; 任选地,扩链剂的NCO反应性基团包含一个或多个肼基 - 类基团(表示选自以下的异氰酸酯反应性基团:优选由以下基团组成:-NRNR2(腙基); -CONRNR2(肼基 ),-NRCONRNR2(氨基脲基);和-ONR2(羟胺基),其中每个R独立地选自H或C1-10氢化碳基); 和(II)任选的第二聚合物,其由包含至少一个不饱和部分,优选烯键式不饱和基团的聚合物前体获得和/或可获得,并且其中任选地第二聚合物可以被亚胺化; 条件是:(α)当第一聚氨酯不包含肼基 - 类基团时,则第二聚合物被仿制; 和(&bgr)时,当第二聚合物不被化学或不存在时,第一种聚氨酯包括类似肼基的基团。 这些粘合剂可以用于将表面胶合板粘附到木材上和/或将胶层层压在胶合板中。

    Aqueous Polyurethane Hybrid Compositions
    95.
    发明申请
    Aqueous Polyurethane Hybrid Compositions 审中-公开
    水性聚氨酯混合组合物

    公开(公告)号:US20110009561A1

    公开(公告)日:2011-01-13

    申请号:US12918097

    申请日:2009-02-16

    IPC分类号: C09D175/00 C09J175/04

    摘要: Waterborne aromatic urethane-acrylic hybrid or composite compositions are disclosed that are low or free from N-methyl pyrrolidone and generally free of volatile organic solvents in their preparation are disclosed. The use of ethylene glycol monoalkyl ether or propylene glycol monoalkyl ethers in preparing the dispersion is taught. The use of ketone functional oligomers to improve the final dispersion quality is taught. The use of acrylate monomer(s) to reduce the viscosity of the prepolymer is taught.

    摘要翻译: 公开了低或不含N-甲基吡咯烷酮并且在其制备中通常不含挥发性有机溶剂的水性芳族聚氨酯 - 丙烯酸混合物或复合组合物。 教导了在制备分散体中使用乙二醇单烷基醚或丙二醇单烷基醚。 教导了使用酮官能低聚物来提高最终的分散质量。 教导了使用丙烯酸酯单体降低预聚物的粘度。

    Water dispersions of non-uniform polyurethane particles
    97.
    发明授权
    Water dispersions of non-uniform polyurethane particles 有权
    不均匀聚氨酯颗粒的水分散体

    公开(公告)号:US07582698B2

    公开(公告)日:2009-09-01

    申请号:US10733027

    申请日:2003-12-11

    摘要: A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers; and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.

    摘要翻译: 一种制备非均匀聚氨酯颗粒的水性分散体的新方法,其包括(a)制备具有不同亲水性的至少两种异氰酸酯封端的聚氨酯预聚物; (b)制备所述预聚物的均匀混合物; 和(c)将混合的预聚物分散在水性介质中。 所得到的预聚物分散体可任选地进一步延伸。 这种方法能够制备核 - 壳颗粒以及其他形态的颗粒,包括“覆盆子”,互穿网络,“盐和胡椒”,“冰淇淋锥”和梯度组成的颗粒。 类似地,可以通过首先制备至少两种不同的异氰酸酯封端的聚氨酯预聚物,制备这种预聚物的均匀混合物,然后将该混合物分散在水性介质中来获得两种不同聚氨酯聚合物的水分散体。

    Aqueous Dispersions Of Nanoparticle/Polyurethane Composites
    98.
    发明申请
    Aqueous Dispersions Of Nanoparticle/Polyurethane Composites 有权
    纳米颗粒/聚氨酯复合材料的水分散体

    公开(公告)号:US20080188605A1

    公开(公告)日:2008-08-07

    申请号:US11813686

    申请日:2006-01-24

    摘要: An aqueous dispersion of nanoparticle/polyurethane composites is made by forming a mixture of nanoparticles and a continuous mass of a polyurethane prepolymer in the substantial absence of water and dispersing the mixture so made in aqueous medium. Alternatively, a polyurethane prepolymer or a mixture of nanoparticles and a continuous mass of a polyurethane prepolymer is dispersed into an aqueous dispersion of nanoparticles.

    摘要翻译: 纳米颗粒/聚氨酯复合材料的水分散体通过在基本上不存在水的情况下通过形成纳米颗粒和连续质量的聚氨酯预聚物的混合物来制备,并将如此制备的混合物在水性介质中分散。 或者,将聚氨酯预聚物或纳米颗粒和连续质量的聚氨酯预聚物的混合物分散到纳米颗粒的水性分散体中。