摘要:
New dichroic dyestuffs for the guest-host type liquid crystal and new liquid crystal compositions containing said dyestuff having an excellent improved dichroism and being prepared by introducing at least one group selected from the group consisting of phenyl, cyclohexyl, phenylcarbonyloxy and phenyloxycarbonyl group into a phenyl, a cyclohexyl or a naphthyl group at its 4-position, which is arranged at the end of a known dichroic dyestuff molecule along the major axis of the molecule.
摘要:
The invention relates to a process for the preparation of aromatic hydroxy compounds, starting from the corresponding halogenated aromatic compounds and replacing the halogen atom or atoms by the hydroxyl group. The process comprises converting the halogenated aromatic compound into the hydroxy compound by treatment with concentrated sulfuric acid, with the addition of an aldehyde and at elevated temperature.The aromatic hydroxy compounds are used as intermediates, for example for the manufacture of disperse and vat dyes.
摘要:
This invention relates to an anthraquinone dyestuff for cellulose containing fibers represented by the formula: ##STR1## wherein R.sup.1 represents amino or hydroxyl, R.sup.2 represents hydrogen, chlorine, bromine, cyano or --SO.sub.2 R wherein R represents methyl, ethyl or phenyl, R.sup.3 and R.sup.4 each represents hydrogen, amino, hydroxyl, nitro, chlorine or bromine, Y represents a connecting group consisting of --O-- or --S--, one of X.sup.1 and X.sup.2 is hydrogen and the other is a group of the formula: ##STR2## wherein --Z-- represents a connecting group consisting of --O-- or --S--, --W.sup.1 represents phenyl or --NR.sup.6 R.sup.7, R.sup.5 represents hydrogen, methyl, ethyl, methoxy, ethoxy, chlorine or bromine, R.sup.6 and R.sup.7 each represents hydrogen or alkyl, alkenyl, cyclohexyl, aryl or aralkyl which may optionally be substituted by lower alkoxy, or NR.sup.6 R.sup.7 represents a 5-membered or 6-membered nitrogen-containing heterocyclic ring formed by combination of R.sup.6 and R.sup.7, and n is 0 or 1, with the proviso that where X.sup.2 is hydrogen, n is 0.
摘要翻译:本发明涉及由下式表示的含纤维素的纤维素染料:其中R1表示氨基或羟基,R2表示氢,氯,溴,氰基或-SO2R,其中R表示甲基,乙基或苯基,R3和R4 各自表示氢,氨基,羟基,硝基,氯或溴,Y表示由-O-或-S-组成的连接基团,X1和X2之一为氢,另一个为下式基团:其中 -Z-表示由-O-或-S-组成的连接基团,-W1表示苯基或-NR6R7,R5表示氢,甲基,乙基,甲氧基,乙氧基,氯或溴,R6和R7各自表示氢或烷基, 烯基,环己基,芳基或芳烷基,其可任选被低级烷氧基取代,或NR 6 R 7表示通过R6和R7的组合形成的5元或6元含氮杂环,n为0或1,条件是 其中X2是氢,n是0。
摘要:
The use of a dye of the general formula I ##STR1## where R is a heterocyclic radical, X is hydrogen, nitro, or unsubstituted or substituted amino, hydroxyl or mercapto and Y is hydrogen, nitro, or unsubstituted or substituted amino, hydroxyl or mercapto, and the ring A can be additionally substituted, in an electro-optical display containing liquid crystals, and a liquid-crystal mixture containing a dye of the general formula in claim 1.
摘要:
1-Hydroxy-4-amino-5- or -8-nitroanthraquinone is obtained in high yields and in high purity when 1,8-dinitroanthraquinone or 1,5-dinitroanthraquinone respectively is reacted below 80.degree. C. in oleum in the presence of boric acid with reducing agents. The products of the process are valuable polyester dyestuffs as well as dyestuff intermediate products.
摘要:
Dyestuff formulations which contain a dyestuff with at least one of the groupings of the formula ##STR1## and an emulsifying polar-nonpolar compound, are outstanding suitable for dyeing synthetic fibres since they are well soluble in the dyeing bath and do not require expensive formulation process for their preparation.In the formulae, the symbols have the following meanings:G is a bridge member,A is alkylene,X is hydrogen, Y, --COY or --CONR.sub.1 R.sub.2,Y is alkyl, cycloalkyl, aralkyl or aryl,R.sub.1 is hydrogen or Y,R.sub.2 is hydrogen or alkyl andn is a number from 1 to 7, with the proviso that n is at least 2 if X is --COY.
摘要:
A composition for nematic liquid crystal color display elements, said composition comprising at least one anthraquinonic dye represented by the following formula ##STR1## wherein X and Y are identical or different and represent --NH.sub.2 or --OH; Z represents halogen, --OR, --NHR, ##STR2## --CONHR.sub.2 or --COOR.sub.2, in which R represents an alkyl group having 1 to 15 carbon atoms or a lower alkyl group optionally substituted by --OH, ##STR3## represents hydrogen, halogen, --OH, --OCH.sub.3, an alkyl group having 1 to 15 carbon atoms, or a methoxy group optionally substituted by ##STR4## and R.sub.2 is a phenyl group, an alkyl group having 2 to 5 carbon atoms or a cyclohexyl group; and n is an integer of 1 or 2 provided that when X is --NH.sub.2 and Y is --OH, and when X and Y are both --OH, n is an integer of 1, and when n represents an integer of 2, the two Z's may be identical or different dissolved in at least one nematic liquid crystal.
摘要:
Basic dyes free from sulfo groups of the formula ##STR1## in which Q signifies an unsubstituted or substituted phenyl or naphthyl radical,R.sub.1 and R.sub.2 signify hydrogen, unsubstituted or substituted alkyl, phenyl or cycloalkyl,R.sub.3 signifies hydrogen, unsubstituted or substituted alkyl or phenyl,the Z containing group signifies a heterocyclic diazo radical containing a quaternary ammonium group,R.sub.4 signifies unsubstituted or substituted alkyl, alkenyl, cycloalkyl or alkoxy,x signifies 1 to 3,A.crclbar. signifies an anion, andD signifies an unsubstituted or substituted phenylene or naphthylene radical are useful for dyeing and printing homo- and co-polymers of acrylonitrile and asymmetrical dicyanoethylene and synthetic polyamides and polyesters modified to contain acid groups. The obtained dyeings are level and fast to light and wet treatments.
摘要:
Liquid crystal compositions containing pleochroic dyes. The pleochroic dyes are substituted anthraquinone dyes containing at least one carbocyclic or heterocyclic group linked to the anthraquinone moiety through a sulfur atom. The dyes are used in guest-host combinations with nematic liquid crystal compositions having positive dielectric anisotropy. Electro-optic devices containing these guest-host combinations are disclosed.
摘要:
A process for the preparation of new dyestuff compositions which contain one or more basic dyestuffs in the form of dyestuff bases from the series of the triarylmethane, indoldiarylmethane, azine, oxazine, thiazine or xanthene dyestuffs or one or more basic dyestuffs of the series of the azo, anthraquinone, phthalocyanine, styryl, quinophthalone, benzoxanthene, naphthoylene-benzimidazole, naphthalimide or nitro series, carrying a primary, secondary or tertiary amino group or a guanidino or hydrazino group, as well as one or more non-ionic or slightly cationic surface-active agents and, optionally, water and/or an organic solvent miscible with water, which process comprises synthesizing the dyestuff in the surface-active agent optionally containing water and/or an organic solvent miscible with water, and then adding, if necessary, water and/or a solvent miscible with water and a further surface-active agent, this process of the invention having the advantage that an intermediate isolation, drying or grinding of the dyestuffs contained in the dyestuff compositions defined above is not necessary, so that the dyestuffs need not be introduced as substance into the surface-active agent and the solvent in a process wherein compositions of this type are prepared by a usual mixing, kneading or melting process; moreover, higher dyestuff yields are obtained in the dyestuff synthesis, and it allows to prepare dyestuff compositions from dyestuffs which are difficult to be isolated in substance after synthesis and often precipitate as oily or smeary products. The dyestuff compositions obtained according to the process of the invention, which are pastes or liquids, have a high stability upon storage. After being diluted with an aqueous solution of an amount at least equivalent to the dyestuff of an inorganic or organic acid, as well as, optionally, after the addition of dyeing and/or printing auxiliaries, the novel dyestuff compositions are suitable for dyeing or printing textile material containing acid groups.