公开(公告)号：US08188192B2

公开(公告)日：2012-05-29

申请号：US12339356

申请日：2008-12-19

申请人： Dale Lee Handlin, Jr. ,  Phillip Doerpinghaus ,  Sandra Horton, legal representative ,  Keith Eiden ,  Margaret Clawson

发明人： Dale Lee Handlin, Jr. ,  Phillip Doerpinghaus ,  Keith Eiden ,  Margaret Clawson

IPC分类号： C08F257/02

CPC分类号： A61L31/048 ,  A61L15/24 ,  C08F8/04 ,  C08J5/18 ,  C08J2353/02 ,  C08K5/01 ,  C08L23/00 ,  C08L23/0853 ,  C08L25/06 ,  C08L53/025 ,  C08L2205/02 ,  Y10S525/901 ,  Y10S526/938 ,  C08L53/02 ,  C08F297/04 ,  C08L2666/04

摘要： Elastomeric films which are both soft and thermally, UV and oxidatively stable are provided. The films are composed of coupled, selectively hydrogenated block copolymers having a relatively high molecular weight and high vinyl content. In addition to the block copolymer other components may be present in formulated films such as other block copolymers, hydrocarbon resins, polyolefins, metallocene polyolefins, homopolystyrene or mineral oils. The softness of the films is determined by the stress at 100% tensile elongation where the films with suitable softness have a 100% stress of about 100 psi or less. While soft, the films also are strong with tensile strengths of 1000 psi or more and suitable hysteresis properties. The elastomeric films are useful as integral components of personal hygiene articles such as gloves, diapers, incontinence products, disposable swimwear and disposable undergarments.

摘要翻译： 提供软和热，UV和氧化稳定的弹性体膜。 该膜由具有相对较高分子量和高乙烯基含量的偶联的选择性氢化嵌段共聚物组成。 除了嵌段共聚物之外，其它组分可以存在于配制的膜中，例如其它嵌段共聚物，烃树脂，聚烯烃，茂金属聚烯烃，均聚苯乙烯或矿物油。 膜的柔软度由100％拉伸伸长率下的应力决定，其中适当柔软度的膜具有约100psi或更小的100％应力。 虽然柔软，但是膜也很强，抗拉强度为1000psi或更大，并且具有合适的滞后性能。 弹性膜可用作个人卫生用品如手套，尿布，失禁产品，一次性泳装和一次性内衣的组成部分。

公开(公告)号：US08124693B2

公开(公告)日：2012-02-28

申请号：US11605025

申请日：2006-11-28

申请人： Joseph P. Kennedy ,  Zheng Fang

发明人： Joseph P. Kennedy ,  Zheng Fang

IPC分类号： C08F293/00 ,  C08F255/08

CPC分类号： C08F297/00 ,  C08F8/06 ,  C08F8/12 ,  C08F8/22 ,  C08F293/005 ,  C08F2438/01 ,  C08F2810/30 ,  C08F2810/40 ,  Y10S525/901 ,  C08F112/12 ,  C08F8/42 ,  C08F110/10

摘要： Various novel block cationomers comprising polyisobutylene (PIB) and poly(2-dimethylamino)ethyl methacrylate) (PDMAEMA) segments have been synthesized and characterized. The specific targets were various molecular weight diblocks (PDMAEMA+) and triblocks (PDMAEMA+-b-PIB-b-PDMAEMA+) with the PIB blocks in the DPn=50-200 (Mn=3,000-9,000 g/mol) range connected to blocks of PDMAEMA+ cations in the DPn=5-20 range. The overall synthetic strategy for the preparation of these block cationomers comprised four steps: 1) Synthesis by living cationic polymerization of mono- and di-allyltelechelic polyisobutylenes, 2) End group transformation to obtain PIBs fitted with termini capable of mediating the atom transfer radical polymerization (ATRP) of DMAEMA, 3) ATRP of DMAEMA and 4) Quaternization of PDMAEMA to PDMAEMA+I− by CH3I. Kinetic and model experiments provided guidance to develop convenient synthesis methods. The microarchitecture of PIB-PDMAEMA di- and triblock and the corresponding block cationomers were confirmed by 1H NMR and FTIR spectroscopy and solubility studies.

摘要翻译： 已经合成了各种包含聚异丁烯（PIB）和聚（2-二甲基氨基）乙基甲基丙烯酸酯）（PDMAEMA）链段的新型嵌段阳离子。 具体目标是各种分子量二嵌段（PDMAEMA +）和三嵌段（PDMAEMA + -b-PIB-b-PDMAEMA +），DPn = 50-200（Mn = 3,000-9,000g / mol）范围内的PIB嵌段连接到 PDMAEMA +阳离子在DPn = 5-20范围内。 制备这些嵌段阳离子的总体合成策略包括四个步骤：1）通过单 - 和二 - 烯丙基可可聚异丁烯的阳离子聚合合成2）端基转化获得配有能够介导原子转移自由基聚合的末端的PIB （ATRP），3）DMAEMA的ATRP和4）通过CH 3 I对PDMAEMA + I-的PDMAEMA进行季铵化。 动力学和模型实验为开发方便的合成方法提供了指导。 通过1 H NMR和FTIR光谱和溶解度研究证实了PIB-PDMAEMA二 - 和三嵌段的微结构和相应的嵌段阳离子。

公开(公告)号：US20090163361A1

公开(公告)日：2009-06-25

申请号：US12339356

申请日：2008-12-19

申请人： Dale Lee Handlin, JR. ,  Phillip Doerpinghaus ,  Keith Eiden ,  Margaret Clawson

发明人： Dale Lee Handlin, JR. ,  Phillip Doerpinghaus ,  Keith Eiden ,  Margaret Clawson

IPC分类号： C08F236/10 ,  B01J20/26

CPC分类号： A61L31/048 ,  A61L15/24 ,  C08F8/04 ,  C08J5/18 ,  C08J2353/02 ,  C08K5/01 ,  C08L23/00 ,  C08L23/0853 ,  C08L25/06 ,  C08L53/025 ,  C08L2205/02 ,  Y10S525/901 ,  Y10S526/938 ,  C08L53/02 ,  C08F297/04 ,  C08L2666/04

摘要： Elastomeric films which are both soft and thermally, UV and oxidatively stable are provided. The films are composed of coupled, selectively hydrogenated block copolymers having a relatively high molecular weight and high vinyl content. In addition to the block copolymer other components may be present in formulated films such as other block copolymers, hydrocarbon resins, polyolefins, metallocene polyolefins, homopolystyrene or mineral oils. The softness of the films is determined by the stress at 100% tensile elongation where the films with suitable softness have a 100% stress of about 100 psi or less. While soft, the films also are strong with tensile strengths of 1000 psi or more and suitable hysteresis properties. The elastomeric films are useful as integral components of personal hygiene articles such as gloves, diapers, incontinence products, disposable swimwear and disposable undergarments.

摘要翻译： 提供软和热，UV和氧化稳定的弹性体膜。 该膜由具有相对较高分子量和高乙烯基含量的偶联的选择性氢化嵌段共聚物组成。 除了嵌段共聚物之外，其它组分可以存在于配制的膜中，例如其它嵌段共聚物，烃树脂，聚烯烃，茂金属聚烯烃，均聚苯乙烯或矿物油。 膜的柔软度由100％拉伸伸长率下的应力决定，其中适当柔软度的膜具有约100psi或更小的100％应力。 虽然柔软，但是膜也很强，抗拉强度为1000psi或更大，并且具有合适的滞后性能。 弹性膜可用作个人卫生用品如手套，尿布，失禁产品，一次性泳装和一次性内衣的组成部分。

公开(公告)号：US20090162592A1

公开(公告)日：2009-06-25

申请号：US12338752

申请日：2008-12-18

申请人： Kiran Baikerikar ,  Syed Z. Mahdi ,  Ben W. Schaefer

发明人： Kiran Baikerikar ,  Syed Z. Mahdi ,  Ben W. Schaefer

IPC分类号： C03C17/32 ,  C03C27/00 ,  C03C17/30 ,  C09D183/04 ,  C09J183/04

CPC分类号： C09D201/02 ,  B60J10/345 ,  C03C17/30 ,  Y10S525/901 ,  Y10S525/925 ,  Y10T428/31612

摘要： In one embodiment, the invention is a composition comprising: a) one or more film forming resins having at least one functional group capable of polymerization; b) one or more adhesion promoters comprising compounds containing one or more unsaturated groups capable of free radical polymerization and one or more trialkoxy silane groups; c) one or more fillers capable of imparting abrasion resistance to the composition when cured; d) one or more compounds which is reactive with the film forming resin which also contains an acidic moiety; and e) one or more compounds comprising a siloxane backbone and one or more active hydrogen groups capable of reacting with the functional groups on a glass bonding adhesive, one or more second adhesion promoters comprising one or more silicon, titanium, zirconium, aluminum, or metal containing compounds, organic materials having reactive groups which are reactive with reactive groups on the surface of substrates or adhesives to which the composition of the invention will be bonded or mixtures thereof.

摘要翻译： 在一个实施方案中，本发明是一种组合物，其包含：a）一种或多种具有至少一个能够聚合的官能团的成膜树脂; b）一种或多种粘合促进剂，其包含含有一个或多个能够自由基聚合的不饱和基团和一个或多个三烷氧基硅烷基团的化合物; c）一种或多种能够在固化时赋予组合物耐磨性的填料; d）一种或多种与还含有酸性部分的成膜树脂反应的化合物; 和e）一种或多种包含硅氧烷主链和能够与玻璃粘结粘合剂上的官能团反应的一个或多个活性氢基团的化合物，一种或多种第二粘合促进剂，其包含一种或多种硅，钛，锆，铝或 含有金属的化合物，具有与基材表面上的反应性基团反应的反应性基团的有机材料或与本发明组合物结合的粘合剂或其混合物。

公开(公告)号：US20080213661A1

公开(公告)日：2008-09-04

申请号：US12118483

申请日：2008-05-09

申请人： Christophe Michot ,  Alain Vallee ,  Paul-Etienne Harvey ,  Michel Gauthier ,  Michel Armand

发明人： Christophe Michot ,  Alain Vallee ,  Paul-Etienne Harvey ,  Michel Gauthier ,  Michel Armand

IPC分类号： H01M10/40 ,  H01M6/16 ,  C08F8/00

CPC分类号： C08F226/06 ,  C07C43/15 ,  C08G65/14 ,  C08G65/16 ,  C08G65/20 ,  C08G65/22 ,  C08G65/337 ,  H01B1/122 ,  H01M4/131 ,  H01M4/133 ,  H01M4/136 ,  H01M4/1393 ,  H01M4/1397 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5815 ,  H01M4/5825 ,  H01M6/164 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  Y10S525/901 ,  Y10S525/919

摘要： The present invention concerns polymers obtained by anionic initiation and bearing functions that can be activated by cationic initiations that are not reactive in the presence of anionic polymerization initiators. The presence of such cationic initiation functions allow an efficient cross-linking of the polymer after moulding, particularly in the form of a thin film. It is thus possible to obtain polymers with well-defined properties in terms of molecular weight and cross-linking density. The polymers of the present invention are capable of dissolving ionic compounds inducing a conductivity for the preparation of solid electrolytes.

摘要翻译： 本发明涉及通过阴离子引发而获得的聚合物，并且可通过在阴离子聚合引发剂存在下不具有反应性的阳离子引发而活化。 这种阳离子引发功能的存在允许聚合物在模制之后，特别是薄膜形式的有效交联。 因此，可以获得在分子量和交联密度方面具有明确特性的聚合物。 本发明的聚合物能够溶解诱导用于制备固体电解质的导电性的离子化合物。

公开(公告)号：US06890991B2

公开(公告)日：2005-05-10

申请号：US10221180

申请日：2001-03-21

申请人： Hideyuki Fujimoto ,  Atsunori Koshirai

发明人： Hideyuki Fujimoto ,  Atsunori Koshirai

IPC分类号： C08L63/00 ,  C08L101/00 ,  C08L101/06 ,  C08L27/12

CPC分类号： C08L63/00 ,  C08L101/00 ,  C08L101/06 ,  Y10S525/901 ,  C08L2666/04 ,  C08L27/00

摘要： The present invention relates to a thermoplastic resin composition which has an improved impact resistance while maintaining mechanical properties such as strength and rigidity. In the present invention, a thermoplastic resin (A) is mixed with a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 μm or less and an organic polymer (b2). In this case, the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and a polymer having an epoxy group was used as the organic polymer (b2). The thermoplastic resin composition of the present invention can be widely used in the fields of automotive parts, electric and electronic parts, and precision instrument parts.

摘要翻译： 本发明涉及一种在保持机械性能如强度和刚性的同时具有改善的耐冲击性的热塑性树脂组合物。 在本发明中，将热塑性树脂（A）与粒径为10μm以下的聚四氟乙烯（b1）和有机聚合物（b2）组成的含聚四氟乙烯的混合粉末（B）混合。 在这种情况下，混合聚四氟乙烯的混合粉末（B），相对于100重量份的热塑性树脂（A），聚四氟乙烯成分的配合量为0.0001〜20重量份， 环氧基用作有机聚合物（b2）。 本发明的热塑性树脂组合物可广泛用于汽车部件，电气电子部件和精密仪器部件领域。

公开(公告)号：US20050064093A1

公开(公告)日：2005-03-24

申请号：US10668989

申请日：2003-09-22

申请人： William Graham ,  Douglas Anton ,  Jeffery Johnson ,  Michael Michalczyk ,  Sape Quashie

发明人： William Graham ,  Douglas Anton ,  Jeffery Johnson ,  Michael Michalczyk ,  Sape Quashie

IPC分类号： B05D5/00 ,  B05D7/00 ,  B05D7/14 ,  B05D3/02

CPC分类号： B05D7/532 ,  B05D5/005 ,  B05D7/14 ,  Y10S525/901

摘要： A method for repairing a basecoat/clearcoat finish or coating comprised of a fluorinated organosilane topcoat. A fluorourethane star polyester additive is added to the fluorinated organosilane topcoat composition to improve recoat adhesion with the repair basecoat.

摘要翻译： 一种用于修补由氟化有机硅烷面漆组成的底漆/透明涂层或涂层的方法。 向氟化有机硅烷面漆组合物中加入氟代氨基甲酸酯聚酯添加剂以改善与修补底涂层的重涂性。

公开(公告)号：US20040152844A1

公开(公告)日：2004-08-05

申请号：US10762357

申请日：2004-01-23

申请人： JSR Corporation

发明人： Tomohisa Konno ,  Toshihiro Tadaki ,  Yoshiyuki Udagawa ,  Hiroshi Akema

IPC分类号： C08F120/02

CPC分类号： C08L21/00 ,  C08L9/00 ,  C08L9/02 ,  C08L9/06 ,  C08L15/00 ,  C08L19/006 ,  C08L23/16 ,  C08L33/066 ,  C08L2205/22 ,  C08L2312/00 ,  Y10S525/901 ,  Y10S525/914 ,  Y10S526/909 ,  C08L2666/08

摘要： An objective of the invention is to provide a rubber composition which has satisfactory processability and dimension stability, and the like, gives a vulcanized rubber exhibiting excellent wearing resistance and tensile strength, and the like, and thus is useful in a belt, a hose and a tire and the like, as well as a crosslinked rubber particle for obtaining such rubber composition. A rubber composition of the invention comprises null1null a crosslinked rubber particle comprising as repeating units (a) 30 to 94.89% by weight of a conjugated diene unit, (b) 5 to 69.89% by weight of an aromatic vinyl unit, (c) 0.01 to 10% by weight of a monomer unit having at least two polymerizable unsaturated group, (d)one polymerizable unsaturated group and an amino group, a hydroxyl group and an epoxy group and (e) 0.1 to 30% by weight of a monomer unit having one polymerizable unsaturated group and a carboxylic group and having a particle size of 10 to 500 nm and a toluene-insolubles of 80 by weight or more and null2null a non-crosslinked rubber component whose toluene-insolubles is less than 20% by weight.

摘要翻译： 本发明的目的是提供一种具有令人满意的加工性和尺寸稳定性等的橡胶组合物，得到具有优异的耐磨性和拉伸强度的硫化橡胶等，因此可用于带，软管和 轮胎等，以及用于获得这种橡胶组合物的交联橡胶颗粒。 本发明的橡胶组合物包含[1]交联橡胶颗粒，其包含作为重复单元（a）30至94.89重量％的共轭二烯单元，（b）5至69.89重量％的芳族乙烯基单元，（c ）0.01〜10重量％的具有至少2个聚合性不饱和基团的单体单元，（d）1个聚合性不饱和基团和氨基，羟基和环氧基，（e）0.1〜30重量％ 具有1个聚合性不饱和基团和羧基的单体单元，其粒径为10〜500nm，甲苯不溶物为80重量份以上，[2]甲苯不溶物的非交联橡胶成分为20以下 重量％。

公开(公告)号：US20030088026A1

公开(公告)日：2003-05-08

申请号：US10221180

申请日：2002-09-20

发明人： Hideyuki Fujimoto ,  Atsunori Koshirai

IPC分类号： C08F008/00 ,  C08L063/00 ,  C08L001/00

CPC分类号： C08L63/00 ,  C08L101/00 ,  C08L101/06 ,  Y10S525/901 ,  C08L2666/04 ,  C08L27/00

摘要： The present invention relates to a thermoplastic resin composition which has an improved impact resistance while maintaining mechanical properties such as strength and rigidity. In the present invention, a thermoplastic resin (A) is mixed with a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 nullm or less and an organic polymer (b2). In this case, the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and a polymer having an epoxy group was used as the organic polymer (b2). The thermoplastic resin composition of the present invention can be widely used in the fields of automotive parts, electric and electronic parts, and precision instrument parts.

摘要翻译： 本发明涉及一种在保持机械性能如强度和刚性的同时具有改善的耐冲击性的热塑性树脂组合物。 在本发明中，将热塑性树脂（A）与粒径为10μm以下的聚四氟乙烯（b1）和有机聚合物（b2）组成的含聚四氟乙烯的混合粉末（B）混合。 在这种情况下，混合聚四氟乙烯的混合粉末（B），相对于100重量份的热塑性树脂（A），聚四氟乙烯成分的配合量为0.0001〜20重量份， 环氧基用作有机聚合物（b2）。 本发明的热塑性树脂组合物可广泛用于汽车部件，电气电子部件和精密仪器部件领域。

公开(公告)号：US06492449B2

公开(公告)日：2002-12-10

申请号：US10139320

申请日：2002-05-07

申请人： Christophe Michot ,  Alain Vallée ,  Paul-Étienne Harvey ,  Michel Gauthier ,  Michel Armand

发明人： Christophe Michot ,  Alain Vallée ,  Paul-Étienne Harvey ,  Michel Gauthier ,  Michel Armand

IPC分类号： C08K310

CPC分类号： C08F226/06 ,  C07C43/15 ,  C08G65/14 ,  C08G65/16 ,  C08G65/20 ,  C08G65/22 ,  C08G65/337 ,  H01B1/122 ,  H01M4/131 ,  H01M4/133 ,  H01M4/136 ,  H01M4/1393 ,  H01M4/1397 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5815 ,  H01M4/5825 ,  H01M6/164 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  Y10S525/901 ,  Y10S525/919

摘要： The present invention concerns polymers obtained by anionic initiation and bearing functions that can be activated by cationic initiations that are not reactive in the presence of anionic polymerization initiators. The presence of such cationic initiation functions allow an efficient cross-linking of the polymer after moulding, particularly in the form of a thin film. It is thus possible to obtain polymers with well-defined properties in terms of molecular weight and cross-linking density. The polymers of the present invention are capable of dissolving ionic compounds inducing a conductivity for the preparation of solid electrolytes.

摘要翻译： 本发明涉及通过阴离子引发而获得的聚合物，并且可通过在阴离子聚合引发剂存在下不具有反应性的阳离子引发而活化。 这种阳离子引发功能的存在允许聚合物在模制之后，特别是薄膜形式的有效交联。 因此，可以获得在分子量和交联密度方面具有明确特性的聚合物。 本发明的聚合物能够溶解诱导用于制备固体电解质的导电性的离子化合物。