Method for the separation of zeolites
    124.
    发明授权
    Method for the separation of zeolites 有权
    沸石分离方法

    公开(公告)号:US06924247B2

    公开(公告)日:2005-08-02

    申请号:US10014853

    申请日:2001-12-14

    摘要: The object of the present invention relates to a simple, rapid and inexpensive process for effecting solid-liquid separations in the case of zeolites, also having small crystals. This process, which is particularly useful for the recovery of zeolite crystals in suspension in the crystallization water, comprises treating this suspension of crystals with an acid or one of its precursors and subjecting the resulting mixture to filtration or decanting.According to a particular aspect of the invention, the crystalline phase is separated in a mixture with oxides which can be used as ligands. Said oxides can be generated by the reagents of the zeolite preparation reagent mixture, not transformed into crystalline phase during the synthesis hydrothermal treatment, or they can be added to the suspension of crystals before the separation treatment, or again they can be generated by precursors suitably added to the crystallization slurry.

    摘要翻译: 本发明的目的涉及在具有小晶体的沸石的情况下实现固液分离的简单,快速和便宜的方法。 对于在结晶水中悬浮的沸石晶体的回收特别有用的该方法包括用酸或其前体之一处理该晶体悬浮液,并将所得混合物过滤或倾析。 根据本发明的特定方面,结晶相与可用作配体的氧化物以混合物分离。 所述氧化物可以通过沸石制备试剂混合物的试剂产生,在合成水热处理期间不转化为结晶相,或者可以在分离处理之前加入到晶体悬浮液中,或者再次由前体合成生成 加入到结晶浆料中。

    Catalyst for steam cracking reactions and related preparation process
    125.
    发明申请
    Catalyst for steam cracking reactions and related preparation process 失效
    催化剂用于蒸汽裂解反应及相关制备工艺

    公开(公告)号:US20030109376A1

    公开(公告)日:2003-06-12

    申请号:US10309145

    申请日:2002-12-04

    IPC分类号: C10G011/04 B01J021/16

    摘要: Catalyst for steam cracking reactions consisting of pure mayenite having the general formula:12CaO.7Al2O3having an X-ray diffraction spectrum as indicated in Table I, obtained with a preparation process comprising the following steps: dissolution of salts containing calcium and aluminum with water; completing of the dissolved salts by means of polyfunctional organic hydroxyacids; drying of the solution resulting from the completing in order to obtain a solid precursor product; calcination of the solid precursor product at a temperature ranging from 1300 to 1400null C. for at least two hours.

    摘要翻译: 用于蒸汽裂解反应的催化剂,其由具有以下通式的纯钙铝石组成:具有表C所示的X射线衍射光谱的12CaO.7Al 2 O 3,其制备方法包括以下步骤:用水溶解含钙和铝的盐; 通过多官能有机羟基酸完成溶解的盐; 干燥由此完成的溶液,以获得固体前体产物; 在1300〜1400℃的温度下煅烧固体前体产物至少2小时。

    Process for separating mixtures of hydrocarbon isomers in gas phase on molecular sieves
    126.
    发明申请
    Process for separating mixtures of hydrocarbon isomers in gas phase on molecular sieves 有权
    在分子筛上分离气相中烃异构体的混合物的方法

    公开(公告)号:US20020062056A1

    公开(公告)日:2002-05-23

    申请号:US09886994

    申请日:2001-06-25

    申请人: ENICHEM S.p.A.

    IPC分类号: C07C007/12

    CPC分类号: C07C7/13

    摘要: A process for separating hydrocarbon isomers in gas phase on molecular sieves, including feeding mixtures of hydrocarbon isomers to a primary adsorption column configured to adsorb isomers with a greater selectivity towards the molecular sieves, feeding effluent from the primary adsorption column to a secondary adsorption column configured to adsorb remaining isomers with a greater selectivity towards the molecular sieves and discharge a stream containing isomers with a lower selectivity towards the molecular sieves, feeding desorbing agent to a desorption column configured to discharge a stream containing isomers with a greater selectivity towards the molecular sieves and the desorbing agent, feeding the stream from the secondary adsorption column to a distillation unit configured to recover the desorbing agent for recycling to the desorption column, feeding the stream from the desorption column to another distillation unit configured to recover the desorbing agent for recycling to the desorption column.

    摘要翻译: 在气相中分离分子筛上的烃异构体的方法,包括将烃异构体的混合物进料到主吸附塔,该吸附塔配置成以更大选择性吸附异构体,向分子筛吸收,将来自主吸附塔的流出物供给至辅助吸附塔 以更大的选择性吸附剩余的异构体,使分子筛以较低的选择性向分子筛排出含有异构体的物流,将脱附剂输送到解吸塔,解吸塔被配置成以更高的选择性向分子筛排出含有异构体的物流, 所述脱附剂将所述二次吸附塔的料流输送到蒸馏单元,所述蒸馏单元被构造成回收所述解吸剂再循环到所述解吸塔,将所述物流从所述解吸塔输送到另一个蒸馏单元,所述蒸馏单元被构造成回收所述解吸剂以再循环 e解吸柱。

    Process for the separation of 2,6-dimethylnaphthalene from mixtures containing it
    128.
    发明申请
    Process for the separation of 2,6-dimethylnaphthalene from mixtures containing it 失效
    从含有它的混合物中分离2,6-二甲基萘的方法

    公开(公告)号:US20020023318A1

    公开(公告)日:2002-02-28

    申请号:US09851131

    申请日:2001-05-09

    申请人: ENICHEM S.p.A.

    IPC分类号: B01D009/02 C07C007/14

    CPC分类号: C07C7/14 C07C15/24

    摘要: Process for the separation of 2,6-dimethylnaphthalene from mixtures containing it, comprising the following operations: crystallization by the addition of a solvent and cooling of the mixture to a temperature higher than the formation value of the first eutectic; removal of the mother liquor by repeated washings; dissolution of the solid obtained; crystallization by cooling; filtration.

    摘要翻译: 用于从含有它的混合物的混合物中分离2,6-二甲基萘的方法,包括以下操作:通过加入溶剂进行结晶并将混合物冷却至高于第一共晶体的形成值的温度; 通过反复洗涤除去母液; 所得固体溶解; 冷却结晶; 过滤。

    Process for the production of expandable particles of styrene polymers
    130.
    发明授权
    Process for the production of expandable particles of styrene polymers 有权
    制备苯乙烯聚合物的可膨胀颗粒的方法

    公开(公告)号:US6147130A

    公开(公告)日:2000-11-14

    申请号:US300312

    申请日:1999-04-28

    摘要: Process for the production of expandable particles of styrene polymers, having improved processability characteristics, which comprises:i) producing expandable particles of styrene polymers containing from 2 to 20% of an expanding agent incorporated;ii) covering these particles with an antistatic agent in a quantity of less than 1% by weight;iii) vigorously frictioning the particles in a mixing apparatus in order to heat their surface, in a short time, by simple mechanical friction;iv) discharging the particles thus treated from the mixing apparatus.

    摘要翻译: 制备具有改进的加工性能的苯乙烯聚合物的可发性颗粒的方法,其包括:i)制备含有2至20%的引发剂的苯乙烯聚合物的可发性颗粒; ii)用小于1重量%的抗静电剂覆盖这些颗粒; iii)在混合装置中大力摩擦颗粒,以便通过简单的机械摩擦在短时间内加热它们的表面; iv)从混合装置排出如此处理的颗粒。