摘要:
Process for the production of propylene starting from mixtures of hydrocarbons, prevalently olefins, the above hydrocarbons having a boiling point ranging from −15° C. to +80° C., preferably from −12° C. to +60° C., which comprises putting the above mixture of hydrocarbons in contact, under cracking conditions, with a large-pore zeolite having a molar ratio Silica/Alumina lower than 200, preferably ranging from 50 to 150.
摘要:
A description follows of a bimetallic catalyst, obtained by dispersing in sequence and alternating the precursors of the single metal components of the catalyst on a carrier, and a process for the synthesis of hydrogen peroxide by the direct reaction of hydrogen with oxygen, in a solvent medium containing a halogenated promoter and an acid promoter, in the presence of said catalyst.
摘要:
A highly selective process is described for preparing 2,6-dimethylnaphthalene which comprises reacting a naphthalene hydrocarbon selected from naphthalene, methylnaphthalenes, dimethylnaphthalenes, trimethylnaphthalenes, polymethylnaphthalenes, and/or their mixtures with one or more benzene hydrocarbons selected from benzene, toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, pentamethylbenzene and/or hexamethylbenzene, under at least partially liquid phase conditions and in the presence of a catalytic composition comprising a zeolite belonging to the MTW structural type and at least one element selected from P, B and Si. The process is preferably carried out in the presence of a methylating agent.
摘要:
The object of the present invention relates to a simple, rapid and inexpensive process for effecting solid-liquid separations in the case of zeolites, also having small crystals. This process, which is particularly useful for the recovery of zeolite crystals in suspension in the crystallization water, comprises treating this suspension of crystals with an acid or one of its precursors and subjecting the resulting mixture to filtration or decanting.According to a particular aspect of the invention, the crystalline phase is separated in a mixture with oxides which can be used as ligands. Said oxides can be generated by the reagents of the zeolite preparation reagent mixture, not transformed into crystalline phase during the synthesis hydrothermal treatment, or they can be added to the suspension of crystals before the separation treatment, or again they can be generated by precursors suitably added to the crystallization slurry.
摘要:
Catalyst for steam cracking reactions consisting of pure mayenite having the general formula:12CaO.7Al2O3having an X-ray diffraction spectrum as indicated in Table I, obtained with a preparation process comprising the following steps: dissolution of salts containing calcium and aluminum with water; completing of the dissolved salts by means of polyfunctional organic hydroxyacids; drying of the solution resulting from the completing in order to obtain a solid precursor product; calcination of the solid precursor product at a temperature ranging from 1300 to 1400null C. for at least two hours.
摘要翻译:用于蒸汽裂解反应的催化剂,其由具有以下通式的纯钙铝石组成:具有表C所示的X射线衍射光谱的12CaO.7Al 2 O 3,其制备方法包括以下步骤:用水溶解含钙和铝的盐; 通过多官能有机羟基酸完成溶解的盐; 干燥由此完成的溶液,以获得固体前体产物; 在1300〜1400℃的温度下煅烧固体前体产物至少2小时。
摘要:
A process for separating hydrocarbon isomers in gas phase on molecular sieves, including feeding mixtures of hydrocarbon isomers to a primary adsorption column configured to adsorb isomers with a greater selectivity towards the molecular sieves, feeding effluent from the primary adsorption column to a secondary adsorption column configured to adsorb remaining isomers with a greater selectivity towards the molecular sieves and discharge a stream containing isomers with a lower selectivity towards the molecular sieves, feeding desorbing agent to a desorption column configured to discharge a stream containing isomers with a greater selectivity towards the molecular sieves and the desorbing agent, feeding the stream from the secondary adsorption column to a distillation unit configured to recover the desorbing agent for recycling to the desorption column, feeding the stream from the desorption column to another distillation unit configured to recover the desorbing agent for recycling to the desorption column.
摘要:
The invention relates to the use of organic carbonates having formula (I) 1 wherein: nnull1-4 R and Rnull are two linear or branched alkyl radicals which contain a number of carbon atoms whose sum is equal to at least 5 and which can be the same or different, as solvents for the washing of metal surfaces.
摘要翻译:本发明涉及具有式(I)的有机碳酸酯的用途,其中:其中: in-line-formula> n = 1-4 line-formula> R和R' 直链或支链烷基,其含有总数等于至少5并且可以相同或不同的碳原子数,作为用于洗涤金属表面的溶剂。
摘要:
Process for the separation of 2,6-dimethylnaphthalene from mixtures containing it, comprising the following operations: crystallization by the addition of a solvent and cooling of the mixture to a temperature higher than the formation value of the first eutectic; removal of the mother liquor by repeated washings; dissolution of the solid obtained; crystallization by cooling; filtration.
摘要:
Process for the polymerization of unsaturated vinyl and/or vinylidene monomers which comprises reacting one or more monomers in the presence of heterocyclic initiators having a nitrogen atom bound to an oxygen atom at a temperature ranging from 100 to 130null C.
摘要:
Process for the production of expandable particles of styrene polymers, having improved processability characteristics, which comprises:i) producing expandable particles of styrene polymers containing from 2 to 20% of an expanding agent incorporated;ii) covering these particles with an antistatic agent in a quantity of less than 1% by weight;iii) vigorously frictioning the particles in a mixing apparatus in order to heat their surface, in a short time, by simple mechanical friction;iv) discharging the particles thus treated from the mixing apparatus.