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    Gasoline sulfur reduction catalyst for fluid catalytic cracking process
    5.
    发明申请
    Gasoline sulfur reduction catalyst for fluid catalytic cracking process 有权
    用于流化催化裂化过程的汽油硫还原催化剂

    公开(公告)号：US20020179492A1

    公开(公告)日：2002-12-05

    申请号：US09833601

    申请日：2001-04-13

    发明人： Xinjin Zhao ,  Wu-Cheng Cheng ,  John Allen Rudesill ,  Richard Franklin Wormsbecher ,  Philip Stephen Deitz

    IPC分类号： C10G011/04 ,  C10G011/05 ,  B01J029/08

    CPC分类号： C10G11/05 ,  B01J23/06 ,  B01J29/084 ,  B01J35/0006 ,  B01J37/0009 ,  B01J2229/16

    摘要： The present invention is directed to certain catalyst compositions and processes that are capable of reducing sulfur compounds normally found as part of the gasoline fraction streams of fluid catalytic cracking processes. The present invention requires an equilibrium cracking catalyst composition comprises at least one Y-type zeolite having kinetic conversion activity of at least about 3 in combination with a Lewis acid containing alumina composite present in at least 50 weight percent of the composition. The resultant equilibrium catalyst composition has a kinetic conversion activity of at least about 2.

    摘要翻译： 本发明涉及某些催化剂组合物和方法，其能够减少通常作为流化催化裂化方法的汽油馏分流的一部分发现的硫化合物。 本发明需要一种平衡裂化催化剂组合物，其包含至少一种具有至少约3的动力学转化活性的Y型沸石与存在于该组合物的至少50重量％中的含有路易斯酸的氧化铝复合材料。 所得的平衡催化剂组合物具有至少约2的动力学转化活性。

    FCC catalysts for feeds containing nickel and vanadium
    6.
    发明申请
    FCC catalysts for feeds containing nickel and vanadium 有权
    用于含镍和钒的饲料的FCC催化剂

    公开(公告)号：US20030136707A1

    公开(公告)日：2003-07-24

    申请号：US10164488

    申请日：2002-06-06

    申请人： ENGELHARD CORPORATION

    发明人： David H. Harris ,  Mingting Xu ,  David Stockwell ,  Rostam J. Madon

    IPC分类号： B01J029/06 ,  B01J029/08 ,  C10G011/02 ,  C10G011/04

    CPC分类号： C10G11/05 ,  B01J21/16 ,  B01J29/06 ,  B01J29/084 ,  B01J29/088 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/108 ,  B01J37/0045 ,  B01J37/0246 ,  B01J2229/42 ,  B01J2229/64 ,  C10G2300/107

    摘要： A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and a particular kaolin which has been calcined through its characteristic exotherm and which produces a catalyst having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. Calcination of the hydrous kaolin to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

    摘要翻译： 由微球制成的流化催化裂化催化剂，其最初含有高岭土，可分散勃姆石氧化铝和硅酸钠或硅溶胶粘结剂。 高岭土部分含有含水高岭土和通过其特征放热煅烧的特定高岭土，并且其产生具有新颖形态的催化剂，其具有包含大孔基质和自由涂覆基质孔壁的结晶沸石。 通过用硅酸钠处理将含水高岭土煅烧成偏高岭土并形成原位沸石，产生含有Y型八面沸石的催化剂，并将可分散的勃姆石转化为过渡型氧化铝。 该催化剂可用于裂解残渣或渣油进料，因为由可分散勃姆石形成的氧化铝相钝化镍和钒污染物。

    Production of olefins
    7.
    发明申请
    Production of olefins 失效
    生产烯烃

    公开(公告)号：US20030062291A1

    公开(公告)日：2003-04-03

    申请号：US10127930

    申请日：2002-04-23

    发明人： Jean-Pierre Dath ,  Walter Vermeiren ,  Koenraad Jacques Herrebout

    IPC分类号： C10G011/00 ,  C10G011/02 ,  C10G011/04

    CPC分类号： C10G51/06 ,  B01J29/40 ,  B01J2229/16 ,  B01J2229/36 ,  C07C4/06 ,  C09K2019/546 ,  C10G11/05 ,  C10G2400/20 ,  C07C11/02

    摘要： A process for cracking an olefin-containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600null C., at an olefin partial pressure of from 0.1 to 2 bars and the feedstock being passed over the catalyst at an LHSV of from 5 to 30hnull1 to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, wherein the olefin-containing hydrocarbon feedstock includes a C5-containing overhead cut from a first fractionator which has been fed with a C5null hydrocarbon feedstock, the-bottom fraction from the first fractionator being a C6null cut and the C5null hydrocarbon feedstock comprises a bottom fraction from a second fractionator which has been fed with a feedstock having at least C4null hydrocarbons, and the overhead from the second fractionator comprises a C4 containing cut, optionally further containing C3 hydrocarbons.

    摘要翻译： 一种用于裂解对流出物中的轻质烯烃具有选择性的含烯烃的烃原料的方法，该方法包括使含有一种或多种烯烃的烃原料通过含有选自具有硅的MFI型结晶硅酸盐的结晶硅酸盐的反应器 /铝原子比为180以上的硅/铝原子比为150〜800的MEL型结晶硅酸盐，其入口温度为500〜600℃，进行了蒸汽工序，在 烯烃分压为0.1至2巴，原料以5至30h -1的LHSV通过催化剂以产生具有比原料低的分子量的烯烃含量的流出物，其中烯烃 - 含有碳氢化合物的原料包括来自已经进料有C5 +烃原料的第一分馏塔的含C5塔顶馏分，来自第一馏分的底馏分 或者是C6 +馏分，并且C5 +烃原料包含来自第二分馏塔的底部馏分，该第二分馏器已经供给具有至少C4 +烃的原料，并且来自第二分馏塔的塔顶馏出物包含含C4馏分，任选地还含有C 3烃。

    Cu-AI/Ce-AI complex oxide combustion catalysts, their preparation and use
    8.
    发明申请
    Cu-AI/Ce-AI complex oxide combustion catalysts, their preparation and use 失效
    Cu-AI / Ce-AI复合氧化物燃烧催化剂，其制备和应用

    公开(公告)号：US20020061273A1

    公开(公告)日：2002-05-23

    申请号：US09826174

    申请日：2001-04-04

    发明人： Bingxiong Lin ,  Wanjing Zhang ,  Yingjun Liu ,  Shijie Li ,  Neng Li

    IPC分类号： C10G011/04 ,  B01J021/00

    CPC分类号： C10G11/182 ,  B01J23/002 ,  B01J23/83 ,  B01J37/0203 ,  B01J37/0205 ,  B01J2523/00 ,  C10G11/04 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/17

    摘要： The present invention relates to non-noble metal combustion catalyst for carbon monoxide comprising CunullAl/CenullAl complex oxides and aluminum oxide support. The catalysts comprise CenullAl complex oxide and CunullAl complex oxide successively loaded on the aluminum oxide support, wherein the loading weight ratio is 0.02-0.10 for CenullAlnullO/Al2O3 and 0.05-0.15 for CunullAlnullO/Al2O3, and the CunullAl complex oxide is dispersed in cluster form on the surface of the aluminum oxide support pre-covered with high dispersed nanoparticles of the CenullAl complex oxide. Furthermore, the present invention relates to a process for preparing the catalysts and their use as combustion promoter with high catalytic activity, high hydrothermal stability and ability of reducing NOx exhaust in the fluid catalytic cracking (FCC) process of petroleum refining.

    摘要翻译： 本发明涉及一种包含Cu-Al / Ce-Al复合氧化物和氧化铝载体的一氧化碳非贵金属燃烧催化剂。 催化剂包含依次负载在氧化铝载体上的Ce-Al复合氧化物和Cu-Al复合氧化物，其中Ce-Al-O / Al2O3的负载重量比为0.02-0.10，Cu-Al-O / Al 2 O 3，并且Cu-Al复合氧化物以簇状分散在预先覆盖有Ce-Al复合氧化物的高分散纳米颗粒的氧化铝载体的表面上。 此外，本发明涉及一种制备催化剂的方法及其用作具有高催化活性，高水热稳定性和在石油精炼的流化催化裂化（FCC））方法中还原NOx排放的能力的助燃剂。

    Gasoline sulfur reduction in fluid catalytic cracking
    10.
    发明申请
    Gasoline sulfur reduction in fluid catalytic cracking 审中-公开

    公开(公告)号：US20030075481A1

    公开(公告)日：2003-04-24

    申请号：US10308697

    申请日：2002-12-03

    发明人： Arthur W. Chester ,  Hye Kyung Cho Timken ,  Terry G. Roberie ,  Michael S. Ziebarth

    IPC分类号： C10G011/04 ,  C10G011/00 ,  C10G025/00

    CPC分类号： C10G11/05 ,  B01J29/166 ,  B01J2229/42

    摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.