公开(公告)号：US08147974B2

公开(公告)日：2012-04-03

申请号：US12338752

申请日：2008-12-18

Applicant: Kiran Baikerikar ,  Syed Z. Mahdi ,  Ben W. Schaefer

Inventor： Kiran Baikerikar ,  Syed Z. Mahdi ,  Ben W. Schaefer

IPC: B32B17/06 ,  B32B9/04 ,  C08J3/28 ,  C08L33/10

CPC classification number: C09D201/02 ,  B60J10/345 ,  C03C17/30 ,  Y10S525/901 ,  Y10S525/925 ,  Y10T428/31612

Abstract: A composition comprising: a)one or more film forming resins having at least one functional group capable of polymerization; b) one or more adhesion promoters comprising compounds containing one or more unsaturated groups capable of free radical polymerization and one or more trialkoxy silane groups; c) one or more fillers capable of imparting abrasion resistance to the composition; d) one or more compounds which is reactive with the film forming resin which also contains an acidic moiety; and e) one or more compounds comprising a siloxane backbone and one or more active hydrogen groups capable of reacting with the functional groups on a glass bonding adhesive: one or more second adhesion promoters comprising one or more silicon, titanium, zirconium, aluminum, or metal containing compounds; organic materials having reactive groups reactive with reactive groups on the surface of substrates or adhesives; or mixtures thereof.

Abstract translation: 一种组合物，其包含：a）一种或多种具有至少一个能够聚合的官能团的成膜树脂; b）一种或多种粘合促进剂，其包含含有一个或多个能够自由基聚合的不饱和基团和一个或多个三烷氧基硅烷基团的化合物; c）能够赋予组合物耐磨性的一种或多种填料; d）一种或多种与还含有酸性部分的成膜树脂反应的化合物; 和e）一种或多种包含硅氧烷主链和能够与玻璃粘结粘合剂上的官能团反应的一个或多个活性氢基团的化合物：一种或多种第二粘合促进剂，其包含一种或多种硅，钛，锆，铝或 含金属化合物; 具有与基材或粘合剂表面上的反应性基团反应的反应性基团的有机材料; 或其混合物。

公开(公告)号：US07842388B2

公开(公告)日：2010-11-30

申请号：US11374421

申请日：2006-03-14

Applicant: Kenneth Joseph Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt

Inventor： Kenneth Joseph Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt

IPC: B32B27/00

CPC classification number: C08G18/3218 ,  C08G18/4854 ,  C08G18/5012 ,  C08G18/5015 ,  C08G18/6674 ,  C08G18/833 ,  C08J3/005 ,  C08J2375/04 ,  C09D175/08 ,  C09D201/02 ,  Y10T428/31504 ,  Y10T428/31551 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

Abstract: Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced. Advantageously, only a minimal amount (such as, e.g., about 2 weight %) of polymeric surface modifier is needed. Being able to achieve desired properties (such as biocidal activity, wettability modification, etc.) without needing much polymeric surface modifier is highly advantageous.

Abstract translation: 使用表面改性聚合物改性聚合物，特别是常规的商品本体聚合物以具有感兴趣的表面活性，所述表面改性聚合物包括有利于与本体聚合物表面迁移的部分以及部分提供感兴趣的活性（例如，杀生物剂 ，润湿性改性（疏水性或亲水性），耐辐射能，提供功能性表面官能团等）。 表面改性聚合物与本体聚合物组合，并且由于存在有利于迁移的部分，主要集中在本体聚合物的表面上，使得提供感兴趣的活性的部分主要位于 生产的散装聚合物制品。 有利地，仅需要最小量（例如约2重量％）的聚合物表面改性剂。 能够实现期望的性质（例如杀生物活性，润湿性改性等）而不需要很多聚合物表面改性剂是非常有利的。

公开(公告)号：US07772334B2

公开(公告)日：2010-08-10

申请号：US11553195

申请日：2006-10-26

Applicant: Timothy S. December ,  Sergio Gonzalez ,  Günther Ott ,  Karl-Heinz Grosse-Brinkhaus

Inventor： Timothy S. December ,  Sergio Gonzalez ,  Günther Ott ,  Karl-Heinz Grosse-Brinkhaus

IPC: C08L63/02 ,  C08L63/10

CPC classification number: C08J3/24 ,  C08G59/18 ,  C09D201/02

Abstract: A crosslinker for polymerizing a film-forming material including an alkyl or aromatic compound comprising at least two functional groups reactive with a film-forming resin and at least one pendent group having a nonionic metal coordinating structure. Coating compositions can include a film-forming material and the crosslinker. The coating compositions can be used to coat a substrate, such as a metal substrate. Applied coating layers on substrates can be cured to form coating films.

Abstract translation: 用于聚合包含至少两个与成膜树脂反应的官能团的烷基或芳族化合物的成膜材料和至少一个具有非离子金属配位结构的侧基的成膜材料的交联剂。 涂料组合物可以包括成膜材料和交联剂。 涂料组合物可用于涂覆基底，例如金属基底。 可以将基材上的涂布层固化，形成涂膜。

公开(公告)号：US07771793B2

公开(公告)日：2010-08-10

申请号：US11290803

申请日：2005-12-01

Applicant: Kenneth Joseph Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt ,  James Wynne

Inventor： Kenneth Joseph Wynne ,  Biao Duan ,  Steven Grunzinger ,  Umit Makal ,  Pinar Kurt ,  James Wynne

IPC: B05D1/00

CPC classification number: C08G18/3218 ,  C08G18/4854 ,  C08G18/5012 ,  C08G18/5015 ,  C08G18/6674 ,  C08G18/833 ,  C08J3/005 ,  C08J2375/04 ,  C09D175/08 ,  C09D201/02 ,  Y10T428/31504 ,  Y10T428/31551 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

Abstract: Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced. Advantageously, only a minimal amount (such as, e.g., about 2 weight %) of polymeric surface modifier is needed. Being able to achieve desired properties (such as biocidal activity, wettability modification, etc.) without needing much polymeric surface modifier is highly advantageous.

Abstract translation: 使用表面改性聚合物改性聚合物，特别是常规的商品本体聚合物以具有感兴趣的表面活性，所述表面改性聚合物包括有利于与本体聚合物表面迁移的部分以及部分提供感兴趣的活性（例如，杀生物剂 ，润湿性改性（疏水性或亲水性），耐辐射能，提供功能性表面官能团等）。 表面改性聚合物与本体聚合物组合，并且由于存在有利于迁移的部分，主要集中在本体聚合物的表面上，使得提供感兴趣的活性的部分主要位于 生产的散装聚合物制品。 有利地，仅需要最小量（例如约2重量％）的聚合物表面改性剂。 能够实现期望的性质（例如杀生物活性，润湿性改性等）而不需要很多聚合物表面改性剂是非常有利的。

公开(公告)号：US07691951B2

公开(公告)日：2010-04-06

申请号：US11868104

申请日：2007-10-05

Applicant: Walter H. Ohrbom ,  Marvin L. Green ,  Gregory G. Menovcik

Inventor： Walter H. Ohrbom ,  Marvin L. Green ,  Gregory G. Menovcik

IPC: C08L67/00 ,  C08G18/00

CPC classification number: C09D201/02 ,  C08F8/00 ,  C08F2800/20 ,  C08G18/4072 ,  C08G18/4233 ,  C08G18/6229 ,  C08G18/6254 ,  C08G18/672 ,  C08G18/8175 ,  C08G2190/00 ,  C09D5/02 ,  C09D133/14 ,  C09D167/00 ,  C09D175/04 ,  C09D201/00 ,  C09D201/025 ,  C08F220/20

Abstract: Disclosed is a method of making reduced VOC polymers and coating compositions containing such polymers. Provided is a mixture (I) comprising a reactant mixture (a) of polymerizable components and a nonvolatile solvent (bnv) that (i) is not a crystalline solid at 25° C., (ii) is nonvolatile, (iii) comprises at least one functional group (F1) and (iv) is a fluid solid. Reactant mixture (a) is polymerized to provide a polymer (a′). The at least one functional group (F1) of nonvolatile solvent (bnv) is reacted with one or more reactants (e) to obtain a nonvolatile solvent (b′nv) comprising at least two functional groups (F2). Obtained is a mixture (II) comprising polymer (a′) in nonvolatile solvent (b′nv) comprising at least two functional groups (F2). The at least one functional group (F1) is substantially nonreactive: (1) with the components of reactive mixture (a), (2) under the polymerization conditions which polymerize reactant mixture (a), and (3) with polymer (a′).

Abstract translation: 公开了一种制备含有这种聚合物的VOC聚合物和涂料组合物的方法。 提供了包含可聚合组分的反应物混合物（a）和不挥发性溶剂（bnv）的混合物（I），其中（i）在25℃下不是结晶固体，（ii）是非挥发性的，（iii）包含 至少一个官能团（F1）和（iv）是流体固体。 将反应物混合物（a）聚合以提供聚合物（a'）。 将不挥发性溶剂（bnv）的至少一种官能团（F1）与一种或多种反应物（e）反应，得到包含至少两个官能团（F2）的非挥发性溶剂（b'nv）。 获得的是包含至少两个官能团（F2）的非挥发性溶剂（b'nv）中的聚合物（a'）的混合物（II）。 至少一个官能团（F1）基本上是非反应性的：（1）在反应混合物（a）和（3）与聚合物（a'）聚合的聚合条件下，反应混合物（a），（2） ）。

公开(公告)号：US07101930B2

公开(公告)日：2006-09-05

申请号：US10887626

申请日：2004-07-09

Applicant: Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

Inventor： Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

IPC: C08J3/00

CPC classification number: C09D201/02 ,  C08F8/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  C08F10/00 ,  C08F20/00

Abstract: A curable, aqueous film-forming composition is provided that includes a polymeric binder comprising reactive functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the polymeric binder, and a copolymer flow control agent comprising at least 30 mol % of residues containing alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer. Components (a) and (b) are substantially hydrophobic and are prepared as an aqueous dispersion comprising polymeric microparticles, prepared by mixing components (a) and (b) together under high shear conditions.A multi-component composite coating composition is also provided, comprising a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. The topcoat is deposited from the film-forming composition described above.

Abstract translation: 提供了一种可固化的水性成膜组合物，其包括含有反应性官能团的聚合物粘合剂，具有至少两个与聚合物粘合剂的官能团反应的官能团的交联剂，以及至少包含共聚物流动控制剂 30mol％的残余物含有来自供体单体和受体单体的交替残基。 共聚物含有至少15摩尔％的异丁烯型供体单体。 组分（a）和（b）基本上是疏水性的，并且被制备成包含通过在高剪切条件下将组分（a）和（b）混合在一起而制备的聚合物微粒的水分散体。 还提供了一种多组分复合涂料组合物，其包含由着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明面漆。 面漆从上述成膜组合物沉积。

公开(公告)号：US07033674B2

公开(公告)日：2006-04-25

申请号：US09932196

申请日：2001-08-17

Applicant: H. Holden Thorp ,  Royce W. Murray ,  Anthony M. Leone ,  Mary Elizabeth Williams

Inventor： H. Holden Thorp ,  Royce W. Murray ,  Anthony M. Leone ,  Mary Elizabeth Williams

IPC: B32B15/04 ,  H01M6/00

CPC classification number: G11C13/0019 ,  B82Y10/00 ,  C08G65/329 ,  C08G65/333 ,  C08G81/00 ,  C08L101/02 ,  C09D201/02 ,  G11C13/0014 ,  Y10T428/31504 ,  Y10T428/31663 ,  Y10T428/31678 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/31971

Abstract: Compositions of biomolecules such as nucleic acids that form molten salts are provided. These compositions molten compositions that have useful electrical properties. Such compositions include a salt of (i) an organic polymer ion such as a polynucleic acid anion, and (ii) a polyether or polysiloxane couterion. Methods of making and using such compositions, along with electrical devices such as memory devices, are also provided.

公开(公告)号：US07008998B2

公开(公告)日：2006-03-07

申请号：US09987823

申请日：2001-11-16

Applicant: Charles L. Tazzia ,  William H. Alford ,  Grant E. Cooley

Inventor： Charles L. Tazzia ,  William H. Alford ,  Grant E. Cooley

IPC: C08K3/00

CPC classification number: C09D5/4496 ,  C09D5/4411 ,  C09D5/4473 ,  C09D201/02

Abstract: The invention relates to a method for preparing aqueous dispersions, especially electrodepositable aqueous dispersions. The invention requires the use of a polymer (a) comprising one or more water dispersible groups per molecule and one or more functional groups (f), and at least one crosslinking agent (b) comprising one or more blocked functional groups (fb) reactive with polymer (a) after unblocking. Crosslinking agent (b) has a Tg of from 40 to 70° C./105 to 158° F. and is a solid at 23.9° C./75° F. when at 100% by weight solids. Crosslinking agent (b) is mixed into polymer (a) at a temperature at or above the melting temperatures of both polymer (a) and compound (b) but below the temperature at which blocked functional groups (fb) unblock. Sufficient water is added to the resulting melt-mixture (ii) to provide an aqueous dispersion.

Abstract translation: 本发明涉及一种制备水性分散体，特别是可电沉积的水性分散体的方法。 本发明需要使用每分子包含一个或多个水分散性基团和一个或多个官能团（f）的聚合物（a）和至少一种包含一个或多个封端官能团的交联剂（b）（f _{>）解除封锁。 向所得熔体混合物（ii）中加入足量的水以提供水分散体。}

公开(公告)号：US20050165157A9

公开(公告)日：2005-07-28

申请号：US10261428

申请日：2002-09-30

Applicant: Walter Ohrbom ,  Sergio Balatan ,  David Law ,  Robert Weise

Inventor： Walter Ohrbom ,  Sergio Balatan ,  David Law ,  Robert Weise

IPC: C09D5/02 ,  C09D133/14 ,  C09D201/00 ,  C09D201/02 ,  C08K3/00

CPC classification number: C09D5/02 ,  C09D133/14 ,  C09D201/00 ,  C09D201/02 ,  C09D201/025

Abstract: The invention provides curable waterborne coating compositions comprising an aqueous dispersion (A) comprising an organic binder component (A1) comprising at least 5% by weight of a reactive component (a), based on the total weight of organic binder component (A1), and at least one crosslinking component (B). The reactive component (a) is substantially free of any heteratoms and is a not a crystalline solid at room temperature and comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups. The curable waterborne coating compositions of the invention show significantly improved pop resistance while also providing improved chip resistance, weathering resistance, flexibility, and/or scratch & mar resistance.

Abstract translation: 本发明提供可固化的水性涂料组合物，其包含基于有机粘合剂组分（A1）的总重量的包含至少5重量％的反应性组分（a）的有机粘合剂组分（A1）的水性分散体（A） 和至少一种交联组分（B）。 反应性组分（a）基本上不含任何杂原子，并且在室温下不是结晶固体，并且包含（i）12至72个碳原子，和（ii）至少两个官能团。 本发明的可固化水性涂料组合物显示出显着改善的弹性阻力，同时还提供改善的耐碎屑性，耐候性，柔韧性和/或抗划痕性。

公开(公告)号：US20040249077A1

公开(公告)日：2004-12-09

申请号：US10887626

申请日：2004-07-09

Inventor： Roxalana L. Martin ,  Edward R. Coleridge ,  Mark A. Tucker ,  Mary E. Grolemund

IPC: C08L033/00 ,  C08L035/00 ,  C08L039/00

CPC classification number: C09D201/02 ,  C08F8/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  C08F10/00 ,  C08F20/00

Abstract: A curable, aqueous film-forming composition is provided that includes a polymeric binder comprising reactive functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the polymeric binder, and a copolymer flow control agent comprising at least 30 mol % of residues containing alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer. Components (a) and (b) are substantially hydrophobic and are prepared as an aqueous dispersion comprising polymeric microparticles, prepared by mixing components (a) and (b) together under high shear conditions. A multi-component composite coating composition is also provided, comprising a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. The topcoat is deposited from the film-forming composition described above.

Abstract translation: 提供了一种可固化的水性成膜组合物，其包括含有反应性官能团的聚合物粘合剂，具有至少两个与聚合物粘合剂的官能团反应的官能团的交联剂，以及至少包含共聚物流动控制剂 30mol％的残余物含有来自供体单体和受体单体的交替残基。 共聚物含有至少15摩尔％的异丁烯型供体单体。 组分（a）和（b）基本上是疏水性的，并且被制备成包含通过在高剪切条件下将组分（a）和（b）混合在一起而制备的聚合物微粒的水分散体。 还提供了一种多组分复合涂料组合物，其包含由着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明面漆。 面漆从上述成膜组合物沉积。