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    Polyolefin production
    152.
    发明授权
    Polyolefin production 失效

    公开(公告)号：US06579822B2

    公开(公告)日：2003-06-17

    申请号：US10066440

    申请日：2002-01-31

    Applicant: Abbas Razavi ,  Olivier Miserque

    Inventor： Abbas Razavi ,  Olivier Miserque

    IPC: B01J3100

    CPC classification number: C07F17/00 ,  C08F4/63908 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  C08F110/06 ,  Y10S526/943 ,  C08F2500/03 ,  C08F2500/15

    Abstract: A metallocene compound having the general formula: CpAXMQ1Q2Cp′A′X′M′Q1′Q2′ wherein Cp and Cp′ are each independently a substituted or unsubstituted cyclopentadienyl moiety; M and M′ are each independently a metal chosen from Group IV B transition metals and vanadium, and coordinate to Cp and Cp′ respectively; X and X′ are each independently a substituted or unsubstituted Group VA or VIA heteroatom and coordinate to M and M′ respectively; A and A′ are bridging groups between Cp and X and between Cp′ and X′ respectively and are independently chosen from —SiR′2—O—SiR′2—, —SinR′m—, —CnR′m— and —CR′2—SiR′2—CR′2—SiR′2—, in which each R′ is independently H or hydrocarbyl having 1 to 20 carbon atoms, n is an integer in the range 1 to 4 and m=2n; each Q1, Q2 and Q1′ and Q2′ is independently a coordinating group which is hydrogen, halogen or hydrocarbyl having 1 to 20 carbon atoms and each of Q1 and Q1′ is coordinated to both M and M′.

    Catalyst compounds with &bgr;-diminate anionic ligands and processes for polymerizing olefins
    154.
    发明授权
    Catalyst compounds with &bgr;-diminate anionic ligands and processes for polymerizing olefins 有权
    具有β-二聚阴离子配体的催化剂化合物和烯烃聚合方法

    公开(公告)号：US06511936B1

    公开(公告)日：2003-01-28

    申请号：US09373729

    申请日：1999-08-13

    Applicant: Klaus H. Theopold ,  Woo-Kyu Kim ,  Leonard A. MacAdams ,  John M. Power ,  Javier M. Mora ,  Albert P. Masino

    Inventor： Klaus H. Theopold ,  Woo-Kyu Kim ,  Leonard A. MacAdams ,  John M. Power ,  Javier M. Mora ,  Albert P. Masino

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C07F7/003 ,  C07F9/00 ,  C07F9/005 ,  C07F11/005 ,  C08F10/02 ,  C08F110/02 ,  C08F110/14 ,  C08F210/16 ,  C08F2410/03 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/01 ,  C08F210/06 ,  C08F2500/10 ,  C08F210/14 ,  C08F4/64044 ,  C08F4/69112 ,  C08F4/68112

    Abstract: The present invention relates to catalyst systems, processes for making such catalysts, intermediates for such catalysts, and olefin polymerization processes using such catalysts wherein such catalyst includes a component represented by the following formula 1A: wherein R and R′ independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl or organosilyl radical; R1, R2, and R3 independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl radical; M is a group IIIB, IVB, VB, VIB, VIIB or VIII transition metal; T independently represents a univalent anionic ligand such as a hydrogen atom, or a substituted or unsubstituted hydrocarbyl halogeno, aryloxido, arylorganosilyl, alkyloriganosilyl, amido, arylamido, phosphido, or arylphosphido group, or two T groups taken together represent an alkylidene or a cyclometallated hydrocarbyl bidentate ligand; L independently represents a sigma donor stabilizing ligand; X, which is optional, represents a relatively weakly coordinated anion; and a=0 to 4 inclusive, b=0 to 4 inclusive, provided a+b≦4.

    Abstract translation: 本发明涉及催化剂体系，制备这种催化剂的方法，这种催化剂的中间体和使用这种催化剂的烯烃聚合方法，其中这种催化剂包括由下式1A表示的组分：其中R和R'独立地表示氢原子，或 取代或未取代的支链或非支链烃基或有机甲硅烷基; R1，R2和R3独立地表示氢原子或取代或未取代的支链或非支链烃基; M是IIIB，IVB，VB，VIB，VIIB 或VIII过渡金属; T独立地表示一价阴离子配体，例如氢原子，或取代或未取代的烃基卤代，芳氧基，芳基有机甲硅烷基，烷基升乳糖基，酰氨基，芳基酰氨基，磷酰基或芳基磷酰基，或两个T基团一起表示 亚烷基或环金属化的烃基二齿配体; L独立地表示σ供体稳定剂 g配体; 任选的X表示相对弱配位的阴离子; 和a = 0〜4，b = 0〜4，其中a + b <= 4。

    Olefin polymerization catalysts and processes for making and using same
    155.
    发明授权
    Olefin polymerization catalysts and processes for making and using same 有权
    烯烃聚合催化剂及其制备和使用方法

    公开(公告)号：US06506704B1

    公开(公告)日：2003-01-14

    申请号：US09274378

    申请日：1999-03-23

    Applicant: Donald Albert Bansleben ,  Eric Francis Connor ,  Robert Howard Grubbs ,  Jason Ivan Henderson ,  Todd Ross Younkin

    Inventor： Donald Albert Bansleben ,  Eric Francis Connor ,  Robert Howard Grubbs ,  Jason Ivan Henderson ,  Todd Ross Younkin

    IPC: B01J3100

    CPC classification number: C07F15/045 ,  C08F10/00 ,  C08F4/80

    Abstract: A process for forming neutral late transition metal chelates useful as polymerization catalysts comprising contacting a bidentate ligand forming compound that is free of electron-withdrawing groups with a di(tertiary amine) late transition metal reagent in the presence of an inert liquid, an olefinic monomer or a polar liquid selected from nitrites, ethers, aromatic heterocyclic amines, alcohols, nitroalkanes, nitroaromatics or mixtures thereof. The process provides a solid product or a solution of a storage stable transition metal bidentate ligand containing catalyst product which remains active for an extended storage period. Alternately, the present process can be conducted in situ in a polymerization zone of olefinic polymerization.

    Abstract translation: 一种形成用作聚合催化剂的中性晚期过渡金属螯合物的方法，包括在惰性液体存在下，将不含吸电子基团的二齿配体形成化合物与二（叔胺）后过渡金属试剂接触，将烯属单体 或选自亚硝酸盐，醚，芳族杂环胺，醇，硝基烷烃，硝基芳族化合物或其混合物的极性液体。 该方法提供固体产物或储存稳定的过渡金属二齿配位体催化剂产物的溶液，其在延长的储存期间保持活性。 或者，本方法可以在烯烃聚合的聚合区中原位进行。

    Catalyst system and its use in a polymerization process
    156.
    发明授权
    Catalyst system and its use in a polymerization process 失效
    催化剂体系及其在聚合过程中的应用

    公开(公告)号：US06495484B1

    公开(公告)日：2002-12-17

    申请号：US09649746

    申请日：2000-08-28

    Applicant: Matthew W. Holtcamp

    Inventor： Matthew W. Holtcamp

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C07F5/061 ,  C07F5/062 ,  C08F4/659 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/602 ,  C08F4/65912 ,  C08F210/14 ,  C08F2500/03

    Abstract: Disclosed are polymerization catalyst activator compositions which include a carbonium cation and an aluminum containing anion. These activator compositions are prepared by combining a carbonium or trityl source and with an aluminum containing complex, preferably a perfluorophenylaluminum compound. Also disclosed are polymerization catalyst systems including the activator composition of the invention, and processes for polymerizing olefins utilizing same.

    Abstract translation: 公开了包括碳鎓阳离子和含铝阴离子的聚合催化剂活化剂组合物。 这些活化剂组合物通过将碳鎓或三苯甲基源与含铝的络合物，优选全氟苯基铝化合物组合来制备。 还公开了包括本发明的活化剂组合物的聚合催化剂体系，以及利用它们聚合烯烃的方法。

    Catalyst composition comprising a reduced transition metal complex and a cocatalyst
    158.
    发明授权
    Catalyst composition comprising a reduced transition metal complex and a cocatalyst 有权
    包含还原过渡金属络合物和助催化剂的催化剂组合物

    公开(公告)号：US06489261B1

    公开(公告)日：2002-12-03

    申请号：US09583914

    申请日：2000-05-31

    Applicant: Gerardus J. M. Gruter ,  Mirko Kranenburg ,  Marc Herklots

    Inventor： Gerardus J. M. Gruter ,  Mirko Kranenburg ,  Marc Herklots

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F4/6392

    Abstract: Catalyst compositions include a reduced transition metal complex of structure (I) and a cocatalyst. where, L1 and L2, may be the same or different, are anionic ligands, other than cyclopentadienyl group, amido group or phosphidino group. At least L1 is able to non-covalently interact with reduced transition metal M via one or more functional groups; for example, L1 can be a phenyl group in which at least one of the ortho-positions is substituted with a functional group capable of donating electron density to the transition metal M. L1 can also be a methyl group in which one or more or the alpha-positions is substituted with a functional group capable of donating electron density to the transition metal M. X, K, and m are defined in the specification. These catalysts may be easily formed as solids and provide improved catalytic performance.

    Abstract translation: 催化剂组合物包括结构（I）的还原过渡金属络合物和助催化剂。其中，L1和L2可以相同或不同，是除了环戊二烯基，酰胺基或磷酰基之外的阴离子配体。 至少L1能够通过一个或多个官能团与还原的过渡金属M非共价相互作用; 例如，L1可以是其中至少一个邻位被能够向过渡金属M提供电子密度的官能团取代的苯基.L1也可以是甲基，其中一个或多个或 α位置被能够向过渡金属M提供电子密度的官能团取代.X，K和m在说明书中定义。 这些催化剂可以容易地形成为固体并提供改进的催化性能。

    Solid catalyst component and catalyst for olefin polymerization, process for producing olefin polymer and process for producing solid catalyst component
    159.
    发明授权
    Solid catalyst component and catalyst for olefin polymerization, process for producing olefin polymer and process for producing solid catalyst component 失效
    用于烯烃聚合的固体催化剂组分和催化剂，用于生产烯烃聚合物的方法和用于生产固体催化剂组分的方法

    公开(公告)号：US06468937B1

    公开(公告)日：2002-10-22

    申请号：US09281212

    申请日：1999-03-30

    Applicant: Kotohiro Nomura ,  Seiki Kiuchi ,  Tatsuya Miyatake

    Inventor： Kotohiro Nomura ,  Seiki Kiuchi ,  Tatsuya Miyatake

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F4/027 ,  C08F4/6546 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/10 ,  C08F2500/24

    Abstract: There are disclosed: (i) a first solid catalyst component obtained by contacting (a) a carrier of carboxyl group-carrying polymer particles having an average particle size of from about 1 to 200 &mgr;m with spherical or elliptical particles morphology (b) an organometallic compound of the number 1, 2 or 13 group of metals in the periodic table of elements, and (c) a transition metal compound of the number 4 group of metals of the periodic table of elements, and a second solid catalyst component obtained by contacting (a), (b), (c) and (d) a phenol compound, and production processes of the two solid catalyst components, (ii) a catalyst obtained by combining the two solid catalyst components with an organoaluminum compound; and (iii) a process for producing an olefin polymer with a catalyst of the invention, wherein the polymer produced is extremely low in its content of lower molecular weight components and low crystallinity components, and superior in its powder properties.

    Abstract translation: 公开了：（i）第一固体催化剂组分，其通过使（a）具有平均粒径为约1-200μm的含羧基的聚合物颗粒的载体与球形或椭圆形颗粒形态（b）接触而获得;（b）有机金属 元素周期表中第1,2族或13族金属的化合物，和（c）元素周期表第4族金属的过渡金属化合物和通过接触获得的第二固体催化剂组分 （a），（b），（c）和（d）酚化合物和两种固体催化剂组分的制备方法，（ii）通过将两种固体催化剂组分与有机铝化合物组合获得的催化剂; 和（iii）用本发明的催化剂生产烯烃聚合物的方法，其中所制备的聚合物的低分子量组分和低结晶度组分的含量极低，并且其粉末性能优异。

    Ruthenium catalysts and method for making same
    160.
    发明授权
    Ruthenium catalysts and method for making same 有权
    钌催化剂及其制备方法

    公开(公告)号：US06455460B1

    公开(公告)日：2002-09-24

    申请号：US09690980

    申请日：2000-10-18

    Applicant: Daniel A. Dobbs ,  Koenraad P. M. Vanhessche ,  Valentin Rautenstrauch

    Inventor： Daniel A. Dobbs ,  Koenraad P. M. Vanhessche ,  Valentin Rautenstrauch

    IPC: B01J3100

    CPC classification number: B01J31/2409 ,  B01J23/462 ,  B01J31/2295 ,  B01J31/24 ,  B01J31/2428 ,  B01J31/2452 ,  B01J31/2471 ,  B01J2531/0205 ,  B01J2531/0266 ,  B01J2531/821 ,  B01J2531/842 ,  C07C67/303 ,  C07C69/75 ,  C07C69/716

    Abstract: A catalyst of ruthenium (II) comprising bidentate phosphine ligands is described which is obtained by a process that comprises treating equimolar amounts of an appropriate Ru complex and a bidentate diphosphine ligand with an acid of the formula H-Anion, wherein the anion is a non-coordinating anion, said acid being used in a ratio of 1 molar equivalent per mole of Ru complex and the treatment being carried out in a non-coordinating or weakly coordinating medium, under an oxygen-free atmosphere. Said catalyst is useful for the preparation of the preferred isomer of the Hedione®, having the configuration (+)-(1R)-cis, and of many other substrates comprising highly hindered carbon-carbon double bonds.

    Abstract translation: 描述了包含二齿膦配体的钌（II）催化剂，其通过包括用式H阴离子的酸处理等摩尔量的合适的Ru配合物和二齿二膦配体的方法获得，其中阴离子是非 - - 配位阴离子，所述酸以每摩尔Ru配合物1摩尔当量的比例使用，并且处理在无配位或弱配位介质中，在无氧气氛下进行。 所述催化剂可用于制备具有（+） - （1R） - 顺式构型的Hedione的优选异构体，以及包含高度受阻碳 - 碳双键的许多其它底物。

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