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公开(公告)号:US10544271B2
公开(公告)日:2020-01-28
申请号:US15435014
申请日:2017-02-16
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Giampaolo Pellegatti , Michele Grazzi , Nicolas Kokel , Antonella Angelini
IPC: C08J5/18 , B29C48/10 , B29C48/88 , C08F210/06 , C08F10/00 , B29C49/00 , B29C49/04 , B29C49/64 , B29C48/00 , B29C48/21 , B29K23/00 , B29K105/00
Abstract: A copolymer of propylene with hexene-1 containing from 5 to 9% by weight of recurring units derived from hexene-1, having a melting temperature from 125 to 140° C. and Melt Flow Rate (ASTM D1238, 230/2.16 Kg) from 0.1 to 3 g/10 min., is used to produce blown films having valuable mechanical and optical properties.
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公开(公告)号:US10435490B2
公开(公告)日:2019-10-08
申请号:US15750391
申请日:2016-07-14
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Giuseppina Maria Algozzini , Diego Brita , Massimo Cenci , Gianni Collina , Tiziano Dall'occo , Maria Di Diego , Benedetta Gaddi , Ofelia Fusco , Giampiero Morini , Lorella Pedriali
IPC: C08F110/02 , C08F110/06 , C08F10/06 , C08F2/34 , C08F4/649 , C08F4/651
Abstract: A Prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID) said prepolymerized catalyst component being characterized by the fact that: the electron donor (ID) is constituted by at least 80% mol of 1,3 diethers with respect to the total molar amount of electron donor compounds; the prepolymerized catalyst has a porosity due to pores with diameters up to 1 μm of less than 0.2 cm3/g; it contains an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.
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公开(公告)号:US20190284316A1
公开(公告)日:2019-09-19
申请号:US16317676
申请日:2017-07-07
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: TIZIANO DALL'OCCO , SIMONA GUIDOTTI , DARIO LIGUORI , GIAMPIERO MORINI
IPC: C08F210/16
Abstract: A catalyst component for the polymerization of olefins, comprising Ti, Mg, halogen, an electron donor (ID) selected from the group consisting of aliphatic cyclic ethers and alkyl esters of aliphatic monocarboxylic acids and a compound of a metal selected from the group consisting of Zn and Cu, wherein the catalyst component is devoid of Zn—C or Cu—C bonds and the Mg/Ti molar ratio ranges from 4.0 to 50.0.
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公开(公告)号:US20190256747A1
公开(公告)日:2019-08-22
申请号:US16312512
申请日:2017-07-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ROBERTA MARCHINI , STEFANO SPATARO , EMANUELE BURGIN , ROBERTA PICA
IPC: C09J123/20
Abstract: A butene-1 polymer composition having MFR values of from 400 to 2000 g/10 min, measured according to ISO 1133 at 190° C. with a load of 2.16 kg, made from or containing A) a butene-1 homopolymer or a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole; B) a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 25% by mole; wherein the composition having a total copolymerized comonomer content from 5% to 18% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0° C. of 65% by weight or more, determined on the total weight of A) and B).
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公开(公告)号:US20190225720A1
公开(公告)日:2019-07-25
申请号:US16339091
申请日:2017-09-22
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ROBERTO DE PALO , CLAUDIO CAVALIERI
IPC: C08F110/08 , C08J5/18 , B29C64/245 , B33Y30/00
Abstract: A plate for use in an extrusion-based additive manufacturing system made from or containing a top layer made from or containing a sheet or film made from or containing 1-butene based copolymer made from or containing from 0 to 70 wt % of ethylene, propylene or alpha olefins of formula CH2═CHR, wherein R is a C3-C20 alkyl radical, based upon the weight of the 1-butene polymer.
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公开(公告)号:US10316122B2
公开(公告)日:2019-06-11
申请号:US15768875
申请日:2016-10-25
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Paola Massari , Caroline Cathelin , Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Marco Ciarafoni , Claudio Cavalieri , Roberto Pantaleoni , Michele Grazzi
Abstract: A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; B) from 10 wt % to 50 wt %; of a copolymer of propylene having from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the total weight of the copolymer; the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the total weight of the polypropylene composition; wherein the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.
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公开(公告)号:US20190112732A1
公开(公告)日:2019-04-18
申请号:US16094647
申请日:2017-03-20
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ROBERTO DE PALO , CLAUDIO CAVALIERI
IPC: D01F6/30 , C08F210/06
CPC classification number: D01F6/30 , B29C64/118 , B33Y30/00 , B33Y70/00 , B33Y80/00 , C08F210/06 , C08F210/16 , C08F2500/12
Abstract: The present disclosure provides a filament for use in an extrusion-based additive manufacturing system made from or containing a propylene ethylene copolymer having: ethylene derived units content ranging from about 3.0 wt % to about 12.0 wt %, based upon the weight of the propylene ethylene copolymer; MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from about 4 to about 20 g/10 min; and xylene solubles measured at 25° C. from about 3 wt % to about 30 wt %, based upon the weight of the propylene ethylene copolymer. The disclosure further provides an extrusion-based additive manufacturing system made from or containing the filament as well as 3D printed articles prepared from the system.
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公开(公告)号:US20190112402A1
公开(公告)日:2019-04-18
申请号:US16087731
申请日:2017-03-23
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: ROBERTA MARCHINI , STEFANO SPATARO , STEFANO PASQUALI , GIANLUCA MUSACCHI
IPC: C08F210/16 , C08F210/02 , C08F210/08 , C08L23/20 , B65D53/06
Abstract: The present disclosure provides a polyolefin composition made from or containing: A) from about 60 to about 89% by weight based upon the total weight of the polyolefin composition of a copolymer of butene-1 with ethylene having a copolymerized ethylene content of up to about 18% by mole based upon the molar composition of the copolymer, and no melting peak detectable at the DSC at the second heating scan; and B) from about 11 to about 40% by weight based upon the total weight of the polyolefin composition of an ethylene polymer having density of from about 0.900 to about 0.970 g/cm3, measured according to ISO 1183 at 23° C.; wherein the amounts of A) and B) are referred to the total weight of A)+B) and the DSC second heating scan is carried out with a heating rate of 10° C. per minute. The composition is useful for preparing gaskets.
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公开(公告)号:US10239267B2
公开(公告)日:2019-03-26
申请号:US13881282
申请日:2011-10-20
Applicant: Mike Rogers , Anja Gottschalk
Inventor: Mike Rogers , Anja Gottschalk
Abstract: Injection stretch blow molding process for preparing polyolefin containers, comprising the following steps: 1) preparing a preform by injection molding a polyolefin composition comprising a polymer (A) selected from ethylene polymers, propylene polymers and mixtures thereof, and a heat absorber (B); 2) supplying heat to reheat the preform prepared in step 1) and stretch blow molding said preform; wherein the heat absorber (B) is selected from phosphates, condensed phosphates, phosphites, and mixed hydroxide/phosphate oxanion compounds of Copper (Cu), Calcium (Ca), Tin (Sn) and/or Iron (Fe).
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公开(公告)号:US10214640B2
公开(公告)日:2019-02-26
申请号:US15536052
申请日:2015-11-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Roberta Marchini , Stefano Spataro , Stefano Pasquali , Gianluca Musacchi
Abstract: The present disclosure provides a polyolefin composition made from or containing: A) from about 63 to about 78% by weight of a copolymer of butene-1 with ethylene having a copolymerized ethylene content of up to about 18% by mole and no melting peak detectable at the DSC at the second heating scan; B) from about 22 to about 37% by weight of (i) a propylene homopolymer, or (ii) a propylene copolymer, or (iii) a mixture of two or more of (i) and (ii), having a melting temperature Tm, measured by DSC at the second heating scan, of from about 130° C. to about 165° C.; wherein (i) the amounts of A) and B) are referred to the total weight of A)+B) and (ii) having a melting enthalpy ΔHfus, measured by DSC at the second heating scan, of from 7 to 30 J/g.
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