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    METHOD FOR REVAMPING AN HF OR SULPHURIC ACID ALKYLATION UNIT
    12.
    发明申请
    METHOD FOR REVAMPING AN HF OR SULPHURIC ACID ALKYLATION UNIT 有权
    用于逆转HF或硫酸碱化单元的方法

    公开(公告)号：US20120159759A1

    公开(公告)日：2012-06-28

    申请号：US13388563

    申请日：2010-08-06

    Applicant: Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xiang Meng ,  Ana Cecilia Patroni ,  Peter Anton Agust Klusener ,  Albertus Vincentius Petrus Van Den Bosch

    Inventor： Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xiang Meng ,  Ana Cecilia Patroni ,  Peter Anton Agust Klusener ,  Albertus Vincentius Petrus Van Den Bosch

    IPC: B23P17/04

    CPC classification number: C07C2/58 ,  C07C2531/14 ,  Y10T29/49716 ,  C07C9/16

    Abstract: The present invention provides a method for revamping an HF or sulphuric acid alkylation unit to an ionic liquid alkylation unit, wherein the HF or sulphuric acid alkylation unit comprise at least: a reactor unit for contacting catalyst and hydrocarbon reactants; a separator unit for separating a reactor effluent into a catalyst phase and an alkylate-comprising hydrocarbon phase; a fractionator unit for fractionating the alkylate-comprising hydrocarbon phase into at least one stream comprising alkylate; and which method includes: providing one or more cyclone units downstream of the reactor unit to separate at least part of the reactor effluent in a catalyst phase and a alkylate-comprising hydrocarbon phase.

    Abstract translation: 本发明提供了将HF或硫酸烷基化单元改性为离子液体烷基化单元的方法，其中HF或硫酸烷基化单元至少包括：用于使催化剂和烃反应物接触的反应器单元; 分离器单元，用于将反应器流出物分离成催化剂相和含烷基化物的烃相; 用于将包含烷基化物的烃相分级成至少一种包含烷基化物的流的分馏器单元; 并且该方法包括：在反应器单元下游提供一个或多个旋风单元，以分离催化剂相中的至少部分反应器流出物和含烷基化物烃相。

    Deep separation method and processing system for the separation of heavy oil through granulation of coupled post-extraction asphalt residue
    14.
    发明申请
    Deep separation method and processing system for the separation of heavy oil through granulation of coupled post-extraction asphalt residue 有权
    通过联合萃取后沥青残渣的造粒分离重油的深度分离方法和加工系统

    公开(公告)号：US20070007168A1

    公开(公告)日：2007-01-11

    申请号：US11265468

    申请日：2005-11-01

    Applicant: Suoqi Zhao ,  Chunming Xu ,  Ren'an Wang ,  Zhiming Xu ,  Xuewen Sun ,  Keng Chung

    Inventor： Suoqi Zhao ,  Chunming Xu ,  Ren'an Wang ,  Zhiming Xu ,  Xuewen Sun ,  Keng Chung

    IPC: C10C1/18 ,  B01J8/04 ,  B01J10/00 ,  C10C3/08

    CPC classification number: C10C3/16

    Abstract: The present invention is a separation method and system in which granulation of coupled post-extraction asphalt residue is used to achieve deep separation of heavy oil. A dispersion solvent is introduced into the asphalt phase after separation by solvent extraction and the asphalt phase undergoes rapid phase change in a gas-solid separator and is dispersed into solid particles while the solvent vaporizes, resulting in low temperature separation of asphalt and solvent with adjustable size of the asphalt particles. The separation method of this invention also includes a three-stage separation of heavy oil feedstock, in which the deasphalted oil phase separated from heavy oil is treated with supercritical solvent and results in the further separation of the resin portion of the deasphalted oil, maximizing the yield and quality of the deasphalted oil. The processes and systems in this invention use atmospheric pressure and a low temperature gas-solid separator instead of a high temperature and high pressure furnace and do not require the feed pre-heating or heat exchange equipment at the inlet of resin separator column, resulting in a simplified process flow and reduced investment.

    Abstract translation: 本发明是一种分离方法和系统，其中使用联合的萃取后沥青残渣的造粒来实现重油的深度分离。 通过溶剂萃取分离后，将分散溶剂引入沥青相中，沥青相在气 - 固分离器中发生快速相变，并在溶剂汽化时分散成固体颗粒，导致沥青和溶剂的低温分离，可调节 沥青颗粒尺寸。 本发明的分离方法还包括重油原料的三段分离，其中用超临界溶剂处理与重油分离的脱沥青油相，并导致脱沥青油的树脂部分的进一步分离，使 脱沥青油的产量和质量。 本发明的方法和系统使用大气压和低温气固分离器代替高温高压炉，并且不需要在树脂分离塔入口处的进料预热或热交换设备，导致 简化流程，减少投资。

    Method for quantifying permeability of vuggy carbonates using wireline logs
    15.
    发明授权
    Method for quantifying permeability of vuggy carbonates using wireline logs 有权
    使用有线日志量化渗碳碳酸盐的渗透率的方法

    公开(公告)号：US06714871B1

    公开(公告)日：2004-03-30

    申请号：US10065581

    申请日：2002-10-31

    Applicant: Chunming Xu ,  Bill M. Newberry

    Inventor： Chunming Xu ,  Bill M. Newberry

    IPC: G01N1508

    CPC classification number: G01N15/088 ,  G01N15/082

    Abstract: A method for quantifying permeability of a vuggy reservoir includes determining a permeability modeled with matrix porosity (K0) of the reservoir, determining a vug porosity (&PHgr;vug) of the reservoir, and quantifying permeability (K) of the reservoir as follows: K=aK0·bc&PHgr;wg, where a, b, and c are constants.

    Abstract translation: 用于量化渗透储层的渗透率的方法包括确定用储层的基质孔隙度（K0）建模的渗透率，确定储层的孔隙度（Phivug），并定量储层的渗透率（K）如下：其中a， b和c是常数。

    Process for preparing an alkylate
    16.
    发明授权
    Process for preparing an alkylate 有权
    制备烷基化物的方法

    公开(公告)号：US08653318B2

    公开(公告)日：2014-02-18

    申请号：US13388470

    申请日：2010-08-06

    Applicant: Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng ,  Ana Cecilia Patroni ,  Peter Anton August Klusener ,  Albertus Vincentius Petrus Van Den Bosch

    Inventor： Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng ,  Ana Cecilia Patroni ,  Peter Anton August Klusener ,  Albertus Vincentius Petrus Van Den Bosch

    IPC: C07C2/54

    CPC classification number: C07C2/58 ,  C07C2527/126 ,  C07C2527/128 ,  C07C2531/22 ,  C07C9/16

    Abstract: The present invention provides process for preparing an alkylate comprising contacting in a reactor a hydrocarbon mixture comprising at least an isoparaffin and an olefin with an acidic ionic liquid catalyst under alkylation conditions to obtain an alkylate, which process further comprises: —withdrawing an alkylate-comprising reactor effluent from the reactor, wherein the reactor effluent comprises an ionic liquid phase and a hydrocarbon phase; —separating at least part the reactor effluent into a hydrocarbon phase effluent and a multiple-phase effluent in a centrifugal separation unit; —fractionating at least part of said hydrocarbon phase effluent into at least a stream comprising alkylate and a stream comprising isoparaffin.

    Abstract translation: 本发明提供了制备烷基化物的方法，其包括在烷基化条件下使反应器中含有至少异链烷烃和烯烃的烃混合物与酸性离子液体催化剂接触以获得烷基化物，该方法还包括： - 将含烷基化物 反应器流出物，其中反应器流出物包含离子液相和烃相; 将反应器流出物的至少一部分分离成烃相流出物和离心分离单元中的多相流出物; 将至少部分所述烃相流出物分馏成至少包含烷基化物的流和包含异链烷烃的料流。

    Alkylation method using ionic liquid as catalyst
    17.
    发明授权
    Alkylation method using ionic liquid as catalyst 有权
    使用离子液体作为催化剂的烷基化方法

    公开(公告)号：US09096487B2

    公开(公告)日：2015-08-04

    申请号：US13519191

    申请日：2010-12-27

    Applicant: Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng

    Inventor： Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng

    IPC: C07C2/60 ,  C07C2/58 ,  B01J31/02 ,  C10G29/20 ,  C10G57/00

    CPC classification number: C07C2/58 ,  B01J31/0278 ,  B01J31/0284 ,  B01J2231/42 ,  C10G29/205 ,  C10G57/005 ,  C10G2300/1081 ,  C10G2300/1092 ,  C10G2300/4081 ,  C10G2300/70

    Abstract: Disclosed is an alkylation process using ionic liquid as catalyst, which process comprises separating halogenated hydrocarbons-rich fraction from the alkylation product by distillation and/or adsorption and reintroducing the separated fraction into the reaction system during the alkylation reaction, wherein the ionic liquid catalyst used in the alkylation reaction has a cation derived from hydrohalide of alkyl amine, hydrohalide of imidazole or hydrohalide of pyridine and an anion derived from one or more metallic compounds. The inventive process effectively utilizes the halogenated hydrocarbons in the alkylation product, prolongs the life of the ionic liquid catalyst, and reduces the halogen content in the alkylate oil.

    Abstract translation: 公开了使用离子液体作为催化剂的烷基化方法，该方法包括通过蒸馏和/或吸附从烷基化产物中分离富含卤代烃的馏分，并在烷基化反应期间将分离的馏分重新引入反应体系，其中所用的离子液体催化剂 在烷基化反应中具有衍生自烷基胺的氢卤化物，咪唑的氢卤化物或吡啶的氢卤化物的阳离子和衍生自一种或多种金属化合物的阴离子。 本发明的方法有效地利用了烷基化产物中的卤代烃，延长了离子液体催化剂的寿命，降低了烷基化油中的卤素含量。

    ALKYLATION METHOD USING IONIC LIQUID AS CATALYST
    18.
    发明申请
    ALKYLATION METHOD USING IONIC LIQUID AS CATALYST 有权
    使用离子液体作为催化剂的烷基化方法

    公开(公告)号：US20130331625A1

    公开(公告)日：2013-12-12

    申请号：US13519191

    申请日：2010-12-27

    Applicant: Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng

    Inventor： Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng

    IPC: C07C2/58

    CPC classification number: C07C2/58 ,  B01J31/0278 ,  B01J31/0284 ,  B01J2231/42 ,  C10G29/205 ,  C10G57/005 ,  C10G2300/1081 ,  C10G2300/1092 ,  C10G2300/4081 ,  C10G2300/70

    Abstract: Disclosed is an alkylation process using ionic liquid as catalyst, which process comprises separating halogenated hydrocarbons-rich fraction from the alkylation product by distillation and/or adsorption and reintroducing the separated fraction into the reaction system during the alkylation reaction, wherein the ionic liquid catalyst used in the alkylation reaction has a cation derived from hydrohalide of alkyl amine, hydrohalide of imidazole or hydrohalide of pyridine and an anion derived from one or more metallic compounds. The inventive process effectively utilizes the halogenated hydrocarbons in the alkylation product, prolongs the life of the ionic liquid catalyst, and reduces the halogen content in the alkylate oil.

    Abstract translation: 公开了使用离子液体作为催化剂的烷基化方法，该方法包括通过蒸馏和/或吸附从烷基化产物中分离富含卤代烃的馏分，并在烷基化反应期间将分离的馏分重新引入反应体系，其中所用的离子液体催化剂 在烷基化反应中具有衍生自烷基胺的氢卤化物，咪唑的氢卤化物或吡啶的氢卤化物的阳离子和衍生自一种或多种金属化合物的阴离子。 本发明的方法有效地利用了烷基化产物中的卤代烃，延长了离子液体催化剂的寿命，降低了烷基化油中的卤素含量。

    Process for preparing an alkylate
    20.
    发明授权
    Process for preparing an alkylate 有权
    制备烷基化物的方法

    公开(公告)号：US08552243B2

    公开(公告)日：2013-10-08

    申请号：US13388478

    申请日：2010-08-05

    Applicant: Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng ,  Ana Cecilia Patroni ,  Peter Anton August Klusener ,  Albertus Vincentius Petrus Van Den Bosch

    Inventor： Zhichang Liu ,  Chunming Xu ,  Rui Zhang ,  Xianghai Meng ,  Ana Cecilia Patroni ,  Peter Anton August Klusener ,  Albertus Vincentius Petrus Van Den Bosch

    IPC: C07C2/56

    CPC classification number: C07C2/60 ,  C07C2527/122 ,  C07C2527/126 ,  C07C9/16

    Abstract: The present invention provides a process for preparing an alkylate, comprising: contacting in a reaction zone a hydrocarbon mixture comprising at least isoparaffin and an olefin with an acidic ionic liquid catalyst under alkylation conditions to obtain an alkylate; withdrawing an alkylate-comprising effluent from the reaction zone; separating at least part of the alkylate-comprising effluent into an hydrocarbon-rich phase and an ionic liquid catalyst-rich phase; fractionating part of the hydrocarbon-rich phase into at least an alkylate-comprising product and a isoparaffin-comprising stream; mixing another part of the hydrocarbon-rich phase with an olefin-comprising stream to form the hydrocarbon mixture; and providing the hydrocarbon mixture to the reaction zone.

    Abstract translation: 本发明提供一种制备烷基化物的方法，包括：在烷基化条件下使反应区中含有至少异链烷烃和烯烃的烃混合物与酸性离子液体催化剂接触，得到烷基化物; 从反应区抽出含烷基化物的流出物; 将至少部分含烷基化物的流出物分离成富烃阶段和离子液体富含催化剂的相; 将部分富烃相分馏成至少含烷基化物的产物和含异链烷烃的流; 将另一部分富烃相与含烯烃的流混合以形成烃混合物; 并将烃混合物提供到反应区。

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