公开(公告)号：US3897381A

公开(公告)日：1975-07-29

申请号：US40715873

申请日：1973-10-17

申请人： DAINIPPON TORYO KK

发明人： TUGUKUNI HIDEYOSHI ,  KANO MASAFUMI ,  CHIKAZOE YOSHIHISA

IPC分类号： C08F2/00 ,  C08F2/44 ,  C08F246/00 ,  C08F291/00 ,  C09D175/00 ,  C08G22/06 ,  C08G22/20

CPC分类号： C08F291/00 ,  C08F2/16

摘要： This invention relates to a process for the preparation of a thermosetting resinous composition which comprises polymerizing (a) a water-soluble resin having an acid group of an acid value of 5 to 300 neutralized with a basic substance and (b) at least one Alpha , Beta -ethylenically unsaturated monomer, at least one of said components (a) and (b) containing a group capable of releasing an isocyanate group under heating, the polymerization being conducted in water at a temperature lower than the isocyanate-releasing temperature, and to a process for the preparation of a powdery thermosetting resinous composition which comprises spray-drying the aqueous dispersion obtained according to the above process.

摘要翻译： 本发明涉及一种制备热固性树脂组合物的方法，该方法包括聚合（a）具有碱性物质中和的酸值为5至300的酸基团的水溶性树脂和（b）至少一种α ，β-烯键式不饱和单体，所述组分（a）和（b）中的至少一种包含在加热下能够释放异氰酸酯基团的基团，聚合反应在低于异氰酸酯释放温度的温度下在水中进行，以及 涉及制备粉末状热固性树脂组合物的方法，其包括喷雾干燥根据上述方法获得的水分散体。

公开(公告)号：US3853577A

公开(公告)日：1974-12-10

申请号：US32134073

申请日：1973-01-05

申请人： BONNTILE CO ,  DAINIPPON TORYO KK

发明人： NISHIDA H ,  YONEYAMA A ,  YAMANISHI M ,  TANAKA S ,  HATANAKA A

IPC分类号： C04B28/02 ,  B05D1/02 ,  B05D5/02 ,  B05D5/06 ,  B29C63/00 ,  B32B37/00 ,  C04B26/14 ,  C04B41/45 ,  E04F13/02 ,  B44C1/20 ,  E04C1/00

CPC分类号： E04F13/02 ,  B05D3/12 ,  B05D5/02 ,  B05D5/061 ,  B05D7/534 ,  B05D7/544 ,  C04B41/4505

摘要： A method of preparing a decorative layer which comprises spraycoating a mortar composition containing 3 - 50 wt% of an epoxy resin and an epoxy hardener, 5 - 70 wt% cement, 5 - 70 wt% of an aggregate powder and 5 - 30 wt% water onto the surface of a base so as to form a concavo-convex surface pattern, pressing the top of the convex portions of the surface while in a semihardened condition to form flat areas on the tops of the convex portions and finish-coating the surface with a synthetic resin enamel or lacquer.

摘要翻译： 一种制备装饰层的方法，其包括喷涂包含3-50重量％的环氧树脂和环氧固化剂，5-70重量％的水泥，5-70重量％的聚集粉末和5-30重量％的环氧树脂的砂浆组合物 重量％的水滴在基材的表面上，以形成凹凸表面图案，在半硬化条件下按压表面的凸部的顶部，以在凸部的顶部上形成平坦区域并进行涂饰 表面用合成树脂搪瓷或漆。

公开(公告)号：US3847851A

公开(公告)日：1974-11-12

申请号：US36976573

申请日：1973-06-13

申请人： DAINIPPON TORYO KK

发明人： TUGUKUMI H ,  MATSUDA M

IPC分类号： C08G63/48 ,  C08G81/02 ,  C08J3/00 ,  C09D201/02 ,  C08F45/28 ,  C09D3/48

CPC分类号： C08J3/00 ,  C08G63/48 ,  C08G81/02 ,  C08J3/005 ,  C08J2300/10 ,  C09D201/02 ,  C08L101/02 ,  C08L2666/02

摘要： 1. A THERMOSETTING SYNTHETIC POLYMER DISPERSION COMPRISING A MIXTURE OF (I) A SYNTHETIC POLYMER DISPERSION COMPRISING PARTICLES OF A COPOLYMER FORMED FROM (A) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMER AND (B) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMER HAVING A CHEMICALLY REACTIVE CROSS-LINKING GROUP AND A PROTECTIVE LAYER FORMED AROUND SAID COPOLYMER PARTICLES, WHICH IS COMPOSED OF A STABILIZER (I) HAVING A COMPONENT COMPARTIBLE WITH SAID COPOLYMER OR BEING CHEMICALLY BONDED THERETO AND (II) BEING SOLVATED IN AN ORGANIC LIQUID HAVING NO POLARITY OR A LOW POLARITY, SAID COPOLYMER PARTICLES BEING STABLY DISPERSED IN THE ORGANIC LIQUID BY SAID PROTECTIVE LAYER AND HAVING AN AVERAGE PARTICLE SIZE OF 0.1 TO 10U, AND (II) A SYNTHETIC POLYMER DISPERSION COMPRISING PARTICLES OF A COPOLYMER FORMED FROM (A) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMELR AND (C) A COPOLYMERIZABLE ETHYLENICALLY UNSATURATED MONOMER HAVING A COMPLEMENTARY, CHEMICALLY REACTIVE CROSS-LINKING GROUP CAPABLE OF REACTING WITH THE CHEMICALLY REACTIVE CROSS-LINKING GROUP OF THE PARTICLES IN DISPERSION (I) AND A PROTECTIVE LAYER FORMED AROUND SAID COPOLYMER PARTICLES, WHICH IS COMPOSED OF A STABILIZER (I) HAVING A COMPONENT COMPARTIBLE WITH SAID COPOLYMER OR BEING CHEMICALLY BONDED THERETO AND (II) BEING SOLVATED IN AN ORGANIC LIQUID HAVING NO POLARITY OR A LOW POLARITY, SAID COPOLYMER PARTICLES BEING STABLY DISPERSED IN THE ORGANIC LIQUID BY SAID PROTECTIVE LAYER AND HAVING AN AVERAGE PARTICLE SIZE OF 0.1 TO 10U.

公开(公告)号：US3786010A

公开(公告)日：1974-01-15

申请号：US17847171

申请日：1971-09-07

申请人： DAINIPPON TORYO KK

发明人： TSUGUKUNI H ,  MATSUDA M

IPC分类号： C08F299/04 ,  C08G63/48 ,  C08L51/08 ,  C08F47/18

CPC分类号： C08G63/48 ,  C08F299/0478 ,  C08L51/08 ,  C08L2666/14

摘要： THIS INVENTION RELATES TO A POLYMER DISPERSION USEFUL ESPECIALLY AS A COATING COMPOSITION, WHICH COMPRISES AN ORGANIC LIQUID AS A DISPERSION MEDIUM AND AN OIL-MODIFED ALKYD RESIN SOLVATED IN THE ORGANIC LIQUID, THE OILMODIFIED ALKYD RESIN BEING BLOCK-OR GRAFT-POLYMERIZED WITH ACRYLONITRILE AND OTHER COPOLYMERIZABLE MONOMERS, AND TO A PROCESS FOR THE PREPARATION OF SUCH POLYMER DISPERSION.

公开(公告)号：US3772206A

公开(公告)日：1973-11-13

申请号：US3772206D

申请日：1971-12-30

申请人： DAINIPPON TORYO KK

发明人： HITOMI T ,  NISHIKAWA S ,  SAKAMOTO H

IPC分类号： C09K11/08 ,  C09K11/77 ,  G01T1/11 ,  C09K1/66

CPC分类号： G01T1/11 ,  C09K11/7703 ,  C09K11/7712

摘要： A THERMOLUMINESCENT MATERIAL WHICH COMPRISES A COMPLEX OXIDE HOST CRYSTAL OF MAGNESIUM OXIDE-BORON OXIDE AND TERBIUM AND/OR DYSPROSIUM AS AN ACTIVATOR ELEMENT INCORPORATED THEREIN SHOWS STRONG THERMOLUMINESCENCE AFTER EXPOSURE TO IONIZING RADIATIONS AND THUS IS USEFUL AS A LUMINESCENT MATERIALS FOR RADIOTHERMOLUMINESCENCE DOSIMETERS.

公开(公告)号：US3470411A

公开(公告)日：1969-09-30

申请号：US3470411D

申请日：1966-09-15

申请人： DAINIPPON TORYO KK

发明人： OZAWA LYUJI ,  TOSHINAI AKIO ,  NAGASHIMA YOSHIHISA ,  NISHIKAWA SATORU

IPC分类号： C09K11/77 ,  C09K11/82 ,  C09K1/44 ,  H01J29/20 ,  H01J61/44

CPC分类号： C09K11/7708

公开(公告)号：US3900630A

公开(公告)日：1975-08-19

申请号：US42917573

申请日：1973-12-28

申请人： DAINIPPON TORYO KK

发明人： MAKISHIMA HIROSHI ,  SHINOHARA TOSHIO ,  KAWAHARA YUKIO ,  NII HIROSHI ,  EBINE SETSUO

IPC分类号： C09D1/02 ,  B05D5/06 ,  B05D7/24 ,  C09D5/00 ,  B44D5/00

CPC分类号： B05D5/062 ,  Y10T428/24471

摘要： A decorative article having a patterned coating film, which is obtained by coating a substrate with a coat of silicate type inorganic paint, applying thereon a coat of a solution of an acid or acidic salt in water and/or an alcohol while the applied coat of paint is in the semi-hardened state, allowing the coated substrate to stand, removing the excess solution by waterwashing, and drying the thus treated substrate to harden the coating.

公开(公告)号：US3856885A

公开(公告)日：1974-12-24

申请号：US30099872

申请日：1972-10-26

申请人： DAINIPPON TORYO KK ,  LEBEN UTILITY CO

发明人： FURUYA A ,  ISHIMARU Y

IPC分类号： C08G63/52 ,  C08L67/06 ,  C08F21/00

CPC分类号： C08G63/52 ,  C08L67/06 ,  C08L27/04

摘要： This invention relates to a process for molding a thermosetting resinous composition, which comprises heating a liquid composition comprising an unsaturated alkyd resin, a vinyl chloride resin, a vinyl monomer and/or a reactive plasticizer, and a polymerization initiator at a temperature ranging from 80* to 160*C. to such an extent that the composition is not completely cured, cooling the composition to obtain a non-tacky partially-cured composition of a suitable form, and heating said partially-cured composition at a temperature ranging from 120* to 180*C. to complete the curing.

摘要翻译： 本发明涉及一种热固性树脂组合物成型方法，该方法包括在80℃的温度范围内加热包含不饱和醇酸树脂，氯乙烯树脂，乙烯基单体和/或反应性增塑剂的液体组合物和聚合引发剂 DEG至160℃至组合物未完全固化的程度，冷却组合物以获得合适形式的非粘性部分固化组合物，并在120℃的温度范围加热所述部分固化的组合物 至180℃以完成固化。

公开(公告)号：US3785991A

公开(公告)日：1974-01-15

申请号：US20975071

申请日：1971-12-20

申请人： DAINIPPON TORYO KK

发明人： TOSHINAI A ,  HASE T

IPC分类号： C09K11/77 ,  C09K11/85 ,  C09K1/06

CPC分类号： C09K11/7772

摘要： THIS INVENTION RELATES TO A PHOSPHOR FOR INFRARED-TOVISIBLE CONVERSION COMPRISING AS A MAIN INGREDIENT A COMPLEX RARE EARTH FLUORIDE HAVING A GENERAL COMPOSITION EXPRESSED BY THE FORMULAE (Y1-X-YYBXAY)F3,

(LA1-X-YYBXAY)F3

OR (LU1-X-YYBXAY)F3, KRESPECTIVELY, WHEREIN X IS IN THE RANGE OF FROM 0.05 TO 0.5, Y IS IN THE RANGE OF FROM 0.02 TO 0.09 WHEN YTTRIUM FLUORIDE IS USED AS THE HOST MATERIAL, AND FROM 0.001 TO 0.1 WHEN LANTHANUM OR LUTETIUM FLUORIDE IS USED AS THE HOST MEATERIAL, AND A IS AT LEAST ONE MEMBER SELECTED FROM ER AND HO, AND ZINC INCORPORATED IN THE COMPLEX RARE EARTH FLUORIDE, AND A PROCESS FOR THE PREPARATION OF A ZINC-INCORPORATED PHOSPHOR FOR INFRARED-TOVISIBLE CONVERSION, WHICH COMPRISES ADDING ZINC FLUORIDE OR ZINC SILICOFLUORIDE PRIOR TO OR AFTER FORMATION OF SAID COMPLEX RARE EARTH FLUORIDE, AND SUBSEQUENT HEATING.

公开(公告)号：US3773729A

公开(公告)日：1973-11-20

申请号：US3773729D

申请日：1971-04-15

申请人： DAINIPPON TORYO KK ,  TAKEDA CHEMICAL INDUSTRIES LTD ,  WAKIMOTO S ,  TUGUKUNI H ,  KANO M ,  MATSUI Y ,  KAZAMA S ,  GOTO J

发明人： WAKIMOTO S ,  TUGUKUNI H ,  KANO M ,  MATSUI Y ,  KAZAMA S ,  GOTO J

IPC分类号： C07C67/00 ,  C07C239/00 ,  C07C241/00 ,  C07C265/10 ,  C07C269/02 ,  C08G18/00 ,  C08G18/08 ,  C08G18/62 ,  C08G18/80 ,  C09D5/44 ,  C09D175/00 ,  C08G22/32 ,  C08G22/12

CPC分类号： C08G18/0823 ,  C08G18/0804 ,  C08G18/6254 ,  C08G18/8061 ,  C09D5/4465 ,  Y10S528/905

摘要： THE PRESENT INVENTION IS DIRECTED TO A BLOCKED ISOCTANATE POLYMER OF THE GENERAL FORMULA:

(B(NCO)-A-NH-COO)M-M(-COOH)P(-OH)(N-M)-(COO(-)Z(+))Q, OR

((B(NCO))2-A-NH-COO)M-M(-COOH)P(-OH)(N-M)-(COO(-)Z(+))Q

WHEREIN BNCO IS A BLOCKED NCO GROUP, A IS A RADICAL DERIVED BY REMOVING ALL NCO GROUPS FROM AN ORGANIC DIISOCYANNATE IN COMPOUND I OR AN ORGANIC TRIISOCYANATE IN COMPOUYND II, M IS A RADICAL DERIVED BY REDUCING ALL OH GROUPS AND CARBOXYL AND ITS SALT GROUPS FROM A HIGH MOLECULAR COMPOUND HAVING A MOLECULAR WEIGHT OF ABOUT 350 TO ABOUT 30,000 AND AN ACID VALUE OF ABOUT 30 TO ABOUT 350 AND CONTAINING N OH GROUPS PER MOLECULE AND CARBOXYL GROUPS, ABOUT 40 TO 100 MOLE PERCENT OF WHICH ARE IN THE FORM OF A QUATERNARY AMMONIUM SALT OR ALKALI METAL SALT, N AND M ARE POSITIVE NUMBERS OF NOT LESS THAN 1, WHEREIN (2+N) IN FORMULA I AND (3+N) IN FORMULA 11 ARE BOTH AT LEAST 5, WHEREAS N/2M IN FORMULA 1 AND N/3M IN FORMULA 11 ARE MORE THAN ABOUT 0.5, BUT LESS THAN ABOUT 4.0, Z IS A QUATERNARY AMMONIUM CATION OF ALKALI METAL CATION, (P+Q) IS SUCH A NUMBER THAT A COMPOUND OF (HO)N-M-(COOH)P+Q HAS AN ACID VALUE OF ABOUT 40 TO ABOUT 150, AND Q/(P+Q)X100 IS 100 TO ABOUT 40. THE PRESENT INVENTION, SIMILARLY, RELATES TO A METHOD OF PRODUCING THE AFOREMENTIONED BLOCKEDISOCYANATE POLYMER TYPE COMPOUNDS. THESE COMPOUNDS ARE USEFUL AS COATING AGENTS, ADHESIVE AGENTS AND THE LIKE.