-
公开(公告)号：US5208335A
公开(公告)日：1993-05-04
申请号：US890065
申请日：1992-05-27
Applicant: Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
Inventor： Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
CPC classification number: B01D53/02 , B01J20/0225 , B01J20/024 , B01J20/04 , B01J20/22 , B01J20/223 , B01J20/3425 , B01J20/3483 , B01J20/3491 , B01J41/043 , C01C3/11 , C07F15/065 , B01D2253/108 , B01D2256/12 , B01D2257/102 , B01D2259/40086 , B01D2259/40088 , C01B2210/0046
Abstract: High Capacity solid state cyanocobaltate complexes represented by the chemical formula:[(A).sub.a (R.sub.4 N).sub.b ].sup.z+.sub.x/z [Co(CN).sub.n ].sup.x- .multidot.pSwhere:A is alkali metal atom, alkaline earth metal atom, Zn, Cd or Hg atom;a is any number from 0 to 2.5each R is independently C.sub.1 -C.sub.1O substituted or unsubstituted alkyl, aryl or aralkyl; or a long chain hydrocarbon polymerb is any number from greater than zero to 3z is 1, 2 or 3;n is any number from 3 to 5;x is n-2;p is any number from greater than zero to 6; andS is a ligand which is capable of coordinating with [(A).sub.a (R.sub.4 N).sub.b 9 .sup.z+, Co or both.are capable of chemically binding oxygen to form novel oxygen adducts, thereby selectively removing oxygen from an oxygen-containing fluid stream. The bound oxygen may be recovered from the complexes by increasing the temperature or by reducing the partial pressure of O.sub.2 above the adduct.
Abstract translation: 由[化学式为[（A）a（R4N）b] z + x / z [Co（CN）n] x-xpS表示的高容量固态氰钴酸盐络合物，其中：A为碱金属原子，碱土金属原子， Zn，Cd或Hg原子; a为0至2.5的任何数，每个R独立地为C 1 -C 10取代或未取代的烷基，芳基或芳烷基; 或长链烃聚合物b是大于0至3的任何数为1,2或3; n是从3到5的任何数字; x是n-2; p是从大于零到6的任何数字; 并且S是能够与[（A）a（R 4 N）b 9 z +，Co或两者配位的配体。 能够化学结合氧以形成新的氧加合物，从而从含氧流体物流中选择性地除去氧。 可以通过增加温度或通过降低加合物上方的O 2分压来从络合物中回收结合的氧。
-
公开(公告)号：US4580404A
公开(公告)日：1986-04-08
申请号：US764150
申请日：1985-08-09
Applicant: Guido P. Pez , William A. Steyert
Inventor： Guido P. Pez , William A. Steyert
CPC classification number: F04B37/04 , Y10S417/901
Abstract: Hydrogen is stored at cryogenic temperatures by adsorption on porous carbon having a nitrogen BET apparent surface area above about 1500 m.sup.2 /g. Hydrogen can be adsorbed and desorbed in the context of a cryopump, having as the pumping element a panel, having large particles of pressed porous carbon thereon.
Abstract translation: 通过在具有大于约1500m 2 / g的氮BET表观表面积的多孔碳上吸附将氢储存在低温温度下。 可以在低温泵的上下文中吸附和解吸氢，其具有作为泵送元件的面板，其上具有大的压制多孔碳颗粒。
-
公开(公告)号：US4254059A
公开(公告)日：1981-03-03
申请号：US62874
申请日：1979-08-01
Applicant: Roger A. Grey , Guido P. Pez
Inventor： Roger A. Grey , Guido P. Pez
IPC: B01J31/18 , B01J31/24 , C07C209/48 , C07C85/20
CPC classification number: C07C209/48 , B01J31/2404 , B01J2231/643 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/842 , B01J31/1895
Abstract: A novel process is described for the homogeneous hydrogenation of nitriles to primary amines utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the high yield hydrogenation of nitriles to primary amines to be conducted under mild conditions of temperature and pressure with high selectivity and eliminates the need for the presence of ammonia to suppress the formation of significant amounts of secondary and tertiary amines.
Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂将腈均相氢化成伯胺的新方法。 使用这些阴离子催化剂允许腈在高温选择性条件下在温和条件下进行的腈的高产率氢化，并且不需要氨的存在来抑制显着量的仲胺和叔胺的形成。
-
公开(公告)号：US4232170A
公开(公告)日：1980-11-04
申请号：US007876
申请日：1979-01-31
Applicant: Roger A. Grey , Guido P. Pez
Inventor： Roger A. Grey , Guido P. Pez
IPC: C07C29/149 , C07C69/675 , C07C27/04 , C07C31/38
CPC classification number: C07C29/149 , Y02P20/52
Abstract: A novel process is described for the homogeneous hydrogenation of carboxylic acid esters to primary alcohols utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted in solution under mild conditions of temperature and pressure with high selectivity and eliminates the disadvantages of utilizing heterogeneous catalysts. A process is also described for decarbonylating formate esters utilizing said compositions as catalysts.
Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的羧酸酯与伯醇的均相氢化的新方法。 使用这些阴离子催化剂允许该方法在温和和高温的温和条件下在溶液中进行，并且消除了利用非均相催化剂的缺点。 还描述了使用所述组合物作为催化剂的甲酸酯脱羧酸酯的方法。
-
公开(公告)号：US4224458A
公开(公告)日：1980-09-23
申请号：US7877
申请日：1979-01-31
Applicant: Roger A. Grey , Guido P. Pez
Inventor： Roger A. Grey , Guido P. Pez
CPC classification number: C07C5/11 , C07C2102/10 , C07C2531/22
Abstract: An improved process is described for the homogeneous hydrogenation of polycyclic aromatic hydrocarbons utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted under mild conditions of temperature and pressure with high selectivity for the production of partially hydrogenated derivatives of polycyclic aromatic hydrocarbons such as 1,2,3,4-tetrahydronaphthalene, and eliminates the need for the presence of base or carbon monoxide atmosphere in the process.
Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的多环芳烃的均相氢化的改进方法。 使用这些阴离子催化剂允许该方法在温和的温度和压力条件下进行，并且高选择性地生产多环芳烃如1,2,3,4-四氢化萘的部分氢化衍生物，并且不需要 在该过程中存在碱或一氧化碳气氛。
-
Patent Agency Ranking
公开(公告)号：US4024169A
公开(公告)日：1977-05-17
申请号：US636197
申请日：1975-11-28
Applicant: Guido P. Pez
Inventor： Guido P. Pez
Abstract: Complexes of the titanium cyclopentadienyl compound ##STR1## and nitrogen, having the probable structure: ##STR2## where the symbol N.apprxeq.N represents a bonding state intermediate between the azo-N=N- bond and the hydrazine =N-N= bond; such complex having the simple dimeric form as indicated by molecular weight determination on this form dissolved in tetrahydrofuran, and having a polymeric form wherein a nitrogen atom of one molecule of the dimeric form is coordinated by a dative link with a Ti atom of another molecule of the dimeric form, as suggested by low solubility of this polymeric form in 1,2-dimethoxyethane and breakdown of this form to the dimeric form by action of tetrahydrofuran.Another related complex is a black solid nitrogen-containing reaction product of the above titanium cyclopentadienyl compound in dry state with nitrogen at about 60 atmospheres pressure, having an infrared spectrum typical of a metallocene compound with no N-N or Ti-N vibration absorption bands.The nitrogen in these complexes is reactive, e.g. with reducing agents such as potassium naphthalene, to afford ammonia. Moreover, the complexes are catalytically active for hydrocarbon conversions such as conversion of ethylene to ethane, butane, 1-butene and 1,3-butadiene.
Abstract translation: 具有可能结构的钛环戊二烯基化合物＆lt; IMAGE＆gt;和氮的配合物：其中符号N APPROX N表示偶氮-N = N-键和肼= N-N =键之间的键合状态; 这种复合物具有简单的二聚体形式，如该形式的分子量测定所示，溶解在四氢呋喃中，并且具有聚合形式，其中一个分子二聚体形式的氮原子与另一个分子的Ti原子 这种二聚体形式，如该聚合物形式在1,2-二甲氧基乙烷中的低溶解度所示，并且通过四氢呋喃的作用将该形式分解成二聚体形式。
-
17.发明授权
公开(公告)号：US5141725A
公开(公告)日：1992-08-25
申请号：US669811
申请日：1991-03-15
Applicant: Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
Inventor： Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
CPC classification number: B01D53/02 , B01J20/0225 , B01J20/024 , B01J20/04 , B01J20/22 , B01J20/223 , B01J20/3071 , B01J20/3425 , B01J20/3483 , B01J20/3491
Abstract: A process is provided for selectively separating oxygen from an oxygen-containing fluid stream by bringing said fluid stream into contact with a high capacity solid state cyanocobaltate complex in a non-aluminosilicate environment represented by the chemical formula:A.sub.x/z.sup.z+ [Co(CN).sub.n ].sup.x- .multidot.pSwhere:A is an alkali, alkaline earth, transition, or Group 12 metal atom;z is 1, 2 or 3;n is any number from 3 to 5;x is n-2;p is any number from greater than zero to 6; andS is a ligand which is capable of coordinating with A.sup.z+, Co or both.These complexes chemically bind oxygen to form novel oxygen adducts, thereby selectively removing oxygen from the fluid stream. The bound oxygen may be recovered by increasing the temperature or by reducing the partial pressure of O.sub.2 above the adduct.
-
公开(公告)号：US5026929A
公开(公告)日：1991-06-25
申请号：US477289
申请日：1990-02-08
Applicant: John A. Marsella , Guido P. Pez , Anne M. Coughlin
Inventor： John A. Marsella , Guido P. Pez , Anne M. Coughlin
IPC: C07C17/00
CPC classification number: C07C17/00
Abstract: A process is disclosed for making a highly fluorinated aromatic compound by contacting a perfluorocycloalkane, such as perfluorodecahydronaphthalene, with a complex of a metal from Groups IA and IIA of the Periodic Table and an organic electron acceptor. The reaction is carried out in an organic solvent and under reducing conditions which are relatively moderate. Best results are obtained using a perfluorocycloalkane having 2-4 condensed rings and a complex of either sodium or lithium and benzophenone thereby making a perfluorinated condensed ring aromatic compound such as perfluoronaphthalene or perfluorophenanthrene.
Abstract translation: 公开了通过使全氟环烷烃如全氟代十氢萘与元素周期表IA和IIA族金属络合物和有机电子受体接触来制备高度氟化的芳族化合物的方法。 该反应在有机溶剂中并在相对温和的还原条件下进行。 使用具有2-4个稠环的全氟环烷烃和钠或锂和二苯甲酮的络合物得到最佳结果，由此制得全氟化稠环芳族化合物如全氟萘或全氟菲。
-
公开(公告)号：US4973456A
公开(公告)日：1990-11-27
申请号：US261653
申请日：1988-10-24
Applicant: Robert Quinn , Guido P. Pez
Inventor： Robert Quinn , Guido P. Pez
CPC classification number: C10K1/14 , B01D53/1493 , C10K1/10 , C10K1/12
Abstract: The present invention is a process for reversibly absorbing acid gases, such as CO.sub.2, H.sub.2 S, SO.sub.2, HCN and the like from gas mixtures. The gas mixture containing one or more of these acid gases is contacted with a hydrated salt of the compositionA.sub.x.sup.m+ B.sub.y.sup.n-.rH.sub.2 Owherein A.sup.m+ is a cation, B.sup.n- is the conjugate base of a weak acid having a pKa corresponding to an ionization constant of the acid greater than 3 as measured in dilute aqueous solution, m and n are independently integers from 1-4, x and y are integers such that the ratio of x to y provides a neutral salt and r is any number greater than zero up to the maximum number of moles of water which can be bound to the salt. The salt hydrate reversibly absorbs the acid gas from the gas mixture.
Abstract translation: 本发明是从气体混合物中可逆地吸收诸如CO 2，H 2 S，SO 2，HCN等酸性气体的方法。 含有一种或多种这些酸性气体的气体混合物与组合物Axm + Byn-.H 2 O的水合盐接触，其中Am +是阳离子，Bn-是具有对应于电离常数的pKa的弱酸的共轭碱 的酸大于3，在稀水溶液中测定，m和n独立地为1-4的整数，x和y为整数，使得x与y的比例提供中性盐，r为大于零的任何数 达到可以与盐结合的水的最大摩尔数。 盐水合物从气体混合物中可逆地吸收酸性气体。
-
公开(公告)号：US4762535A
公开(公告)日：1988-08-09
申请号：US57403
申请日：1987-06-02
Applicant: Guido P. Pez , Daniel V. Laciak
Inventor： Guido P. Pez , Daniel V. Laciak
IPC: B01D53/22 , B01D19/00 , B01D53/58 , B01D61/38 , B01D69/00 , B01D69/14 , C01C1/04 , C01C1/10 , C01C1/12 , C01C3/02 , C02F1/20
CPC classification number: B01D61/38 , B01D69/141 , C01C1/0458 , C01C1/12 , C01C3/0212 , Y02P20/52
Abstract: The present invention is a process for separating ammonia from mixtures of other gases or from aqueous streams. The ammonia-containing mixture is contacted with a membrane containing, as the active component, a salt having the structural formula: NR.sub.4.sup.+ X.sup.-, wherein each R is independently H or a straight chain or branched alkyl group and X.sup.- is an organic or inorganic anion. The membrane is useful for the selective permeation of ammonia from mixtures of gases containing ammonia, nitrogen and hydrogen.
-
-
-
-
-
-
-
-
-
Search Results
34
records
(took 0.014 seconds)
