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公开(公告)号：US20100186866A1
公开(公告)日：2010-07-29
申请号：US12439740
申请日：2007-09-04
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
IPC分类号： B60C5/14
CPC分类号： B60C1/0008 , B60C5/14 , C08L21/00 , C08L23/16 , Y10T152/10495 , C08L2666/06 , C08L2666/08
摘要： A pneumatic tire comprising an air permeation preventive layer comprising a film of a thermoplastic resin composition containing a polyvinyl alcohol or ethylene vinyl alcohol copolymer, to which a protective film of a rubber composition containing an ethylene propylene rubber (EPM) or ethylene propylene diene rubber (EPDM) is, directly or via an adhesive, placed adjacent thereto, as one layer in at least one side thereof, whereby both a further reduction in the air leakage rate of the pneumatic tire and a good durability can be achieved and furthermore a reduction in the weight of the tire can be achieved.
摘要翻译： 1.一种充气轮胎，其特征在于，具备防透气层，所述充气轮胎包含含有聚乙烯醇或乙烯乙烯醇共聚物的热塑性树脂组合物的膜，所述防粘层含有乙丙橡胶（EPM）或乙烯丙烯二烯橡胶 EPDM）直接或通过粘合剂在其至少一个侧面上作为一层放置，由此可以实现充气轮胎的空气泄漏速度的进一步降低和良好的耐久性，并且还可以减少 可以实现轮胎的重量。
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12.发明授权Stabilized dynamically vulcanized thermoplastic elastomer compositions useful in fluid barrier applications 有权用于流体屏障应用的稳定的动态硫化热塑性弹性体组合物公开(公告)号：US09540510B2
公开(公告)日：2017-01-10
申请号：US13140080
申请日：2008-12-17
IPC分类号： C08L77/00 , C08L51/00 , C08L15/02 , C08K5/3475 , C08K5/101 , C08L23/28 , C08L51/04 , C08L51/06 , C08L51/08 , C08L53/02 , C08L55/02 , C08K5/00 , C08L9/02 , C08L15/00
CPC分类号： C08L77/00 , C08K5/005 , C08L9/02 , C08L15/00 , C08L23/283 , C08L51/00 , C08L51/04 , C08L51/06 , C08L51/08 , C08L53/02 , C08L55/02 , C08L2666/02 , C08L2666/24 , C08L2666/14 , C08L2666/04 , C08L2666/06
摘要： A stabilized, dynamically vulcanized thermoplastic elastomer composition comprising dispersed dynamically vulcanized particles of at least one first elastomer or rubber comprising halogenated isobutylene-containing elastomer and dispersed particles of at least one second elastomer or rubber comprising at least one functional group capable of reacting with and grafting to a polyamide, the particles of the at least one first and at least one second elastomers dispersed in a continuous thermoplastic polyamide or nylon resin matrix comprising at least one nylon homopolymer, nylon copolymer or mixture thereof, the composition or the at least one first elastomer further comprising at least one stabilizer against degradation induced by exposure to actinic, particularly ultraviolet, radiation. The compositions are preferably produced in a mixing extruder and are suitable for producing durable, flexible, thermoplastic elastomer fluid barrier films or layers useful in industrial articles such as vehicle tire innerliners and hoses.
摘要翻译： 一种稳定的，动态硫化的热塑性弹性体组合物，其包含至少一种包含含卤代异丁烯的弹性体的至少一种第一弹性体或橡胶的分散的动态硫化颗粒和至少一种第二弹性体或橡胶的分散颗粒，所述第二弹性体或橡胶包含至少一个能与载体 至少一种第一和至少一种第二弹性体的颗粒分散在包含至少一种尼龙均聚物，尼龙共聚物或其混合物的连续热塑性聚酰胺或尼龙树脂基质中，所述组合物或至少一种第一弹性体 进一步包含至少一种稳定剂，其防止通过暴露于光化特别是紫外线辐射而引起的降解。 组合物优选在混合挤出机中制备，并且适用于生产用于工业制品例如车辆轮胎内衬和软管的耐用的，柔性的，热塑性的弹性体流体屏障膜或层。
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公开(公告)号：US09272491B2
公开(公告)日：2016-03-01
申请号：US13810090
申请日：2011-03-18
申请人： Shusaku Tomoi , Yuichi Hara
发明人： Shusaku Tomoi , Yuichi Hara
CPC分类号： B60C5/14 , B32B7/02 , B32B25/08 , B32B25/14 , B32B27/08 , B32B27/28 , B32B27/306 , B32B27/34 , B32B2250/42 , B32B2270/00 , B32B2597/00 , B60C5/00 , B60C2005/145 , Y10T428/2495 , Y10T428/3192
摘要： A laminate comprising at least one layer of a first thermoplastic resin composition alternately stacked with at least two layers of a second thermoplastic resin composition, so that the outermost layers are the layers of the second thermoplastic resin composition, wherein the first thermoplastic resin composition, comprises at least one selected from the group consisting of ethylene-vinyl alcohol copolymer and modified ethylene-vinyl alcohol copolymers, and the second thermoplastic resin composition has a different composition from the first thermoplastic resin composition, and wherein, in any adjacent pair of the layer of the first thermoplastic resin composition and the layer of the second thermoplastic resin composition, the layer of the first thermoplastic resin composition and the layer of the second thermoplastic resin composition have a specific tensile modulus ratio and a specific thickness ratio.
摘要翻译： 一种层压体，包括至少一层第一热塑性树脂组合物，其交替地层叠有至少两层第二热塑性树脂组合物，使得最外层是第二热塑性树脂组合物的层，其中第一热塑性树脂组合物包含 选自乙烯 - 乙烯醇共聚物和改性乙烯 - 乙烯醇共聚物中的至少一种，第二热塑性树脂组合物与第一热塑性树脂组合物具有不同的组成，并且其中在任何相邻的一层 第一热塑性树脂组合物和第二热塑性树脂组合物层，第一热塑性树脂组合物层和第二热塑性树脂组合物层具有比拉伸模量比和比厚度比。
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公开(公告)号：US08960250B2
公开(公告)日：2015-02-24
申请号：US12446877
申请日：2006-10-26
CPC分类号： B60C1/0008 , B32B1/08 , B32B7/12 , B32B25/08 , B32B2250/03 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2307/7265 , B32B2323/046 , B32B2355/00 , B32B2597/00 , B32B2605/00 , B60C5/14 , B60C2005/145 , Y10T428/1386 , Y10T428/1393 , Y10T428/265 , Y10T428/31515 , Y10T428/3154 , Y10T428/31663 , Y10T428/31721 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/31917 , Y10T428/31924 , Y10T428/31931
摘要： An article having a fluid permeation prevention layer, such as a pneumatic tire or hose. A tire for example includes an outer tread layer, intermediate sidewall and carcass layers and an innermost air permeation prevention layer: (i) the air permeation prevention (APP) layer having an upper and a lower surface, the layer having a polymer composition exhibiting an air permeation coefficient (APC) of about 25×10′12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of about 1 MPa to about 500 MPa, the polymer composition comprising: (A) at least 10 wt % of at least one. thermoplastic resin component having an APC of about 25×10″12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of more than 500 MPa, which is preferably a polyamide resin or mixture, and (B) at least 10 wt % of at least one elastomer component having an APC of more than about 25×10″12 cc cm/cm2 sec cmHg (at 30° C.) and a Young's modulus of not more than 500 MPa, which elastomer component is preferably a halogen-containing rubber or mixture, the total amount (A)+(B) being not less than about 30 wt %, and the elastomer component is a dispersed vulcanized, discontinuous phase in the thermoplastic resin matrix; and (ii) at least one thermoplastic laminate layer bonded to at least said lower surface of the APP layer, the thermoplastic layer comprising a film-forming, semi-crystalline, substantially hydrophobic carbon chain polymer having a glass transition temperature, Tg, of less than about −200 C.
摘要翻译： 具有防渗漏层的物品，例如充气轮胎或软管。 轮胎例如包括外胎面层，中间侧壁和胎体层以及最内部的防透气层：（i）具有上表面和下表面的防透气层（APP）层，所述层具有聚合物组合物， 大约25×10'12 cc cm / cm 2·sec·cmHg（30℃）或更低，杨氏模量为约1MPa至约500MPa的透气系数（APC），所述聚合物组合物包含：（A） 至少10重量％的至少一个。 具有约25×10 12 cc cm / cm 2·sec·cmHg（30℃）的APC和大于500MPa的杨氏模量的热塑性树脂组分（优选聚酰胺树脂或混合物）和（B ）至少10重量％的至少一种具有APC大于约25×10 12 cc cm / cm 2·sec·cmHg（30℃）的APC和不大于500MPa的杨氏模量的弹性体组分，该弹性体 组分优选为含卤素橡胶或混合物，总量（A）+（B）不小于约30重量％，弹性体组分为热塑性树脂基体中分散的硫化不连续相; 和（ii）至少一层结合至所述APP层的至少所述下表面的热塑性层压层，所述热塑性层包含成膜，半结晶，基本疏水的碳链聚合物，其玻璃化转变温度Tg低于 比约-200℃
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公开(公告)号：US20140041781A1
公开(公告)日：2014-02-13
申请号：US14113063
申请日：2011-04-21
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
IPC分类号： B60C5/12
CPC分类号： B60C1/0008 , C08K5/17 , C08L23/283 , C08L51/06 , C08L77/00 , C08L71/02
摘要： In order to improve fatigue durability of a thermoplastic elastomer composition composed of a matrix phase of a thermoplastic resin and dispersed phases of a rubber, the thermoplastic elastomer composition comprises (A) 100 parts by weight of a halogenated poly(isoolefin-co-p-alkylstyrene) rubber, (B) 40 to 120 parts by weight of a polyamide resin, and (C) 0.5 to 10 parts by weight of an amine having at least one hydroxyl group. The amine (C) having at least one hydroxyl group is preferably a compound represented by formula (1): where R1 is a C1-30 alkyl; R2 is —(C2H4O)n—H, where n is an integer of 1 to 30; and R3 is —(C2H4O)m—H, where m is an integer of 1 to 30, a C1-30 alkyl, or hydrogen.
摘要翻译： 为了提高由热塑性树脂的基质相和橡胶分散相构成的热塑性弹性体组合物的疲劳寿命，该热塑性弹性体组合物包含（A）100重量份卤化聚（异烯烃 - 共 - 对 - 烷基苯乙烯）橡胶，（B）40〜120重量份聚酰胺树脂，（C）0.5〜10重量份具有至少一个羟基的胺。 具有至少一个羟基的胺（C）优选为由式（1）表示的化合物：其中R1为C1-30烷基; R2是 - （C2H4O）n-H，其中n是1至30的整数; 并且R 3是 - （C 2 H 4 O）m -H，其中m是1至30的整数，C 1-3烷基或氢。
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公开(公告)号：US20100024941A1
公开(公告)日：2010-02-04
申请号：US12446877
申请日：2006-10-26
IPC分类号： B32B25/08 , B32B27/34 , B32B27/36 , B32B25/16 , B32B27/32 , B32B27/06 , B32B25/20 , B32B27/08 , B32B27/30 , B32B5/00 , B32B1/08 , B60C1/00 , B32B27/04
CPC分类号： B60C1/0008 , B32B1/08 , B32B7/12 , B32B25/08 , B32B2250/03 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2307/7265 , B32B2323/046 , B32B2355/00 , B32B2597/00 , B32B2605/00 , B60C5/14 , B60C2005/145 , Y10T428/1386 , Y10T428/1393 , Y10T428/265 , Y10T428/31515 , Y10T428/3154 , Y10T428/31663 , Y10T428/31721 , Y10T428/3175 , Y10T428/31797 , Y10T428/31855 , Y10T428/31917 , Y10T428/31924 , Y10T428/31931
摘要： An article having a fluid permeation prevention layer, such as a pneumatic tire or hose. A tire for example includes an outer tread layer, intermediate sidewall and carcass layers and an innermost air permeation prevention layer: (i) the air permeation prevention (APP) layer having an upper and a lower surface, the layer having a polymer composition exhibiting an air permeation coefficient (APC) of about 25×1O′12 cc cm/cm2 sec cmHg (at 30* C) or less and a Young's modulus of about 1 MPa to about 500 MPa, the polymer composition comprising: (A) at least 10 wt % of at least one. thermoplastic resin component having an APC of about 25×1O″12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of more than 500 MPa, which is preferably a polyamide resin or mixture, and (B) at least 10 wt % of at least one elastomer component having an APC of more than about 25×10″12 cc cm/cm2 sec cmHg (at 30° C.) and a Young's modulus of not more than 500 MPa, which elastomer component is preferably a halogen-containing rubber or mixture, the total amount (A)+(B) being not less than about 30 wt %, and the elastomer component is a dispersed vulcanized, discontinuous phase in the thermoplastic resin matrix; and (ii) at least one thermoplastic laminate layer bonded to at least said lower surface of the APP layer, the thermoplastic layer comprising a film-forming, semi-crystalline, substantially hydrophobic carbon chain polymer having a glass transition temperature, Tg, of less than about −200 C.
摘要翻译： 具有防渗漏层的物品，例如充气轮胎或软管。 轮胎例如包括外胎面层，中间侧壁和胎体层以及最内部的防透气层：（i）具有上表面和下表面的防透气层（APP）层，所述层具有聚合物组合物， 空气透过系数（APC）为约25×10 -2 cm 3 / cm 2·sec·cmHg（30℃）或更低，杨氏模量为约1MPa至约500MPa，所述聚合物组合物包含：（A）至少10重量％ 至少有一个的％。 具有约25×10 -2 cm cm / cm 2·sec·cmHg（30℃）的APC和大于500MPa的杨氏模量（优选聚酰胺树脂或混合物）的热塑性树脂组分，和（B） 至少10重量％的至少一种弹性体组分具有大于约25×10'12cc cm / cm 2·sec·cmHg（30℃）和不大于500MPa的杨氏模量，弹性体组分为 优选含卤素橡胶或混合物，总量（A）+（B）不小于约30重量％，弹性体组分是热塑性树脂基质中分散的硫化不连续相; 和（ii）至少一层结合至所述APP层的至少所述下表面的热塑性层压层，所述热塑性层包含成膜，半结晶，基本疏水的碳链聚合物，其玻璃化转变温度Tg低于 比约-200℃
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公开(公告)号：US09643452B2
公开(公告)日：2017-05-09
申请号：US13259062
申请日：2011-03-07
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
IPC分类号： B32B3/00 , B60C19/00 , C09J153/02 , B60C5/14 , B60C1/00 , C09J111/00 , C08L15/02 , C08L61/06 , C08L61/14
CPC分类号： B60C5/14 , B60C1/0008 , B60C2005/145 , C08L15/02 , C08L61/06 , C08L61/14 , C09J111/00 , C09J153/02 , C09J161/06 , Y10T428/265 , Y10T428/2874
摘要： Provided is an adhesive composition that provides excellent adhesion between a thermoplastic resin or a thermoplastic elastomer in which an elastomer component is dispersed in the thermoplastic resin and a tire by a combination of general-purpose materials, without using any special polymer. The adhesive composition comprises 100 parts by weight of a base polymer and 20 to 50 parts by weight of a resol-type phenolic resin-based resin crosslinking agent, wherein 100 parts by weight of the base polymer comprises 80 to 99 parts by weight of a thermoplastic elastomer and 1 to 20 parts by weight of a halogenated rubber. The resol-type phenolic resin-based resin crosslinking agent is preferably an alkylphenol-formaldehyde resin. Examples of the thermoplastic elastomer can include styrene-butadiene-styrene block copolymers, and examples of the halogenated rubber can include chloroprene rubber and chlorosulfonated polyethylene.
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公开(公告)号：US08921483B2
公开(公告)日：2014-12-30
申请号：US14113063
申请日：2011-04-21
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
CPC分类号： B60C1/0008 , C08K5/17 , C08L23/283 , C08L51/06 , C08L77/00 , C08L71/02
摘要： In order to improve fatigue durability of a thermoplastic elastomer composition composed of a matrix phase of a thermoplastic resin and dispersed phases of a rubber, the thermoplastic elastomer composition comprises (A) 100 parts by weight of a halogenated poly(isoolefin-co-p-alkylstyrene) rubber, (B) 40 to 120 parts by weight of a polyamide resin, and (C) 0.5 to 10 parts by weight of an amine having at least one hydroxyl group. The amine (C) having at least one hydroxyl group is preferably a compound represented by formula (1): where R1 is a C1-30 alkyl; R2 is —(C2H4O)n—H, where n is an integer of 1 to 30; and R3 is —(C2H4O)m—H, where m is an integer of 1 to 30, a C1-30 alkyl, or hydrogen.
摘要翻译： 为了提高由热塑性树脂的基质相和橡胶分散相构成的热塑性弹性体组合物的疲劳寿命，该热塑性弹性体组合物包含（A）100重量份卤化聚（异烯烃 - 共 - 对 - 烷基苯乙烯）橡胶，（B）40〜120重量份聚酰胺树脂，（C）0.5〜10重量份具有至少一个羟基的胺。 具有至少一个羟基的胺（C）优选为由式（1）表示的化合物：其中R1为C1-30烷基; R2是 - （C2H4O）n-H，其中n是1至30的整数; 并且R 3是 - （C 2 H 4 O）m -H，其中m是1至30的整数，C 1-3烷基或氢。
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公开(公告)号：US08546478B2
公开(公告)日：2013-10-01
申请号：US13392724
申请日：2011-03-18
申请人： Shusaku Tomoi , Kouichi Kawaguchi
发明人： Shusaku Tomoi , Kouichi Kawaguchi
CPC分类号： C08K3/04 , B60C1/0008 , C08J3/28 , C08J2323/22 , C08L23/22 , C08L23/283 , C08L25/18 , C08L77/02 , C08L77/06
摘要： Disclosed is a method for producing a thermoplastic elastomer composition having a phase structure comprising a continuous phase comprising at least one thermoplastic resin and a disperse phase comprising dynamically crosslinked elastomer particles finely dispersed in the continuous phase, the method being characterized by dispersing in at least one crosslinkable elastomer component furnace carbon black having a BET nitrogen adsorption specific surface area of from 100 to 260 m2/g and a primary particle average particle diameter of from 10 to 25 nm in an amount of 1 to 15 parts by weight with respect to 100 parts by weight of the at least one crosslinkable elastomer component, prior to or during dynamic crosslinking.
摘要翻译： 公开了一种具有相结构的热塑性弹性体组合物的方法，所述相组织包括连续相，该连续相包含至少一种热塑性树脂和包含在连续相中细分散的动态交联的弹性体颗粒的分散相，该方法的特征在于将至少一种 交联性弹性体成分炉炭黑，其BET氮吸附比表面积为100〜260m2 / g，一次粒子平均粒径为10〜25nm，相对于100份为1〜15份 的至少一种可交联弹性体组分，在动态交联之前或期间。
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公开(公告)号：US20130112330A1
公开(公告)日：2013-05-09
申请号：US13810090
申请日：2011-03-18
申请人： Shusaku Tomoi , Yuichi Hara
发明人： Shusaku Tomoi , Yuichi Hara
CPC分类号： B60C5/14 , B32B7/02 , B32B25/08 , B32B25/14 , B32B27/08 , B32B27/28 , B32B27/306 , B32B27/34 , B32B2250/42 , B32B2270/00 , B32B2597/00 , B60C5/00 , B60C2005/145 , Y10T428/2495 , Y10T428/3192
摘要： A laminate comprising at least one layer of a first thermoplastic resin composition alternately stacked with at least two layers of a second thermoplastic resin composition, so that the outermost layers are the layers of the second thermoplastic resin composition, wherein the first thermoplastic resin composition, comprises at least one selected from the group consisting of ethylene-vinyl alcohol copolymer and modified ethylene-vinyl alcohol copolymers, and the second thermoplastic resin composition has a different composition from the first thermoplastic resin composition, and wherein, in any adjacent pair of the layer of the first thermoplastic resin composition and the layer of the second thermoplastic resin composition, the layer of the first thermoplastic resin composition and the layer of the second thermoplastic resin composition have a specific tensile modulus ratio and a specific thickness ratio.
摘要翻译： 一种层压体，包括至少一层第一热塑性树脂组合物，其交替地层叠有至少两层第二热塑性树脂组合物，使得最外层是第二热塑性树脂组合物的层，其中第一热塑性树脂组合物包含 选自乙烯 - 乙烯醇共聚物和改性乙烯 - 乙烯醇共聚物中的至少一种，第二热塑性树脂组合物与第一热塑性树脂组合物具有不同的组成，并且其中在任何相邻的一层 第一热塑性树脂组合物和第二热塑性树脂组合物层，第一热塑性树脂组合物层和第二热塑性树脂组合物层具有比拉伸模量比和比厚度比。
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