公开(公告)号：US10086367B2

公开(公告)日：2018-10-02

申请号：US15426843

申请日：2017-02-07

Applicant: BASF CORPORATION

Inventor： Gary M. Smith ,  Robert McGuire, Jr. ,  Bilge Yilmaz

IPC: B01J29/06 ,  B01J29/14 ,  B01J37/28 ,  B01J37/02 ,  C10G11/05 ,  C10G11/18 ,  B01J35/08 ,  B01J29/08 ,  B01J37/00

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US09441167B2

公开(公告)日：2016-09-13

申请号：US14134629

申请日：2013-12-19

Applicant: BASF Corporation

Inventor： Robert McGuire, Jr. ,  Gary M. Smith ,  Bilge Yilmaz

IPC: C10G11/04 ,  C10G11/02 ,  C10G11/18

CPC classification number: C10G11/04 ,  B01J21/02 ,  B01J29/088 ,  B01J35/0006 ,  B01J37/0045 ,  B01J37/04 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2229/64 ,  C10G11/02 ,  C10G11/18

Abstract: Fluid catalytic cracking (FCC) processes are described, the processes utilizing one or more boron oxide components. Also described are FCC compositions and methods of manufacture. One or more boron oxide components on FCC compatible inorganic particles are added to a FCC unit to crack hydrocarbon feeds, resulting in lower hydrogen and coke yields.

Abstract translation: 流程催化裂化（FCC）方法描述了利用一种或多种氧化硼组分的方法。 还描述了FCC组合物和制造方法。 将FCC兼容的无机颗粒上的一种或多种氧化硼组分加入到FCC单元中以裂解烃进料，导致较低的氢气和焦炭产率。

公开(公告)号：US10207257B2

公开(公告)日：2019-02-19

申请号：US15256472

申请日：2016-09-02

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  David Stockwell ,  Gary M. Smith

IPC: B01J29/06 ,  B01J29/08 ,  B01J35/02 ,  B01J29/064 ,  B01J29/10 ,  B01J29/16 ,  C10G45/02 ,  C10G47/20 ,  C10G65/12 ,  C10G47/16 ,  B01J37/02 ,  B01J37/00 ,  B01J35/10

Abstract: A zeolite-containing fixed bed catalyst is formed by pre-shaping a mixture of a reactive aluminum-containing component and a matrix component into pre-shaped particles, and contacting the pre-shaped particles with a reactive liquid containing a silicate for a sufficient time and temperature to form an in-situ zeolite within the pre-shaped particles. The contacting of the pre-shaped particles and the liquid is achieved such that there is relative movement between the pre-shaped particles and the liquid.

公开(公告)号：US20180126365A1

公开(公告)日：2018-05-10

申请号：US15861423

申请日：2018-01-03

Applicant: BASF Corporation

Inventor： Robert McGuire, JR. ,  Gary M. Smith ,  Bilge Yilmaz

IPC: B01J29/08 ,  C10G11/04 ,  B01J23/755 ,  B01J21/16 ,  B01J21/04 ,  B01J21/02 ,  B01J35/00 ,  B01J37/04 ,  B01J37/02 ,  B01J37/00 ,  C10G11/18 ,  C10G11/05

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US09895680B2

公开(公告)日：2018-02-20

申请号：US14134614

申请日：2013-12-19

Applicant: BASF Corporation

Inventor： Robert McGuire, Jr. ,  Gary M. Smith ,  Bilge Yilmaz

IPC: B01J29/06 ,  C10G11/05 ,  B01J29/08 ,  C10G11/04 ,  C10G11/18 ,  B01J37/04 ,  B01J35/00 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J29/088 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/26 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US09796932B2

公开(公告)日：2017-10-24

申请号：US14134640

申请日：2013-12-19

Applicant: BASF Corporation

Inventor： Gary M. Smith ,  Robert McGuire, Jr. ,  Bilge Yilmaz

IPC: B01J29/08 ,  C10G11/04 ,  C10G11/18 ,  B01J37/04 ,  B01J37/28 ,  B01J35/00 ,  B01J21/02 ,  B01J21/16 ,  B01J29/06 ,  B01J37/00 ,  B01J37/06

CPC classification number: C10G11/04 ,  B01J21/02 ,  B01J21/16 ,  B01J29/06 ,  B01J29/061 ,  B01J29/088 ,  B01J35/0006 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/64 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles first particle type comprising one or more boron oxide components and a first matrix component and a second particle type having a composition different from the first particle type, the second particle type comprising a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

公开(公告)号：US20170001179A1

公开(公告)日：2017-01-05

申请号：US15256472

申请日：2016-09-02

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  David Stockwell ,  Gary M. Smith

IPC: B01J29/08 ,  B01J35/02

CPC classification number: B01J29/084 ,  B01J29/06 ,  B01J29/064 ,  B01J29/106 ,  B01J29/166 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1066 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0072 ,  B01J37/0215 ,  B01J2229/64 ,  C10G45/02 ,  C10G47/16 ,  C10G47/20 ,  C10G65/12 ,  C10G2400/02

Abstract: A zeolite-containing fixed bed catalyst is formed by pre-shaping a mixture of a reactive aluminum-containing component and a matrix component into pre-shaped particles, and contacting the pre-shaped particles with a reactive liquid containing a silicate for a sufficient time and temperature to form an in-situ zeolite within the pre-shaped particles. The contacting of the pre-shaped particles and the liquid is achieved such that there is relative movement between the pre-shaped particles and the liquid.

Abstract translation: 通过将含活性铝的组分和基质组分的混合物预成型为预成型颗粒并使预成型颗粒与含有硅酸盐的反应性液体接触足够的时间来形成含沸石的固定床催化剂 和温度以在预成形颗粒内形成原位沸石。 实现预形状颗粒和液体的接触，使得在预形状颗粒和液体之间存在相对运动。

公开(公告)号：US09433934B2

公开(公告)日：2016-09-06

申请号：US13899816

申请日：2013-05-22

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  David Stockwell ,  Gary M. Smith

IPC: B01J29/06 ,  B01J29/08 ,  B01J29/064 ,  B01J29/10 ,  B01J29/16 ,  C10G45/02 ,  C10G47/20 ,  C10G65/12 ,  C10G47/16 ,  B01J35/02 ,  B01J37/02 ,  B01J37/00 ,  B01J35/10

CPC classification number: B01J29/084 ,  B01J29/06 ,  B01J29/064 ,  B01J29/106 ,  B01J29/166 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1066 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0072 ,  B01J37/0215 ,  B01J2229/64 ,  C10G45/02 ,  C10G47/16 ,  C10G47/20 ,  C10G65/12 ,  C10G2400/02

Abstract: A zeolite-containing fixed bed catalyst is formed by pre-shaping a mixture of a reactive aluminum-containing component and a matrix component into pre-shaped particles, and contacting the pre-shaped particles with a reactive liquid containing a silicate for a sufficient time and temperature to form an in-situ zeolite within the pre-shaped particles. The contacting of the pre-shaped particles and the liquid is achieved such that there is relative movement between the pre-shaped particles and the liquid.

Abstract translation: 通过将含活性铝的组分和基质组分的混合物预成型为预成型颗粒并使预成型颗粒与含有硅酸盐的反应性液体接触足够的时间来形成含沸石的固定床催化剂 和温度以在预成形颗粒内形成原位沸石。 实现预形状颗粒和液体的接触，使得在预形状颗粒和液体之间存在相对运动。

公开(公告)号：US20150175900A1

公开(公告)日：2015-06-25

申请号：US14134640

申请日：2013-12-19

Applicant: BASF Corporation

Inventor： Gary M. Smith ,  Robert McGuire, JR. ,  Bilge Yilmaz

IPC: C10G11/04 ,  B01J29/08

CPC classification number: C10G11/04 ,  B01J21/02 ,  B01J21/16 ,  B01J29/06 ,  B01J29/061 ,  B01J29/088 ,  B01J35/0006 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/64 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles first particle type comprising one or more boron oxide components and a first matrix component and a second particle type having a composition different from the first particle type, the second particle type comprising a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

Abstract translation: 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含包含一种或多种氧化硼组分的颗粒第一颗粒类型和具有不同于第一颗粒类型的组成的第一基质组分和第二颗粒类型，第二颗粒类型包括第二基质组分，磷组分和20 95％（重量）的沸石组分。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油进料，导致较低的氢气和焦炭产率。

公开(公告)号：US20150174559A1

公开(公告)日：2015-06-25

申请号：US14134600

申请日：2013-12-19

Applicant: BASF Corporation

Inventor： Gary M. Smith ,  Robert McGuire, JR. ,  Bilge Yilmaz

IPC: B01J29/08 ,  C10G11/02

CPC classification number: B01J29/146 ,  B01J21/04 ,  B01J21/16 ,  B01J23/8472 ,  B01J29/088 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/28 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/36 ,  C10G11/05 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

Abstract translation: 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含含有沸石，非沸石组分和稀土组分的催化微球。 微球用磷改性。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油原料，导致较低的氢气和焦炭产率。