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公开(公告)号：US20140097098A1
公开(公告)日：2014-04-10
申请号：US14048223
申请日：2013-10-08
Applicant: BASF SE
Inventor： Mathias Weickert , Stefan Marx , Ulrich Müller , Peter Renze , Christian-Andreas Winkler
IPC: F17C11/00
CPC classification number: F17C11/005 , F17C11/00 , F17C11/007
Abstract: Described is a method of charging a sorption store with a gas. The sorption store comprises a closed container which is at least partly filled with an adsorption medium and has an inlet and an outlet which can each be closed by a shut-off element. The method comprises the steps: (a) closing of the outlet shut-off element and opening of the inlet shut-off element, (b) introduction of gas to be stored under a predetermined pressure through the inlet, (c) rapid opening of the outlet shut-off element with the inlet shut-off element open so that a gas flow having a predetermined flow rate is established in the container, (d) reduction of the flow rate as a function of the adsorption rate of the gas adsorbed in the store, and (e) complete closing of the outlet shut-off element.
Abstract translation: 描述了一种用气体对吸附物料进行充电的方法。 吸附储存器包括至少部分地填充有吸附介质的封闭容器，并且具有能够被截止元件封闭的入口和出口。 该方法包括以下步骤：（a）关闭出口关闭元件并打开入口关闭元件，（b）通过入口引入要在预定压力下储存的气体，（c）快速打开 具有入口关闭元件的出口关闭元件打开，使得在容器中建立具有预定流速的气流，（d）作为吸附在吸附剂中的气体的吸附速率的函数的流量的降低 商店，（e）完全关闭出口关闭元件。
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12.发明申请Acetylene Bridged Linkers and Metal-Organic Frameworks (MOFs) Produced Thereof 有权乙炔桥连接器和金属有机框架（MOF）生产公开(公告)号：US20140081044A1
公开(公告)日：2014-03-20
申请号：US14030096
申请日：2013-09-18
Applicant: BASF SE
Inventor： Stefan Maurer , Ulrich Müller , Vijay Narayanan Swaminathan , Shrirang Bhikaji Hindalekar , Amal Pandya
Abstract: Described are acetylene bridged linkers, metal-organic frameworks produced thereof, processes for producing the linkers and the metal-organic frameworks, and the use of the metal-organic frameworks. The metal-organic frameworks possess an enhanced ability to adsorb and desorb high amounts of gases, in particular methane or hydrogen. The metal-organic frameworks have a high porosity and, thus, a high inner surface.
Abstract translation: 描述的是乙炔桥连接体，由其制备的金属 - 有机骨架，用于制备连接体和金属 - 有机骨架的方法，以及金属 - 有机骨架的用途。 金属 - 有机骨架具有增强的吸附和解吸大量气体，特别是甲烷或氢气的能力。 金属 - 有机骨架具有高孔隙率，因此具有高内表面。
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公开(公告)号：US20130210620A1
公开(公告)日：2013-08-15
申请号：US13759393
申请日：2013-02-05
Applicant: BASF SE
Inventor： Christoph Kiener , Ulrich Müller , Markus Schubert
CPC classification number: B01J20/0211 , B01J20/226 , B01J20/28042 , B01J20/28066 , B01J20/3085 , B01J31/1691 , B01J31/2239 , B01J2231/48 , B01J2231/72 , B01J2531/31 , C01B3/001 , C01B3/508 , C07C51/418 , Y02C10/08 , Y02E60/324 , Y10T428/249953 , C07C63/38 , C07C57/15 , C07C63/26
Abstract: Porous metal organic frameworks formed by AlIII ions to which fumarate ions are coordinated to produce a framework structure; shaped bodies comprising such porous metal organic frameworks, and also the preparation and use thereof for the uptake of a substance for the purposes of its storage, controlled release, separation, chemical reaction or as support.
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公开(公告)号：US12157674B2
公开(公告)日：2024-12-03
申请号：US17480364
申请日：2021-09-21
Applicant: BASF SE
Inventor： Andrei-Nicolae Parvulescu , Ulrich Müller , Stefan Maurer , Yu Dai , Feng-Shou Xiao , Xiangju Meng , Yeqing Wang
IPC: C01B37/00 , B01J20/10 , B01J20/30 , B01J29/70 , B01J29/86 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/30 , C01B39/12
Abstract: The present invention relates to a process for the production of a zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, said process comprising (i) preparing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I) R1R2R3N (I) wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, and wherein the mixture prepared in (i) and crystallized in (ii) contains 35 wt.-% or less of H2O based on 100 wt.-% of YO2 contained in the mixture prepared in (i) and crystallized in (ii), as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process and to its use.
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15.发明授权公开(公告)号：US11091425B2
公开(公告)日：2021-08-17
申请号：US16464966
申请日：2017-11-29
Applicant: BASF SE
Inventor： Andrei-Nicolae Parvulescu , Alvaro Gordillo , Marie Katrin Schroeter , Johann-Peter Melder , Juergen Bechtel , Thomas Heidemann , Stephan A. Schunk , Ulrich Müller
IPC: C07C209/16 , B01J29/18 , C01B39/26 , C07C211/10 , C07C211/14
Abstract: The present invention relates to a process for the conversion of ethane-1,2-diol to ethane-1,2-diamine and/or linear polyethylenimines of the formula H2N—[CH2CH2NH]n—CH2CH2NH2 wherein n≥1 comprising (i) providing a catalyst comprising a zeolitic material comprising YO2 and X2O3, wherein Y is a tetravalent element and X is a trivalent element, wherein the zeolitic material is selected from the group consisting of zeolitic materials having the MOR, FAU, CHA and/or GME framework structure, including combinations of two or more thereof; (ii) providing a gas stream comprising ethane-1,2-diol and ammonia; (iii) contacting the catalyst provided in (i) with the gas stream provided in (ii) for converting ethane-1,2-diol to ethane-1,2-diamine and/or linear polyethylenimines.
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Patent Agency Ranking
16.发明授权公开(公告)号：US10266417B2
公开(公告)日：2019-04-23
申请号：US15264314
申请日：2016-09-13
Applicant: BASF SE
Inventor： Mathias Feyen , Ulrich Müller , Andrei-Nicolae Parvulescu , Bernd Bastian Schaack , Sebastian Ahrens , Dirk Gerhard , Sunghee Son , Gabriele Iffland , Bianca Seelig
IPC: C01B39/40 , B01J29/40 , C01B39/48 , B01J29/89 , B01J29/00 , B01J20/18 , C01B39/06 , B01J29/035 , B01J29/06 , C01B39/04 , C01B39/08 , B01J20/30 , B01J20/28 , C01B37/02 , B01J35/10 , B01J37/00 , B01J37/04 , B01J37/06 , B01J37/30 , C01B37/00
Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
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公开(公告)号：US10202323B2
公开(公告)日：2019-02-12
申请号：US15744324
申请日：2016-07-15
Applicant: BASF SE
Inventor： Andrei-Nicolae Parvulescu , Ulrich Müller , Thomas Fenlon , Sumana Chaturvedula , Stefan Rüdenauer , Andreas Lanver , Ralf Pelzer , Klaus Ebel
Abstract: A process for preparing an arylpropene from a diarylpropane by gas phase thermolysis in the presence of boron containing zeolitic material comprising a membered ring (MR) pore system greater than 10 MR.
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公开(公告)号：US09987624B2
公开(公告)日：2018-06-05
申请号：US15033402
申请日：2014-11-05
Applicant: BASF SE
Inventor： Andrei-Nicolae Parvulescu , Ulrich Müller , Georg Uhl , Joaquim H. Teles , Nicolas Vautravers , Dominic Riedel
IPC: C01B39/06 , C01B39/48 , B01J29/70 , C01B39/12 , C07C45/58 , B01J35/00 , B01J35/10 , B01J37/08 , B01J37/30 , C01B39/02 , C01B39/46
CPC classification number: B01J29/7088 , B01J35/002 , B01J35/1019 , B01J37/08 , B01J37/30 , B01J2229/183 , B01J2229/186 , C01B39/026 , C01B39/06 , C01B39/12 , C01B39/46 , C01B39/48 , C07C45/58 , C07C2601/10 , C07C47/225
Abstract: A process for preparing a tin-containing zeolitic material having an MWW-type framework structure comprising providing a zeolitic material having an MWW-type framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, and incorporating tin into the zeolitic material via solid-state ion exchange.
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19.发明授权Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure 有权用于生产CHA型结构的沸石材料的无机无合成工艺公开(公告)号：US09527751B2
公开(公告)日：2016-12-27
申请号：US13673661
申请日：2012-11-09
Applicant: BASF SE
Inventor： Stefan Maurer , Hanpeng Jin , Jeff Yang , Ulrich Müller
CPC classification number: C01B39/02 , B01J29/7015 , C01B39/026 , C01B39/46
Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a CHA-type framework structure comprising YO2, X2O3, and optionally comprising Z2O5, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises YO2, X2O3, and optionally comprises Z2O5; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, X is a trivalent element, and Z is a pentavalent element, wherein optionally one or more sources for Z2O5 are further provided in step (1), and wherein if the CHA framework of the seed crystals does not contain Z2O5, the seed crystals then have a YO2:X2O3 molar ratio of 5 or greater than 5.
Abstract translation: 本发明涉及一种用于生产具有包含YO 2，X 2 O 3和任选地包含Z 2 O 5的CHA型骨架结构的沸石材料的有机模板合成方法，其中所述方法包括以下步骤：（1）提供包含 YO2的一种或多种来源，X 2 O 3的一种或多种来源和具有CHA骨架结构的晶种，其中晶种的CHA骨架结构包含YO 2，X 2 O 3，并且任选包含Z 2 O 5; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，Z是五价元素，其中在步骤（1）中还可以任选地提供一种或多种Z2O5源，并且其中如果晶种的CHA骨架不包含 Z2O5，然后晶种的YO 2：X 2 O 3摩尔比为5或大于5。
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公开(公告)号：US20150361325A1
公开(公告)日：2015-12-17
申请号：US14760623
申请日：2014-01-15
Applicant: WINTERSHALL HOLDING GMBH , BASF SE
Inventor： Riichiro Kimura , Stefan Maurer , Andrei-Nicolae Parvulescu , Lorenz Siggel , Ulrich Müller , Thomas Frechen , Bernd Hinrichsen
Abstract: The present invention relates to a process for recovering oil from a subterranean formation by injecting both solid particles and water into the formation. An oil-in-water emulsion that is stabilized by solid particles is formed in the pores of the formation. This emulsion is recovered from the subterranean formation.
Abstract translation: 本发明涉及通过将固体颗粒和水注入到地层中从地层中回收油的方法。 在地层的孔中形成由固体颗粒稳定的水包油乳液。 从地层中回收该乳液。
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