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154 条记录 (耗时 0.023 秒)

    Preparation of 4-nitrothioanisole
    11.
    发明授权
    Preparation of 4-nitrothioanisole 失效
    4-硝基硫代苯甲醚的制备

    公开(公告)号：US4298761A

    公开(公告)日：1981-11-03

    申请号：US110588

    申请日：1980-01-09

    申请人： Hermann Hagemann ,  Erich Klauke ,  Gerd-Michael Petruck

    发明人： Hermann Hagemann ,  Erich Klauke ,  Gerd-Michael Petruck

    IPC分类号： C07C319/14 ,  C07C20060101 ,  C07C67/00 ,  C07C313/00 ,  C07C323/09 ,  C07C149/32

    CPC分类号： C07C323/00

    摘要： A process for the preparation of 4-nitrothioanisole comprising successively in a single vessel and without intermediate isolation reacting 4-nitrochlorobenzene with Na.sub.2 S.sub.2, then with an alkaline Na.sub.2 S solution and with a methylating agent. Advantageously the reactions are effected in methanol or aqueous methanol, the reactions with Na.sub.2 S.sub.2 and Na.sub.2 S are carried out at a temperature between about 50.degree. to 70.degree. C., the Na.sub.2 S.sub.2 is formed in situ in about 20% excess from Na.sub.2 S and sulphur, the Na.sub.2 S solution is rendered alkaline with sodium methylate or sodium hydroxide, and methylation is effected with methyl chloride at about 27.degree. to 35.degree. C. The product is produced in such high yield and purity that it can be employed directly for chlorination, without extensive purification, to produce insecticide intermediates.

    摘要翻译： 一种制备4-硝基硫代苯甲醚的方法，其依次包括在单一容器中，不用中间分离使4-硝基氯苯与Na 2 S 2反应，然后与碱性Na 2 S溶液和甲基化试剂反应。 有利地，反应在甲醇或甲醇水溶液中进行，与Na 2 S 2和Na 2 S的反应在约50℃至70℃之间的温度下进行，Na 2 S 2原位形成于Na 2 S和硫中约20％过量， 用甲醇钠或氢氧化钠将Na 2 S溶液呈碱性，用甲基氯在约27-35℃进行甲基化。产物以高产率和纯度生产，可直接用于氯化，无需大量纯化 ，生产杀虫剂中间体。

    Preparation of new fluoropivalic acid fluorides
    12.
    发明授权
    Preparation of new fluoropivalic acid fluorides 失效
    新氟氟酸氟化物的制备

    公开(公告)号：US4549994A

    公开(公告)日：1985-10-29

    申请号：US630490

    申请日：1984-07-13

    申请人： Hermann Hagemann ,  Erich Klauke ,  Ernst Kysela

    发明人： Hermann Hagemann ,  Erich Klauke ,  Ernst Kysela

    IPC分类号： A01N47/12 ,  C07C51/00 ,  C07C51/58 ,  C07C53/50 ,  C07C67/00 ,  C07C239/00 ,  C07C271/10 ,  C07C271/14

    CPC分类号： C07C53/50 ,  C07C51/58

    摘要： A process for the preparation of a compound according to claim 1, comprising reacting a compound of the formula ##STR1## in which R.sup.3, R.sup.4 and R.sup.5 each independently is CH.sub.3 or CH.sub.2 Cl, at least one of the radicals R.sup.3, R.sup.4 and R.sup.5 being CH.sub.2 Cl,with a metal fluoride at elevated temperature. The products are new and useful as intermediates for making other compounds, especially carbamate insecticide synergists.

    摘要翻译： 一种制备根据权利要求1的化合物的方法，包括使下式化合物（其中R 3，R 4和R 5各自独立地为CH 3或CH 2 Cl）反应，基团R 3，R 4和R 5中的至少一个为CH 2 Cl ，在高温下用金属氟化物。 该产品作为制备其他化合物，特别是氨基甲酸酯杀虫剂增效剂的中间体是新的和有用的。

    2,4-diamino-6-trifluoromethylpyrimidine compounds useful as herbicides
    15.
    发明授权
    2,4-diamino-6-trifluoromethylpyrimidine compounds useful as herbicides 失效
    用作除草剂的2,4-二氨基-6-三氟甲基嘧啶化合物

    公开(公告)号：US4877443A

    公开(公告)日：1989-10-31

    申请号：US2881

    申请日：1987-01-13

    申请人： Michael Schwamborn ,  Erich Klauke ,  Robert R. Schmidt ,  Hans-Joachim Santel ,  Robert H. Strang

    发明人： Michael Schwamborn ,  Erich Klauke ,  Robert R. Schmidt ,  Hans-Joachim Santel ,  Robert H. Strang

    IPC分类号： A01N43/54 ,  C07D239/48

    CPC分类号： C07D239/48 ,  A01N43/54

    摘要： Herbicidally active 2,4-diamino-6-haloalkylpyrimidines of the formula ##STR1## in which R.sup.1 and R.sup.3, independently of one another, represent hydrogen or alkyl,R.sup.2 and R.sup.4, independently of one another, represent hydrogen, alkyl which is optionally substituted by halogen, cyano, alkoxy, alkylthio or by cyclopropyl, represent cycloalkyl, alkenyl which is optionally substituted by halogen, or alkinyl, andR.sup.5 represents alkyl which is substituted by halogen, with the proviso that R.sup.1, R.sup.2, R.sup.3 andR.sup.4 do not simultaneously represent hydrogen whenR.sup.5 represents trichloromethyl, and with the provisio that R.sup.1 and R.sup.2 do not simultaneously represent hydrogen when R.sup.4 represents alkyl which is substituted by alkoxy or alkylthio.

    摘要翻译： R1和R3彼此独立地代表氢或烷基，R2和R4彼此独立的除草活性的2,4-二氨基-6-卤代烷基嘧啶，其中R 1和R 3彼此独立地代表氢，任选被取代的烷基 卤素，氰基，烷氧基，烷硫基或环丙基代表环烷基，任选被卤素或炔基取代的烯基，R 5表示被卤素取代的烷基，条件是R1，R2，R3和R4不同时 当R5表示三氯甲基时表示氢，当R 4表示被烷氧基或烷硫基取代的烷基时，R1和R2不同时表示氢。

    Orthotrifluoromethyl containing phenylazonaphthol dyestuffs
    16.
    发明授权
    Orthotrifluoromethyl containing phenylazonaphthol dyestuffs 失效
    含三氟甲基苯基苯并萘酚染料

    公开(公告)号：US4757137A

    公开(公告)日：1988-07-12

    申请号：US534914

    申请日：1983-09-22

    申请人： Gerhard Wolfrum ,  Erich Klauke ,  Hans-Gunter Otten

    发明人： Gerhard Wolfrum ,  Erich Klauke ,  Hans-Gunter Otten

    IPC分类号： C09B29/01 ,  C09B29/30 ,  C09B43/124 ,  C09B62/028 ,  C09B62/47 ,  C09B29/033 ,  C09B62/02

    CPC分类号： C09B29/0007 ,  C09B29/30 ,  C09B43/124 ,  C09B62/028

    摘要： Azo dyestuffs of the formula ##STR1## wherein R.sub.1 denotes acyl,R.sub.2 denotes hydrogen, fluorine, chlorine or trifluoromethyl,R.sub.3 denotes hydrogen, optionally substituted C.sub.1 -C.sub.4 -alkyl, cyclohexyl or optionally substituted phenyl andR.sub.4 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl groupare suitable for dyeing natural and synthetic fibre materials, for example for dyeing wool or polyamide fibres, in level read to violet shades with very good fastnesses to light, wet processing and perspiration, the color yield being good.

    摘要翻译： 其中R 1表示酰基，R 2表示氢，氟，氯或三氟甲基，R 3表示氢，任选取代的C 1 -C 4 - 烷基，环己基或任意取代的苯基，R 4表示氢或C 1 -C 4 - 烷基 适用于染色天然和合成纤维材料，例如用于染色羊毛或聚酰胺纤维，水平读成紫罗兰色，具有非常好的耐光牢度，湿润加工和出汗，色泽良好。

    2,4-dihalogenobenzoyl-(thio)urea insecticides
    17.
    发明授权
    2,4-dihalogenobenzoyl-(thio)urea insecticides 失效
    2,4-二卤代苯甲酰 - （硫）脲类杀虫剂

    公开(公告)号：US4711905A

    公开(公告)日：1987-12-08

    申请号：US746554

    申请日：1985-06-19

    申请人： Wilhelm Sirrenberg ,  Erich Klauke ,  Ingeborg Hammann ,  Wilhelm Stendel

    发明人： Wilhelm Sirrenberg ,  Erich Klauke ,  Ingeborg Hammann ,  Wilhelm Stendel

    IPC分类号： A01N47/34 ,  C07C67/00 ,  C07C275/54 ,  C07C309/66 ,  C07C313/00 ,  C07C317/42 ,  C07C323/20 ,  C07C323/44 ,  C07C325/00 ,  C07C335/26 ,  C07D317/46 ,  C07D319/08 ,  C07D319/20 ,  C07C127/22

    CPC分类号： C07D319/08 ,  A01N47/34 ,  C07C275/54 ,  C07C309/66 ,  C07C317/42 ,  C07C323/20 ,  C07C323/44 ,  C07D317/46 ,  C07D319/20

    摘要： A 2,4-dihalogenobenzoyl-(thio)urea of the formula ##STR1## in which X represents sulphur or oxygen,X.sup.1 and X.sup.2 are identical or different and represent fluorine, chlorine, bromine or iodine,R.sup.1 represents hydrogen, halogen or optionally substituted radicals from the series comprising alkyl, alkoxy and alkylthio,R.sup.2 represents hydrogen, halogen, cyano, nitro, or optionally substituted radicals from the series comprising alkyl, alkylthio, alkylsulphonyl, alkoxy, aryloxy, alkylcarbonyl, alkoxycarbonyl, alkoxycarbonylalkyl and alkoxycarbonylalkylthio, orR.sup.1 and R.sup.2 together represent an optionally substituted alkylenedioxy radical or --CF.sub.2 --O--CF.sub.2 --O--,R.sup.3 represents hydrogen, halogen or an optionally substituted alkyl, alkoxy or aryloxy radical, andR.sup.4 represents hydrogen, halogen, or optionally substituted radicals from the series comprising alkyl, alkylthio and alkoxy, with the exception of those cases in which X represents oxygen, X.sup.1 andX.sup.2 represent chlorine and (a) R.sup.1 represents chlorine, R.sup.2 represents OCF.sub.2 CHFCl and R.sup.3 andR.sup.4 represent hydrogen, or (b) R.sup.1 represents chlorine, R.sup.2 represents OCF.sub.3 and R.sup.3 and R.sup.4 represent hydrogen, or (c) R.sup.1 represents chlorine,R.sup.2 represents SCF.sub.3 and R.sup.3 and R.sup.4 represent hydrogen, or (d) R.sup.1 represents OCF.sub.3 and R.sup.2,R.sup.3 and R.sup.4 represent hydrogen, or (e) R.sup.2 represent OCF.sub.3 and R.sup.1, R.sup.3 and R.sup.4 represent hydrogen.

    摘要翻译： 其中X表示硫或氧，X 1和X 2的式（I）的2,4-二卤代苯甲酰基（硫代）脲相同或不同，表示氟，氯，溴或碘，R 1表示氢，卤素 或烷基，烷硫基，烷基磺酰基，烷氧基，芳氧基，烷基羰基，烷氧基羰基，烷氧基羰基烷基和烷氧基羰基烷基硫基的系列中的R 2表示氢，卤素，氰基，硝基或任选取代的基团， 或R 1和R 2一起表示任选取代的亚烷基二氧基或-CF 2 -O-CF 2 -O-，R 3表示氢，卤素或任选取代的烷基，烷氧基或芳氧基，且R 4表示氢，卤素或任选取代的基团， 该系列包括烷基，烷硫基和烷氧基，但X表示氧的情况除外，X1和X2表示氯，（a）R1表示氯 ，R2表示OCF2CHFCl，R3和R4表示氢，或（b）R1表示氯，R2表示OCF3，R3和R4表示氢，或（c）R1表示氯，R2表示SCF3，R3和R4表示氢，或（d ）R1表示OCF3和R2，R3和R4表示氢，或（e）R2表示OCF3，R1，R3和R4表示氢。

    Certain trimethyl silyl-lower-alkyl esters of pyridyloxy-phenoxy-lower alkanoic acids, compositions containing same and herbicidal method of use
    19.
    发明授权
    Certain trimethyl silyl-lower-alkyl esters of pyridyloxy-phenoxy-lower alkanoic acids, compositions containing same and herbicidal method of use 失效
    吡啶氧基 - 苯氧基 - 低级链烷酸的某些三甲基甲硅烷基 - 低级烷基酯，含有该组合物的组合物和除草方法

    公开(公告)号：US4518416A

    公开(公告)日：1985-05-21

    申请号：US495883

    申请日：1983-05-18

    申请人： Heinz Forster ,  Erich Klauke ,  Uwe Priesnitz ,  Hans-Jochem Riebel ,  Ludwig Eue ,  Robert R. Schmidt

    发明人： Heinz Forster ,  Erich Klauke ,  Uwe Priesnitz ,  Hans-Jochem Riebel ,  Ludwig Eue ,  Robert R. Schmidt

    IPC分类号： A01N43/40 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N55/00 ,  A01N57/16 ,  C07D213/64 ,  C07D213/643 ,  C07D405/12 ,  C07F7/08 ,  C07F9/58

    CPC分类号： C07D213/643 ,  A01N43/40 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N55/00 ,  A01N57/16 ,  C07D405/12 ,  C07F7/0812 ,  C07F9/582

    摘要： Novel substituted pyridyl-phenyl ethers of the formula ##STR1## in which X represents trifluoromethyl or chlorine,Y represents hydrogen or chlorine,R.sup.1 represents hydrogen or methyl andR.sup.2 represents formyl or the radicals of the formulae ##STR2## in which R.sup.3 represents alkyl with 1 to 4 carbon atoms, or the two radicals R.sup.3 together represent an alkylene chain with 2 or 3 carbon atoms,R.sup.4, R.sup.5, R.sup.6 and R.sup.7 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms,m represents 1 or 2,n represents 0 or 1 andZ represents trimethylsilyl, optionally substituted azolyl which is bonded via nitrogen or the radicals of the formulae ##STR3## in which R.sup.8 represents alkyl with 1 to 4 carbon atoms, or the two radicals R.sup.8 together represent an alkylene chain with 2 or 3 carbon atoms,R.sup.9 represents alkyl with 1 to 4 carbon atoms,X.sup.1 represents oxygen or sulphur andR.sup.10 and R.sup.11 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms,and their use as herbicides.

    摘要翻译： 新颖的式（I）的取代的吡啶基 - 苯基醚，其中X表示三氟甲基或氯，Y表示氢或氯，R1表示氢或甲基，R2表示甲酰基或式“IMAGE”的基团，其中R3 表示具有1至4个碳原子的烷基，或两个基团R 3一起表示具有2或3个碳原子的亚烷基链，R 4，R 5，R 6和R 7彼此独立地表示氢或具有1至4个碳原子的烷基，m表示 1或2，n表示0或1，Z表示三甲基甲硅烷基，任选取代的通过氮键合的唑基或其中R 8表示具有1至4个碳原子的烷基的式“IMAGE”的基团，或两个基团R8一起表示 具有2或3个碳原子的亚烷基链，R 9表示具有1至4个碳原子的烷基，X 1表示氧或硫，R 10和R 11彼此独立地表示氢或具有1至4个碳原子的烷基，并且它们用作 除草剂。