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公开(公告)号:US11958936B2
公开(公告)日:2024-04-16
申请号:US16640004
申请日:2018-09-14
Applicant: Dow Global Technologies LLC
Inventor: Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson , Anthony P. Gies , Manjiri R. Paradkar
IPC: C08G18/58 , C08G18/48 , C08G18/76 , C08G59/14 , C08G65/26 , C09D175/04 , C09J175/04
CPC classification number: C08G18/58 , C08G18/4825 , C08G18/4829 , C08G18/4854 , C08G18/7621 , C08G18/7671 , C08G59/145 , C08G65/2654 , C08G65/266 , C09D175/04 , C09J175/04 , C08G2110/0008 , C08G2110/0025 , C08G2190/00
Abstract: A method of producing a polyether polyol includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, and the low molecular weight initiator has a nominal hydroxyl functionality of at least 2. The one or more monomers includes at least one selected from propylene oxide and butylene oxide. The polymerization catalyst is a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R1, R2, R3, and R4 are each independent, R1 includes a fluoroalkyl-substituted phenyl group, R2 incudes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, R3 includes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, and optional R4 includes a functional group or functional polymer group, R1 being different from at least one of R2 and R3.
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公开(公告)号:US11912822B2
公开(公告)日:2024-02-27
申请号:US16642216
申请日:2018-09-14
Applicant: Dow Global Technologies LLC
Inventor: Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson
CPC classification number: C08G65/2654 , C07F5/027 , C08G18/4841 , C08G18/4854 , C08G18/7621 , C08G18/7671 , C08G65/266 , C08G65/2684 , C08G2650/22 , C08G2650/38 , C08G2650/44 , C10M107/34 , C11D1/72
Abstract: A method of producing a polyether polyol includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, and the low molecular weight initiator has a nominal hydroxyl functionality at least 2. The polymerization catalyst is a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R1, R2, R3, and R4 are each independent, R1 includes a fluoroalkyl-substituted phenyl group, R2 incudes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, R3 includes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, and optional R4 includes a functional group or functional polymer group, R1 being different from at least one of R2 and R3.
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公开(公告)号:US20230174693A1
公开(公告)日:2023-06-08
申请号:US17922923
申请日:2021-05-07
Applicant: Dow Global Technologies LLC
Inventor: Rafael Huacuja , Richard Keaton , Jerzy Klosin , Sukrit Mukhopadhyay , David M. Pearson , Todd D. Senecal , William H.H. Woodward
IPC: C08F210/16 , C07F5/02 , C07F7/08
CPC classification number: C08F210/16 , C07F5/027 , C07F7/0814
Abstract: Processes of polymerizing olefins. The process includes polymerizing contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presence of a catalyst system comprising a procatalyst and a bimetallic activator complex. The bimetallic activator complex includes an anion and a countercation. The anion having a structure according to formula (I).
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公开(公告)号:US11447584B2
公开(公告)日:2022-09-20
申请号:US17043483
申请日:2019-03-26
Applicant: Dow Global Technologies LLC
Inventor: Todd D. Senecal , Sukrit Mukhopadhyay , Richard J. Keaton , Jerzy Klosin , Rafael Huacuja , David M. Pearson , William H. H. Woodward
IPC: C08F4/642 , C08F210/16 , C08F210/02 , C08F4/64 , C08F4/643 , C08F4/659 , C08F210/04 , C08F210/14
Abstract: Embodiments of this disclosure include processes of polymerizing olefins, the process comprising contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presence of a catalyst system, the catalyst system comprising a Group IV metal-ligand complex and a metallic activator ionic complex, the metallic activator ionic complex comprising an anion and a countercation, the anion having a structure according to formula (I):
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公开(公告)号:US11367835B2
公开(公告)日:2022-06-21
申请号:US16344406
申请日:2017-06-26
Inventor: Anatoliy N. Sokolov , Brian Goodfellow , Robert David Grigg , Liam P. Spencer , John W. Kramer , David D. Devore , Sukrit Mukhopadhyay , Peter Trefonas, III
Abstract: The present invention provides a quantum dot light emitting diode comprising i) an emitting layer of at least one semiconductor nanoparticle made from semiconductor materials selected from the group consisting of Group II-VI compounds, Group II-V compounds, Group III-VI compounds, Group III-V compounds, Group IV-VI compounds, Group I-III-VI compounds, Group II-IV-VI compounds, Group II-IV-V compounds, or any combination thereof; and ii) a polymer for hole injection or hole transport layer, comprising one or more triaryl aminium radical cations having the structure (S1).
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公开(公告)号:US20220033567A1
公开(公告)日:2022-02-03
申请号:US17277187
申请日:2019-09-17
Applicant: Dow Global Technologies LLC
Inventor: Kshitish A. Patankar , Arjun Raghuraman , Thomas P. Willumstad , Mark F. Sonnenschein , Jody Henning , Heather A. Spinney , David R. Wilson , Sukrit Mukhopadhyay
Abstract: Hydroxyl-containing copolymers of butylene oxide and ethylene oxide having a hydroxyl equivalent weight of at least 150, an average of 1.8 to 6 hydroxyl groups per molecule of which hydroxyl groups at least 70% are primary hydroxyl groups and an oxyethylene content of no greater than 10% by weight based on the weight of the copolymer, are useful for making polyurethanes. These polyols are characterized by high reactivity and fast curing times. Polyurethanes made using these polyols have excellent mechanical properties and are highly hydrophobic.
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17.
公开(公告)号:US20220025085A1
公开(公告)日:2022-01-27
申请号:US17311530
申请日:2019-12-19
Applicant: Dow Global Technologies LLC
Inventor: Andrew M. Camelio , Endre Szuromi , David D. Devore , Robert DJ Froese , Brad C. Bailey , Matthew D. Christianson , Sukrit Mukhopadhyay , Jerzy Klosin
IPC: C08F210/16 , C07F7/00
Abstract: Catalyst systems that include a chain transfer agent and a metal-ligand complex according to formula (I).
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公开(公告)号:US10818860B2
公开(公告)日:2020-10-27
申请号:US16311186
申请日:2017-06-26
Inventor: Anatoliy N Sokolov , Brian Goodfellow , Robert David Grigg , Liam P Spencer , John W Kramer , David D Devore , Sukrit Mukhopadhyay , Peter Trefonas, III
Abstract: The present invention provides a quantum dot light emitting diode comprising i) an emitting layer of at least one semiconductor nanoparticle made from semiconductor materials selected from the group consisting of Group II-VI compounds, Group II-V compounds, Group III-VI compounds, Group III-V compounds, Group IV-VI compounds, Group I-III-VI compounds, Group II-IV-VI compounds, Group II-IV-V compounds, or any combination thereof; and ii) a polymer for hole injection or hole transport layer; and the polymer comprises, as polymerized units, at least one or more monomers having a first monomer structure comprising a) a polymerizable group, b) an electroactive group with formula NAr1Ar2Ar3 wherein Ar1, Ar2 and Ar3 independently are C6-C50 aromatic substituents, and (c) a linker group connecting the polymerizable group and the electroactive group.
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公开(公告)号:US10454036B2
公开(公告)日:2019-10-22
申请号:US15504389
申请日:2015-01-08
Applicant: Dow Global Technologies LLC , Rohm and Haas Electronic Materials LLC , Rohm and Haas Electronic Materials Korea Ltd.
Inventor: Liam P. Spencer , Hong-Yeop Na , Yoo-Jin Doh , Chun Liu , Minrong Zhu , Jichang Feng , Zhengming Tang , Shaoguang Feng , Kenneth L. Kearns, Jr. , Timothy De Vries , Sukrit Mukhopadhyay , John W. Kramer , Peter Trefonas, III , David D. Devore , William H. H. Woodward
IPC: H01L51/54 , H01L51/00 , C07D209/86 , C08G61/12 , H01L51/50
Abstract: The present invention relates to a polymeric charge transfer layer comprising a polymer and a p-dopant. The polymer comprises as polymerized units, Monomer A, Monomer B, and Monomer C crosslinking agent. The present invention further relates to an organic electronic device, especially an organic light emitting device containing the polymeric charge transfer layer.
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公开(公告)号:US09972792B2
公开(公告)日:2018-05-15
申请号:US15083331
申请日:2016-03-29
Inventor: Timothy S. De Vries , Kenneth L. Kearns, Jr. , Travis E. McIntire , Sukrit Mukhopadhyay , Peter Trefonas, III , William H. H. Woodward
CPC classification number: H01L51/0077 , H01B1/12 , H01B1/121 , H01L51/0035 , H01L51/0058 , H01L51/0067 , H01L51/0079 , H01L51/5076 , H01L51/5253 , H01L2251/558
Abstract: Aspects of the invention provide a composition having a blend of an electron transport material and an organo alkali-metal salt wherein the salt has a glass transition greater than 115° C. The organo-alkali metal salt may be selected from the group consisting of lithium 2-(2-pyridyl)phenolate (LiPP), lithium 2-(2′,2″-bipyridine-6′-yl)phenolate (LiBPP), 2-(isoquinoline-10-yl)phenolate (LiIQP), and lithium 2-(2-phenylquinazolin-4-yl)phenolate and lithium 2-(4-phenylquinazolin-2-yl)phenolate. In a preferred embodiment, the organo-alkali metal salt is lithium 2-(2′,2″-bipyridine-6′-yl)phenolate (LiBPP). Aspects of the invention also provide films and devices having a film layer prepared from the composition.
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