公开(公告)号：US20200061592A1

公开(公告)日：2020-02-27

申请号：US16545148

申请日：2019-08-20

Applicant: ExxonMobil Research and Engineering Company

Inventor： Preeti Kamakoti ,  Scott J. Weigel ,  Karl G. Strohmaier ,  Helge Jaensch ,  Marc H. Anthonis ,  Martine Dictus ,  Brita Engels ,  Darryl D. Lacy ,  Sina Sartipi

IPC: B01J29/40 ,  B01J29/78 ,  B01J29/70 ,  C10G35/095 ,  B01J29/08 ,  B01J37/08 ,  B01J35/10

Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.

公开(公告)号：US20200010772A1

公开(公告)日：2020-01-09

申请号：US16572946

申请日：2019-09-17

Applicant: ExxonMobil Research and Engineering Company

Inventor： Ajit B. Dandekar ,  Bradley R. Fingland ,  Kendall S. Fruchey ,  Scott J. Weigel

IPC: C10M101/02 ,  C10G47/18 ,  C10G65/12 ,  C10G69/02

Abstract: Systems and methods are provided for producing lubricant basestocks having a reduced or minimized aromatics content. A first processing stage can perform an initial amount of hydrotreating and/or hydrocracking. A first separation stage can then be used to remove fuels boiling range (and lower boiling range) compounds. The remaining lubricant boiling range fraction can then be exposed under hydrocracking conditions to a USY catalyst including a supported noble metal, such as Pt and/or Pd. The USY catalyst can have a desirable combination of catalyst properties, such as a unit cell size of 24.30 or less (or 24.24 or less), a silica to alumina ratio of at least 50 (or at least 80), and an alpha value of 20 or less (or 10 or less). In some aspects, the effluent from the second (hydrocracking) stage can be dewaxed without further separation. In such aspects, a portion of the dewaxed effluent can be used as a recycle quench stream to cool the hydrocracking effluent prior to entering the dewaxing reactor.

公开(公告)号：US10457877B2

公开(公告)日：2019-10-29

申请号：US15468406

申请日：2017-03-24

Applicant: ExxonMobil Research and Engineering Company

Inventor： Ajit B. Dandekar ,  Bradley R. Fingland ,  Kendall S. Fruchey ,  Scott J. Weigel

IPC: C10G65/12 ,  C10M101/02 ,  C10G69/02 ,  C10G47/18

Abstract: Systems and methods are provided for producing lubricant basestocks having a reduced or minimized aromatics content. A first processing stage can perform an initial amount of hydrotreating and/or hydrocracking. A first separation stage can then be used to remove fuels boiling range (and lower boiling range) compounds. The remaining lubricant boiling range fraction can then be exposed under hydrocracking conditions to a USY catalyst including a supported noble metal, such as Pt and/or Pd. The USY catalyst can have a desirable combination of catalyst properties, such as a unit cell size of 24.30 or less (or 24.24 or less), a silica to alumina ratio of at least 50 (or at least 80), and an alpha value of 20 or less (or 10 or less). In some aspects, the effluent from the second (hydrocracking) stage can be dewaxed without further separation. In such aspects, a portion of the dewaxed effluent can be used as a recycle quench stream to cool the hydrocracking effluent prior to entering the dewaxing reactor.

公开(公告)号：US20190105647A1

公开(公告)日：2019-04-11

申请号：US16212922

申请日：2018-12-07

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David C. Calabro ,  Kiara M. Benitez ,  Machteld M.W. Mertens ,  Scott J. Weigel ,  Doron Levin ,  Randall D. Partridge

IPC: B01J31/26 ,  B01J29/70 ,  C07C5/10 ,  B01J31/12 ,  B01J29/74 ,  B01J29/44 ,  B01J29/40 ,  B01J35/00 ,  C10G47/16 ,  B01J37/00 ,  C10G45/54 ,  C10G45/64

Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

公开(公告)号：US10022700B2

公开(公告)日：2018-07-17

申请号：US14966284

申请日：2015-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David Charles Calabro ,  Lei Zhang ,  Kiara M. Benitez ,  Himanshu Gupta ,  Xiaochun Xu ,  Scott J. Weigel ,  Darryl Donald Lacy ,  Bal Kaul ,  James William Gleeson ,  Wenyih Frank Lai ,  Mobae Afeworki ,  Simon Christopher Weston ,  David A. Griffin ,  Meghan Nines

IPC: B01J20/22 ,  B01D15/00 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J20/26 ,  B01D53/04 ,  B01J20/28 ,  B01J20/286 ,  B01J20/30 ,  B01J20/32 ,  B01J29/03 ,  C01B37/00 ,  C08F36/04 ,  C08F36/20 ,  C08G77/60 ,  C08F2/00 ,  C08F2/42 ,  C10G25/00 ,  C10G45/44 ,  B01J20/02 ,  B01J20/16 ,  B01D53/02 ,  B01D53/047 ,  B01J23/44 ,  B01J31/02 ,  B01J37/02 ,  C10G45/52 ,  B01J35/10 ,  C07F7/08 ,  C08G77/26 ,  C10M101/02 ,  B01D67/00 ,  B01D69/10 ,  B01D71/70 ,  C10G31/09 ,  C23C16/56 ,  C08F2/10 ,  C08F4/659 ,  C08F4/6592

Abstract: Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each R1 is a Z1OZ2Z3SiZ4 group, wherein each Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z2 and Z3 independently represent a hydroxyl group, a C1-C4 alkyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z4 represents a C1-C8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

公开(公告)号：US20220380686A1

公开(公告)日：2022-12-01

申请号：US17634961

申请日：2020-07-14

Applicant: ExxonMobil Research and Engineering Company

Inventor： Brandon J. O'Neill ,  Joseph M. Falkowski ,  Allen W. Burton ,  Scott J. Weigel

IPC: C10G47/18 ,  B01J29/74 ,  B01J35/10 ,  B01J8/08

Abstract: A hydrocarbon feed stream, particularly one comprising heavier hydrocarbons, may be converted to valuable products such as motor gasoline and/or lubricating oil by employing one or more large pore zeolitic catalysts, which may be prepared from a precursor zeolite. In some examples, a large pore zeolitic catalyst may be utilized to selectively reduce the endpoint of a hydrocarbon composition.

公开(公告)号：US20220213125A1

公开(公告)日：2022-07-07

申请号：US17612464

申请日：2019-12-13

Applicant: ExxonMobil Research and Engineering Company

Inventor： Gerardo J. Majano ,  Joseph M. Falkowski ,  Scott J. Weigel ,  Matthew T. Kapelewski ,  Pavel Kortunov

IPC: C07F1/08 ,  B22F1/10 ,  B22F3/20 ,  C01B37/00

Abstract: Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced in powder form. Extrusion of powder-form MOFs to produce shaped bodies has heretofore proven difficult due to loss of surface area and poor crush strength of MOF extrudates, in addition to phase transformations occurring during extrusion. The choice of mixing conditions and the mixing solvent when forming MOF extrudates can impact these factors. Extrudates comprising a MOF consolidated material may feature the MOF consolidated material having a BET surface area of about 50% or greater relative to that of a pre-crystallized MOF powder material used to form the extrudate. X-ray powder diffraction of the extrudate shows about 20% or less conversion of the MOF consolidated material into a phase differing from that of the pre-crystallized MOF powder material.

公开(公告)号：US20220143586A1

公开(公告)日：2022-05-12

申请号：US17430758

申请日：2020-01-22

Applicant: ExxonMobil Research and Engineering Company

Inventor： Tilman W. Beutel ,  Gerardo J. Majano Sanchez ,  Walter Weissman ,  Brian M. Weiss ,  Himanshu Gupta ,  John F. Brody ,  Scott J. Weigel

IPC: B01J29/70 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

Abstract: The present disclosure provides mesoporous catalyst compounds and compositions having one or more group 13 atoms. The present disclosure further relates to processes for converting hydrocarbon feedstocks to small olefins. In one aspect, a catalyst compound includes a zeolite having a structural type selected from MFI, MSE, MTW, Theta-One (TON), Ferrierite (FER), AFI, AFS, ATO, BEA, BEC, BOG, BPH, CAN, CON, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITN, IWR, IWW, LTL, MAZ, MEI, MOR, MOZ, OFF, OKO, OSI, SAF, SAO, SEW, SFE, SFO, SSF, SSY, and USI, or a combination thereof, the zeolite having a silicon to aluminum molar ratio (Si/Al ratio) of from about 5 to about 40. In one aspect, a catalyst composition includes the catalyst compound and one or more group 13 metal.

公开(公告)号：US11318450B2

公开(公告)日：2022-05-03

申请号：US16545148

申请日：2019-08-20

Applicant: ExxonMobil Research and Engineering Company

Inventor： Preeti Kamakoti ,  Scott J. Weigel ,  Karl G. Strohmaier ,  Helge Jaensch ,  Marc H. Anthonis ,  Martine Dictus ,  Brita Engels ,  Darryl D. Lacy ,  Sina Sartipi

IPC: B01J29/40 ,  B01J29/08 ,  B01J29/70 ,  B01J29/78 ,  B01J35/10 ,  B01J37/08 ,  C10G35/095

Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.

公开(公告)号：US10677160B2

公开(公告)日：2020-06-09

申请号：US15273800

申请日：2016-09-23

Applicant: ExxonMobil Research and Engineering Company

Inventor： Narasimhan Sundaram ,  Ramesh Gupta ,  Hans Thomann ,  Hugo S. Caram ,  Loren K. Starcher ,  Franklin F. Mittricker ,  Simon C. Weston ,  Scott J. Weigel

IPC: F02C3/34 ,  F02C6/04 ,  B01D53/047 ,  F01K17/04 ,  F02C9/16

Abstract: Systems and methods are provided for combined cycle power generation while reducing or mitigating emissions during power generation. Recycled exhaust gas from a power generation combustion reaction can be separated using a swing adsorption process so as to generate a high purity CO2 stream while reducing/minimizing the energy required for the separation and without having to reduce the temperature of the exhaust gas. This can allow for improved energy recovery while also generating high purity streams of carbon dioxide and nitrogen.