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11.发明授权
公开(公告)号：US5574116A
公开(公告)日：1996-11-12
申请号：US214691
申请日：1994-03-18
CPC分类号： C08F10/00
摘要： A process is disclosed for the polymerization of olefins, using (i) a catalyst and (ii) an organometallic activator from Groups I, II or III of the Periodic Table at temperatures between 20.degree. and 250.degree. C., and pressure up to 200 bar, in solution, or in suspension in an inert liquid hydrocarbon, at temperatures between 160.degree. and 350.degree. C., under pressures of between 400 and 3000 bar, in a continuous manner in a reactor where the mean residence time of the catalyst is between 1 and 150 seconds. The catalyst comprises at least one titanium compound, at least one halogen-containing organoaluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihaloalkane. The titanium compound is essentially a titanium (III) compound, the total content of titanium (II) and titanium (IV) being less than or equal to 15% of the total content of titanium. The catalyst is obtained by a process comprising, in a first step, the reduction of a titanium (IV) compound in an .alpha.,.omega.-dihaloalkane by means of a molar excess of at least one halogen-containing organoaluminum compound, in the absence of an ether, and, in a second step, the addition to the reaction mixture of a compound which forms a magnesium halide in situ without supplementary reduction of the titanium compound obtained in the first step. Molar ratios of the .alpha.,.omega.-dihaloalkane, the titanium compound, halogen-containing organoaluminum, and the compound which forms a magnesium halide in situ are also described.
摘要翻译： 公开了一种用于烯烃聚合的方法，其使用（i）催化剂和（ii）在20℃至250℃之间的元素周期表第I，II或III族的有机金属活化剂，压力高达200 在惰性液体烃中，160-150℃的温度下，在400-3000巴的压力下，在反应器中连续地在惰性液体烃中悬浮或悬浮，其中催化剂的平均停留时间为 1到150秒之间。 催化剂包含至少一种钛化合物，至少一种含卤素的有机铝化合物和至少一种α，ω-二卤代烷烃中的悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物，钛（II）和钛（IV）的总含量小于或等于钛总含量的15％。 该催化剂是通过一种方法获得的，该方法包括在第一步骤中，通过摩尔过量的至少一种含卤素的有机铝化合物在α，ω-二卤代烷烃中还原钛（IV）化合物， 醚，并且在第二步中，在没有补充还原第一步中获得的钛化合物的情况下向原位形成镁卤化物的化合物的反应混合物加入。 还描述了α，ω-二卤代烷烃，钛化合物，含卤素的有机铝和原位形成卤化镁的化合物的摩尔比。
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公开(公告)号：US5194676A
公开(公告)日：1993-03-16
申请号：US674745
申请日：1991-03-26
摘要： Saturated carboxylic esters are produced from alkyl formate and an olefin, without the presence of substantial amounts of carbon monoxide, at a temperature of 120.degree. to 280.degree. C., under a pressure of 1 to 3,000 bars, in the presence of a catalyst based on ruthenium coordinated by ligands selected from carbon monoxide, halogen atoms and amines, and in the presence of an amide as a solvent. The catalyst is selected from catalysts consisting essentially of RuCl.sub.3.3H.sub.2 O; catalysts consisting essentially of the combination of an RuCl.sub.3.3H.sub.2 O together with at least one stabilizer selected from iodine, covalent iodides and quaternary ammonium halides; catalysts comprising Ru.sub.3 (CO).sub.12 together with at least one stabilizer such as is mentioned above; and catalysts selected from RuI.sub.3, [RuCl.sub.2 (CO).sub.3 ].sub.2, Ru(NH.sub.3).sub.6 Cl.sub.3 and [Ru(NH.sub.3).sub.5 Cl]Cl.sub.2, comprising, where appropriate, in addition, at least one stabilizer such as is mentioned above.
摘要翻译： 在120至280℃的温度下，在1至3,000巴的压力下，在催化剂基的存在下，将饱和羧酸酯由甲酸烷基酯和烯烃生产，而不存在大量的一氧化碳 在由选自一氧化碳，卤素原子和胺的配体和在作为溶剂的酰胺存在下配位的钌上。 催化剂选自基本上由RuCl 3·3H 2 O组成的催化剂; 基本上由RuCl 3·3H 2 O与至少一种选自碘，共价碘化物和季铵卤化物的稳定剂的组合组成的催化剂; 包含Ru 3（CO）12的催化剂以及如上所述的至少一种稳定剂; 以及选自RuI 3，[RuCl 2（CO）3] 2，Ru（NH 3）6 Cl 3和[Ru（NH 3）5 Cl] Cl 2的催化剂，在适当的情况下还包括至少一种如上所述的稳定剂。
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13.发明授权Catalytic composition for the polymerization of olefins and its process of preparation 失效用于烯烃聚合的催化组合物及其制备方法
公开(公告)号：US5068014A
公开(公告)日：1991-11-26
申请号：US369229
申请日：1989-06-22
CPC分类号： C08F10/00
摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.
摘要翻译： 制备烯烃聚合催化组合物的方法。 在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。 所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物。 钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。
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14.发明授权Process for selective electrochemical dimerization of conjugated dienes to form vinylcyclohexenes 失效选择性电化学二聚化共轭二烯以形成乙烯基环己烯的方法
公开(公告)号：US4238301A
公开(公告)日：1980-12-09
申请号：US37549
申请日：1979-05-09
申请人： Francis Petit , Dominique Huchette
发明人： Francis Petit , Dominique Huchette
IPC分类号： C25B3/10
CPC分类号： C25B3/10
摘要： A process is provided for the selective electrochemical dimerization of conjugated dienes to form vinylcyclohexenes with a selectivity of up to 100%. An electrochemical catalytic system is provided for effecting the reaction.
摘要翻译： 提供了一种用于选择性电化学二聚化共轭二烯以形成乙烯基环己烯的方法，其选择性高达100％。 提供用于进行反应的电化学催化体系。
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15.发明授权Catalytic composition for the polymerization of olefins and its process of preparation 失效用于烯烃聚合的催化组合物及其制备方法
公开(公告)号：US5356848A
公开(公告)日：1994-10-18
申请号：US117319
申请日：1993-09-07
CPC分类号： C08F10/00
摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.
摘要翻译： 制备烯烃聚合催化组合物的方法。 在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。 所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物。 钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。
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16.发明授权
公开(公告)号：US5210202A
公开(公告)日：1993-05-11
申请号：US811673
申请日：1991-12-23
申请人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
发明人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
IPC分类号： B01J31/18 , B01J31/00 , B01J31/24 , C07B31/00 , C07B53/00 , C07B61/00 , C07C1/00 , C07C2/32 , C07C2/42 , C07C2/46 , C07C2/52 , C07C11/02 , C07C13/20 , C07C29/136 , C07C29/88 , C07C33/22 , C07C45/49 , C07C45/50 , C07C67/00 , C07C231/00 , C07C231/12 , C07C231/20 , C07C233/47 , C07F7/18 , C07F9/46 , C07F9/50 , C07F9/53 , C07F9/572 , C07F15/00
CPC分类号： C07F15/0073 , C07C2/465 , C07C2/52 , C07C45/505 , C07F7/188 , C07F9/46 , C07F9/572 , C07C2101/16 , C07C2531/22
摘要： Chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphinoxy radical of the formula W=OP (R).sub.2, in which R is a hydrocarbon radical selected from the group consisting of alkyl, aryl, and cycloalkyl radicals, wherein the ligand is selected from the group consisting of:those of the formula ##STR1## those of the forumula ##STR2## those of the formula ##STR3## those of the formula ##STR4##
摘要翻译： 包含至少一个胺基团和至少一个式W = OP（R）2的二烃基次膦基的手性含磷配体，其中R是选自烷基，芳基和环烷基的烃基，其中 该配体选自：式（I）的化合物（I）的化合物的组合
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17.发明授权N-substituted derivatives of .alpha.-mercapto alkylamines, their preparation process and the intermediates obtained, their use as medicaments and the compositions containing them 失效（ALPHA）-MERCAPTO ALKYLAMINES的N-取代衍生物，其制备方法和所获得的中间体，它们作为药物和包含它们的组合物使用
公开(公告)号：US5190974A
公开(公告)日：1993-03-02
申请号：US725985
申请日：1991-07-05
IPC分类号： A61K31/17 , C07C319/20 , C07C323/41 , C07C323/44 , C07C327/30 , C07C327/42 , C07C331/24 , C07C335/04 , C07D211/58 , C07D213/75 , C07D243/08 , C07D243/24 , C07D295/10 , C07D295/15 , C07D295/215 , C07D295/32
CPC分类号： C07D213/75 , C07C323/44 , C07C327/30 , C07D211/58 , C07D243/08 , C07D243/24 , C07D295/15 , C07D295/215
摘要： Novel .alpha.-mercapto-alkylamines in all possible racemic, enantiomeric and diastereoisomeric forms of the formula ##STR1## wherein n, R.sub.1, R.sub.2, X, A, R.sub.3A and R.sub.4A are set forth in the claims and their non-toxic, pharmaceutically acceptable acid addition salts having excellent analgesic, psychotropic and enkephalinase inhibiting properties.
摘要翻译： 新颖的α-巯基 - 烷基胺在所有可能的外消旋，对映异构体和非对映异构体形式的式IA中，其中n，R1，R2，X，A，R3A和R4A在权利要求书中阐述，并且其无毒的药学上可接受的 酸加成盐具有优异的镇痛，精神病和脑啡肽酶抑制特性。
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18.发明授权Chiral phosphorus compounds, a process for their manufacture and their application to the catalysis of enantioselective synthesis reactions 失效CHIRAL PHOSPHORUS化合物，其制备方法及其应用于催化合成反应的应用
公开(公告)号：US5099077A
公开(公告)日：1992-03-24
申请号：US398539
申请日：1989-10-11
申请人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
发明人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
IPC分类号： B01J31/18 , B01J31/00 , B01J31/24 , C07B31/00 , C07B53/00 , C07B61/00 , C07C1/00 , C07C2/32 , C07C2/42 , C07C2/46 , C07C2/52 , C07C11/02 , C07C13/20 , C07C29/136 , C07C29/88 , C07C33/22 , C07C45/49 , C07C45/50 , C07C67/00 , C07C231/00 , C07C231/12 , C07C231/20 , C07C233/47 , C07F7/18 , C07F9/46 , C07F9/50 , C07F9/53 , C07F9/572 , C07F15/00
CPC分类号： C07F15/0073 , C07C2/465 , C07C2/52 , C07C45/505 , C07F7/188 , C07F9/46 , C07F9/572 , C07C2101/16 , C07C2531/22
摘要： A method of using a chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphioxy radical of the formula W=OP (R).sub.2 ; from the group consisting of:those of the formula ##STR1## those of the formula ##STR2## those of the formula ##STR3## those of the formula ##STR4## in a hydrogenation reaction for the synthesis of optically active organic compounds comprising reacting at least one organic compound that does not possess a center of asymmetry with (A), on the one hand, at least one transition metal complex of the formula MZq in which M is a metal in group VIII of the Periodic Classification, q is the coordination number of the metal M, and Z is an atom or molecule capable of complexing the metal M and (B), on the other hand, at least one ligand L.
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19.发明授权Catalyst system, process for its preparation and its application to the manufacture of aldehydes 失效催化剂体系，其制备方法及其在制醛中的应用
公开(公告)号：US5024983A
公开(公告)日：1991-06-18
申请号：US323718
申请日：1989-03-15
申请人： Eric Paumard , Sylvain Mutez , Andre Mortreux , Francis Petit
发明人： Eric Paumard , Sylvain Mutez , Andre Mortreux , Francis Petit
CPC分类号： B01J31/188 , B01J31/2409 , C07C45/50 , B01J2231/321 , B01J2531/828
摘要： The catalyst system is characterized in that it comprises:at least one platinum complex of formula LPtX.sub.2 in which L is an organic compound containing at least two phosphorus atoms capable of coordinating platinum and X is a halogen atom, andat least one combination formed between iron and an alkene carbonate, the alkene group preferably containing from 2 to 6 carbon atoms.The process for its preparation is characterized in that at least one combination formed between iron adn the alkene carbonate is reacted with at least one platinum complex of formula LPtX.sub.2 in at least one solvent for the said complex, at a temperature of between 10.degree. C. and the boiling point of the said solvent. The combination of iron and of an alkene carbonate may be formed by electrochemical reduction.Application of the catalyst system to the manufacture of aldehydes by hydroformylation of an organic compound containing ethylenic unsaturation, consisting in reacting the said organic compound with a mixture of carbon monoxide and hydrogen in the presence of an effective quantity of the said catalyst system, at a temperature of between 10.degree. and 300.degree. C. and at a pressure of between 10 and 350 bars.
摘要翻译： 该催化剂体系的特征在于它包括：至少一种式LPtX2的铂络合物，其中L是含有能配位铂的至少两个磷原子的有机化合物，X是卤素原子，并且在铁 和烯烃碳酸酯，烯烃基团优选含有2至6个碳原子。 其制备方法的特征在于，在碳酸甲酯之间形成的至少一种组合与至少一种式LPtX2的铂络合物在所述络合物的至少一种溶剂中在10℃的温度下反应。 和所述溶剂的沸点。 铁和碳酸烯烃的组合可以通过电化学还原形成。 在有效量的所述催化剂体系的存在下，将所述有机化合物与一氧化碳和氢气的混合物反应，所述有机化合物含有烯属不饱和基团的加成甲酰化将所述催化剂体系应用于醛的制备中， 温度在10℃至300℃之间，压力在10至350巴之间。
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公开(公告)号：US5320994A
公开(公告)日：1994-06-14
申请号：US844931
申请日：1992-03-04
CPC分类号： C08F10/00
摘要： The process comprises, in a first step, the reduction of a titanium (IV) compound in an .alpha.,.omega.-dihalogenoalkane using a molar excess of at least one halogenated organoaluminium compound in the absence of an ether, and then in a second step, the addition of a reaction mixture of a compound capable of forming a magnesium halide in-situ, without additional reduction of the titanium compound obtained in the first step. The catalyst contains at least one titanium compound, at least one halogenated organoaluminium compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogenoalkane; the titanium cmpound is essentially a titanium (III) compound, the total titanium (II) and titanium (IV) content being less than or equal 15% to the total titanium content. It may also contain at least one vanadium compound, an inert solvent, at least one partially polymerized .alpha.-olefin and at least one organometallic activator from groups I to II of the Periodic Classification. Also described is a process for polymerization of olefins in the presence of said catalyst.
摘要翻译： 该方法在第一步中包括在不存在醚的情况下使用摩尔过量的至少一种卤化有机铝化合物还原α，ω-二卤代烷烃中的钛（IV）化合物，然后在第二步中， 加入能够原位形成卤化镁的化合物的反应混合物，而不需要额外还原在第一步中获得的钛化合物。 催化剂在至少一种α，ω-二卤代烷烃中含有至少一种钛化合物，至少一种卤化有机铝化合物和悬浮液中的至少一种无机镁化合物; 钛化合物基本上是钛（III）化合物，总钛（II）和钛（IV）含量小于或等于总钛含量的15％。 它还可以含有至少一种钒化合物，惰性溶剂，至少一种部分聚合的α-烯烃和至少一种有机金属活化剂，其定期分类来自I至II组。 还描述了在所述催化剂存在下烯烃聚合的方法。
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