摘要:
The present invention refers to light emitting compounds, especially to phosphorescent compounds useful for electroluminescent applications, for example forming a layer in OLEDs and laser applications undoped to emit visible light when excited by electric current. The compounds of the present invention comprise a core structure according to general formula (I), wherein Met=Ir, Pt, Pd, Ru, Rh, Re, or Os with n=1-3, m=3-n for Ir, Ru, Rh, Re or Os and with n=1 or 2, m=2-n for Pt or Pd, wherein r and s are independently positive natural numbers, preferably varying by a maximum of 2, more preferably identical, wherein groups U and V can be selected independently from a chemical bond, any substituted or unsubstituted aromatic or non-aromatic poly- or mono-cyclic group, alkyl, a double bond, a triple bond, nitrogen, oxygen, sulfur, selenium, telluride, NR with R selected from hydrogen, alkyl, aryl or heteroaryl, wherein Ar3 is an aromatic or non-aromatic moiety which allows the formation of chemical bonds to groups U and V, respectively, from neighbouring atoms contained in moiety Ar3, A1 and wherein formula (II) is a saturating ligand.
摘要:
The present invention relates to the use of transition metal-carbene complexes in organic light-emitting diodes (OLEDs), to a light-emitting layer, to a blocking layer for electrons or excitons, or to a blocking layer for holes, each comprising these transition metal-carbene complexes, to OLEDs comprising these transition metal-carbene complexes, to devices which comprise an inventive OLED, and to transition metal-carbene complexes.
摘要:
Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitrites and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
摘要:
Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
摘要:
The present invention relates to chemical compounds that can be used in electrooptical applications. The electrically conductive and optical properties of these compounds, e.g. hole transporting, electron transporting and/or light emitting properties can be predetermined by substituting the core structure of these compounds with respective residues. The core structure (1) of the compounds according to the invention comprises two opposing aromatic moieties which are chemically bonded through an intermediate central atom. This central atom has a tetraedric configuration and therefore provides an orthogonal orientation to the organic moieties.
摘要:
The invention relates to cyclic bioisosteres of derivatives of a purine system having a general structural formula R1=—H, —NH2, —Br, —Cl, —OH, —COOH, B=—N═, —CH═, Z=—CH═, —N═, A=—N═ at B=—N═, Z=—CH—, A=—CH═ at B=—N═, Z=—CH—, A=—CH═ at B=—N═, Z=—N═, A=—CH═ at B=—CH═, Z=—CH═, A=—CH═ at B=—CH═, Z=—N═, and their pharmacologically acceptable salts having a normalizing effect on endocellular processes, in particular, it is capable eliminating endocellular metabolic acidosis and capable of binding excessively formed free radicals, in particular, free-radical forms of oxygen, capable of normalizing the nitrergic mechanisms of the cells, and also capable of interreacting with adenosine-sensitive receptors on the membrane of non-nuclear cells and in nuclei-containing cells to decrease the aggregation of thrombocytes. The compounds according to the invention have hepatoprotective effect and can be used for producing pharmaceutical compositions on their base.
摘要:
A two-layered anode (1′) has a lower layer (2) including a non-conductive carrier material to which a conductive electrode layer (3′) is applied. Non-conductive areas, formed by partial removal of the electrode layer, have a predetermined structure corresponding to the structure of a structured polymer film (11) to be formed. The anode (1′) is connected with a platinum cathode in an electrolyte into which compounds of low molecular weight, preferably monomers of the polymer film (11), are introduced. During current flow, a conductive polymer film (11) of the predetermined structure is formed on conductive areas brought into contact with the electrolyte. A non-conductive substrate layer (13) is applied to the structured polymer film (11). The structured polymer film (11) adheres to the non-conductive substrate layer (13) and can be released from the electrode (1′) without damaging the electrode.
摘要:
Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitrites and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
摘要:
The invention relates to an organic white light-emitting diode comprising at least one blue light-emitting fluoranthene derivative of the general formula I as component A and at least one blue light-emitting arylamine derivative as component B, the HOMO energies and LUMO energies of components A and B being different, with the condition that the LUMO energy of component A is higher than the HOMO energy of component B; to a composition comprising at least one blue light-emitting fluoranthene derivative of the formula I as component A and at least one blue light-emitting arylamine derivative as component B, the HOMO energies and LUMO energies of components A and B being different, with the condition that the LUMO energy of component A is higher than the HOMO energy of component B; and also to a light-emitting layer comprising a composition and to an organic white light-emitting diode comprising an inventive composition or an inventive light-emitting layer. The invention further relates to a device selected from the group consisting of stationary visual display units such as visual display units of computers, televisions, visual display units in printers, kitchen appliances and advertising panels, illuminations, information panels and mobile visual display units such as visual display units in mobile telephones, laptops, vehicles and destination displays in buses and trains, comprising at least one inventive organic light-emitting diode, and to the use of an inventive composition in an organic white light-emitting diode.
摘要:
The present invention relates to the use of polymeric materials comprising at least one transition metal-carbene complex in organic light-emitting diodes (OLEDs), polymeric materials comprising at least one selected transition metal-carbene complex, a process for preparing the polymeric materials of the invention, a light-emitting layer comprising at least one polymeric material used according to the invention or at least one polymeric material of the invention, an organic light-emitting diode (OLED) comprising the light-emitting layer of the invention and devices comprising the organic light-emitting diode of the invention.