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31 条记录 (耗时 0.025 秒)

    Photopolymerizable mixture, and a recording material produced therefrom
    14.
    发明授权
    Photopolymerizable mixture, and a recording material produced therefrom 失效
    光聚合性混合物及其制备的记录材料

    公开(公告)号：US5085974A

    公开(公告)日：1992-02-04

    申请号：US174426

    申请日：1988-03-28

    申请人： Werner Frass ,  Dieter Mohr ,  Klaus Rode

    发明人： Werner Frass ,  Dieter Mohr ,  Klaus Rode

    IPC分类号： C08F20/20 ,  C08F2/48 ,  C08F2/50 ,  C08F20/34 ,  G03F7/027 ,  G03F7/028 ,  G03F7/031

    CPC分类号： G03F7/031 ,  G03F7/027 ,  Y10S430/116

    摘要： A photopolymerizable mixture is disclosed which comprisesa) a polymeric binder,b) an acrylate or alkacrylate of a polyhydric alcohol containing one or more groups which are photooxidizable on exposure in the presence of the photoreducible dye, and one or more urethane groups,c) a photoreducible dye as photoinitiator.The mixture is suitable for the production of printing plates and photoresists and is distinguished by increased photosensitivity, which can be even further increased by the addition of a photolytically cleavable compound which contains at least one trihalomethyl group. A recording material comprising the photopolymerizable mixture is also disclosed.

    摘要翻译： 公开了一种可光聚合的混合物，其包含a）聚合物粘合剂，b）含有一个或多个在可光还原染料存在下可曝光的可氧化的基团的多元醇的丙烯酸酯或烷基丙烯酸酯，以及一种或多种氨基甲酸酯基团，c） 作为光致引发剂的光还原染料。 该混合物适用于印刷版和光致抗蚀剂的生产，其特征在于增加光敏性，通过加入含有至少一个三卤代甲基的可光解裂解的化合物，可以进一步提高。 还公开了包含可光聚合混合物的记录材料。

    Process for the production of relief forms with a developing solvent comprising phenol ether
    15.
    发明授权
    Process for the production of relief forms with a developing solvent comprising phenol ether 失效
    用包含酚醛树脂的开发溶剂生产消除形式的方法

    公开(公告)号：US5077177A

    公开(公告)日：1991-12-31

    申请号：US519468

    申请日：1990-05-07

    申请人： Werner Frass ,  Hans-Joachim Schlosser ,  Guenther Schoen

    发明人： Werner Frass ,  Hans-Joachim Schlosser ,  Guenther Schoen

    IPC分类号： G03F7/00 ,  G03F7/32 ,  G03F7/40

    CPC分类号： G03F7/325

    摘要： The invention describes a developing solvent for layers which are crosslinkable by photopolymerization and contain a binder based on an elastomeric polymer, a photopolymerizable monomer compatible therewith and a photoinitiator. The developing solvent comprises a phenol ether of the general formula I ##STR1## wherein R.sup.1 denotes (C.sub.1 -C.sub.6)n-alkyl or iso-alkyl, cycloalkyl or (C.sub.6 -C.sub.12)-aryl andR.sup.2 denotes hydrogen, (C.sub.1 -C.sub.6)n-alkyl or iso-alkyl or --OR.sup.1.Compared with solvents of the prior art, the developing solvent of the present invention is non-toxic, can quickly be removed from the layer and has a high capacity for layer components.

    摘要翻译： 本发明描述了用于层的显影溶剂，其可通过光聚合交联并且含有基于弹性体聚合物的粘合剂，与其相容的可光聚合单体和光引发剂。 显影溶剂包括通式I的苯酚醚，其中R 1表示（C 1 -C 6）正烷基或异烷基，环烷基或（C 6 -C 12） - 芳基，R 2表示氢，（C 1 -C 6） 正烷基或异烷基或-OR 1。 与现有技术的溶剂相比，本发明的显影溶剂是无毒的，可以从层中快速去除并且具有高的层组分能力。

    Photopolymerizable composition comprising (meth)acrylates with photooxidizable groups and a recording material produced therefrom
    16.
    发明授权
    Photopolymerizable composition comprising (meth)acrylates with photooxidizable groups and a recording material produced therefrom 失效
    包含（甲基）丙烯酸酯和可光氧化基团的光聚合组合物和由其制备的记录材料

    公开(公告)号：US5043249A

    公开(公告)日：1991-08-27

    申请号：US287278

    申请日：1988-12-21

    申请人： Klaus Rode ,  Joachim Gersdorf ,  Dieter Mohr ,  Werner Frass

    发明人： Klaus Rode ,  Joachim Gersdorf ,  Dieter Mohr ,  Werner Frass

    IPC分类号： C08F2/44 ,  C08F2/50 ,  C08F290/00 ,  C08F299/00 ,  G03F7/029

    CPC分类号： G03F7/0295 ,  Y10S430/116

    摘要： A photopolymerizable mixture is described comprising (a) a polymeric binder, (b) an acrylate or alkacrylate of a polyhydric alcohol, said compound being free of urethane groups and further comprising at least one group which is photooxidizable on exposure to actinic radiation in the presence of a photoreducible dye, (c) a photoinitiator comprising a photoreducible dye, (d) a second photoinitiator comprising a trihalomethyl compound capable of being cleaved by irradiation, and (e) a third photoinitiator comprising an acridine, phenazine or quinoxaline compound. The mixture is suitable for the production of printing plates and photoresists and displays increased photosensitivity.

    摘要翻译： 描述了可光聚合的混合物，其包含（a）聚合物粘合剂，（b）多元醇的丙烯酸酯或丙烯酸烷基酯，所述化合物不含氨基甲酸酯基团，并且还包含至少一个在存在光化辐射的情况下可光氧化的基团 的光还原性染料，（c）包含光还原性染料的光引发剂，（d）包含能够通过照射被切割的三卤甲基化合物的第二光引发剂，和（e）包含吖啶，吩嗪或喹喔啉化合物的第三光引发剂。 该混合物适用于生产印版和光致抗蚀剂并显示增加的光敏性。

    Process for the electrochemical roughening of aluminum for use as printing plate supports, in an aqueous mixed electrolyte
    17.
    发明授权
    Process for the electrochemical roughening of aluminum for use as printing plate supports, in an aqueous mixed electrolyte 失效
    在水性混合电解质中电化学粗化铝作为印版支撑体的方法

    公开(公告)号：US4618405A

    公开(公告)日：1986-10-21

    申请号：US726244

    申请日：1985-04-23

    申请人： Dieter Mohr ,  Werner Frass

    发明人： Dieter Mohr ,  Werner Frass

    IPC分类号： B41N3/00 ,  B41N3/03 ,  C25F3/04

    CPC分类号： B41N3/034 ,  C25F3/04

    摘要： Disclosed is a process for electrochemically roughening aluminum or aluminum alloys for use as printing plate supports, in an aqueous mixed electrolyte solution containing hydrochloric acid (HCl) and, as an additional inorganic electrolyte, at least one compound selected from the group consisting of condensed phosphoric acids, amidosulfonic acid, and the water-soluble alkali metal salts and ammonium salts thereof. In particular, the solution contains from 0.5 to 10% by weight of HCl and from 0.05 to 5.0% by weight of the additional inorganic electrolyte (for example, diphosphoric acid or polyphosphoric acid). The support materials which are particularly uniformly roughened are employed in the production of offset-printing plates.

    摘要翻译： 公开了一种在含有盐酸（HCl）的含水混合电解质溶液中作为印版支持体的电化学粗化铝或铝合金的方法，以及作为另外的无机电解质的至少一种选自缩合磷酸盐 酸，酰胺磺酸及其水溶性碱金属盐和铵盐。 特别地，该溶液含有0.5-10重量％的HCl和0.05-5.0重量％的另外的无机电解质（例如二磷酸或多磷酸）。 特别均匀地粗糙化的支撑材料用于胶版印刷版的生产。

    Process for developing exposed diazo negative-working reproduction layers using aqueous developer having salt of aromatic carboxylic acid with adjacent group substituent
    18.
    发明授权
    Process for developing exposed diazo negative-working reproduction layers using aqueous developer having salt of aromatic carboxylic acid with adjacent group substituent 失效
    使用具有芳香族羧酸盐和相邻基团取代基的含水显影剂对曝光的重氮负性再生层进行显影的方法

    公开(公告)号：US4579811A

    公开(公告)日：1986-04-01

    申请号：US566395

    申请日：1983-12-28

    申请人： Loni Schell ,  Werner Frass ,  Inge Gros

    发明人： Loni Schell ,  Werner Frass ,  Inge Gros

    IPC分类号： G03F7/32 ,  G03F7/08 ,  G03C5/34 ,  G03F7/26

    CPC分类号： G03F7/32

    摘要： Disclosed is a developer composition for exposed, light-sensitive, negative-working reproduction layers, which may contain an organic binder, comprising water and a salt of a substituted aromatic carboxylic acid, in particular, from about 5 to 60% by weight of at least one salt of an aromatic carboxylic acid having substituents which are immediately adjacent to the carboxyl group and represent an amino group, a hydroxyl group, and/or chlorine or bromine. Also disclosed is a process for developing the reproduction layers utilizing the disclosed developers, wherein the reproduction layer contains, in particular, a polymeric organic binder with an acetal, anhydride, amide and/or a carboxyl group.

    摘要翻译： 公开了一种用于曝光，感光，负作用的再生层的显影剂组合物，其可以含有有机粘合剂，其包含水和取代的芳族羧酸的盐，特别是约5至60重量％的 具有与羧基紧邻并且表示氨基，羟基和/或氯或溴的取代基的芳族羧酸的至少一种盐。 还公开了利用所公开的显影剂开发再生层的方法，其中再生层尤其含有具有缩醛，酸酐，酰胺和/或羧基的聚合物有机粘合剂。

    Process for electrochemically modifying electrochemically roughened aluminum support materials and the use of these materials in the manufacture of offset printing plates
    19.
    发明授权
    Process for electrochemically modifying electrochemically roughened aluminum support materials and the use of these materials in the manufacture of offset printing plates 失效
    用于电化学修饰电化学粗糙化的铝支撑材料的方法以及这些材料在胶版印刷版的制造中的应用

    公开(公告)号：US4482444A

    公开(公告)日：1984-11-13

    申请号：US504874

    申请日：1983-06-16

    申请人： Werner Frass ,  Dieter Mohr

    发明人： Werner Frass ,  Dieter Mohr

    IPC分类号： C25F3/20 ,  B41N3/00 ,  B41N3/03 ,  C25F3/04 ,  B41N1/08 ,  C25D11/16 ,  G03F7/02

    CPC分类号： C25F3/04 ,  B41N3/034 ,  Y10S204/08

    摘要： This invention pertains to a process for electrochemically modifying electrochemically roughened aluminum or aluminum alloy-based support materials for printing plates. An aluminum or aluminum alloy-based support material is electrochemically roughened using alternating current in an electrolyte containing at least one from the group consisting of hydrochloric acid and nitric acid. Subsequently, at least one surface of the material is treated in an aqueous electrolyte, with the roughened material being made the cathode. The cathodic treatment results in removal of material from the surface in the order of from 0.1 to 10 g/m.sup.2, and is carried out in an aqueous electrolyte which has a pH value in the range from 3 to 11 and includes at least one water-soluble salt in a concentration ranging from 5 g/l up to the saturation limit thereof. The cathodic treatment is appropriately conducted using direct current at a current density from 3 to 100 A/dm.sup.2, at a temperature from 15.degree. to 90.degree. C., and for a duration from 5 to 90 seconds. The removal of material is optionally followed by an anodic oxidation of the support material and a hydrophilizing post-treatment of the oxide layer.Support materials which have been prepared in this manner are used in the manufacture of offset printing plates carrying a radiation-sensitive coating.

    摘要翻译： 本发明涉及一种用于电化学改性印刷板的电化学粗糙化的铝或铝合金基载体材料的方法。 在含有至少一种由盐酸和硝酸组成的组的电解质中，使用交流电在电化学上粗糙化铝或铝合金基载体材料。 随后，材料的至少一个表面在含水电解质中被处理，粗化材料被制成阴极。 阴极处理导致从表面去除材料的量为0.1〜10g / m 2，并且在pH值为3〜11的水性电解质中进行，并且包含至少一种水溶性聚合物， 浓度范围为5g / l至其饱和极限的可溶性盐。 阴极处理使用直流电流以3〜100A / dm 2的电流密度，15〜90℃的温度适当进行5〜90秒。 材料的去除任选地随后是载体材料的阳极氧化和氧化物层的亲水后处理。 以这种方式制备的支撑材料用于制造携带辐射敏感涂层的胶版印刷版。