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11.发明授权Process for preparing aliphatic straight-chain and beta-alkyl-branched carboxylic acids 有权制备脂肪族直链和β-烷基支链羧酸的方法公开(公告)号：US07138544B2
公开(公告)日：2006-11-21
申请号：US11237294
申请日：2005-09-28
Applicant: Helmut Springer , Frank Winsberg
Inventor： Helmut Springer , Frank Winsberg
IPC: C07C51/235
CPC classification number: C07C51/235 , C07C53/126
Abstract: The present invention relates to a process for preparing aliphatic straight-chain and β-alkyl-branched carboxylic acids by catalytic oxidation of aldehydes by means of oxygen or oxygen-containing gas mixtures. Alkali metal carboxylates or alkaline earth metal carboxylates or a mixture thereof in an amount, calculated as alkali metal or alkaline earth metal, of from 1 mmol each to from 10 mmol each per mole of aldehyde used and also metals or compounds of metals of groups 5 to 11 of the Periodic Table of the Elements in amounts of not more than 5 ppm, based on aldehyde used, are present as catalyst.
Abstract translation: 本发明涉及通过氧或含氧气体混合物催化氧化醛制备脂族直链和β-烷基支链羧酸的方法。 碱金属或碱土金属的碱金属羧酸盐或碱土金属羧酸盐或其混合物，其用量为碱金属或碱土金属，每摩尔使用的醛为1mmol至10mmol，以及第5族金属或金属化合物 以所使用的醛为基准，不超过5ppm的元素周期表中的11个作为催化剂存在。
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12.发明授权Process for the preparation of esters of 5-alkylpyridine-2,3-dicarboxylic acid 失效制备5-烷基吡啶-2,3-二羧酸的方法
公开(公告)号：US5182400A
公开(公告)日：1993-01-26
申请号：US741603
申请日：1991-08-07
Applicant: Jurgen Weber , Peter Lappe , Helmut Springer
Inventor： Jurgen Weber , Peter Lappe , Helmut Springer
IPC: B01J31/02 , C07B61/00 , C07D213/80 , C07D213/803
CPC classification number: C07D213/80
Abstract: Process for the preparation of 5-alkylpyridine-2,3-dicarboxylic esters by reaction of 2-oxosuccinic esters with 2-alkylacrolein oximes.
Abstract translation: 通过2-氧代琥珀酸酯与2-烷基丙烯醛肟的反应制备5-烷基吡啶-2,3-二羧酸酯的方法。
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公开(公告)号：US5091546A
公开(公告)日：1992-02-25
申请号：US588665
申请日：1990-09-26
Applicant: Peter Lappe , Helmut Springer
Inventor： Peter Lappe , Helmut Springer
CPC classification number: B01J31/4046 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/2404 , B01J38/62 , C01G55/00 , C01G55/001 , C07C45/82 , C22B11/042 , C22B3/06 , B01J2231/321 , B01J2531/822 , B01J31/04 , B01J31/26 , Y02P10/214 , Y02P10/234 , Y02P20/584
Abstract: A process for the recovery of rhodium from distillation residues of crude products from the oxo synthesis with rhodium complexed with an organic phosphorous III compound comprising treating the said distillation residues with oxygen or an oxygen containing gas in the presence of an alkali metal salt of a monocarboxylic acid of 2 to 5 carbon atoms at 60.degree. to 120.degree. C. at atmospheric or elevated pressure to form a water-soluble rhodium compound and extracting the mixture with water to obtain an aqueous phase containing the water soluble rhodium compound in a very simple manner without any substantial loss of rhodium.
Abstract translation: 一种从有机磷III化合物络合的铑的氧代合成的粗制产品的蒸馏残余物中回收铑的方法，包括在一元羧酸的碱金属盐存在下用氧或含氧气体处理所述蒸馏残余物 在大气压或高压下在60-120℃下加入2至5个碳原子的酸形成水溶性铑化合物并用水萃取该混合物，以非常简单的方式获得含有水溶性铑化合物的水相 没有铑的实质损失。
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公开(公告)号：US5072058A
公开(公告)日：1991-12-10
申请号：US632353
申请日：1990-12-21
Applicant: Georg Dambkes , Peter Lappe , Franz Thonnessen , Helmut Springer
Inventor： Georg Dambkes , Peter Lappe , Franz Thonnessen , Helmut Springer
Abstract: A process for the preparation of 2,2-dimethylpropane-1,3-diol by an addition reaction between isobutyraldehyde and formaldehyde in the presence of tertiary amines as the catalyst, hydrogenation of the reaction mixture, and subsequent distillation. Before the distillation, formaldehyde is added to the hydrogenation product to remove unwanted basic impurities.
Abstract translation: 在叔胺作为催化剂存在下，通过异丁醛和甲醛之间的加成反应制备2,2-二甲基丙烷-1,3-二醇的方法，反应混合物的氢化和随后的蒸馏。 在蒸馏之前，将甲醛加入到氢化产物中以除去不需要的碱性杂质。
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公开(公告)号：US5064508A
公开(公告)日：1991-11-12
申请号：US574609
申请日：1990-08-28
Applicant: Jurgen Weber , Peter Lappe , Helmut Springer
Inventor： Jurgen Weber , Peter Lappe , Helmut Springer
CPC classification number: C07C45/82 , C07C45/50 , C07C45/85 , Y10S203/06
Abstract: A process for the separation of 2-methylalkanals from a mixture thereof with at least one alpha unbranched aldehyde thereof comprising distillation of said mixture in the presence of formaldehyde and an aldolization catalyst whereby the alpha unbranched aldehydes are converted to alpha alkylacrolein and the 2-methylalkanals are recovered in a high purity.
Abstract translation: 一种从其混合物与至少一种α未分支醛分离2-甲基链烷醇的方法，其包括在甲醛和醛醇化催化剂存在下蒸馏所述混合物，由此将所述α无支链醛转化为α-烷基丙烯醛和2-甲基链烷醛 以高纯度回收。
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Patent Agency Ranking
公开(公告)号：US4885383A
公开(公告)日：1989-12-05
申请号：US248544
申请日：1988-09-23
Applicant: Jurgen Weber , Helmut Springer , Peter Lappe
Inventor： Jurgen Weber , Helmut Springer , Peter Lappe
IPC: C07B61/00 , B01J27/02 , C07C67/08 , C07C69/003
CPC classification number: C07C67/08 , C07C2101/14
Abstract: A process for the preparation of methyl carboxylates by the reaction of mono or dicarboxylic acids having more than 5 carbon atoms and methanol in the presence of acidic catalysts at temperatures from 100.degree. to 150.degree. C. and below the boiling point of the carboxylates being produced.
Abstract translation: 在酸性催化剂存在下，在100-150℃的温度和低于所生产的羧酸盐的沸点下，通过使具有多于5个碳原子的一元或二元酸与甲醇反应制备甲基羧酸酯的方法 。
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公开(公告)号：US4283564A
公开(公告)日：1981-08-11
申请号：US106211
申请日：1979-12-21
Applicant: Wolfgang Bernhagen , Hanswilhelm Bach , Eike Brundin , Wilhelm Gick , Helmut Springer , Adolf Hack
Inventor： Wolfgang Bernhagen , Hanswilhelm Bach , Eike Brundin , Wilhelm Gick , Helmut Springer , Adolf Hack
CPC classification number: C07C45/75
Abstract: A process for preparing methacrolein by catalytic reaction of propionaldehyde with formaldehyde is disclosed wherein the catalyst comprises a mixture of secondary amine and organic carboxylic acid with up to 8 carbon atoms.
Abstract translation: 公开了通过丙醛与甲醛的催化反应制备甲基丙烯醛的方法，其中催化剂包含仲胺和具有至多8个碳原子的有机羧酸的混合物。
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公开(公告)号：US07317128B2
公开(公告)日：2008-01-08
申请号：US10967597
申请日：2004-10-18
Applicant: Peter Lappe , Helmut Springer , Rainer Lukas
Inventor： Peter Lappe , Helmut Springer , Rainer Lukas
IPC: C07C209/00
CPC classification number: C07C209/26 , C07C47/347 , C07C47/445 , C07C2603/68 , C07C211/19
Abstract: A process for preparing 3(4),8(9)-bis(aminomethyl)tricycle-[5.2.1.02,6]decane by hydroformylating dicyclopentadiene with subsequent reductive amination wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in a first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Periodic Table to give 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene is converted, in a homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane
Abstract translation: 通过加氢甲酰化二环戊二烯制备3（4），（9） - 双（氨基甲基）三环[5.2.1.0 2,6]癸烷的方法，随后还原胺化，其中携带二环戊二烯的加氢甲酰化 在两个阶段中，并且在第一加氢甲酰化阶段中，使用过渡金属化合物的水溶液在非均相反应体系中进行反应，所述过渡金属化合物含有复合结合形式的水溶性有机磷（III）化合物，第VIII族 ，得到8（9） - 甲酰基三环[5.2.1.0 2,6]癸-3-烯，并在第二加氢甲酰化阶段，由此得到的8（9） - 甲酰三环 在元素周期表第Ⅷ族过渡金属化合物存在下，在均相有机相中，将[5.2.1.0]癸-3-烯转化为3（4） ，8（9） - 二甲基三环[5.2.1.0 2,6]癸烷
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19.发明申请Catalytic process for preparing aliphatic straight-chain and beta-alkyl-branched carboxylic acids 有权用于制备脂族直链和β-烷基支链羧酸的催化方法公开(公告)号：US20070265467A1
公开(公告)日：2007-11-15
申请号：US11787868
申请日：2007-04-18
Applicant: Helmut Springer
Inventor： Helmut Springer
IPC: C07C51/235 , C07C51/16
CPC classification number: C07C51/235 , C07C53/126
Abstract: A catalytic process for preparing aliphatic straight-chain and β-alkyl-branched carboxylic acids of 5 to 13 carbon atoms by catalytic oxidation of the corresponding aldehydes by means of oxygen or oxygen-containing gas mixtures in the liquid phase in the presence of a catalyst system contains alkali metal carboxylates or alkaline earth metal carboxylates or a mixture thereof in an amount, calculated as alkali metal or alkaline earth metal, of 0.5 mmol to 15 mmol per mol of aldehyde used and also metals of groups 4 to 12 of the Periodic Table of the Elements, cerium or lanthanum in amounts of not more than 5 ppm, based on the aldehyde used, or compounds of such metals, with the catalyst system being the reaction product from an aldehyde oxidation reaction.
Abstract translation: 通过在催化剂存在下通过含氧或含氧气体混合物在液相中催化氧化相应的醛来制备5至13个碳原子的脂肪族直链和β-烷基支链羧酸的催化方法 系统含有碱金属羧酸盐或碱土金属羧酸盐或其混合物，其用量为碱金属或碱土金属，其用量为每摩尔醛为0.5mmol至15mmol，以及周期表第4至12族的金属 的元素，铈或镧的量不大于5ppm，基于所使用的醛或这些金属的化合物，催化剂体系是醛醛氧化反应的反应产物。
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公开(公告)号：US20060058561A1
公开(公告)日：2006-03-16
申请号：US11184136
申请日：2005-07-19
Applicant: Helmut Springer
Inventor： Helmut Springer
IPC: C07C1/00
CPC classification number: C07C1/24 , C07C2527/053 , C07C11/04
Abstract: A process for dehydrating 2-methylpentanediol-2,4 to a mixture of 2-methyl-1,3-pentadiene and 4-methyl-1,3-pentadiene at elevated temperature in the presence of an acid catalyst using a polyglycol ether as a heat carrier, wherein a polyglycol ether containing from 80 to 100% by weight of a polyethylene glycol dimethyl ether of the formula CH3(OCH2CH2)nOCH3 where n=2-8 and from 0 to 20% by weight of a polyethylene glycol monomethyl ether of the formula CH3(OCH2CH2)nOH where n=2-8 based in each case on the total mass of polyglycol ether, is used.
Abstract translation: 在酸催化剂存在下，在升高的温度下将2-甲基戊二醇-2,4-脱水成2-甲基-1,3-戊二烯与4-甲基-1,3-戊二烯的混合物的方法，使用聚乙二醇醚作为 热载体，其中包含80至100重量％的式CH 3（OCH 2 CH 2）2的聚乙二醇二甲醚的聚乙二醇醚， 其中n = 2-8和0至20重量％的式CH 3的聚乙二醇单甲基醚， 其中n = 2-8，基于聚乙二醇醚的总质量，其中n = 2-8是（OCH 2 CH 2 CH 2） 用过的。
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