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    HYDROCRACKING PROCESS USING A ZEOLITE MODIFIED BY BASIC TREATMENT
    11.
    发明申请
    HYDROCRACKING PROCESS USING A ZEOLITE MODIFIED BY BASIC TREATMENT 有权
    使用通过基础处理改性的沸石的水解工艺

    公开(公告)号：US20130090233A1

    公开(公告)日：2013-04-11

    申请号：US13684264

    申请日：2012-11-23

    Applicant: IFP ENERGIES NOUVELLES

    Inventor： Laurent SIMON ,  Emmanuelle GUILLON

    IPC: C01B39/00 ,  B01J29/16 ,  B01J29/14

    CPC classification number: C01B39/00 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/40 ,  C10G45/08 ,  C10G45/12 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/1007 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/04

    Abstract: The present invention describes a hydrocracking and/or hydrotreatment process using a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component selected from the group VIB elements and the non-precious elements of group VIII of the periodic table, used alone or in a mixture, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminium between 2.5 and 20, an initial weight fraction of extra-lattice aluminium atoms greater than 10%, relative to the total weight of aluminium present in the zeolite, an initial mesopore volume measured by nitrogen porosimetry greater than 0.07 ml·g−1 and an initial crystal lattice parameter a0 between 24.38 Å and 24.30 Å, said zeolite being modified by a) a stage of basic treatment comprising mixing said dealuminated zeolite Y with a basic aqueous solution, and at least one stage c) of thermal treatment.

    Abstract translation: 本发明描述了使用催化剂的加氢裂化和/或加氢处理方法，所述催化剂包含活性相，所述活性相含有至少一种选自元素周期表中VIB族元素和VIII族非贵金属的氢化/脱氢组分， 混合物和包含至少一种脱铝沸石Y的载体，其具有2.5至20的硅与铝的总初始原子比，相对于铝的总重量，超晶格铝原子的初始重量分数大于10％ 存在于沸石中，通过氮气孔隙度法测量的初始中孔体积大于0.07ml·g -1，初始晶格参数a0在24.38埃至24.30埃之间，所述沸石通过以下步骤进行修饰：a）碱性处理阶段，包括将所述 用碱性水溶液脱铝沸石Y和至少一个热处理阶段c）。

    METHOD FOR HYDROCRACKING HYDROCARBON FEEDSTOCKS USING A CATALYST COMPRISING A ZEOLITE AND AN AMORPHOUS MESOPOROUS ALUMINA
    13.
    发明申请
    METHOD FOR HYDROCRACKING HYDROCARBON FEEDSTOCKS USING A CATALYST COMPRISING A ZEOLITE AND AN AMORPHOUS MESOPOROUS ALUMINA 审中-公开

    公开(公告)号：US20180362861A1

    公开(公告)日：2018-12-20

    申请号：US16060069

    申请日：2016-11-16

    Applicant: IFP ENERGIES NOUVELLES

    Inventor： Malika BOUALLEG ,  Antoine DAUDIN ,  Emmanuelle GUILLON

    IPC: C10G47/20 ,  B01J21/04 ,  B01J29/08 ,  B01J29/16 ,  B01J37/00 ,  B01J37/03 ,  B01J37/08

    Abstract: The present invention describes a process for hydrocracking at least one hydrocarbon feed in which at least 50% by weight of the compounds have an initial boiling point of more than 300° C. and a final boiling point of less than 540° C. using at least one catalyst comprising at least one metal from group VIB and/or at least one metal from group VIII of the periodic classification of the elements and a support comprising at least one zeolite containing at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms (12MR), and at least one binder, said support being prepared from a highly dispersible alumina gel, said hydrocracking process being operated at a temperature in the range 200° C. to 480° C., at a total pressure in the range 1 MPa to 25 MPa, with a ratio of the volume of hydrogen to the volume of hydrocarbon feed in the range 80 to 5000 litres per litre and with an hourly space velocity (HSV), defined as the ratio of the volume flow rate of liquid hydrocarbon feed to the volume of catalyst charged into the reactor, in the range 0.1 to 50 h−1.

    PROCESS FOR ISOMERIZING AN AROMATIC C8 CUT IN THE PRESENCE OF A CATALYST BASED ON AN EUO ZEOLITE AND A PARTICULAR SODIUM CONTENT
    15.
    发明申请
    PROCESS FOR ISOMERIZING AN AROMATIC C8 CUT IN THE PRESENCE OF A CATALYST BASED ON AN EUO ZEOLITE AND A PARTICULAR SODIUM CONTENT 有权
    基于EUO ZEOLITE和特定钠含量的催化剂存在下的异构C8切割的方法

    公开(公告)号：US20140135550A1

    公开(公告)日：2014-05-15

    申请号：US14077242

    申请日：2013-11-12

    Applicant: IFP Energies nouvelles

    Inventor： Emmanuelle GUILLON ,  Laure BRANDHORST

    IPC: C07C5/27

    CPC classification number: C07C5/2775 ,  B01J21/04 ,  B01J23/42 ,  B01J23/44 ,  B01J23/58 ,  B01J29/7446 ,  B01J37/0009 ,  C07C2521/04 ,  C07C2529/74 ,  Y02P20/52 ,  C07C15/08

    Abstract: A process for isomerizing an aromatic cut containing at least one aromatic compound containing eight carbon atoms per molecule, which includes bringing the aromatic cut into contact with a catalyst containing a zeolite with structure type EUO, which catalyst has been prepared by obtaining a zeolite with structure type EUO having an overall Si/Al atomic ratio in the range 5 to 45, a sodium content in the range 500 to 5000 ppm by weight, with a Na/Al ratio in the range 5% to 20% by mole, and thereafter performing the following: i) preparing a support by shaping the zeolite with a matrix such that the zeolite content is in the range 8% to 15% by weight with respect to the support; ii) depositing at least one metal from group VIII of the periodic classification of the elements onto the support or onto the zeolite; wherein the catalyst contains a final sodium content of 75 to 600 ppm by weight.

    Abstract translation: 异构化含有至少一种每分子含有8个碳原子的芳香族化合物的芳香族馏分的方法，其中包括使芳族切割与含有结构型EUO的沸石的催化剂接触，该催化剂是通过获得具有结构的沸石 具有5至45的整体Si / Al原子比的铝型EUO，钠含量在500至5000重量ppm的范围内，Na / Al比在5％至20摩尔％的范围内，然后进行 以下：i）通过使基质形成沸石来制备载体，使得沸石含量相对于载体为8重量％至15重量％; ii）将元素周期性分类的VIII族中的至少一种金属沉积到载体上或沸石上; 其中所述催化剂含有最终的钠含量为75至600重量ppm。

    PROCESS FOR CONVERSION OF PARAFFINIC FEEDSTOCKS OBTAINED FROM THE BIOMASS OF MIDDLE DISTILLATE BASES EMPLOYING AT LEAST ONE IZM-2 ZEOLITE-BASED CATALYST
    16.
    发明申请
    PROCESS FOR CONVERSION OF PARAFFINIC FEEDSTOCKS OBTAINED FROM THE BIOMASS OF MIDDLE DISTILLATE BASES EMPLOYING AT LEAST ONE IZM-2 ZEOLITE-BASED CATALYST 有权
    使用至少一种基于IZM-2沸石的催化剂从中间馏分物质生物量中获得的分离进料的方法

    公开(公告)号：US20130165730A1

    公开(公告)日：2013-06-27

    申请号：US13723580

    申请日：2012-12-21

    Applicant: IFP Energies Nouvelles

    Inventor： Christophe BOUCHY ,  Emmanuelle GUILLON ,  Filipe Manuel MARQUES MOTA

    IPC: C07C5/22

    CPC classification number: C07C5/226 ,  B01J29/72 ,  B01J29/74 ,  B01J29/78 ,  B01J2229/20 ,  B01J2229/42 ,  C10G3/46 ,  C10G3/47 ,  C10G45/62 ,  C10G45/64 ,  Y02P30/20

    Abstract: The invention relates to a process for conversion of a paraffinic feedstock that has a number of carbon atoms of between 9 and 25, whereby said paraffinic feedstock is produced starting from renewable resources, employing a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, taken by themselves or in a mixture, and a substrate that comprises at least one IZM-2 zeolite and at least one binder, with said process being carried out at a temperature of between 150 and 500° C., at a pressure of between 0.1 MPa and 15 MPa, at an hourly volumetric flow rate of between 0.1 and 10 h−1, and in the presence of a total quantity of hydrogen mixed with the feedstock such that the hydrogen/feedstock ratio is between 70 and 2,000 Nm3/m3 of feedstock.

    Abstract translation: 本发明涉及一种转化石蜡原料的方法，该方法具有9至25个碳原子，其中所述链烷烃原料是从可再生资源开始生产的，该催化剂包含至少一种氢化脱氢金属 选自由本身或混合物中的VIB族和VIII族的金属形成的基团，以及包含至少一种IZM-2沸石和至少一种粘合剂的基材，所述方法 在0.1〜15MPa的压力下，以0.1〜10h -1的小时体积流量，在150〜500℃的温度下进行，在总量为 氢气与原料混合，使氢/原料比为70至2,000 Nm3 / m3的原料。

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