公开(公告)号：US20130180886A1

公开(公告)日：2013-07-18

申请号：US13723616

申请日：2012-12-21

Applicant: TOTAL RAFFINAGE MARKETING ,  IFP ENERGIES NOUVELLES

Inventor： Laurent SIMON ,  Bertrand GUICHARD ,  Gregory LAPISARDI ,  Hugues DULOT ,  Valentina DE GRANDI ,  Delphine MINOUX ,  Jean Pierre DATH

IPC: B01J31/34 ,  C10G47/20

CPC classification number: B01J31/34 ,  B01J27/188 ,  B01J27/19 ,  B01J29/064 ,  B01J29/076 ,  B01J29/166 ,  B01J29/7815 ,  B01J31/0209 ,  B01J31/04 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J2229/42 ,  C10G47/20

Abstract: The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VIB and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm−1, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm−1.The invention also concerns the process for preparing the catalyst and its use in hydroconversion.

Abstract translation: 本发明涉及一种含有载体的催化剂，其包括至少一种粘合剂和至少一种沸石，该沸石具有至少一个通道，其开口由含有12个氧原子的环所限定，所述催化剂包含磷，至少一个C 1 -C 4 琥珀酸二烷基酯，乙酸和氢化脱氢功能，其包含来自VIB族的至少一种元素和来自VIII族的至少一种元素，催化剂的拉曼光谱包含990和/或974cm -1处的带，其特征在于至少一个Keggin 杂多阴离子，所述琥珀酸的特征带和乙酸的特征主带在896cm -1。 本发明还涉及制备催化剂的方法及其在加氢转化中的用途。

公开(公告)号：US20130090233A1

公开(公告)日：2013-04-11

申请号：US13684264

申请日：2012-11-23

Applicant: IFP ENERGIES NOUVELLES

Inventor： Laurent SIMON ,  Emmanuelle GUILLON

IPC: C01B39/00 ,  B01J29/16 ,  B01J29/14

CPC classification number: C01B39/00 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/40 ,  C10G45/08 ,  C10G45/12 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/1007 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/04

Abstract: The present invention describes a hydrocracking and/or hydrotreatment process using a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component selected from the group VIB elements and the non-precious elements of group VIII of the periodic table, used alone or in a mixture, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminium between 2.5 and 20, an initial weight fraction of extra-lattice aluminium atoms greater than 10%, relative to the total weight of aluminium present in the zeolite, an initial mesopore volume measured by nitrogen porosimetry greater than 0.07 ml·g−1 and an initial crystal lattice parameter a0 between 24.38 Å and 24.30 Å, said zeolite being modified by a) a stage of basic treatment comprising mixing said dealuminated zeolite Y with a basic aqueous solution, and at least one stage c) of thermal treatment.

Abstract translation: 本发明描述了使用催化剂的加氢裂化和/或加氢处理方法，所述催化剂包含活性相，所述活性相含有至少一种选自元素周期表中VIB族元素和VIII族非贵金属的氢化/脱氢组分， 混合物和包含至少一种脱铝沸石Y的载体，其具有2.5至20的硅与铝的总初始原子比，相对于铝的总重量，超晶格铝原子的初始重量分数大于10％ 存在于沸石中，通过氮气孔隙度法测量的初始中孔体积大于0.07ml·g -1，初始晶格参数a0在24.38埃至24.30埃之间，所述沸石通过以下步骤进行修饰：a）碱性处理阶段，包括将所述 用碱性水溶液脱铝沸石Y和至少一个热处理阶段c）。

公开(公告)号：US20190185768A1

公开(公告)日：2019-06-20

申请号：US16225738

申请日：2018-12-19

Applicant: IFP Energies nouvelles

Inventor： Thibaut CORRE ,  Alberto SILVA SERVIA ,  Laurent SIMON ,  Frederic BAZER-BACHI

IPC: C10G69/04 ,  C10G45/08 ,  C10G11/18 ,  C10G11/02 ,  B01J23/882

CPC classification number: C10G69/04 ,  B01J23/882 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  C10G11/02 ,  C10G11/18 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/70 ,  C10G2300/703

Abstract: A method for hydrotreatment of a vacuum-distillate-type hydrocarbon feedstock that contains sulfur and nitrogen compounds is described, with said method for hydrotreatment of a vacuum-distillate-type feedstock comprising a specific concatenation of catalysts that makes it possible to increase the overall activity and the overall stability of the method.

公开(公告)号：US20130165316A1

公开(公告)日：2013-06-27

申请号：US13720026

申请日：2012-12-19

Applicant: Total Raffinage Marketing ,  IFP Energies Nouvelles

Inventor： Bertrand GUICHARD ,  Laurent SIMON ,  Sylvie LOPEZ ,  Valentina DE GRANDI ,  Delphine MINOUX ,  Jean-Pierre DATH

IPC: B01J31/34 ,  C07C5/10 ,  C10G45/12

CPC classification number: B01J37/0205 ,  B01J21/04 ,  B01J23/24 ,  B01J23/28 ,  B01J23/85 ,  B01J23/882 ,  B01J23/90 ,  B01J27/14 ,  B01J27/19 ,  B01J29/076 ,  B01J31/0201 ,  B01J31/0209 ,  B01J35/002 ,  B01J37/0203 ,  B01J37/20 ,  B01J37/28 ,  B01J38/52 ,  B01J38/62 ,  C07C5/10 ,  C07C2601/14 ,  C10G45/08 ,  C10G45/50 ,  Y02P20/584 ,  C07C13/18

Abstract: A process for the preparation of a catalyst from a catalytic precursor comprising a support based on alumina and/or silica-alumina and/or zeolite and comprising at least one element of group VIB and optionally at least one element of group VIII, by impregnation of said precursor with a solution of a C1-C4 dialkyl succinate. An impregnation step for impregnation of said precursor which is dried, calcined or regenerated, with at least one solution containing at least one carboxylic acid other than acetic acid, then maturing and drying at a temperature less than or equal to 200° C., optionally a heat treatment at a temperature lower than 350° C., followed by an impregnation step with a solution containing at least one C1-C4 dialkyl succinate followed by maturing and drying at a temperature less than 200° C. without subsequent calcination step. The catalyst is used in hydrotreatment and/or hydroconversion.

Abstract translation: 一种从催化前体制备催化剂的方法，其包含基于氧化铝和/或二氧化硅 - 氧化铝和/或沸石的载体，并且包含至少一种VIB族元素和任选的至少一种VIII族元素，通过浸渍 所述前体与C1-C4二烷基琥珀酸酯的溶液。 浸渍步骤，用于用至少一种含有至少一种不同于乙酸的羧酸的溶液干燥，煅烧或再生的所述前体浸渍，然后在小于或等于200℃的温度下熟化和干燥，任选地 在低于350℃的温度下进行热处理，随后用含有至少一种C 1 -C 4二烷基琥珀酸酯的溶液进行浸渍步骤，然后在低于200℃的温度下熟化和干燥，而无需随后的煅烧步骤。 催化剂用于加氢处理和/或加氢转化。