Ionic liquid based mixtures for gas storage and delivery
    11.
    发明授权
    Ionic liquid based mixtures for gas storage and delivery 有权
    用于气体储存和输送的离子液体基混合物

    公开(公告)号:US07404845B2

    公开(公告)日:2008-07-29

    申请号:US10948277

    申请日:2004-09-23

    IPC分类号: B01D19/00 F17C11/00

    摘要: A mixture and method for the storage and delivery of at least one gas are disclosed herein. In one aspect, there is provided a mixture for the storage and delivery of at least one gas comprising: an ionic liquid comprising an anion and a cation; and at least one gas that is disposed within and is reversibly chemically reacted with the ionic liquid. In another aspect, there is provided a method for delivering at least one gas from a mixture comprising an ionic liquid and at least one gas comprising: reacting the at least one gas and the ionic liquid to provide the mixture and separating the at least one gas from the mixture wherein the at least one gas after the separating step is substantially the same as the at least one gas prior to the reacting step.

    摘要翻译: 本文公开了用于储存和输送至少一种气体的混合物和方法。 在一个方面,提供了用于储存和输送至少一种气体的混合物,其包括:包含阴离子和阳离子的离子液体; 以及至少一种气体,其设置在离子液体内并与其离子液体可逆地化学反应。 在另一方面,提供了一种从包含离子液体和至少一种气体的混合物输送至少一种气体的方法,包括:使至少一种气体和离子液体反应以提供混合物并将至少一种气体 从其中在分离步骤之后的至少一种气体与反应步骤之前的至少一种气体基本上相同的混合物。

    Method for removing titanium dioxide deposits from a reactor
    12.
    发明授权
    Method for removing titanium dioxide deposits from a reactor 失效
    从反应器中除去二氧化钛沉积物的方法

    公开(公告)号:US07267842B2

    公开(公告)日:2007-09-11

    申请号:US10800880

    申请日:2004-03-15

    IPC分类号: C23C16/00 H05H1/24

    摘要: A process for the selective removal of a TiO2-containing substance from an article for cleaning applications is disclosed herein. In one embodiment, there is provided a process for removing a TiO2-containing substance from an article comprising: providing the article having the TiO2-containing substance deposited thereupon; reacting the substance with a reactive gas comprising at least one selected from a fluorine-containing cleaning agent, a chlorine-containing cleaning agent and mixtures thereof to form a volatile product; and removing the volatile product from the article to thereby remove the substance from the article.

    摘要翻译: 本文公开了用于从用于清洁应用的制品中选择性除去含TiO 2的物质的方法。 在一个实施方案中,提供了从制品中除去含TiO 2的物质的方法,包括:提供其上沉积有含TiO 2的物质的制品; 使物质与包含选自含氟清洗剂,含氯清洗剂及其混合物中的至少一种的反应性气体反应以形成挥发性产物; 并从制品中除去挥发性产物,从而从制品中除去物质。

    Process for purifying fluoroxy compounds
    13.
    发明授权
    Process for purifying fluoroxy compounds 失效
    氟氧化合物的纯化方法

    公开(公告)号:US07002040B2

    公开(公告)日:2006-02-21

    申请号:US10353211

    申请日:2003-01-28

    IPC分类号: C07C53/00 C07C55/00

    CPC分类号: B01D53/02 C07C71/00

    摘要: This invention relates generally to a improvement in a process for the purification of fluoroxy compounds, such as bis(fluoroxy)difluoromethane and fluoroxytrifluoromethane produced by the fluorination of carbon oxides. The improvement in effecting purification of the fluoroxy compounds is effected by initially selectively removing the fluorine by contacting with a crystalline zeolite and then removing the carbon oxide by selective adsorption.

    摘要翻译: 本发明一般涉及氟化合物如二(氟氧基)二氟甲烷和通过氟化氧化碳生产的氟氧三氟甲烷的纯化方法的改进。 通过首先通过与结晶沸石接触选择性除去氟化物,然后通过选择性吸附除去碳氧化物来实现氟氧化合物的纯化的改进。

    Wick systems for complexed gas technology
    14.
    发明授权
    Wick systems for complexed gas technology 失效
    复合气体技术的芯片系统

    公开(公告)号:US07648682B2

    公开(公告)日:2010-01-19

    申请号:US11743925

    申请日:2007-05-03

    IPC分类号: B01D50/00 B01D53/02 B01D19/00

    CPC分类号: F17C11/00 Y10T137/0396

    摘要: The invention relates to an improvement in apparatus and process for effecting storage and delivery of a gas. The storage and delivery apparatus is comprised of a storage and dispensing vessel containing a medium capable of storing a gas and permitting delivery of the gas stored in the medium from the vessel, the improvement comprising: (a) a reactive liquid having Lewis acidity or basicity; (b) a gas liquid complex in a reversible reacted state formed under conditions of pressure and temperature by contacting the gas having Lewis acidity with the reactive liquid having Lewis basicity or the gas having Lewis basicity with the reactive liquid having Lewis acidity; (c) a non-reactive wick medium holding and dispersing the reactive liquid and the gas liquid complex therein.

    摘要翻译: 本发明涉及用于实现气体的储存和输送的设备和方法的改进。 储存和输送装置由储存和分配容器组成,储存和分配容器含有能够储存气体并允许从容器中输送存储在介质中的气体的介质,其改进包括:(a)具有路易斯酸度或碱度的反应性液体 ; (b)在压力和温度条件下通过使具有路易斯酸度的气体与具有路易斯碱性的反应性液体或具有路易斯碱性的气体与具有路易斯酸度的反应性液体接触而形成的可逆反应状态的气液络合物; (c)保持并分散其中的反应性液体和气体液体络合物的非反应性芯吸介质。

    Ionic liquid based mixtures for gas storage and delivery
    15.
    发明授权
    Ionic liquid based mixtures for gas storage and delivery 失效
    用于气体储存和输送的离子液体基混合物

    公开(公告)号:US07563308B2

    公开(公告)日:2009-07-21

    申请号:US11208723

    申请日:2005-08-23

    IPC分类号: B01D19/00 F17C11/00

    摘要: A mixture and method for the storage and delivery of a gas are disclosed herein. In one aspect, there is provided a mixture comprising: an ionic liquid comprising an anion and a cation, at least a portion of the gas that is disposed within and reversibly chemically reacted with the ionic liquid, and optionally an unreacted gas. In another aspect, there is provided a method for delivering a gas from a mixture comprising an ionic liquid and one or more gases comprising: reacting at least a portion of the gas with the ionic liquid to provide the mixture comprising a chemically reacted gas and an ionic liquid and separating the chemically reacted gas from the mixture wherein the chemically reacted gas after the separating step has substantially the same chemical identity as the chemically reacted gas prior to the reacting step.

    摘要翻译: 本文公开了用于储存和输送气体的混合物和方法。 在一个方面,提供了一种混合物,其包含:包含阴离子和阳离子的离子液体,所述气体的至少一部分设置在离子液体内并可逆地与离子液体化学反应,以及任选的未反应气体。 在另一方面,提供了一种从包含离子液体和一种或多种气体的混合物输送气体的方法,包括:使至少一部分气体与离子液体反应,以提供包含化学反应气体和 离子液体并且从混合物中分离化学反应的气体,其中分离步骤之后的化学反应气体在反应步骤之前具有与化学反应气体基本上相同的化学同一性。

    Method for depositing zinc oxide at low temperatures and products formed thereby
    18.
    发明授权
    Method for depositing zinc oxide at low temperatures and products formed thereby 有权
    低温沉积氧化锌的方法及由此形成的产品

    公开(公告)号:US08197914B2

    公开(公告)日:2012-06-12

    申请号:US11284193

    申请日:2005-11-21

    IPC分类号: H05H1/24

    摘要: The present invention discloses plasma enhanced chemical vapor deposition (PECVD) process for depositing n-type and p-type zinc oxide-based transparent conducting oxides (TCOs) at low temperatures with excellent optical and electrical properties on glass and temperature sensitive materials such as plastics and polymers. Specifically, it discloses PECVD process for depositing n-type ZnO by doping it with B or F and p-type ZnO by doping it with nitrogen excellent optical and electrical properties on glass and temperature sensitive materials such as plastics and polymers for TCO application. The process utilizes a mixture of volatile zinc compound, argon and/or helium as a diluent gas, carbon dioxide as an oxidant, and a dopant or reactant to deposit the desired ZnO-based TCOs.

    摘要翻译: 本发明公开了一种用于在低温下沉积n型和p型氧化锌基透明导电氧化物(TCO)的等离子体增强化学气相沉积(PECVD)工艺,在玻璃和温度敏感材料如塑料上具有优异的光学和电学性能 和聚合物。 具体地说,它公开了用于通过用B或F和p型ZnO掺杂以将氮掺杂在玻璃上的优异的光学和电学性质以及用于TCO应用的诸如塑料和聚合物的温度敏感材料来沉积n型ZnO的PECVD工艺。 该方法利用挥发性锌化合物,氩和/或氦气作为稀释气体,二氧化碳作为氧化剂和掺杂剂或反应物的混合物以沉积所需的ZnO基TCO。

    Recovery of NF3 from Adsorption Operation
    19.
    发明申请
    Recovery of NF3 from Adsorption Operation 有权
    从吸附操作中回收NF3

    公开(公告)号:US20110100209A1

    公开(公告)日:2011-05-05

    申请号:US12760843

    申请日:2010-04-15

    IPC分类号: B01D53/04

    摘要: During the conventional temperature swing adsorption (TSA) process, NF3 co-adsorbed with the impurities is vented during regeneration. This invention is a novel TSA cycle in which the co-adsorbed NF3 is recovered. In this novel TSA cycle, a control scheme is used to stop the adsorption prior to the saturation of the adsorber with impurities and use a recovery purge gas (either co-current or counter-current) to release the co-adsorbed NF3 off the saturated adsorber. The effluent of the inert purge gas can be combined with the effluent of the on-stream vessel or can be recycled to the feed of the on-stream vessel. 10%-100% of the co-adsorbed NF3 is recovered and made available as product in this novel TSA cycle. Thus the overall process yield of NF3 is increased. The removing of the co-adsorbed NF3 from the adsorber also prevents adsorber degradation thus prolonging the useful life of the adsorber.

    摘要翻译: 在传统的变温吸附(TSA)过程中,在再生期间与杂质共吸附的NF3被排出。 本发明是一种新的TSA循环,其中回收了共吸附的NF3。 在这种新的TSA循环中,使用控制方案在吸附剂饱和之前停止吸附,并使用回收吹扫气体(或者是电流或逆流)来释放饱和吸附的NF3。 吸附剂。 惰性吹扫气体的流出物可以与流动容器的流出物组合,或者可以再循环到流动容器的进料中。 共同吸附的NF3的10%-100%被回收,并在本新型TSA循环中作为产品获得。 因此,NF3的整体加工产率增加。 从吸附器除去共吸附的NF3也可以防止吸附剂的降解,从而延长吸附器的使用寿命。

    Ionic Liquid Based Mixtures For Gas Storage and Delivery
    20.
    发明申请
    Ionic Liquid Based Mixtures For Gas Storage and Delivery 有权
    用于气体储存和输送的离子液体混合物

    公开(公告)号:US20090272938A1

    公开(公告)日:2009-11-05

    申请号:US12493751

    申请日:2009-06-29

    IPC分类号: H01J7/18

    摘要: A mixture and method for the storage and delivery of a gas are disclosed herein. In one aspect, there is provided a mixture comprising: an ionic liquid comprising an anion and a cation, at least a portion of the gas that is disposed within and reversibly chemically reacted with the ionic liquid, and optionally an unreacted gas. In another aspect, there is provided a method for delivering a gas from a mixture comprising an ionic liquid and one or more gases comprising: reacting at least a portion of the gas with the ionic liquid to provide the mixture comprising a chemically reacted gas and an ionic liquid and separating the chemically reacted gas from the mixture wherein the chemically reacted gas after the separating step has substantially the same chemical identity as the chemically reacted gas prior to the reacting step.

    摘要翻译: 本文公开了用于储存和输送气体的混合物和方法。 在一个方面,提供了一种混合物,其包含:包含阴离子和阳离子的离子液体,所述气体的至少一部分设置在离子液体内并可逆地与离子液体化学反应,以及任选的未反应气体。 在另一方面,提供了一种从包含离子液体和一种或多种气体的混合物输送气体的方法,包括:使至少一部分气体与离子液体反应,以提供包含化学反应气体和 离子液体并且从混合物中分离化学反应的气体,其中分离步骤之后的化学反应气体在反应步骤之前具有与化学反应气体基本上相同的化学同一性。