Low-viscosity allophanates containing actinically curable groups
    11.
    发明授权
    Low-viscosity allophanates containing actinically curable groups 有权
    含有光化固化基团的低粘度脲基甲酸酯

    公开(公告)号:US07361723B2

    公开(公告)日:2008-04-22

    申请号:US11080706

    申请日:2005-03-14

    摘要: A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.

    摘要翻译: 一种制备含有脲基甲酸酯基团的粘合剂的方法,其在通过两个单键键合的脲基甲酸酯基的氧原子上含有具有活化基团的活性基团,所述活性基团在与光化辐射接触时可与烯属不饱和化合物进行聚合反应; 该方法包括使A)一种或多种含有脲二酮基团的化合物与B)一种或多种OH官能化合物,其含有能够在暴露于光化辐射下与烯键式不饱和化合物进行聚合反应的基团,和C)任选地进一步的NCO- 活性化合物和D)在一种或多种含有酚氧化物的化合物的存在下作为催化剂。 粘合剂可用于制备涂料,涂料,涂料组合物,粘合剂,印刷油墨,浇铸树脂,牙科化合物,尺寸,光致抗蚀剂,立体光刻系统,复合材料和密封剂的树脂。

    Low-viscosity allophanates containing actinically curable groups
    12.
    发明授权
    Low-viscosity allophanates containing actinically curable groups 有权
    含有光化固化基团的低粘度脲基甲酸酯

    公开(公告)号:US07960446B2

    公开(公告)日:2011-06-14

    申请号:US12072022

    申请日:2008-02-22

    摘要: A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.

    摘要翻译: 一种制备含有脲基甲酸酯基团的粘合剂的方法,其在通过两个单键键合的脲基甲酸酯基的氧原子上含有具有活化基团的活性基团,所述活性基团在与光化辐射接触时可与烯属不饱和化合物进行聚合反应; 该方法包括使A)一种或多种含有脲二酮基团的化合物与B)一种或多种OH官能化合物,其含有能够在暴露于光化辐射下与烯键式不饱和化合物进行聚合反应的基团,和C)任选地进一步的NCO- 活性化合物和D)在一种或多种含有酚氧化物的化合物的存在下作为催化剂。 粘合剂可用于制备涂料,涂料,涂料组合物,粘合剂,印刷油墨,浇铸树脂,牙科化合物,尺寸,光致抗蚀剂,立体光刻系统,复合材料和密封剂的树脂。

    Self-crosslinking polyurethane dispersions and a process for their preparation
    14.
    发明申请
    Self-crosslinking polyurethane dispersions and a process for their preparation 审中-公开
    自交联聚氨酯分散体及其制备方法

    公开(公告)号:US20070004856A1

    公开(公告)日:2007-01-04

    申请号:US11475691

    申请日:2006-06-27

    IPC分类号: C08G18/08

    摘要: The present invention relates to a process for preparing self-crosslinking polyurethane dispersions by I) reacting a1) polyisocyanates with a2) at least one hydroxyl component having an average OH functionality of ≧2 and a number average molecular weight of 62 to 2500 g/mol, wherein the hydroxyl component contains at least one acid-functional compound containing at least one isocyanate-reactive group, to form an NCO-functional and optionally OH-functional prepolymer, II) then reacting the NCO-functional and optionally OH-functional prepolymer with a3) a hydroxyl component having an average OH functionality of >1 and a4) optionally another polyisocyanate component, which may be the same as or different from a1), to form an OH-functional and NCO-free polyurethane, III) adding a blocked polyisocyanate either before, during or after the reaction of steps I) and II), or forming a blocked polyisocyanate in situ from a polyisocyanate and a blocking agent after the reaction of step II) has taken place, IV) neutralizing the acid groups of the resulting composition by adding a5) a neutralizing agent, and V) dispersing the resulting composition in water. The present invention also relates to the dispersions prepared by the present invention and to their use in coating, adhesive and sealant compositions.

    摘要翻译: 本发明涉及一种制备自交联聚氨酯分散体的方法,其方法是使a1)多异氰酸酯与a2)至少一种平均OH官能度> = 2,数均分子量为62〜2500g / mol,其中所述羟基组分含有至少一种含有至少一个异氰酸酯反应性基团的酸官能化合物,以形成NCO-官能和任选的OH-官能预聚物,II)然后使所述NCO-官能和任选的OH-官能预聚物 其中a3)具有平均OH官能度> 1的羟基组分和a4)任选地可以与a1)相同或不同的另一种多异氰酸酯组分,以形成OH-官能和无NCO的聚氨酯,III)加入 在步骤I)和II)的反应之前,期间或之后封闭的多异氰酸酯,或在步骤II)的反应之后由多异氰酸酯和封闭剂原位形成封端多异氰酸酯具有ta 呃地方,IV)通过添加a)中和剂中和所得组合物的酸基,和V)将得到的组合物分散在水中。 本发明还涉及由本发明制备的分散体及其在涂料,粘合剂和密封剂组合物中的用途。

    Aqueous coatings for food containers
    16.
    发明申请
    Aqueous coatings for food containers 审中-公开
    食品容器用水性涂料

    公开(公告)号:US20060149019A1

    公开(公告)日:2006-07-06

    申请号:US11301622

    申请日:2005-12-13

    IPC分类号: C08G18/00

    摘要: The present invention relates to aqueous coating compositions containing A) at least one polyisocyanate which contains an average of at least two NCO groups per molecule and in which at least 85% of the NCO groups are blocked with a blocking agent selected from ε-caprolactam and/or a hydroxycarboxylic acid, and B) at least one hydrophilic polyester polyol containing an average of at least two reactive hydroxyl groups per molecule, or a mixture of hydrophilic and non-hydrophilic polyester polyols, wherein component B) has an acid number of ≧15 mg KOH/g, a hydroxyl number of 20 to 300 mg KOH/g and a weight average molecular weight, Mw, of >1500 g/mol, wherein the equivalent ratio between the blocked isocyanate groups of component A) and the isocyanate-reactive groups of component B) is 0.5 to 5.0:1. The present invention also relates to a process for preparing these aqueous coating compositions, to coatings obtained from these aqueous coating compositions, particularly coatings for packaging and for the interior of cans.

    摘要翻译: 本发明涉及包含A)至少一种多异氰酸酯的水性涂料组合物,其每分子含有平均至少两个NCO基团,其中至少85%的NCO基团用封闭剂封闭,所述封闭剂选自ε-己内酰胺和 /或羟基羧酸,和B)至少一种含有每分子平均至少两个反应性羟基的亲水性聚酯多元醇,或亲水性和非亲水性聚酯多元醇的混合物,其中组分B)的酸值> = 15mg KOH / g,羟值为20-300mg KOH / g,重均分子量M w> 1500g / mol,其中封端异氰酸酯之间的当量比 组分A)和组分B)的异氰酸酯反应性基团为0.5至5.0:1。 本发明还涉及一种制备这些水性涂料组合物的方法,由这些水性涂料组合物获得的涂料,特别是用于包装的涂料和罐内部。