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    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
    11.
    发明授权
    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process 有权
    在烯烃聚合中的茂金属催化剂的活化剂固体载体，制备这种载体的方法以及相应的催化体系和聚合方法

    公开(公告)号：US06605561B1

    公开(公告)日：2003-08-12

    申请号：US09822840

    申请日：2001-04-02

    Applicant: Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    Inventor： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    IPC: B01J3116

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F110/02 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/025 ,  C08F4/65916

    Abstract: Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminium and/or magnesium Lewis-acid sites of formula: or —Mg—F, the groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.

    Abstract translation: 在烯烃聚合中作为催化剂的金属茂的活化剂固体支持物，其特征在于它由一组由至少一种多孔矿物氧化物形成的固体催化组分的载体颗粒组成，所述颗粒已被修饰以便 在表面上携带式：或-Mg-F的铝和/或镁路易斯酸位点，来自与由载体的基础颗粒携带的-OH自由基反应的官能化试剂的基团，官能化反应已经 随后进行氟化反应。 根据本发明的催化体系包括（a）茂金属催化剂，如果需要，其进行预烷基化处理; （b）助催化剂; 如上所述，如果茂金属催化剂（a）已经被烷基化，则助催化剂（b）可能不存在，而且（c）金属茂的活化剂固体载体。

    Catalytic component and its use in olefin polymerization
    12.
    发明授权
    Catalytic component and its use in olefin polymerization 失效
    催化组分及其在烯烃聚合中的应用

    公开(公告)号：US06433108B1

    公开(公告)日：2002-08-13

    申请号：US09505968

    申请日：2000-02-17

    Applicant: Jean Malinge ,  Claude Brun ,  Jean-Loup Lacombe

    Inventor： Jean Malinge ,  Claude Brun ,  Jean-Loup Lacombe

    IPC: C08F402

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6555 ,  C08F4/6546 ,  C08F2500/07 ,  C08F2500/04 ,  C08F210/14

    Abstract: The invention relates to a process for the manufacture of a solid catalytic component for the polymerization or copolymerization of olefins, resulting in a polymer or copolymer with broadened molecular mass distribution. The process includes a first stage including bringing into contact a) a solid support including at its surface at least 5 hydroxyl groups per square nanometre (OH/nm2) and b) an organic magnesium derivative, and optionally, preferably, c) an aluminoxane, to obtain a first solid, and then a second stage including bringing the first solid and a chlorinating agent into contact to obtain a second solid and then, in a later stage, impregnation of the second solid with a transition metal derivative.

    Abstract translation: 本发明涉及制备用于烯烃聚合或共聚的固体催化剂组分的方法，产生具有扩大分子量分布的聚合物或共聚物。 该方法包括使第一阶段包括接触）固体支持物，其表面包括每平方毫米至少5个羟基（OH / nm 2）和b）有机镁衍生物，和任选地优选c）铝氧烷，以获得 第一固体，然后包括使第一固体和氯化剂接触以获得第二固体，然后在稍后阶段中用过渡金属衍生物浸渍第二固体。

    Polybenzhydrol compositions ending with ethylenic unsaturated groups, cross-linked polymides resulting from their thermal polyermization and the use of said compositions
    15.
    发明授权
    Polybenzhydrol compositions ending with ethylenic unsaturated groups, cross-linked polymides resulting from their thermal polyermization and the use of said compositions 失效
    以乙烯基不饱和基团结束的聚二醇化合物组合物，由它们的热多化引起的交联聚酰亚胺和所述组合物的使用

    公开(公告)号：US4987218A

    公开(公告)日：1991-01-22

    申请号：US55287

    申请日：1987-05-29

    Applicant: Jean Malinge ,  Guy Rabilloud ,  Bernard Sillion

    Inventor： Jean Malinge ,  Guy Rabilloud ,  Bernard Sillion

    IPC: C08F299/02 ,  C08G73/10 ,  C08G73/12

    CPC classification number: C08G73/1078 ,  C08G73/10 ,  C08G73/101

    Abstract: Polymer compositions comprising poly(benzhydrolimide) chains ending with ethylenic unsaturated groups complying with the general formula: ##STR1## wherein Ar is a divalent aromatic radical and R a hydrogen atom or a monovalent hydrocarbon radical. They can be prepared by reacting, under imidation condition, at least one primary diamine with at least one benzydrol 3,3', 4,4'-tetracarboxylic acid, a bis (ortho-acid-ester) or a tetraester of such acid and with an anhydride, an acid-ester or a diester of dicarboxylic cycloaliphatic acid with ethylenic unsaturation. These compositions may be converted to cross-linked polymides by thermal polyemrization. They can be used in particular for manufacturing composite materials, adhesives, molded articles and protective coatings withstanding high temperatures.

    Abstract translation: 聚合物组合物包含以乙烯不饱和基团结束的聚（苯甲酰亚胺）链，其符合以下通式：其中Ar为二价芳族基团，R为氢原子或一价烃基。 它们可以通过在酰亚胺化条件下使至少一种伯二胺与至少一种苯并三氢呋喃3,3'，4,4'-四羧酸，这种酸的双（邻 - 酸酯）或四酯反应来制备，和 与酸酐，酸酯或具有烯属不饱和度的二羧酸脂环族酸的二酯。 这些组合物可以通过热聚合转化成交联聚酰亚胺。 它们可以特别用于制造复合材料，粘合剂，模制品和耐高温保护涂层。

    Precursor of copolyphthalocyanine-imide lattice, preparation, and the resultant lattice
    16.
    发明授权
    Precursor of copolyphthalocyanine-imide lattice, preparation, and the resultant lattice 失效
    共聚酞菁 - 酰亚胺晶格的前体，制备和所得的晶格

    公开(公告)号：US4645821A

    公开(公告)日：1987-02-24

    申请号：US758949

    申请日：1985-07-25

    Applicant: Jean Malinge ,  Guy Rabilloud ,  Bernard Sillion

    Inventor： Jean Malinge ,  Guy Rabilloud ,  Bernard Sillion

    IPC: C08G73/00 ,  C07D209/48 ,  C08G73/10 ,  C08G73/06

    CPC classification number: C07D209/48 ,  C08G73/10 ,  C08G73/1035

    Abstract: Aromatic polyimide compositions, precursors of copolyphthalocyanine-imides,heir manufacturing process and the resultant copolyphthalocyanine-imides, are described.These compositions may result for the reaction of 80.degree.-300.degree. C. of an aromatic tetra acid, diester-diacid, tetraester or dianhydride compound of formula: ##STR1## with an aromatic amino-dinitrile ##STR2## and optionally an aromatic diamine NH.sub.2 --Ar--NH.sub.2. A subsequent heating at 200.degree.-300.degree. C. provides, by cross-linking, copolyphthalocyanine-imides, which are hardened resins, stable at 250.degree.-300.degree. C. in continuous use.

    Abstract translation: 描述了芳族聚酰亚胺组合物，共聚酞菁 - 酰亚胺的前体，它们的制备方法和所得的共聚酞菁 - 酰亚胺。 这些组合物可能导致80-300℃的芳香族四酸，二酯 - 二酸，四酯或二酐化合物与芳香族氨基二腈和任选的芳族二胺NH 2 -Ar-NH2。 随后在200-300℃下加热，通过交联，共聚酞菁 - 酰亚胺，它们是硬化树脂，在250-300℃下连续使用时稳定。

    Method for copolymerization and resulting copolymers
    19.
    发明授权
    Method for copolymerization and resulting copolymers 失效
    共聚方法和所得共聚物

    公开(公告)号：US06730744B1

    公开(公告)日：2004-05-04

    申请号：US09937090

    申请日：2002-07-15

    Applicant: Guillaume Desurmont ,  Hajime Yasuda ,  Jean Malinge

    Inventor： Guillaume Desurmont ,  Hajime Yasuda ,  Jean Malinge

    IPC: C08F29708

    CPC classification number: C08F297/08 ,  C08F110/14 ,  C08F210/06 ,  C08F210/14 ,  C08F2500/15 ,  C08F210/16 ,  C08F220/06

    Abstract: The invention concerns a method for preparing block copolymers comprising steps which consist in: polymerising a first monomer using an organolanthanide catalyst wherein said catalyst in the form of a hydride complex of a trivalent metal from the group of rare earths; then in polymerising at least a second monomer. The invention also concerns block copolymers whereof the blocks are polyolefins.

    Abstract translation: 本发明涉及一种制备嵌段共聚物的方法，其包括以下步骤：使用有机镧系元素催化剂聚合第一单体，其中所述催化剂为来自稀土族的三价金属的氢化物络合物; 然后聚合至少一种第二单体。 本发明还涉及嵌段共聚物，其中嵌段是聚烯烃。

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