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    Oxidation of hydrocarbons
    11.
    发明授权
    Oxidation of hydrocarbons 有权
    碳氢化合物的氧化

    公开(公告)号：US08658836B2

    公开(公告)日：2014-02-25

    申请号：US12678419

    申请日：2008-10-08

    申请人： Francisco M. Benitez ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma ,  John Scott Buchanan ,  Jon E. Stanat

    发明人： Francisco M. Benitez ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma ,  John Scott Buchanan ,  Jon E. Stanat

    IPC分类号： C07C409/00

    CPC分类号： C07C409/08 ,  C07B41/00 ,  C07C37/07 ,  C07C37/08 ,  C07C37/20 ,  C07C45/33 ,  C07C45/53 ,  C07C51/313 ,  C07C407/00 ,  C07C409/04 ,  C07C409/10 ,  C07C409/14 ,  C07C2601/14 ,  C07C49/403 ,  C07C55/14 ,  C07C39/04 ,  C07C39/16

    摘要： In a process for oxidizing a hydrocarbon to the corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, a reaction medium comprising a hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N, and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3; and R3 can be any of the entities listed for R1. The contacting is conducted under conditions such as to maintain the concentration of both water and organic acids in the reaction medium below 50 ppm.

    摘要翻译： 在将烃类氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，将包含烃的反应介质与含氧气体在含有通式 （I）：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代烃基，或从SO 3 H，NH 2，OH和NO 2基团，或从原子H，F，Cl，Br和 我提供R1和R2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1〜3; 而R3可以是为R1列出的任何实体。 在使反应介质中的水和有机酸的浓度保持在50ppm以下的条件下进行接触。

    Oxidation of Hydrocarbons
    14.
    发明申请
    Oxidation of Hydrocarbons 有权
    碳氢化合物的氧化

    公开(公告)号：US20120149941A1

    公开(公告)日：2012-06-14

    申请号：US13386250

    申请日：2010-07-13

    申请人： Kun Wang ,  Jihad M. Dakka ,  Stephen Zushma

    发明人： Kun Wang ,  Jihad M. Dakka ,  Stephen Zushma

    IPC分类号： C07C407/00

    CPC分类号： C07C409/08 ,  C07C407/00 ,  C07C409/14 ,  C07C2601/14 ,  C07C409/10

    摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with at least one solid sorbent chosen from alkali metal carbonates, alkali metal bicarbonates, alkali metal hydroxides, alkali metal hydroxide-carbonate complexes, alkaline earth metal carbonates, alkaline earth metal bicarbonates, alkaline earth metal hydroxides and alkaline earth metal hydroxide-carbonate complexes to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.

    摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触： 其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1至3，R3可为R1列出的任何实体。 接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，流出物用至少一种选自碱金属碳酸盐，碱金属碳酸氢盐，碱金属氢氧化物，碱金属氢氧化物 - 碳酸盐的固体吸附剂处理 络合物，碱土金属碳酸盐，碱土金属碳酸氢盐，碱土金属氢氧化物和碱土金属氢氧化物 - 碳酸盐络合物，以去除至少部分未反应的酰亚胺催化剂并产生包含所述氧化的烃产物的经处理的流出物。 然后可以回收有机相。

    Process For Producing Phenol
    15.
    发明申请
    Process For Producing Phenol 有权
    生产苯酚的方法

    公开(公告)号：US20110301387A1

    公开(公告)日：2011-12-08

    申请号：US13143975

    申请日：2010-01-25

    申请人： Kun Wang ,  Francisco M. Benitez ,  James R. Lattner ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma

    发明人： Kun Wang ,  Francisco M. Benitez ,  James R. Lattner ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma

    IPC分类号： C07C37/08

    CPC分类号： C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C2601/08 ,  C07C2601/14 ,  C07C49/403 ,  C07C49/10 ,  C07C49/395 ,  C07C49/08 ,  C07C39/04

    摘要： Disclosed is a process for producing phenol or a substituted phenol and a co-product comprising the steps of (i) contacting a first stream comprising an alkylaromatic compound with a second stream comprising an oxygen-containing gas in the presence of a first catalyst comprising a cyclic imide under conditions to convert at least a portion of said alkylaromatic compound to an alkylaromatic hydroperoxide, (ii) producing an effluent stream comprising said cyclic imide, said alkylaromatic hydroperoxide, and said alkylaromatic compound wherein said effluent stream has an alkylaromatic hydroperoxide concentration of from 10 to 40 wt %; and (iii) contacting in a second reactor at least a portion of said effluent stream with a second catalyst to convert said alkylaromatic hydroperoxide to a product stream comprising phenol and said co-product.

    摘要翻译： 公开了一种生产苯酚或取代苯酚和副产物的方法，包括以下步骤：（i）在包含含氧气体的第一催化剂的存在下，将包含烷基芳族化合物的第一物流与包含含氧气体的第二物流接触，所述第一催化剂包含 环状酰亚胺在将至少一部分所述烷基芳族化合物转化为烷基芳香族氢过氧化物的条件下，（ii）产生包含所述环状酰亚胺，所述烷基芳族氢过氧化物和所述烷基芳族化合物的流出物流，其中所述流出物流具有烷基芳香族氢过氧化物浓度 10〜40重量％ 和（iii）在第二反应器中将至少一部分所述流出物流与第二催化剂接触，以将所述烷基芳香族氢过氧化物转化成包含苯酚和所述副产物的产物流。

    Oxidation of Hydrocarbons
    16.
    发明申请
    Oxidation of Hydrocarbons 有权
    碳氢化合物的氧化

    公开(公告)号：US20100222609A1

    公开(公告)日：2010-09-02

    申请号：US12675342

    申请日：2008-10-08

    申请人： Jihad M. Dakka ,  James C. Vartuli ,  Stephen Zushma

    发明人： Jihad M. Dakka ,  James C. Vartuli ,  Stephen Zushma

    IPC分类号： C07C51/255 ,  C07C61/08 ,  C07C49/00 ,  C07C45/27 ,  C07C409/00 ,  C07C27/10 ,  C07C35/02 ,  C07C39/12

    CPC分类号： C07C409/04 ,  B01D15/00 ,  B01J31/0235 ,  C07C29/50 ,  C07C37/08 ,  C07C37/20 ,  C07C45/33 ,  C07C45/53 ,  C07C407/00 ,  C07C407/003 ,  C07C409/08 ,  C07C409/14 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/403 ,  C07C35/08 ,  C07C39/04 ,  C07C39/16 ,  C07C409/06 ,  C07C409/10

    摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with a solid sorbent to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.

    摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触： 其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; 1是0,1或2; m为1至3，R3可为R1列出的任何实体。 接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，并且用固体吸附剂处理流出物以除去至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的经处理的流出物。 然后可以回收有机相。

    Oxidation of hydrocarbons
    17.
    发明授权
    Oxidation of hydrocarbons 有权
    碳氢化合物的氧化

    公开(公告)号：US08658835B2

    公开(公告)日：2014-02-25

    申请号：US13386250

    申请日：2010-07-13

    申请人： Kun Wang ,  Jihad M. Dakka ,  Stephen Zushma

    发明人： Kun Wang ,  Jihad M. Dakka ,  Stephen Zushma

    IPC分类号： C07C45/00 ,  C07C37/08 ,  C07C407/00

    CPC分类号： C07C409/08 ,  C07C407/00 ,  C07C409/14 ,  C07C2601/14 ,  C07C409/10

    摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst and the effluent is treated with at least one solid sorbent to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.

    摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有环状酰亚胺的催化剂存在下与含氧气体接触。 接触产生包含氧化烃产物和未反应的酰亚胺催化剂的流出物，并且用至少一种固体吸附剂处理流出物以除去至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的处理流出物。 然后可以回收有机相。

    Process for producing phenol
    18.
    发明授权
    Process for producing phenol 有权
    苯酚生产工艺

    公开(公告)号：US08592634B2

    公开(公告)日：2013-11-26

    申请号：US13143975

    申请日：2010-01-25

    申请人： Kun Wang ,  Francisco M. Benitez ,  James R. Lattner ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma

    发明人： Kun Wang ,  Francisco M. Benitez ,  James R. Lattner ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma

    IPC分类号： C07C37/08

    CPC分类号： C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C2601/08 ,  C07C2601/14 ,  C07C49/403 ,  C07C49/10 ,  C07C49/395 ,  C07C49/08 ,  C07C39/04

    摘要： Disclosed is a process for producing phenol or a substituted phenol and a co-product comprising the steps of (i) contacting a first stream comprising an alkylaromatic compound with a second stream comprising an oxygen-containing gas in the presence of a first catalyst comprising a cyclic imide under conditions to convert at least a portion of said alkylaromatic compound to an alkylaromatic hydroperoxide, (ii) producing an effluent stream comprising said cyclic imide, said alkylaromatic hydroperoxide, and said alkylaromatic compound wherein said effluent stream has an alkylaromatic hydroperoxide concentration of from 10 to 40 wt %; and (iii) contacting in a second reactor at least a portion of said effluent stream with a second catalyst to convert said alkylaromatic hydroperoxide to a product stream comprising phenol and said co-product.

    摘要翻译： 公开了一种生产苯酚或取代苯酚和副产物的方法，包括以下步骤：（i）在包含含氧气体的第一催化剂的存在下，将包含烷基芳族化合物的第一物流与包含含氧气体的第二物流接触，所述第一催化剂包含 环状酰亚胺在将至少一部分所述烷基芳族化合物转化为烷基芳香族氢过氧化物的条件下，（ii）产生包含所述环状酰亚胺，所述烷基芳族氢过氧化物和所述烷基芳族化合物的流出物流，其中所述流出物流具有烷基芳香族氢过氧化物浓度 10〜40重量％ 和（iii）在第二反应器中将至少一部分所述流出物流与第二催化剂接触，以将所述烷基芳香族氢过氧化物转化成包含苯酚和所述副产物的产物流。