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公开(公告)号：US08487138B2
公开(公告)日：2013-07-16
申请号：US12601549
申请日：2008-07-11
申请人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
发明人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
IPC分类号： C07C45/00 , C07C309/00 , C07C37/08 , C07C51/16
CPC分类号： C07C409/08 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/53 , C07C51/313 , C07C407/00 , C07C407/003 , C07C409/04 , C07C409/10 , C07C2601/14 , Y02P20/52 , C07C55/14 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/14
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of formula (I) and the effluent is treated with an aqueous solution of a base to produce an aqueous phase comprising at least part of the unreacted imide catalyst of formula (I) and an organic phase comprising oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触： 其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; 1为0,1或2; m为1至3，R3可为R1列出的任何实体。 接触产生包含氧化烃产物和式（I）的未反应酰亚胺催化剂的流出物，流出物用碱的水溶液处理以产生包含至少部分式（I）的未反应的酰亚胺催化剂的水相， 和包含氧化烃产物的有机相。 然后可以回收有机相。
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公开(公告)号：US20100234589A1
公开(公告)日：2010-09-16
申请号：US12601549
申请日：2008-07-11
申请人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
发明人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
IPC分类号： C07C27/10 , C07C51/235 , C07D201/02 , C07C407/00 , C07C37/08 , C07C45/53
CPC分类号： C07C409/08 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/53 , C07C51/313 , C07C407/00 , C07C407/003 , C07C409/04 , C07C409/10 , C07C2601/14 , Y02P20/52 , C07C55/14 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/14
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of formula (I) and the effluent is treated with an aqueous solution of a base to produce an aqueous phase comprising at least part of the unreacted imide catalyst of formula (I) and an organic phase comprising oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触： 其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; 1是0,1或2; m为1至3，R3可为R1列出的任何实体。 接触产生包含氧化烃产物和式（I）的未反应酰亚胺催化剂的流出物，流出物用碱的水溶液处理以产生包含至少部分式（I）的未反应的酰亚胺催化剂的水相， 和包含氧化烃产物的有机相。 然后可以回收有机相。
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公开(公告)号：US08658839B2
公开(公告)日：2014-02-25
申请号：US12675342
申请日：2008-10-08
申请人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
发明人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
IPC分类号： C07C35/08 , C07D209/48
CPC分类号： C07C409/04 , B01D15/00 , B01J31/0235 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/33 , C07C45/53 , C07C407/00 , C07C407/003 , C07C409/08 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/06 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with a solid sorbent to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触： 其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1至3，R3可为R1列出的任何实体。 接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，并且用固体吸附剂处理流出物以除去至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的经处理的流出物。 然后可以回收有机相。
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公开(公告)号：US20100222609A1
公开(公告)日：2010-09-02
申请号：US12675342
申请日：2008-10-08
申请人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
发明人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
IPC分类号： C07C51/255 , C07C61/08 , C07C49/00 , C07C45/27 , C07C409/00 , C07C27/10 , C07C35/02 , C07C39/12
CPC分类号： C07C409/04 , B01D15/00 , B01J31/0235 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/33 , C07C45/53 , C07C407/00 , C07C407/003 , C07C409/08 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/06 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with a solid sorbent to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译： 在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触： 其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; 1是0,1或2; m为1至3，R3可为R1列出的任何实体。 接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，并且用固体吸附剂处理流出物以除去至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的经处理的流出物。 然后可以回收有机相。
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公开(公告)号：US20100217048A1
公开(公告)日：2010-08-26
申请号：US12601578
申请日：2008-07-08
IPC分类号： C07C37/08 , C07C407/00 , C07C45/53
CPC分类号： C07C409/08 , B01J23/34 , B01J29/035 , B01J35/1057 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, with oxygen in the presence of a catalyst comprising a manganese oxide molecular sieve to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I).The hydroperoxide of formula (II) may then be converted to a phenol and an aldehyde or a ketone of the general formula R1COCH2R2 (III), in which R1 and R2 have the same meaning as in formula (I). In the case where the ketone is cyclohexanone, this may then be dehydrogenated to produce further phenol.
摘要翻译： 在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成具有 所述环状基团任选被取代，并且R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基与氧在含有氧化锰分子筛的催化剂存在下反应 以产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义。 然后将式（II）的氢过氧化物转化为通式为R 1 COCH 2 R 2（III）的酚和醛或酮，其中R 1和R 2具有与式（I）中相同的含义。 在酮是环己酮的情况下，然后可以将其脱氢以产生另外的苯酚。
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6.发明授权Multi-component molecular sieve catalyst compositions and their use in aromatics reactions 有权多组分分子筛催化剂组合物及其在芳烃反应中的应用公开(公告)号：US07276638B2
公开(公告)日：2007-10-02
申请号：US11392804
申请日：2006-03-29
申请人： Jihad M. Dakka , James C. Vartuli , John S. Buchanan , Jose G. Santiesteban , Doron Levin , Lorenzo C. DeCaul
发明人： Jihad M. Dakka , James C. Vartuli , John S. Buchanan , Jose G. Santiesteban , Doron Levin , Lorenzo C. DeCaul
IPC分类号： C07C2/66
CPC分类号： B01J37/0009 , B01J21/06 , B01J21/066 , B01J23/10 , B01J29/06 , B01J29/40 , B01J29/82 , B01J35/0006 , B01J35/002 , B01J37/03 , B01J2229/20 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2/864 , C07C2521/06 , C07C2523/10 , Y02P20/52 , C07C15/08
摘要： The invention relates to a process for producing alkylated aromatic hydrocarbons, preferably with an oxygen or sulfur containing alkylating agent, in the presence of a multi-component molecular sieve catalyst composition that includes a molecular sieve and an active metal oxide. The invention is also directed to methods of making and formulating the multi-component molecular sieve catalyst composition useful in producing alkylated aromatics.
摘要翻译： 本发明涉及在包含分子筛和活性金属氧化物的多组分分子筛催化剂组合物的存在下，优选用含氧或含硫烷基化剂制备烷基化芳烃的方法。 本发明还涉及制备和配制用于制备烷基化芳族化合物的多组分分子筛催化剂组合物的方法。
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7.发明申请公开(公告)号：US20100324326A1
公开(公告)日：2010-12-23
申请号：US12869275
申请日：2010-08-26
IPC分类号： C07C253/18 , C07C51/25 , C07C51/215 , C07C253/00
CPC分类号： B01J35/002 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07D301/08 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula MoaVbNbcTedSbeOf wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 1.0, and f is dependent upon the oxidation state of the other elements, the catalyst further characterized by having at least two crystal phases, the first crystal phase being an orthorhombic M1 phase and the second crystal phase being a pseudo-hexagonal M2 phase, the orthorhombic M1 phase present in an amount between greater than 60 weight percent to less than 90 weight percent. The catalysts disclosed herein exhibit a chemisorption of NH3 of less than about 0.2 mmole per gram of metal oxide.
摘要翻译： 用于氧化烷烃，烯烃或其混合物的催化剂。 催化剂包括具有式MoaVbNbcTedSbeOf的混合金属氧化物，其中当a = 1时，b = 0.01至1.0，c = 0.01至1.0，d = 0.01至1.0，e = 0.01至1.0，f取决于氧化 其他元素的状态，催化剂的特征还在于具有至少两个结晶相，第一晶相是正交的M 1相，第二晶相是拟六方晶系的M 2相，正交晶相M1相位存在于较大的 超过60重量％至小于90重量％。 本文公开的催化剂表现出每克金属氧化物小于约0.2毫摩尔的NH 3的化学吸附。
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公开(公告)号：US07985883B2
公开(公告)日：2011-07-26
申请号：US12601578
申请日：2008-07-08
IPC分类号： C07C45/53 , C07C37/08 , C07C407/00
CPC分类号： C07C409/08 , B01J23/34 , B01J29/035 , B01J35/1057 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, with oxygen in the presence of a catalyst comprising a manganese oxide molecular sieve to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I). The hydroperoxide of formula (II) may then be converted to a phenol and an aldehyde or a ketone of the general formula R1COCH2R2 (III), in which R1 and R2 have the same meaning as in formula (I). In the case where the ketone is cyclohexanone, this may then be dehydrogenated to produce further phenol.
摘要翻译： 在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成具有 所述环状基团任选被取代，并且R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基与氧在含氧化锰分子筛 以产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义。 然后将式（II）的氢过氧化物转化为通式为R 1 COCH 2 R 2（III）的酚和醛或酮，其中R 1和R 2具有与式（I）中相同的含义。 在酮是环己酮的情况下，然后可以将其脱氢以产生另外的苯酚。
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9.发明申请公开(公告)号：US20080161602A1
公开(公告)日：2008-07-03
申请号：US11998778
申请日：2007-11-30
IPC分类号： C07C51/215 , C01G39/02
CPC分类号： B01J35/002 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07D301/08 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula MoaVbNbcTedSbeOf wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 1.0, and f is dependent upon the oxidation state of the other elements, the catalyst further characterized by having at least two crystal phases, the first crystal phase being an orthorhombic M1 phase and the second crystal phase being a pseudo-hexagonal M2 phase, the orthorhombic M1 phase present in an amount between greater than 60 weight percent to less than 90 weight percent. The catalysts disclosed herein exhibit a chemisorption of NH3 of less than about 0.2 mmole per gram of metal oxide.
摘要翻译： 用于氧化烷烃，烯烃或其混合物的催化剂。 催化剂包括具有以下分子式的混合金属氧化物：其中R a，R b，C b， 其中，当a = 1时，b = 0.01〜1.0，c = 0.01〜1.0，d = 0.01〜1.0，e = 0.01〜1.0，f为依赖性 在其它元素的氧化态下，催化剂的特征还在于具有至少两个结晶相，第一晶相为正交晶相M1相，第二晶相为伪六边形M2相，斜方晶相M1存在于 大于60重量％至小于90重量％。 本文公开的催化剂表现出每克金属氧化物小于约0.2毫摩尔的NH 3的化学吸附。
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10.发明授权公开(公告)号：US07807601B2
公开(公告)日：2010-10-05
申请号：US11998778
申请日：2007-11-30
CPC分类号： B01J35/002 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07D301/08 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula MoaVbNbcTedSbeOf wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 1.0, and f is dependent upon the oxidation state of the other elements, the catalyst further characterized by having at least two crystal phases, the first crystal phase being an orthorhombic M1 phase and the second crystal phase being a pseudo-hexagonal M2 phase, the orthorhombic M1 phase present in an amount between greater than 60 weight percent to less than 90 weight percent. The catalysts disclosed herein exhibit a chemisorption of NH3 of less than about 0.2 mmole per gram of metal oxide.
摘要翻译： 用于氧化烷烃，烯烃或其混合物的催化剂。 催化剂包括具有式MoaVbNbcTedSbeOf的混合金属氧化物，其中当a = 1时，b = 0.01至1.0，c = 0.01至1.0，d = 0.01至1.0，e = 0.01至1.0，f取决于氧化 其他元素的状态，催化剂的特征还在于具有至少两个结晶相，第一晶相是正交的M 1相，第二晶相是拟六方晶系的M 2相，正交晶相M1相位存在于较大的 超过60重量％至小于90重量％。 本文公开的催化剂表现出每克金属氧化物小于约0.2毫摩尔的NH 3的化学吸附。
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