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    Process for polymerizing .alpha.-olefins containing at least 3 carbon atoms and catalyst therefor
    11.
    发明授权
    Process for polymerizing .alpha.-olefins containing at least 3 carbon atoms and catalyst therefor 失效
    用于聚合含有至少3个碳原子的α-烯烃和其催化剂的方法

    公开(公告)号：US4221894A

    公开(公告)日：1980-09-09

    申请号：US951973

    申请日：1978-10-16

    申请人： Yoshihisa Ushida ,  Kiyoshi Odawara ,  Norio Kashiwa ,  Akinori Toyota ,  Syuji Minami

    发明人： Yoshihisa Ushida ,  Kiyoshi Odawara ,  Norio Kashiwa ,  Akinori Toyota ,  Syuji Minami

    IPC分类号： C08F4/02 ,  C08F4/64 ,  C08F10/00 ,  C08F10/06

    CPC分类号： C08F10/00 ,  C08F4/022 ,  Y10S526/906

    摘要： A process for polymerizing or copolymerizing .alpha.-olefins having at least 3 carbon atoms or copolymerizing .alpha.-olefins having at least 3 carbon atoms with not more than 50 mole % of ethylene in the presence of a catalyst composed of an organometallic compound of a metal of Groups I to III of the periodic table and a titanium catalyst component supported on a halogen-containing magnesium compound, said titanium catalyst component being a solid reaction product obtained by treating (i) a mechanically copulverized product of a halogen-containing compound and an organic acid ester with (ii) an organo-metallic compound of a metal of Groups I to III of the periodic table, and then reacting the resulting solid product with (iii) a titanium compound in the absence of mechanical pulverization.

    摘要翻译： 在具有至少3个碳原子的α-烯烃或具有至少3个碳原子的α-烯烃与不超过50摩尔％的乙烯的聚合或共聚的催化剂的存在下，在由金属的有机金属化合物 元素周期表的I至III族和负载在含卤素的镁化合物上的钛催化剂组分，所述钛催化剂组分是通过处理（i）含卤素化合物和有机物的机械共缩合产物得到的固体反应产物 酸酯与（ⅱ）元素周期表第I至III族金属的有机金属化合物反应，然后在没有机械粉碎的情况下使得到的固体产物与（ⅲ）钛化合物反应。

    Process for preparing highly stereoregular polyolefins and catalyst used therefor
    12.
    发明授权
    Process for preparing highly stereoregular polyolefins and catalyst used therefor 失效
    制备高立体规则聚烯烃的方法和用于其的催化剂

    公开(公告)号：US4157435A

    公开(公告)日：1979-06-05

    申请号：US710658

    申请日：1976-08-02

    申请人： Akinori Toyota ,  Norio Kashiwa ,  Syuji Minami

    发明人： Akinori Toyota ,  Norio Kashiwa ,  Syuji Minami

    IPC分类号： C08F4/02 ,  C08F10/00 ,  C08F10/06

    CPC分类号： C08F4/022 ,  C08F10/00 ,  Y10S526/904 ,  Y10S526/906

    摘要： A process for preparing highly stereoregular polyolefins in the presence of a catalyst comprising (A) a titanium-containing solid catalyst component composed of an organic complex derived from(i) a magnesium halide(ii) an organopolysiloxane selected from the group consisting of compounds of the formulaQ(Q.sub.2 SiO).sub.n SiQ.sub.3, (Q.sub.2 SiO).sub.n and X(Q.sub.2 SiO).sub.n SiQ.sub.2 X,(iii) an organic carboxylic acid ester, and(iv) a titanium compound of the formulaTi(OR).sub.l X.sub.4-l, and(B) an organoaluminum catalyst component of the formulaR'mAl(OR').sub.3-m,said organic complex being derived by bringing the component (i) into contact with a combination of the components (ii) and (iii) or a combination of the components (ii), (iii) and (iv) under mechanical pulverisation conditions and then treating the resulting pulverized composition with the component (iv) in the absence of mechanical pulverization.

    摘要翻译： 一种在催化剂存在下制备高立体规则聚烯烃的方法，包括（A）含钛固体催化剂组分，其由衍生自（I）选自由化合物组成的组中选择的一种有机金属氧化物（II）的有机络合物组成的含钛固体催化剂组分 式（QSiO）nSiQ3，（Q2SiO）n和X（Q2SiO）nSiQ2X，（iii）有机羧酸酯和（Ⅳ）式（Ⅺ）Ⅺ4-Ⅳ的钛化合物和（B） 一种式R'mAl（OR'）3-m的有机铝催化剂组分，通过使组分（I）与组分（II）和（III）的组合接触得到的有机复合物或其组合 组件（II），（III）和（IV）在机械搅拌条件下，然后在组织（IV）的机械搅拌条件下处理结晶粉化组合物。

    Catalyst for polymerizing alpha-olefins and process for polymerization
    13.
    发明授权
    Catalyst for polymerizing alpha-olefins and process for polymerization 失效
    用于聚合α-烯烃的催化剂和聚合方法

    公开(公告)号：US5654248A

    公开(公告)日：1997-08-05

    申请号：US433545

    申请日：1995-05-02

    申请人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

    发明人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

    IPC分类号： C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/10 ,  C08F110/02 ,  B01J31/00 ,  B01J37/00

    CPC分类号： C08F10/10 ,  C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925

    摘要： A prepolymerized solid catalyst for gaseous phase or slurry polymerization of alpha olefins is disclosed. The catalyst comprises a porous carrier having a particle size of 20 to 200 microns onto which has been deposited an aluminoxane and a transition metal compound having at least one cycloalkadienyl group, the transition metal being from group 4 of the Periodic Table. The transition metal is present in an amount of 0.003 to 3 mmol/gm of carrier, and the aluminum to transition metal atomic ratio is from 15 to 1000. This catalyst is then prepolymerized with 0.2 to 30 gm of an alpha olefin per gram of catalyst to form the final prepolymerized solid catalyst having an intrinsic viscosity of 0.2 to 20 dl/gm as measured in decalin at 135 deg C.

    摘要翻译： 公开了一种用于α-烯烃的气相或淤浆聚合的预聚合固体催化剂。 催化剂包括粒径为20-200微米的多孔载体，其上沉积有铝氧烷和具有至少一个环二烯基的过渡金属化合物，过渡金属来自元素周期表第4族。 过渡金属的存在量为0.003至3mmol / gm的载体，铝与过渡金属的原子比为15至1000.然后将该催化剂与每克催化剂0.2至30gm的α-烯烃预聚合 以形成在135℃萘烷中测得的特性粘度为0.2-20dl / gm的最终预聚固体催化剂

    Process for polymerizing olefins and catalyst for polymerizing olefins
    14.
    发明授权
    Process for polymerizing olefins and catalyst for polymerizing olefins 失效
    烯烃聚合方法和烯烃聚合催化剂

    公开(公告)号：US5652303A

    公开(公告)日：1997-07-29

    申请号：US567876

    申请日：1995-12-06

    申请人： Naoshi Ishimaru ,  Mamoru Kioka ,  Akinori Toyota

    发明人： Naoshi Ishimaru ,  Mamoru Kioka ,  Akinori Toyota

    IPC分类号： C08F4/646 ,  C08F4/654 ,  C08F10/00 ,  C08F297/08 ,  C08F4/651

    CPC分类号： C08F297/08 ,  C08F10/00 ,  Y10S526/904

    摘要： A catalyst for polymerization of an olefin, said catalyst being formed from[A] a solid titanium catalyst component comprising magnesium, titanium, halogen and an electron donor as essential ingredients,[B] an organoaluminum compound catalyst component, and[C] an electron donor catalyst component comprising at least two electron donors including an electron donor (1) and an electron donor (2), the MFR (a) of homopolypropylene obtained by using the electron donor (1) together with the solid titanium catalyst component [A] and the organoaluminum compound catalyst component [B] has the following relation to the MFR (b) of homopolypropylene obtained by using the electron donor (2) under the same polymerization conditions as in the case of using the electron donor (1)log [MFR (b)/MFR (a)].gtoreq.1.5.This catalyst can give an olefin polymer having a broad molecular weight. Also provided is a process for polymerizing or copolymerizing an olefin in the presence of the above catalyst.

    摘要翻译： 用于烯烃聚合的催化剂，所述催化剂由[A]包含镁，钛，卤素和电子给体的固体钛催化剂组分作为必要成分[B]有机铝化合物催化剂组分和[C] 供体催化剂组分，其包含至少两个包括电子给体（1）和电子给体（2）的电子给体，通过使用电子给体（1）与固体钛催化剂组分[A]获得的均聚丙烯的MFR（a） 有机铝化合物催化剂组分[B]与使用电子给体（2）在与使用电子给体（1）的情况相同的聚合条件下获得的均聚丙烯的MFR（b）与[MFR （b）/ MFR（a）]> = 1.5。该催化剂可以得到具有宽分子量的烯烃聚合物。 还提供了在上述催化剂存在下使烯烃聚合或共聚的方法。

    Modified polyolefin particles and process for preparation thereof
    16.
    发明授权
    Modified polyolefin particles and process for preparation thereof 失效
    改性聚烯烃颗粒及其制备方法

    公开(公告)号：US5523358A

    公开(公告)日：1996-06-04

    申请号：US235419

    申请日：1994-04-22

    申请人： Toshiyuki Hirose ,  Hajime Inagaki ,  Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa

    发明人： Toshiyuki Hirose ,  Hajime Inagaki ,  Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa

    IPC分类号： C08F255/00 ,  C08J3/09 ,  C08J3/11 ,  C08L23/26

    CPC分类号： C08F255/00

    摘要： A process for preparation of modified polyolefin particles which comprises contacting and reacting(A) 100 wt. parts of polyolefin particles with(B) 0.01 to 50 wt. parts of at least one ethylenic unsaturated compound selected from the group consisting of carboxyl group-containing ethylenic unsaturated compounds or their carboxylic anhydrides or their carboxylic acid derivatives, hydroxyl group-containing ethylenic unsaturated compounds, amino-group-containing ethylenic unsaturated compounds, and glycidyl group-containing ethylenic unsaturated compounds,in the presence of(C) more than 10 wt. parts to not more than 50 wt. parts of a medium of a liquid state at ordinary temperature whose solubility in water at 20.degree. C. is 0.5 wt. % or less and which is capable of swelling the polyolefin, and(D) 0.01 to 10 wt. parts of a radical initiator; andmodified polyolefin particles prepared by the aforesaid process.

    摘要翻译： 一种制备改性聚烯烃颗粒的方法，其包括使（A）100重量％ （B）0.01〜50wt。 至少一种选自含羧基的烯属不饱和化合物或其羧酸酐或其羧酸衍生物，含羟基的烯属不饱和化合物，含氨基的烯属不饱和化合物和缩水甘油基中的至少一种烯属不饱和化合物 在（C）大于10重量％存在下，含有基团的烯属不饱和化合物。 部分至不超过50wt。 常温下液态介质的一部分在20℃下在水中的溶解度为0.5wt。 ％以下，能够使聚烯烃溶胀，（D）0.01〜10重量％ 部分自由基引发剂; 和通过上述方法制备的改性聚烯烃颗粒。

    Process for polymerizing olefins and polymerization catalyst therefor
    18.
    发明授权
    Process for polymerizing olefins and polymerization catalyst therefor 失效
    烯烃聚合方法和聚合催化剂

    公开(公告)号：US5438110A

    公开(公告)日：1995-08-01

    申请号：US328568

    申请日：1994-10-24

    申请人： Naoshi Ishimaru ,  Mamoru Kioka ,  Akinori Toyota

    发明人： Naoshi Ishimaru ,  Mamoru Kioka ,  Akinori Toyota

    IPC分类号： C08F10/00 ,  C08F297/08 ,  C08F4/654

    CPC分类号： C08F297/08 ,  C08F10/00 ,  Y10S526/904 ,  Y10S526/916

    摘要： An olefin polymerization catalyst formed from (A) a solid titanium catalyst component containing magnesium, titanium and halogen as essential ingredients, (B) an organoaluminum compound, and (C) an organosilicon compound containing a cyclopentyl group, a cyclopentenyl group, a cyclopentadienyl group or a derivative derived from any of these groups.A polymerization process which comprises polymerizing or copolymerizing olefins in the presence of the olefin polymerization catalyst to form a homopolyolefin having high stereoregularity or a copolyolefin having a narrow composition distribution.

    摘要翻译： 由（A）含有镁，钛和卤素作为必要成分的固体钛催化剂组分形成的烯烃聚合催化剂，（B）有机铝化合物和（C）含有环戊基，环戊烯基，环戊二烯基的有机硅化合物 或衍生自任何这些组的衍生物。 一种聚合方法，其包括在烯烃聚合催化剂存在下聚合或共聚烯烃以形成具有高立构规整性的均聚烯烃或具有窄组成分布的共聚烯烃。

    Injection-molded article having high-quality appearance
    19.
    发明授权
    Injection-molded article having high-quality appearance 失效
    具有高品质外观的注塑制品

    公开(公告)号：US5403647A

    公开(公告)日：1995-04-04

    申请号：US983755

    申请日：1992-12-01

    申请人： Akimasa Kaneishi ,  Akinori Toyota

    发明人： Akimasa Kaneishi ,  Akinori Toyota

    IPC分类号： B29C45/17 ,  B32B3/00

    CPC分类号： B29C45/1704 ,  Y10T428/24479 ,  Y10T428/2457 ,  Y10T428/24744 ,  Y10T428/24942 ,  Y10T428/2495

    摘要： An injection-molded article of a thermoplastic resin having a base body defining an outer shape of the injection-molded article, a thick-wall portion rising from the base body, and a foot portion formed on the base body and at a foot of the thick-wall portion, the foot portion rising from the base portion, having a thickness which gradually increases toward the thick-wall portion, and having a (maximum thickness of the foot portion)/(width extending from the thick-wall portion to an end of the foot portion) ratio of 1/40 to 1/2, at least the thick-wall portion having a hollow portion.

    摘要翻译： 一种热塑性树脂的注塑制品，具有限定注塑制品的外形的基体，从基体上升的厚壁部分和形成在基体上的脚部， 厚壁部，从基部突出的脚部，具有朝向厚壁部逐渐增大的厚度，并且具有（从脚部的最大厚度）/（从厚壁部向宽度部延伸的宽度 脚部的末端）比率为1/40至1/2，至少厚壁部分具有中空部分。